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Keywords: Thermoelectric generators are an environmentally friendly source of electrical power whose applications range
Thermoelectric generator from waste heat recovery to conversion of solar energy into electricity. Low conversion eciencies however
Cooling inhibit their wide scale deployment. Research into thermoelectrics has therefore primarily focused on
Eciency improvement of material properties, leading to remarkable progress in the area which has not translated into
Thermal management
high performing thermoelectric generators. System level eciency is signicantly dependent on eective
thermal management. Heat dissipation mechanisms employed to remove waste heat from the cold side of a
thermoelectric device are reviewed in this work. The prevalent methods of cooling thermoelectric devices are
categorized and based on published experimental data, their contribution on the overall conversion eciency of
thermoelectric generators is quantied. A broad range of devices from low heat to high thermal ux have been
covered in this work and will help guide future endeavors in thermoelectric generator design and testing.
Compared with conventional electric power generators, thermo- 2.1. Theoretical eciency
electric generator (TEG) oer many advantages such as reliability, no
moving parts and environmentally friendly. TEGs accomplish this by The conversion eciency, TE is dependent on the temperature
exploiting the thermal energy of electrons (and holes) for the energy dierence T and the gure of merit ZT (the eective ZT across T )
conversion between heat and electricity. However wide scale applica- dened as ZT = (S 2T / ) and determined by the three main material
tion of TEGs has been hindered by their low productivity, due to low parameters: the Seebeck coecient or thermo power S (V / K ), the
thermal-to-electrical conversion eciencies (typically < 10%) [13] electrical resistivity ( m ) and the thermal conductivity (W /(m K ))
limiting their use in specialized military, medical and space elds. [8]. The thermoelectric eciency is given by:
Nevertheless, in applications where the thermal energy is abundant or
T TC 1+ZT 1
very low cost, as is the case with solar energy or waste heat, TEGs are TE = H
commercially viable. Two directions have been highlighted for achiev- TH 1+ZT + (TC / TH ) (1)
ing wider applications of thermoelectric devices [4], rst is to promote
The term in the rst parenthesis on the right hand side is the Carnot
the intrinsic eciencies of thermoelectric materials and the other is to
eciency of the thermoelectric device operating between hot and cold
improve the way TEMs are integrated into electrical power producing
temperature reservoirs of TH and TC respectively. As is evident from Eq.
units, of which thermal management is an important part. While there
(1), the conversion eciency depends on the operating temperature
is signicant work on hot side thermal management of TEMs, focusing
and the gure of merit.
on solar energy [5], automotive exhaust [6], and waste heat [7]; cold
The theoretical eciency of thermoelectric power generators for
side thermal management has received less attention. In this paper, we
dierent ZT s are shown in Fig. 1 against the eciencies of other power
review dierent methods used to dissipate heat from the cold side of
generation systems [9].
the TEM over a broad range of operating parameters and present their
performance parameters.
2.2. Figure of merit and eciency
Corresponding author at: School of Mechanical & Manufacturing Engineering (SMME), National University of Sciences & Technology (NUST), Islamabad, Pakistan.
E-mail addresses: m.sajid@smme.nust.edu.pk (M. Sajid), Ibrahim.hassan@qatar.tamu.edu (I. Hassan), aziz.rahman@qatar.tamu.edu (A. Rahman).
http://dx.doi.org/10.1016/j.rser.2017.04.098
Received 18 October 2015; Received in revised form 21 April 2017; Accepted 27 April 2017
1364-0321/ 2017 Elsevier Ltd. All rights reserved.
M. Sajid et al. Renewable and Sustainable Energy Reviews 78 (2017) 1522
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M. Sajid et al. Renewable and Sustainable Energy Reviews 78 (2017) 1522
Fig. 4. Eect of increasing cold side temperature on thermoelectric eciency. Fig. 6. Classication of thermoelectric cooling systems.
