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Return of metal to its low energy oxide form in which it originally existed as an ore with
complete loss of metallic properties.
ENERGY ENERGY
STABLE IN OUT
UNSTABLE STABLE
The rust on iron does not form by the direct action of oxygen on iron. It forms by an electrochemical
process in which Fe is oxidized to form hydrated ferric oxide Fe2O3.H2O in one region of the metal
surface and oxygen is reduced in another region. The iron surface and droplet of water on the
surface form a tiny galvanic cell. The different regions of metal surface acts as anode and cathode
and the aqueous phase acts as an electrolyte. In this galvanic cell Fe is oxidized to Fe2+ in the
region called anode region and Oxygen is reduced near the edge of the droplet of another region
called cathode region.
September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 14
CORROSION BASICS
Component of Corrosion Cell :
Anode:
The electrode of an electrochemical cell at which oxidation occurs. Electrons flow away from the
anode in the external circuit.
Cathode:
The electrode of an electrochemical cell at which reduction is the principal reaction. Electrons flow
toward the cathode in the external circuit
Electrolyte:
A chemical substance containing ions in an electric field
CATHODE Cu Fe ANODE
+ ve -ve
CATHODE Cu Fe ANODE
+ ve -ve
CATHODE Fe ANODE
Cu
+ ve -ve
-
+ OH
H
+
H
-
OH
ELECTROLYTE
September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 18
CORROSION BASICS
Electro-chemical (Corrosion) Cell :
Icorr
CONDUCTOR
CATHODE Fe ANODE
Cu
+ ve -ve
e-
-
+ OH
H
+
H Fe+
-
OH
ELECTROLYTE
September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 19
CORROSION BASICS
Electro-chemical (Corrosion) Cell :
+ve to ve - DIRECTION OF CURRENT FLOW
Icorr
CONDUCTOR
CATHODE Cu Fe ANODE
+ ve -ve
e-
-
+ OH
H
+
H Fe+
-
OH
ELECTROLYTE
September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 20
CORROSION BASICS
Electro-chemical (Corrosion) Cell :
+ve to ve - DIRECTION OF CURRENT FLOW
Icorr
CONDUCTOR
CATHODE Cu Fe ANODE
+ ve -ve
e-
+ -
H+
H OH
+
H Fe+
- -
OH OH
ELECTROLYTE
September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 21
CORROSION BASICS
Electro-chemical (Corrosion) Cell :
+ve to ve - DIRECTION OF CURRENT FLOW
Icorr
CONDUCTOR
CATHODE Fe ANODE
e-
Cu
+ ve -ve
e-
+ -
H+
H OH
+
H Fe+
Fe+
- -
OH OH
ELECTROLYTE
September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 22
CORROSION BASICS
Electro-chemical (Corrosion) Cell :
+ve to ve - DIRECTION OF CURRENT FLOW
Icorr
CONDUCTOR
CATHODE Fe ANODE
e-
Cu
e-
+ ve -ve
e-
+ -
H+
H OH
+
H Fe+ Fe+
Fe+
- -
OH OH
ELECTROLYTE
September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 23
CORROSION BASICS
Electro-chemical (Corrosion) Cell :
+ve to ve - DIRECTION OF CURRENT FLOW
Icorr
CONDUCTOR
CATHODE Fe ANODE
e-
Cu
e-
e- H+
+ -
H OH
+
H Fe+ Fe+
Fe+
- -
OH OH
ELECTROLYTE
September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 24
CORROSION BASICS
SOIL ( ELECTROLYTE ) Typical Corrosion Cell :
Ia
e-
- 0.4 V Ec
Ia O2+2H2O+4e- 4OH-
Fe3+ +e- Fe2+
e-
- 0.4 V Ec
Ia O2+2H2O+4e- 4OH-
Fe3+ +e- Fe2+
e-
V Ea - Ec
- 0.45 V Ec Ia = R= R
DESIGN
MATERIAL SELECTION
ENVIRONMENT CONTROL
BARRIER COATINGS
CP (CATHODIC PROTECTION)
Avoidance of water traps in above ground pipe-work and structural steelwork or if they cannot be avoided,
provide necessary drainage facilities.
Avoidance of dissimilar metal contacts using isolating joints or selecting materials as close together as
possible in the Galvanic Series.
To select a material with a very high corrosion resistance to the environment. In making such selection,
consideration must be given to cost, mechanical strength, ease of production, welding, bimetallic corrosion etc.
