5 191

5
1. 96 97 98 99 100 101 102 103 104
2.
1 1 1 2 3 3 1 2 2
3.
4.
5.
6.

5-1

1 p.219

1.
(1)

1

CH3CH2OHCH3CHO

(2)
0 Cl2 Cl 0

Cu2 2
12F 1

Al 3
H 1
NaHH 1

2

H2O2 O 1

KO2 O 12

192 ()

MnO4 Mn 7O 27241
2.
8
A A A A A A A

1 2 3 4 5 6 7

0 0 5 4 3 2 1
F 0F2O 2OF20Fe
3.

Fe3O4 Fe 83332

1

(A) (B) (C)
(D) (E)

[]
(A)(B)(E)

[]
96.
(A) (B) (C) (D) (E)

2

(A) OCl2OF2 (B) Na2S2O3Na2S4O6 (C) NaHH2 (D) Fe2O3K3[Fe(CN)6]
(E) NiNi(CO)4

[]
(A) OCl2 O 2OF2 O 2
(B) Na2S2O3 S 2Na2S4O6 S 2.5
(C) NaHH 1H2H 0
(D) Fe 3
(E) Ni 0Ni(CO)4 Ni 0
 5 193
[] 1.
(A) KHHClH2O 1 (B) H2O2KMnO4MgO O
2 (C) K2Cr2O7K2CrO4KMnO4BaO2 O 2 (D) NaClNa2O2
1. (A) KH 1(B) H2O2
NaOH Na 1
1(C) BaO2 1

(D)Na 1

2. 2
(A) CH3COOH (B) CH2CH2 (C) CH4 (D) CH3OCH3 (E) CH3COCH3


2. (A) (B) (C) (D) (E)

3
YBa2Cu3O7xY Sc x0.1
77.
(A)14 (B)3 (C)4 (D)
2.27 (E) 2

[]
(A) 270.113.8(C) 2A
2(E) 2

[] 4 (A) 0(B)17(C)27(D)2
(E)34
(A) F (B) Cl (C) Mn (D) Zn (E) Ce

2 p.219

1.

H2 H 0 1H2 CuO Cu
2 0CuO
2.
194 ()

4

(A) CrO42 Cr2O72 (B) Fe(OH)3 Fe(OH)2 (C) Al3 Al(OH)4 (D) HgCl2 Hg2Cl2
(E) HCl Cl2

[]

(A) CrO42 Cr2O72
6 6
(B) Fe(OH)3 Fe(OH)2
3 2
(C) Al3 Al(OH)4
3 3
(D) HgCl2 Hg2Cl2
2 1
(E) HCl Cl2
1 0

[] 1.
(A) C2O42 CO2 (B) S2O32 S4O62 (C) MnO4 MnO2
(D) Cu(OH)2 Cu(NH3)42 (E) Cr2O72 CrO42
1. (A) C3 4(B) S2

2.5(C) Mn7 4(D) Cu2 2(E) Cr6 6
2. 5 H2O22 MnO46 H 5 O22 Mn28 H2O
(C) MnO4 Mn2

(A) H (B) H2O2 (D) O2 H2O2

2. (A) H (B) H2O2 (C)

MnO4 Mn2

5

(A) (B) (C) (D) (E) 65.

[]

(A) S4(B) O1(C) Cl1(D) S2(E) N3

[]
(A) CO (B) N2O (C) As2O3 (D) P4O6 (E) SO3 99.

(A) C 2
(B) N 1(C) As 3(D) P 3(E) S
6
 5 195

3 p.224

11

6

(A) 2 H2O 2 H2O2 (B) S2 H2SO4 3 SO22 H2O (C) MnO2Na2C2O42 H2SO4
MnSO42 CO2Na2SO42 H2O (D) 3 KClO 2 KClKClO2 (E) 3 HNO2 HNO32
NOH2O

[]

(A) 2 H2O 2 H2O2
1 2 0 0

(B) S2 H2SO4 3 SO22 H2O
0 6 4
(C) MnO2Na2C2O42 H2SO4 MnSO42 CO2Na2SO42 H2O
4 3 2 4
(D) 3 KClO 2 KClKClO2
1 1 5
(E) 3 HNO2 HNO32 NOH2O
3 5 2

[]
(A) S2 H2SO4 3 SO22 H2O (B) 2 CuCl CuCuCl2 (C) 3 ClO ClO32 Cl
(D) P43 OH3 H2O 3 H2PO2PH3 (E) 3 Cl26 OH ClO35 Cl3 H2O

(A)S2 H2SO4 3 SO22 H2O
0 6 4

196 ()

4 p.224

1.

