Professional Documents
Culture Documents
Minerals Engineering
journal homepage: www.elsevier.com/locate/mineng
a r t i c l e i n f o a b s t r a c t
Article history: A froth transport model for industrial otation cells characterisation has been developed in terms of oper-
Received 29 December 2011 ating variables for a three-phase system (i.e., gas, liquid and valuable/non-valuable solid). The new
Accepted 29 October 2012 approach, based on previous literature, involves three transport mechanisms: a vertical transport zone,
Available online 4 December 2012
a combined vertical and horizontal transport zone that allows the liquid and solid phases to be carried
to the concentrate stream, and a mechanism in which the gas phase is gradually removed from the
Keywords: top of the froth (bubble collapse).
Froth otation
To develop and evaluate the model, non-conventional measurements were conducted in a 130 m3 o-
Froth modelling
Froth transport
tation cell in the Cu/Mo rougher circuit at Division El Teniente, Codelo-Chile. The solid axial prole in the
Froth recovery froth, the froth recovery and the froth transport times for the three phases (measured by radioactive trac-
Froth residence time ers), are among the most important measured variables. The mean froth residence times and froth recov-
ery estimations were used as boundary conditions in the proposed model.
The aim of the froth transport model was to provide a simple and practical understanding of the froth
performance in the otation equipment. A practical description of the froth zone behaviour will allow
new designs and congurations to be evaluated for the radial and peripheral launders in mechanical cells,
improve the recovery of valuable minerals and decrease the gangue entrainment into the concentrate
stream.
2012 Elsevier Ltd. All rights reserved.
0892-6875/$ - see front matter 2012 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.mineng.2012.10.016
18 F. Contreras et al. / Minerals Engineering 41 (2013) 1724
Three stages inside the froth were dened with a common 2. Froth transport model
height h. Stage 1 corresponds to a stagnant zone of length x0, where
the mass ow rate entering the froth, gf(x) = g0, is the same as the Based on Moys and Zheng models, a new approach was devel-
one exiting from the top of froth, gb(x) = g0. In Stage 2 (with length oped to describe and t data obtained at industrial scale. This mod-
L0 x0), the velocity has a vertical and a horizontal component, and el represents the three-phase behaviour of gas, liquid and solid
the entering ow rate, gf(x) = g 00 , is not completely recovered at the (valuable and gangue) in the froth using a simple approach that in-
top of the froth, gb(x), because of the froth stability. Fig. 1 shows cludes a small number of assumptions. The analysis was conducted
that a fraction (1 a) of the gas entering the froth zone exits in a bi-dimensional system, where the froth zone was represented
through the top of the froth. The a fraction corresponds to the by a rectangular section located between the pulpfroth interface
mass ow rate reported to the concentrate stream. The concentrate and the top of the froth.
stream denes the amount of gas transferred to Stage 3, where no
vertical mass ow rate is present. This zone represents the conti-
2.1. Froth transport zones and otation cell diagram
nuity of the stream function, where the term (L L0 ) corresponds
to a tting parameter. This parameter is used to adjust the froth
A schematic of the froth model diagram is shown in Fig. 3, in
mean residence time, which only considers the horizontal trans-
which two froth zones are observed.
port of bubbles recovered from Stage 2 at a constant velocity.
The aforementioned model (Fig. 1) was validated for a gasli-
Vertical transport zone: This zone is dened similar to the model
quid system in a 5 L pilot cell. However, this model and other sim-
proposed by Zheng et al. (2004). The vertical zone affects all the
ilar models (Murphy et al., 1996; Neethling and Cilliers, 2003) have
components (solid, liquid and gas). The height of the vertical
not been validated at industrial scale due to the complexity in esti-
transport zone, Hf, goes from the pulpfroth interface to the
mating the parameters. Also, the cited models only deal with the
launder lip level.
trajectory and velocity of the froth and no other sub-processes
Combined transport zone (vertical and horizontal): The height of
occurring in the froth.
the combined transport zone is hf, Fig. 3. In this zone, the solid
Another froth transport model was proposed by Zheng et al.
and liquid components are transported to the concentrate
(2004), who dened three transport zones: a stagnant zone, a ver-
stream. At the same time, gas gradually exits from the top of
tical transport zone and a horizontal transport zone (Fig. 2).
the froth. Considering the local gas recovery as the gas fraction
As shown in Fig. 2, a fraction of uniformly distributed gas ow
that enters the froth at location x and that is transported to the
(Vin) enters the vertical transport zone and reaches the horizontal
concentrate stream, a minimum local gas recovery is dened at
zone, while the remainder of the gas ow enters the stagnant zone.
a distance far from the lauder (x = 0) and a maximum local gas
The stagnant zone corresponds to a region where the froth phase
recovery is dened near the lip (x = L).