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M. Sajid et al. Renewable and Sustainable Energy Reviews 78 (2017) 1522
Table 1
Maximum allowable heat flux at wind speeds of 0 m/s for bare plate, 1 m/s for heat pipe and 5 m/s for nned heat exchangers (based on data from [35]).
Type A 150 C 4.0 to 16.3 8.1 to 21.4 9.7 to 22.1 10.6 to 23.4 32.7 to 40.3
Type B 250 C 8.3 to 31.1 15.3 to 48.9 18.1 to 50.3 19.5 to 52.2 59.0 to 76.7
limiting heat ux value was also lower than that achieved with the high performance extruded aluminum heat sink used in the study gave
other heat exchanger congurations. This behavior can be attributed to an average cold side temperature of 123 C for a hot side temperature
the smaller n gap in heat pipe heat exchanger that restricts convection of 275 C and ambient conditions of 28 C. The indicated temperature
heat transfer which is the dominant mode of heat transfer at lower dierence across the TEG is 152 C while the open circuit voltage
temperatures. obtained implies an actual temperature dierence of 85 C. The
considerable divergence between the two was due to the contact
resistance at the interfaces between the mounting plate and heat sink.
3.1.1. Passive cooling
The principles of dry draft cooling were employed by zdemir et al.
[32] to build and test a prototype solar TEG with an isolated wind 3.1.2. Fan cooled
chimney for cooling. They presented performance data for the device The importance of managing cold side temperature in air cooled
over an eight hour daytime cycle for two days in the month of august. TEG devices has been highlighted with optimization studies [3740]
While the ambient temperature in the chimney varies from 30 C to with steady state and transient heat sources. Mastbergen and Willson
40 C the cold side temperature of TEG sees an increase from 30 C to a [41] presented a prototype TEG with a forced air-cooling for the cold
maximum of 77 C before dropping later in the day. With an eective side with a 1Wfan. The net power of 4 W generated by the TE generator
ZT <0.2 the eciencies are quite low. In Fig. 7 Ratio of thermal was sucient to power an array of high intensity LEDs.
eciency to Carnot eciency for a prototype wind chimney TEG with The used of fan cooled TEGs in automotive waste heat recovery has
naturally varying & xed cold side temperature Fig. 7 we take the been widely studied [4246]. Notably Hsu et al. [45,47] investigated a
experimentally measured hot side temperatures and compare the range of heat sink congurations while employing forced air cooling of
eciency ratios obtained using observed cold side temperatures and the cold side of the device (Fig. 8). In the earlier work three
a xed temperature of 30 C. The maximum conversion eciency congurations comprising ten, twenty two and forty four ns in their
obtained is just under 6% of Carnot eciency across the thermal heat sinks were studied in order to nd the optimal conguration.
gradient while the average eciency ratio is approximately 3% across Their system generated a maximum of 44.13 W of power at which the
the observed cycle. The curves indicate that eective thermal manage- average temperature dierence is 88.3 K with 343.7 K at the cold side
ment of cold side temperature could yield two fold increase in thermal of the TEG indicating a peak conversion eciency of 2.1%. A similar
to electrical conversion eciency averaging just above 6% with a peak conversion eciency was reported by Gou et al. [39] while forced air
of 12% of Carnot eciency. This analysis highlights the eect of heat cooling of TEG employed in industrial waste heat recovery. They were
transfer irreversibility on the performance of TEG as a signicant able to restrict the peak cold side temperature increase to a 14 K
holdup in improvement of conversion eciency. concluding that irreversibility in cold-side heat transfer is a bottle neck
The eect of prevalent wind conditions on the performance of a in the enhancement of system performance.
passively cooled solar TEG was investigated by Moraes et al. [33]. The Natural convection cooling systems while unable to deliver desir-
device features a solar evacuated tube as a heat source and a CPU able cold side temperatures, have the advantage of no parasitic power
cooler as a heat sink and is exposed to 804.1 W/m2 of articial solar consumption. Whereas forced air systems employ a widely available
radiation. Their results indicate that due to enhanced convective heat uid medium ensuring air cooled systems nd continued applications
transfer in windy conditions at the cold end of the TEM the power in low heat ux scenarios.
production increases.