2.
Step 1
Step 2
Step 3 H OH
Step 4 H2O H O

Step 1

Step 2

MnO45 Fe28 H Mn25 Fe34 H2O Step 3Step 4

3.
Step 1


Step 2 H OH
Step 3 H2OHO
Step 4


NO3 (aq)3 e NO(g) NO3 (aq)4 H (aq)3 e NO(g)

Step 13 NO3 (aq)4 H (aq)3 e NO(g)2 H2O(l)(1)2

H2S(g) S(s)2 e H2S(g) S(s)2 H (aq)2 e (2)3
Step 4

2 NO3 (aq)2 H (aq)3 H2S(g) 2 NO(g)3 S(s)4 H2O(l)
4. pH

(1) O2(g)4 H(aq)4 e 2 H2O(l)
H

 5 197
(2)
H2O2(aq)2 H(aq)2 e 2 H2O(l)

H2O2(aq) O2(aq)2 H (aq)2 e
pH [H] pH
[H]
5.


MnO48 H5 e Mn24 H2O

KMnO4 MnO42 H2O3 e MnO24 OH

MnO4e MnO42

K2Cr2O7 Cr2O7214 H6 e 2 Cr37 H2O

H2O2 H2O22 H 2 e 2 H2O

HNO3 NO34 H3 e NO2 H2O
HNO3 NO32 He NO2H2O
H2SO4 SO424 H2 e SO22 H2O
X2 X22 e 2 X
Ce4 Ce4e Ce3
Fe3 e Fe2

Fe3

O3 O32 H 2 e O2H2O
H2C2O4 H2C2O4 2 CO22 H2 e
H2O2 H2O2 O22 H2 e

H2S H2S S2 H2 e

SO2( SO32

SO22 H2O SO424 H2 e
HSO3 )
X X 12 X2e

Sn2 Sn2 Sn42 e
Fe2 Fe2 Fe3e
NaMg Na Nae

I 1
S2O32 2

2 S4O6 e
2

S2O32

Cl MnO
S2O325 H2O
2
2 SO4210 H8 e
4
198 ()

7

(1) MnO2(s)H(aq)Cl(aq)
(2) Cr2O72(aq)SO32(aq)H(aq)
(3) H2O2(aq)I(aq)H(aq)
(4) KIO3Na2S2O5 K2SO4Na2SO4SO3I2

[] (1) MnO2(s)4 H2 Cl Mn2Cl22 H2O

(2) Cr2O723 SO328 H 2 Cr33 SO424 H2O
(3) H2O22 I2 H I22 H2O
(4) 4 KIO35 Na2S2O5 2 K2SO45 Na2SO43 SO32 I2

[] a MnO4 b NO2 c H2O d OH e NO3 f MnO2

(A) ad (B) bd (C) ac3 (D) abcde (E) abde


2 MnO4 3 NO2 H2O 2 OH 3 NO3 2 MnO2

8
CuHNO3 Cu(NO3)2NO
(1)
(2) HNO3
(3) 0.6 mol mol 87.

[] (1) 3 Cu8 HNO3 3 Cu(NO3)22 NO4 H2O(2) 25 (3) 1.6 mol

2
(2) 8 HNO3 2 NO 8 100 25
3 8
(3) x1.6 mol
0.6 x

[] ZnHNO3 Zn(NO3)2NH4NO3H2O(l)
HNO3
(A) 14 (B) 18 (C) 19 (D) 110
4 Zn10 HNO3 4 Zn(NO3)2NH4NO33 H2O


HNO3 NH4 HNO3 10
 5 199

9
(1) P4OHH2O H2PO2PH3
(2) P4

[] (1) P43 OH3 H2O 3 H2PO2PH3(2) 25

30412 121

1P4 3P412 OH12 H2O 4PH312 H2PO2

0 0 3 1

1044 43
P43 OH 3 H2O 3 H2PO2PH3

1
P4 PH3 P4 100 25
4

[] Cl2OH ClO3 Cl H2O
(A) Cl2 (B) OH (C)

ClO3 1 (D) 16 (E) 5

3 Cl26 OH ClO3 5 Cl 3 H2O
0 5 1


(B)OH
(D) 3615318

10
(1) AuHClNO3 AuCl4NOH2O
(2) Cr2O72C2O42H Cr3CO2H2O

[] (1) Au4 H 4 Cl NO3 AuCl4 NO2 H2O
(2) Cr2O723 C2O4214 H 2 Cr36 CO27 H2O
(1) Au4 Cl AuCl43 e
1