and the pulp are at equilibrium with negligible mass transfer to
the other zones. Only a fraction of the gas ow rate entering the
To evaluate the froth transport model, a cylindrical cell with
horizontal transport zone is reported to the concentrate stream
internal radial launders was considered (Fig. 4). In this gure, d
due to the bubbles bursting on the froth surface. The break-up of
is the mean transport length in the cross-section area dened by
points ABCD, in which the concentrate is carried to the internal
launders. The mean distance, d, was selected to describe the aver-
age mineral transport to the concentrate, i.e., minerals that reach
the internal launder. Thus, L = d is taken as the distance from the
Horizontal
hf Transport Zone 0 x L
Stagnant Fout
Zone
Hf Vertical
Transport Zone
Vin
0 R
Fig. 2. Froth transport model (Zheng et al., 2004). Fig. 3. Froth transport zones.
F. Contreras et al. / Minerals Engineering 41 (2013) 1724 19
Fig. 4. Flotation cell section with radial and internal launders. 2.3. Froth transport
Table 1 similar to that observed when measuring the axial grade proles
Industrial cell dimensions (Fig. 4). and the mean froth residence times (Yianatos et al., 2008b). Table
Dimensions Length (m) 2 shows the operational parameters measured directly at indus-
BE 2.95 trial scale.
CD 0.95 To obtain the model solution and relate the corresponding vari-
AB 0.36 ables, the froth transport model must satisfy the following
d 0.60 assumptions:
Table 3 Table 3 shows the RF,j and the MFRTj values employed to t the
Froth recovery data and froth transport times. froth transport model.
Valuable mineral Liquid Gangue (45 lm) Gas
The froth recovery of valuable minerals (RF,VAL) was 59% from
(true otation) entrainment experimental testing using the bubble load method for a total froth
RF,j (%) 59 11.7a 1.1d 46b
depth HF of 15 1 cm (Yianatos et al., 2008a). It was supposed that
MFRTj (s) 35 23 14 1112c differences in the froth depth from 15 to 18 cm have a minor effect
a
in the froth recovery of valuable minerals.
Estimated using Eq. (19) and the overall water balance.
b
Reported by Hadler and Cilliers (2009).
The froth recovery of liquid was estimated from the experimen-
c
Estimated by a theoretical relationship (Zheng et al., 2004). tal data shown in Table 4 along with water mass balances and the-
d
Estimated by a theoretical relationship (Yianatos and Contreras, 2010a). oretical relationships. The liquid ow rate ILF (ton/h) entering the
froth was obtained from Eq. (19) considering a packed bubble bed,
with gas hold-up eG,IN = 74%, near the pulp/froth interface (Neeth-
ling et al., 2003).
Table 4
Operating conditions in the 130-m3 rougher otation cell.
1 eG;IN %sol
Feed tonnage (tph) 870 ILF JG AC qSL 1 19
Feed solid percentage (%) 35.5
eG;IN 100
Feed copper grade (%) 0.83
Concentrate solid percentage (%) 46.6 where AC and qSL correspond to the cross-sectional area of the cell at
Concentrate copper grade (%) 21.6 the interface level (21 m2) and the slurry density, respectively.
C/F ratio (%) 2.63 The liquid ow rate in the concentrate stream was calculated
Overall water recovery Rw (%) 1.66
using the overall mass balance in the mechanical cell with the data
Froth depth (cm) 1820
from Table 4, obtaining a liquid froth recovery RF,LIQUID of 11.7%.
The overall gangue recovery was estimated by the method re-
ported by Yianatos and Contreras (2010a) using the experimental
Solid percentage per size class, % data shown in Table 4 along with theoretical relationships. Only
0 10 20 30 40 50 60 70 ne gangue particles (45 lm) are considered to be transported
0 by entrainment with the liquid motion at the interface level.
Measurements of axial solid percentage were conducted at the
10 centre of the region limited by the launders and the froth crowder
Pulp/Froth Interface
using a variable speed peristaltic pump and a suction tube of var-
20 iable length. The samples were subjected to chemical assays and
Cell depth, cm
that the mean froth residence time, Eq. (18), depends on the hori-
40
far (x) zontal transport time, Eq. (12), which is a function of the horizontal
30 transport velocity, uH(x), and therefore a function of far(x).
%
20
4. Results and discussion
10
(a)
0 Fig. 7 shows the results of the froth transport model based on
experimental data. Fig. 7a and b shows the cumulative air recovery
10
function far(x) and the horizontal transport velocity uH(x), respec-
Horizontal transport
8
velocity, cm/s
uH ( x)
tively. Both functions are related to Eq. (10) taking into account
6 the boundary condition, uH(L), which was measured by using the
4 Visiofroth system. These variables were dened for satisfying the
froth surface velocity at the overow level uH(L) = 9 cm/s, (launder
2
0
(b) lip, x = L = 60 cm) and the air recovery value (a = far(L)) of 46%, as
shown in Tables 2 and 3, respectively.
