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ISBN 978604821338-1
ABSTRACT
In this study, field observation was conducted to identify waterquality variation characteristics in a tidal urban river
network in Osaka, Japan,and threedimensional hydrodynamic and water quality simulations were conducted to
understand the variability characteristics of current, salinity, water temperature, water quality, and materials transport in
the estuarine basin.The observation results showed that water quality variations in the estuary were strongly affected by
the seawater intrusion process and the mixingof water masses from various sources.The simulations adeptly reproduced
time variability of tidal elevation and water quality distributions although further improvements are necessaryto
reproduce the vertical mixing process around the salt-water interface in the downstream area.The simulation results
showed that biochemical processes and watersediment interactions exerted during outflow to the coast had a minor
influence on the waterquality variations in this estuary. Tracer experiments indicated thatthe contribution of the Neya
River water, which is highly polluted by human sewage and industrial effluent, to the water quality degradationwas
almost the same around the mouths of the three downstream rivers.
1
Yodo River
5 km
20 km Osaka City Neya River
Rivers Basin Basin
Yodo River
Basin
Aji River
Okawa River
Osaka
Bay Yamato River St.4 St.6
Basin
St.A St.5
Neya River
St.1 St.B
St.2
Shirinashi River
Yamato River
The Pacific Ocean Osaka Bay
Figure 1. Study area. Yellow circles, orange diamond shapes, blue squares, and red triangles indicate the following field survey sites,
model validation sites, treated sewage outlets from treatment plants, and constantwater quality monitoring system sites (under the
management of the Ministry of Land, Infrastructure, Transport and Tourism in Japan), respectively. Red solid lines and purple dotted
lines indicate upstream and downstream boundaries, respectively.
DO (mg/L)
Yodo River, the biggest river in Osaka. In the NeyaRiver 20 4
Basin, there are 30 large and small rivers and a headrace 15 3
channel connecting to the Yodo River. All of thesemeetat
St.5,as illustrated in Figure 1. Near St.5, the Neya River 10 2
meetsthe Okawa River, which derives from the Yodo 5 1
River. Thereafter, the river divides into three rivers (the 0 0
Aji, Shirinashi, and Kizu rivers).Finally,all rivers flow into 1950 1960 1970 1980 1990 2000 2010 2020
a harbor located at the head of Osaka Bay.This is an
alluvial basin containing sediments transported from the Figure 2.Changes of water quality in the Kizu River. The
Yodo and Yamato rivers. Since river slopesare 1/3000 to original data were measured by Osaka Prefecture on an annual
1/12500 in the middle and lower basin and 1/1000 in the basis before 1959 and a monthly basis after 1968. BOD and DO
upper basin, most of the area in the river waters is affected concentrations indicate annual mean and minimum values,
by the sea (Irie et al., 2009). respectively.
2
pattern; almostthe entire study area is located in an significantly, as in other estuaries.
estuarine basin; large amounts of anthropogenic pollutant
Figure 4 shows the time series of the TN and TP
loadsflow into the upper stream area (i.e., the Neya River
concentrations in the surface and bottom layers at St.A
Basin); relativelynon-polluted river water inflows from the
and St.B. In the bottom layer at St.A, the concentrations of
Okawa River in the middle area; and the topography
both TN and TP indicated higher levels in the ebb tide
around the river mouths is extremely complex.
period, when freshwater constituted the layer, and
decreasing levels in the flood tide period, when sea water
3. FIELD SURVEY
intruded into the bottom layer. On the other hand, in the
3.1 Method surface layer at St.A, major changes in water quality were
observed from 11/4 22:00 to 11/5 5:00, although fresh
To obtain the data used for model validation and to clarify
variationcharacteristics of water quality in the estuarine
river, a field survey was conducted during a continuous
tidal period from November 4 to November5, 2013. Using St. A
a multisensor profiler (AAQ-1183, JFE ADVANTEC),
vertical profiles of salinity, temperature, and
turbiditywere measured, and water samples were
collected approximately every hour and a half at St.Aand
St.B(see Figure 1). The water qualities (NH4N, NO2N,
NO3N, DIN, DON, TDN, PN, TN, PO4P, DOP, TDP,
PP, TP, SiO2Si, DOC, POC, TOC, COD) of the samples
were analyzed using the autoanalyzer AACS V (BLTEC)
and TOC-V (SHIMAZU). In addition, Glass fiber filter
paper with 0.6micrometer trapping efficiency (GS-25, St. B
ADVANTEC) was used for analyses of SS and dissolved
matters.