NO33 e4 H NO2 H2O

2


1
2 Au4 H 4 Cl NO3 AuCl4 NO2 H2O

(2) C2O42 2 CO22 e

1

Cr2O726 e14 H 2 Cr37 H2O

2
2 2 3

1 3
2 Cr2O7 3 C2O4 14 H 2 Cr 6 CO27 H2O

[]
ZnH NO3 Zn2NH4 H2O
Zn Zn2 2 e (1)


10 HNO38 e NH43 H2O (2)
(1)4(2) 4 Zn10 HNO3 4 Zn2NH43 H2O
200 ()

11 pH

(A)H2O2 O2 (B)H2O2 pH
(C) O2 pH (D)
(E) F2

[]
(A) H2O2 H2O O2

(B) H2O22 H 2 e 2 H2OH2O2 pH
H2O2 2 HO22 eH2O2 pH
(C) O24 H4 e 2 H2OO2 pH
(D)

[] [H]
(A) NO3 (B) Cl2 (C) H2O2 (D) Fe3 (E) MnO2


[H ] H

(A) NO3 3 e 4 H NO2 H2O(B)Cl22 e 2 Cl
3 2
(C) H2O22 e 2 H 2 H2O(D) Fe e Fe

(E) MnO22 e 4 H Mn2 2 H2O

*

( ) 1.
(A) (B)
(C) F (D) Pb3O4
Pb (E) Na2S2O3 S 2
1. (A) ScY 3(B)
Cl 1357(C) O

2(E) S

( ) 2.
(A)
(B)
(C)
(D)
(E) 2. (A)
(B)
CaCO3 CaOCO2
2 2
(C)
 5 201
( ) 3.
(A) H2S (B) KMnO4 (C) H2O2 (D) SO2 (E) KNO2
3. 8(A) H2S(B) KMnO4(C) H2O2(D) SO2(E) KNO2
2 7 1 4 3

( ) 4.
94.
(A) (B) (C) (D) (E) 2
74 0
1 1
1 631
4. (A)1(B) 0 (C) (D)2(E)
0 5 2
1 0
1
2

( ) 5.
2 HNO3(aq)H2S(g) S(s)2 NO2(g)2 H2O(l)
2 HNO3(aq)3 H2S(g) 3 S(s)2 NO(g)4 H2O(l)
2 HNO3(aq)4 H2S(g) 4 S(s)NH4NO3(aq)3 H2O(l)
2 HNO3(aq)5 H2S(g) 5 S(s)N2(g)6 H2O(l)

92.
(A) (B) (C) (D) (E)
5. 2 HNO3(aq)H2S(g) S(s)2 NO2(g)2 H2O(l)
5 4 1
2 HNO3(aq)3 H2S(g) 3 S(s)2 NO(g)4 H2O(l)
5 2 3
2 HNO3(aq)4 H2S(g) 4 S(s)NH4NO3(aq)3 H2O(l)
5 3 8
2 HNO3(aq)5 H2S(g) 5 S(s)N2(g)6 H2O(l)
5 0 5

( ) 6. Cr2O72H2O2H Cr3O2H2O
(A) 24 (B) H2O2 (C) Cr2O72
3 (D) H2O2 6 O2 (E) Cr2O72

6. Cr2O72 3 H2O28 H 2 Cr3 3 O27 H2O

(B) H2O2 (C) 6 (D) 2 e (E)

( ) 7.
7. (B)
(A) CaC22 H2O Ca(OH)2C2H2
(B) 2 Na2 H2O 2 NaOHH2 2 Na2 H2O 2 NaOHH2
0 1 1 0
(C) x Na2CO3x SiO2 [Na2SiO3] xx CO2

(D) Cr2O722 OH 2 CrO42H2O
(E) HCOOH COH2O
202 ()
8. (A) 2 H2O2 2 H2OO2
( ) 8. 1 2 0
H2O2
(A) 2 H2O2 2 H2OO2
(B) Cl2H2O HClHOCl (B) Cl2H2O HClHOCl
0 1 1
(C) ClO35 Cl6 H 3 Cl23 H2O Cl2

(D) 2 Cl22 CaO Ca(OCl)2CaCl2
(C) ClO3 5 Cl 6 H 3 Cl23 H2O
5 1
(E) P43 OH3 H2O PH33 H2PO2 0
Cl ClO3