Fig. 7c shows the specic recovery function, SRFj(x), for the valu-
Specific recovery function, %
100
Valuable -True flotation able mineral, liquid and ne gangue, which simultaneously satisfy
80 Liquid Eqs. (17) and (18) and the experimental values of RF,j and MFRTj
60
Gangue -Entrainment
(c) shown in Table 3.
The model results are consistent with the experimental data of
40 axial grade prole measured in two locations of a 130 m3 industrial
otation cell. Location 1 corresponds to the central position of the
20 region limited by the froth crowder and the overow lip, whereas
location 2 corresponds to a position close to one of the internal
0
launder, as shown in Fig. 8. The experimental results showed that,
0 10 20 30 40 50 60
at location 1, which is the farthest position from the internal laun-
Distance, cm
der lip, a higher copper grade (approximately 5%) was observed
Fig. 7. Froth transport model results. with respect to location 2 at different froth depths. This phenome-
non is related to the bubbles bursting in the froth surface, which
promotes water drainage and ne particles (entrained gangue) to
3.1. Model tting
drop back to the pulp zone. Similarly, Fig. 7c shows that the SRF(x)
function for ne gangue is almost negligible far from the overow
Firstly, the cumulative air recovery function, far(x), and the hor-
lip. Also, it is expected that lower water drainage near the overow
izontal transport velocity, uH(x), must be determined. The bound-
lip results in lower copper grades because of the higher entrain-
ary conditions for far(x) are dened by Eqs. (5) and (6), while
ment of ne particles (the SRF(x) function of entrained gangue is
uH(L) must match the measured froth surface velocity (VisioFroth)
higher near the discharge).
near the launder lip.
Fig. 9 shows the ne solid percentage as function of the froth
The specic recovery functions, SRFj(x), must be obtained in or-
depth, which was measured in the centre of the region limited
der to satisfy Eqs. (17) and (18). For each jth component (liquid and
by the froth crowder and the launders of the otation cell. It was
valuable and non-valuable solid), the SRFj(x) must match the
observed that the fraction (%) of ne particles decreases while
18
% Cu Profile (Location1)
% Cu Profile (Location 2)
15
Distance above the interface, cm
12
0
0 10 20 30 40
Cu grade, %
0 5. Conclusions
0 10 20 30 40 50 60
Distance, cm A froth transport model based on previous literature was devel-
Case 1 Case 2 Case 3 oped and evaluated using experimental data from a 130 m3 rough-
er otation cell.
Fig. 10. Effect of the mean transport length. The model was calibrated using experimental data obtained in
this study and data from axial solid grade proles, size distribution
proles in the froth zone, froth mean transport times, froth surface
velocity, supercial gas rate, and froth recovery of gas, water and
Table 5 solid (valuable and gangue), previously reported.
Recovery results varying the mean transport distance.
The froth model results showed that the liquid and gangue
Case 1 Case 2 Case 3 recovered in the concentrate originate preferentially from the zone
L = 60 cm L = 30 cm L = 10 cm near the overow lip, whereas the transport of valuable minerals
RF,VALUABLE (%) 59.1 89.3 99.4 was more distributed throughout the entire froth.
RF,LIQUID (%) 11.7 20.0 35.7 A sensitivity analysis showed that froth recoveries of valuable
RF,GANGUE (%) 1.0 2.0 4.6
mineral near 100% could be achieved by decreasing the mean
RF,GANGUE/RF,VALUABLE 1.8 2.2 4.6
(%) transport distance. However, a signicant increase in water and
RF,LIQUID/RF,VALUABLE (%) 19.9 22.4 36.0 gangue recovery (by entrainment) was also observed. This effect
decreases the concentrate grade and increases the concentrate
ow rate, which eventually requires the downstream processing
capacity to be increased.
moving upwards inside the froth due to water drainage. In addi- Equipment designed with lower froth transport distances and
tion, the percentage of ne particles on top of froth (far from the larger overowing lip length is expected to improve metallurgical
launder) was lower than in concentrate, which is mainly due to performance. For this purpose, a proper manipulation of the froth
ne gangue entrainment near the overow lip. depth and gas rate is required to keep the concentrate grade and
owrate in the range of operation.
4.1. Sensitivity
Acknowledgments
The effect of froth transport near the launder lip was evaluated
by decreasing the effective distance for horizontal transport into The authors are grateful to El Teniente Division CODELCO-Chile
the froth overow. This condition simulates an industrial applica- for providing access to their plant and for their valuable assistance
tion in which internal launders in the froth zone might be added. in the experimental work. Funding for process modelling and
Using the proposed froth transport model, three cases were consid- control research is provided by CONICYT, Project Fondecyt
ered: L = 60 cm (case 1), L = 30 cm (case 2) and L = 10 cm (case 3), 1100854, NEIM, ICM-MINECON, and Santa Maria University,
as shown in Fig. 10. Project 271068.