3.2 Water quality variations
Figure 3 showsthe observed time series of the vertical
profiles of salinity at St.A and St.B. At both St.A and St.B,
fresh water was distributed vertically at the ebb tide
period, whereas a distinct saltwater wedge was observed Figure 3.Time series of the salinity profiles observed at St. A and
from the flood tide to hightide period.The graph of the St. B.
time series atSt.A indicatesthat density fields vary
0.6
3.0 0 0
0.4
2.0 -50 -50
4.0 50 50
T-P (mg/L)
T-N (mg/L)
0.6
3.0 0 0
0.4
2.0 -50 -50
Figure 4.Time series of observed concentrations of TN and TP in the surface and bottom layers at St.A and St.B, and the tide
elevation at the Osaka Port, as measured by the Japan Meteorological Agency.
3
water occupied the surface layer during this period. This geometry and its advection and dispersion fields was
is probably because the OkawaRiver waterflowed into the obtained from ECOMSED. The model structure is shown
site by around11/5 0:00.TheNeyaRiver water inflowed in Figure 5. The model is based upon the principle of mass
thereafter. After around 11/5 5:00, the concentrationsof T conservation and describes interactions among model
N and TP decreased because of vertical mixing of the variables thorough physical and biochemical processes in
bottom intruded seawater with the surface layer.
terms of O, C, N, P, and Si. The waterquality model has 23
These observation results indicate that the water quality state variables, including three phytoplanktons (winter
variationsat this estuarine site (St.A)are strongly affected diatom, summer diatom, and summer nondiatom),
by the seawater intrusion and the mixing of the water nutrients (NH4N, [NO2+NO3]N, PO4P, SiO2Si),
masses from various sources. The graphs of data from St.B particulate and dissolved organic nitrogen, phosphorus,
suggest that the same mechanism applies at St.B. and carbon, algal exudate dissolved organic carbon,
biogenic silica, dissolved oxygen, and oxygen demand
4. NUMERICAL SIMULATION equivalents (ODU). The organic matter is classified as
4.1 Model overview either a refractory component or a labile component.
Current and density fields were simulated by a quasi-3D The sediment flux model consists of two layers: a thin and
hydrodynamic model, ECOMSED, which was developed aerobic upper layer and a permanently anaerobic lower
by HydroQual Inc.(2002) and based on the Princeton layer. The model represents the depositional fluxes of
Ocean Model. This model is a quasi-3D model with a free particulate matter from the water column to the benthic
surface and uses a mode splitting technique that solves the bed, the early diagenesis fluxes of the organic matter in
volume transport separately from the vertical velocity the bed, and oxygen consumption and nutrient release
shear. The governing equations are the continuity fluxes between the bed and overlying water. The organic
equation, conservation of momentum in horizontal and matter in sediment is split into three fractions with
vertical directions, diffusion equations of salinity and different decay rates, known as the G3 model.
water temperature, and state equation of density. 4.2 Calculation conditions
Hydrostatic and Boussinesq assumptions are introduced.
The horizontal eddy viscosity and diffusivity coefficients The analytical period was from October 14 to November
are parameterized using a Smagorinskyscheme (1963). In 14, 2009. The model was spun-up for the previous 14 days
addition, vertical eddy viscosity and diffusivity with initial conditions of no motion with typical water
coefficients are estimated based on a 21/2 order temperature and salinity distributions in November. The
turbulence closure scheme developed by Mellor and model has 136 104 horizontal grids in the curvilinear
Yamada (1982). orthogonal coordinate system with 50400 meters
resolution and 20 vertical layers in the -coordinate
Water and benthic qualities were simulated by RCA system (equal partitioning).
(RowColumn AESOP). RCA was also developed by
HydroQual Inc.(2004) and information concerning model The locations of the open boundary are shown in Figure 1.
In the model, barotropic and baroclinic conditions in the
ODU
Figure 5.Model variables and biochemical processes computed in a water-benthic quality model.