(D) 2 Cl22 CaO Ca(OCl)2CaCl2
0 1 1
Cl2


(E) P43 OH 3 H2O PH3H2PO2
0 3 1
P4

9.
1 Na2Cr2O7 CrCl3
6 3

2 Cr(OH)3 CrCl3

( ) 9. 3 3

3 Cr(OH)3 NaCrO2

3 3

4 NaCrO2 Na2CrO4
3 6

5 CrCl3 Na2CrO4

3 6

6 Na2CrO4 Na2Cr2O7

6 6

(A)
4
5 (B)
1
3
6 (C)
1
4 (D)
2
3
5 (E)
1
4
5

( )10.
a K2Cr2O7b H2SO4c H2S w KHSO4x Cr2(SO4)3y H2Oz S
(A) axbywcz (B) axbcw3xzby
(C) axbc2wycz (D) axbywcz
(E) axbcywzby
10. K2Cr2O75 H2SO43 H2S 2 KHSO4Cr2(SO4)37 H2O3 S

( )11. 11. X CO(A)(B)5

0 (C)

KNO3(s)C(s)S(s) K2S(s)N2(s)3 X(s) (D) 0 2 (E) 0 2


(A) K (B) N (C) O (D) C (E) S 100.
 5 203
*( )12. H2O2 77.
2
(A)H2O2 Fe (B) H2O2
(C) H2O2 (D)
H2O2 (E) H2O2
pH
12.(B)H2O2 H2O(D) H2O22 H 2 e 2 H2O
H2O2 (E)H2O2

H2O2 2 H O22 e pH

13.
*( ) 13. (A) CuO Cu
2 0
(A) 3 CuO2 NH3 3CuN23 H2O (B) HCl H2
(B) Zn2 HCl ZnCl2H2 1 0
(C) K2Cr2O7 K2CrO4
(C) K2Cr2O72 KOH 2 K2CrO4H2O 6 6
(D) H2O2 H2O
(D) 2 FeSO4H2O2H2SO4 Fe2(SO4)32 H2O 1 2
(E) H2SO4 CaSO4
(E) Ca(OH)2H2SO4 CaSO42 H2O 6 6
(A)(B)(D)

*( )14. Br2Na2CO3 NaBrNaBrO3CO2

(A) Na2CO3
(B) Br2
1
(C) CO32 CO2 2 O22 e

(D) Br2 Br2 83.3

(E) 18 14. 3 Br2+3 Na2CO3 5 NaBrNaBrO33 CO2
Br2(C)
1
Br26 OH BrO3 5 e 3 H2O(D)
2
5
10083.3 (E) 15
6

15. Cr2O72(aq)SO32(aq)H(aq) Cr3(aq)SO42(aq)H2O(l)

(1)
(2)
(3)
2 2

(1) SO3 H2O SO4 2 e 2 H
(2) Cr2O726 e14 H 2 Cr37 H2O
(3) Cr2O723 SO328 H 2 Cr33 SO424 H2O

15. SO32 H2O SO42 2 e 2 H 1

Cr2O72 6 e 14 H 2 Cr3 7 H2O 2

2 Cr2O72 3 SO32 8 H 2 Cr3 3 SO42 4 H2O
1 3
204 ()

*( ) 1.
93.
CH3OH HCHO ()
HCHO HCOOH ()
CH3OH HCOOH()
()()()
(A)() (B) (C)()
2 (D)() 2 (E)()
4 1. (A)()()()
(B)C CH3OH2
HCHO0HCOOH2
2 e 2 e
(C)(D)(E) CH3OH HCHO HCOOH
(D) 2

*( ) 2. Cu3PHNO3 Cu(NO3)2H3PO4NOH2O

(A) 1 Cu3P 11 (B) 1 Cu3P 8
(C) HNO3 HNO3 37.9 (D) HNO3
HNO3 42.3 (E) HNO3
34.4 2.

(A)(B) Cu3P Cu2 H3PO4 1 Cu3P 11
11 11
(C)(D) 100 37.9 (E) 10034.4
1118 31118
 5 205

5-2

1 p.230

1.

2.

3. mC V nC V
mnCV
MnO4 Mn2 m5C2O42 CO2n2


4.

H+
Mn2(aq)


MnO4 (aq)

5.
(1) I2 I
(2)

1 I2

2 I2

I22 S2O32 2 IS4O62
I2

(3)


1 I KI I I2

Na2S2O3 I2

2 I2

K2Cr2O7
Cr2O726 I14 H 2 Cr33 I27 H2O
I22 S2O32 2 IS4O62
Cr2O72 I2 S2O32
6.