24 F. Contreras et al. / Minerals Engineering 41 (2013) 1724
References Neethling, S.J., Lee, H.T., Cilliers, J.J., 2003. Simple relationships for predicting the
recovery of liquid from owing foams and froths. Minerals Engineering 16,
11231130.
Barbian, N., Hadler, K., Ventura-Medina, E., Cilliers, J.J., 2005. The froth stability
Schwarz, S., Grano, S., 2005. Effect of particle hydrophobicity on particle and
column: linking froth stability and otation performance. Minerals Engineering
water transport across a otation froth. Colloids and Surfaces A 256, 157
18 (3), 317324.
164.
Dyer, C., 1995. An investigation into the properties of the froth phase in the otation
Seaman, D.R., Franzidis, J.-P., Manlapig, E.V., 2004. Bubble load measurement in the
process. MSc Thesis, University of Witwatersrand, South Africa.
pulp zone of industrial otation machinesa new device for determining the
Feteris, S.M., Frew, J.A., Jowett, A., 1987. Modeling the effect of froth depth in
froth recovery of attached particles. International Journal Mineral Processing 74
otation. International Journal of Mineral Processing 20, 121135.
(1), 113.
Hadler, K., Cilliers, J.J., 2009. The relationship between the peak in air recovery and
Tsatouhas, G., Grano, S.R., Vera, M., 2006. Case studies on the performance and
otation bank performance. Minerals Engineering 22 (5), 451455.
characterization of the froth phase in industrial otation circuits. Minerals
Leiva, J., 2011. Caracterizacin de la Supercie de Espumas de Flotacin Industrial.
Engineering 19, 774783.
Master Thesis, Chemical Engineering Department, Santa Mara University, Chile.
Vera, M.A., Mathe, Z.T., Franzidis, J.P., Harris, M.C., Manlapig, E.V., OConnor, C.T.,
Massinaei, M., Kolahdoozan, M., Noaparast, M., Oliazadeh, M., Yianatos, J.,
2002. The modeling of froth zone recovery in batch and continuously operated
Shamsadini, R., Yarahmadi, M., 2009. Froth zone characterization of an
laboratory otation cells. International Journal of Mineral Processing 64, 135
industrial otation column in rougher circuit. Minerals Engineering 22 (3),
151.
272278.
Yianatos, J.B., Moys, M.H., Contreras, F., Villanueva, A., 2008a. Froth recovery of
Morales, P., Coddou, F., Yianatos, J., Contreras, F., Cataln, M., Daz, F., 2009.
industrial otation cells. Minerals Engineering 21 (1214), 817825.
Hydrodynamic performance of the division Codelco Norte concentrators large
Yianatos, J., Bergh, L., Tello, K., Diaz, F., Villanueva, A., 2008b. Froth mean residence
otation cells. In: VI International Mineral Processing Seminar, Procemin,
time measurement in industrial otation cells. Minerals Engineering 21 (12
Santiago, Chile, December 24.
14), 982988.
Moys, M.H., 1984. Residence time distributions and mass transport in the froth
Yianatos, J., Contreras, F., Morales, P., Coddou, F., Elgueta, H., Ortz, J., 2009. A novel
phase of the otation process. International Journal of Mineral Processing 13
scale-up method for mechanical otation cells. Minerals Engineering 23, 876
(2), 117142.
883.
Moys, M.H., Yianatos, J., Larenas, J., 2010. Measurement of particle loading on
Yianatos, J., Contreras, F., 2010a. Particle entrainment model for industrial otation
bubbles in the otation process. Minerals Engineering 23 (2), 131136.
cells. Powder Technology 197, 260267.
Murphy, D.G., Zimmerman, W., Woodburn, E.T., 1996. Kinematic model of bubble
Yianatos, J., Contreras, F., 2010b. On the carrying capacity limitations in large
motion in a otation froth. Powder Technology 87, 312.
otation cells. Canadian Metallurgical Quarterly 49 (4), 345352.
Neethling, S.J., Cilliers, J.J., 1999. A visual kinematic model of owing foams
Zheng, X., Franzidis, J.-P., Manlapig, E., 2004. Modelling of froth transportation in
incorporating coalescence. Powder Technology 101, 249256.
industrial otation cells: Part I. Development of froth transportation models for
Neethling, S.J., Cilliers, J.J., 2003. Modeling otation froths. International Journal of
attached particles. Minerals Engineering 17 (910), 981988.
Mineral Processing 72 (14), 267287.