4
300
St. 1 simulation observation
250
200
150
100
50
0
15-Oct 20-Oct 25-Oct 30-Oct 4-Nov 9-Nov 14-Nov
300
St. 5
250
water level (cm)
200
150
100
50
0
15-Oct 20-Oct 25-Oct 30-Oct 4-Nov 9-Nov 14-Nov
5
Figure 7 shows calculatedvariations of vertical vertical profiles of salinity and water temperature
distributions of salinityat St.A and St.B. Comparison with measured off the coast of the port area were applied for
the observation results shown in Figure 3 indicates that the models open boundary condition.
the model reproduces the seawater intrusion process from
Figure 9 illustrates a comparison of the water qualities in
the rising tide to the hightide period. However,
the surface layer of the observation and simulation results.
simulated saline water in the bottom layer at St.A remains
Note that the simulated values of COD were estimated by
from the ebb tide to the lowtide period, in contrast to
the relationship of TOC and COD obtained by
what was observed. Figure 8 shows simulated vertical
observations, because the waterquality model includednot
crosssectional distribution of the currents and density
COD but carbon as an item of organic matter. There isa
averaged over 15 days at St.1, St.A, and St.4. This figure
small difference between the observed and simulated
shows a model of a typical distribution pattern in
results of COD at St.1 and TN at St.3 and St.4. However,
estuaries,which is a pattern of fresh water plume in the
with allowance for the low frequency of the observations
upper layer and saline intrusion in the lower layer. There
times, the model would appear to have an acceptable
was a clear density current near St.A. Although it seemed
reproducibility of the waterquality structures in the study
that strong vertical mixing occurs at the density interface,
area.
the numerical model did not exactly reproduce the vertical
mixing judging from the comparison of the results
5. INFLUENCEON WATER QUALITY OF
illustrated in Figure 3 and Figure 7. This suggests that
BIOCHEMICAL PROCESSESDURING
there is a need for further improvements in the method of
OUTFLOW TO COAST
evaluating bottom roughness and aneed for a higher-level
turbulent model.Another possible explanation forthe lack 5.1 Analysis overview
of agreement between the simulated boundary location of
To propose an effective plan for water quality
density stratification and the observed result is that the
improvement, elucidatingwater pollution mechanisms in
the water is important. Water quality variation in the
St.1 St.A St.4 downstream area of an urban tidal river network is mainly
subjected to two processes: physical processes, such as
advection diffusion and mixing of the water masses
obtained from various sources, and biochemical processes
during outflow to the coast, such as phytoplankton
photosynthesis, microbial actions, and watersediment
interactions. It is important to clarify the dominant
impacts on water quality variation in order to correctly
predictthe effectiveness of waterquality improvement
measures. For example, if mixing of the water masses
from various sources has a dominant impact on
waterquality variation in the lower area,the improvement
Figure 8.Simulated longitudinal distribution of the mean of the water quality in the upper stream may produce a
currents and densities (sigma T) for 15 days (November 115) significant effect on that in the lower area. However, if the
along St.1, St.A, and St.4. biochemical processes and sediment influences are more
than negligible, other plans, such as benthic-quality
amelioration and dredging,also may be required.
6
5.0 Neya River water Oh River water Treated water
100%
4.0
80%
composition ratio
TOC (mg/L)
3.0
60%
2.0
40%
1.0
20%
0.0
1-Nov 3-Nov 5-Nov 7-Nov 9-Nov 11-Nov 13-Nov 15-Nov 0%
Aji River Shirinashi River Kizu River
12 8.0
Simulation Observation
10
6.0
COD (mg/L)
8
DO (mg/L)
6 4.0
4
2.0
2
0 0.0
St.1 St.2 St.3 St.4 St.5 St.1 St.2 St.3 St.4 St.5
8.0 0.4
6.0 0.3
T-N (mg/L)
T-P (mg/L)
4.0 0.2
2.0 0.1
0.0 0.0
St.1 St.2 St.3 St.4 St.5 St.1 St.2 St.3 St.4 St.5
Figure 9. Comparisons of the water qualities in the surface layer between the simulation and observation results. The simulated values
indicate the 15days average from November 1 to 15. The observed values indicate the average of the observation data obtained in
November 2009, November 2010, and November 2011.
7
As shown in the previous section, the analysis indicated ACKNOWLEDGMENTS
that the biochemical processes during outflow to the coast
We would like to express our sincere appreciation to the
had less influence on the waterquality variation around
staff of Osaka Prefecture and Osaka City for their help.
the river mouths, with the exception of DO. To estimate
This research was supported in part by a grant from the
the contributions of the fresh water from the three origins
Obayashi Foundation.
(the Neya River, the Okawa River, and the treatment
water inflowing directly to the river) to the water quality
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River mouth
Figure 11. In all rivers, the proportion of Neya River water
COD 3.5 4.4 4.8
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T-N 1.5 2.8 3.4
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T-P 0.11 0.18 0.17
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