HOWEVER
Whilst it is relatively simple to select a material that will not corrode, this is of no use if the other properties
required are not met. It is, therefore, of vital importance that decisions to change a material are made by all
interested parties.
To modify the environment to reduce its corrosiveness by eliminating or neutralising the corrosive elements.
The use of inhibitors (generally used for controlling internal corrosion) including oxygen scavengers and
biocides.
For above ground atmospheric corrosion, a barrier coating is the normal choice i.e., a suitable paint system
for the application. Should the coating break down then this will be visible and repair/repainting can be readily
carried out.
Cathodic Protection (CP) systems help prevent corrosion from occurring on the exterior of structures that
are in contact with environment, by substituting a new source of electrons, commonly referred to as either a
sacrificial anode or impressed current anode. Both systems operate by imparting a direct current onto the
buried structures, using devices called rectifiers. As long as the current is sufficient, corrosion is prevented,
or at least mitigated and held in check.
In most cases, coatings on the exterior of a pipe are used in conjunction with CP. Coatings have a high
dielectric strength, which prevents the flow of electrons to the pipes surroundings, thus interrupting the
electro-chemical reaction of the metal with its environment.
Coating: 95-99 %
Cathodic Protection (CP): 5 1 %
The following criteria is adopted for use on buried steel structures in contact with
soil/water according to NACE standard (SP-0169).
_
+ _
+ _ _
+ _ _
-0.85 VDC
-1.2 VDC
_ _
+
_ +
protective CP current
PIPE
anode
primary structure
MMO Anode in
cathode September 26, 2017 Coke backfill
IES - INDUSTRIAL ENGINEERING SERVICES 59
CATHODIC PROTECTION
Impressed Current Cathodic Protection System :
-
DC CURRENT SOURCE
0
+
STEEL
ANODIC AREA
- 0.6
ANODE
- 0.4 CATHODIC AREA September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 60
CATHODIC PROTECTION
Impressed Current Cathodic Protection System :
I
- 0 DC CURRENT SOURCE
+
STEEL
ANODE
- 0.55 CATHODIC AREA September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 61
CATHODIC PROTECTION
Impressed Current Cathodic Protection System :
I
- 0
+DC CURRENT SOURCE
ANODE
- 0.6 CATHODIC AREA September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 62
CATHODIC PROTECTION
Impressed Current Cathodic Protection System :
I
- 0 DC CURRENT SOURCE
+
CATHODIC AREA
I
-0.85
STEEL
ANODE
- 0.85 CATHODIC AREA September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 63
TYPICAL ICCP SYSTEM ARRANGEMENT
TRANSFORMER / RECTIFIER
POSITIVE JUNCTION
BOX
NEGATIVE JUNCTION
BOX
TEST POST
Pure hydrocarbon fluids are usually not corrosive and do not require corrosion control for internal
surfaces. However, based upon experience, internal corrosion may occur in aboveground storage
tanks that have internal surfaces exposed to water, sediments, or other contaminants. Generally,
coatings are used to reduce or eliminate corrosion on internal surfaces. For tanks in petroleum
service, internal Cathodic Protection in conjunction with coatings has not gained widespread use, but
under certain conditions it can be effective in protecting against corrosion at holidays in the coating.
(Reference: API 651: Cathodic Protection of Aboveground Petroleum Storage Tanks).
For water storage tank it is required to install SACP or ICCP system according to NACE or other
standards.
Metals commonly used as galvanic anodes in soil are magnesium and zinc. The anodes are usually
distributed inside the tank and the tank bottom.
September 26, 2017 IES - INDUSTRIAL ENGINEERING SERVICES 71
CATHODIC PROTECTION
Cathodic Protection for Tanks & Vessels
ICCP system shall not be practical and effective in the internal of Petroleum Storage Tank due to
variation in the level of accumulated corrosive medium (hence water) in Tank as per NACE and API
guideline.
For water storage tank it is required to install SACP or ICCP system according to NACE or other
standards.
Galvanic anodes are limited in current output by the system-to-anode driving voltage and the circuit
resistance. It may be more economical to cathodically protect bare, poorly coated, or very large
structures with impressed current-type systems. Galvanic cathodic protection systems may be more
economical on small-diameter Tanks.
Considering the size and number of Tanks, current requirements, soil conditions and other influencing
factors Impressed Current Cathodic Protection system is more likely feasible and effective means of
protection of Tanks bottom plate external.
N
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MP
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Rectifier
Ring Wall