Natural convection cooling was employed by Nuwayhid et al. 3.2. Water cooled
[34,36] to maintain cold side temperatures on TEG used for waste
heat recovery from a woodstove. In the rst prototype the maximum Because of the superior heat transport properties of water, it nds
power was less than one watt per module. The commercially available widespread application in TEGs [4852]. For instance, the thermal
eciency of a parabolic trough concentrator combined with TEMs
placed in the receiver tube with water cooling was found to be <4%
[53]. While a thermodynamic analysis of water cooled a parabolic dish
combined with a Bi-Te module predicted a solar-to-electricity eciency
of 2.81% at a temperature of 280 C [54]. The major drawback of
forced water cooling is that it parasitically draws power from the
generated amount reducing the net output of the TEG.
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M. Sajid et al. Renewable and Sustainable Energy Reviews 78 (2017) 1522
Fig. 8. Schematics of automotive waste heat recovery using TEG from Hsu et al. [47].
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M. Sajid et al. Renewable and Sustainable Energy Reviews 78 (2017) 1522
Fig. 10. Schematic of a closed loop thermosyphonic heat pipe thermoelectric generator
[65].
Fig. 12. Performance parameters (a) Eciency and (b) Power output of TEGs employ-
ing dierent heat dissipation strategies and operating between dierent temperatures.
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M. Sajid et al. Renewable and Sustainable Energy Reviews 78 (2017) 1522
Table 2 losses of pumping and pipe friction can be cost eective. While natural
Performance characteristics of various cooling mechanisms used in TEGs from published ventilation remains advantageous because of its independence from the
works.
provision of water source despite its lower performance parameters.
Cooling Tc, Cold side T, , P, Reference
mechanism Temperature Temperature Conversion Power 5. Conclusion
(K) across TEM eciency output
(%) (W) This work summarizes the various cooling methods that have been
Passive air 349.8 110.7 4.59 0.83 [32] employed to maintain cold side temperature of a thermoelectric
cooling 298 425 2.90 0.48 [68] generator. The dependence of thermoelectric conversion eciency on
315 135 3 1.8 [69] cold side temperature was highlighted at the beginning, laying the
318 155 4 3 [70] grounds for the necessity of focusing on cooling of TEGs. The overview
396 152 2.1 4.2 [34]
of performance parameters for the various heat rejection techniques
363 150 3.2 2.4 [71]
418 135 1.2 0.57 [72] provides useful insight into prospects of integrating these systems with
Fan cooled 318 76 2.40 1.08 [73] thermoelectric generation. Evaporative heat pipe systems have the
373 30 0.34 0.52 [47] lowest cooling potential which is useful for low temperature TEGs
343.7 88.3 2.16 5.52 [45]
while forced convection of water can cater to larger thermal systems
335 17.8 2 0.85 [39]
Passive 336 27 1 3.2 [57] with higher heat uxes. The information presented can also be used for
water 363 120 Not 9.5 [55] combining the thermoelectric generators with a heat source, designing
Available the cooling system and a standalone power generation system. This
338 160 2 2.3 [74] research shows the great potential of thermoelectric generators to be
Forced 303 270 1.59 6 [52]
combined either with concentrated solar thermal systems, industrial
water 325.7 97.4 0.78 1.75 [58]
cooling 300 600 0.13 0.86 [27] heat recovery systems or any other available heat source together with
317 109 2.90 4.9 [63] passive cooling to become a feasible technology for medium to large
303 120 4.44 2.61 [51] scale power generation with the attraction of minimal moving parts.
294 63 0.80 0.34 [75]
Finally, this review highlights the potential of improving performance
291 198 2.70 3 [76]
Heat pipe 318 55 2.10 1.04 [44]
of TEGs by rening the thermal management of cold side of the
333 86.7 2.02 1.12 [66] thermoelectric cell.
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