206 ()

1
30.0 mL Sn2 10.0 mL KMnO4 0.120 M
Sn2 M 85.
(A) 0.100 (B) 0.200 (C) 0.360 (D) 0.900 (E) 0.600

[]
H+
MnO4 Mn2Sn2 Sn4
CM30.020.12010.05
CM0.100

[] 3.00 g 200 mL 25 mL 0.04 M KMnO4

32.0 mLFe56
(A) 96 (B) 90.5 (C) 85.3 (D) 81.5 (E) 89.5
3.00 25 32


56 200
C10.04
1000
5C96

2
2
0.1 M 5 mL 0.3 M KMnO4 0.5 mL
KMnO4
(A) SO2 (B) Na2C2O4 (C) BaCl2 (D) Na2CO3 (E) FeSO4

[]
KMnO4 KMnO4
KMnO4 0.30.550.75
(A) SO2 SO422 e SO2 20.1510.75
(B) C2O42 2 CO22 e Na2C2O4 20.151
(C) 2 Cl Cl22 e BaCl2 20.151
(D) CO32
4
(E) Fe2 Fe3e FeSO4 10.150.50.75

[] 0.1 M


(A) K2Cr2O7 (B) KMnO4 (C) Ce(SO4)2 (D) H2O2 Fe2 e mol e mol0.1Vn
1

V n
n
(A) n6(B) n5(C) n2(D) n2
 5 207

3
0.15 M 30.0 mL 45.0 mL
25.0 mL 25.0 mL
M
(A) 0.01 (B) 0.02 (C) 0.05 (D) 0.01 (E) 0.1

[]
30.0 45.0
0.15 CM1 2 CM10.05M
1000 1000
25.0 25.0
0.05 2CM2 5
1000 1000
CM20.02M

[] 20 mL NaHSO3(aq) 50 mL 0.02 N Ba(OH)2(aq) NaHSO3(aq) 30 mL

KMnO4(aq) 80 mL
(1) NaHSO3 Ba(OH)2
(1) NaHSO3 M CM20 mL10.0250 mLCM0.1M

(2) NaHSO3 e molKMnO4 e mol
(2) KMnO4 M 0.1302CM'805

(1) 0.1 M(2) 0.015 M CM'0.015 M

4
4
1.30 g Cr2O72 40.0 mL 2.15 M Fe2 Cr3
Fe2 80.0 mL 0.200 M MnO4 Fe3
(1) Fe2 Cr2O72 MnO4
(2) Cr2O72 Fe2 mol
(3)
(4) Cr52.0 81.

[] (1) MnO45 Fe28 H Mn25 Fe34 H2OCr2O726 Fe214 H 2 Cr3

6 Fe37 H2O(2) 0.08 mol(3) 2.0103 mol(4) 8.0

(2) 0.20580.01030.080 mol

(3)Cr2O72mol62.15140.00.200580.0103
Cr2O72mol1.0103 mol2.0103 mol
2.010352.0
(4) 1.30 100 8.0

[] 5 mL 0.015 M KMnO4 5 mL MnO4

0.10 M 2.5 mL
1 L gSn119Cl35.5S32
(A) 11.9 (B) 5.38 (C) 2.38 (D) 2.69 (E) 3.58

5 2.5 5
CM 20.10 10.015 5
1000 1000 1000
12.5 12.5
CM 12152.69g
1000 1000
208 ()

5
K2Cr2O7 3 g KI
0.40 M Na2S2O3 30.0 mL

[] 19.6
14 HCr2O726 e 2 Cr37 H2O

2 S2O32 S4O62 2 e
3C6 3
294 0.40130.010 C19.6

[] KMnO4(aq) 30.0 mL KI KMnO4(aq) Mn2

0.05 M Na2S2O3 I2 45.0 mL KMnO4 M

(A) 0.15 (B) 0.075 (C) 0.03 (D) 0.015 (D) KMnO4 e molNa2S2O3 e mol
CM30 mL50.05451

CM0.015

6

86.
(A) HNO3 (B) HCl (C) H2SO4 (D)(COOH)2

[]
(A) HNO3 4 HNO33 e 2 H2ONO2
(B) HCl 2 Cl Cl22 e
(C) H2SO4 H
(D) H2C2O4 C2O42 2 CO22 e
 5 209

*

( ) 1. 0.1 M KMnO4 KMnO4

(A) H2O2 (B) C2H5OH (C) FeSO4 (D) H2C2O4

1. (A) H2O2 O22 e (B) C2H5OH CH3COOH4 e

(C) Fe2 Fe3 e (D) H2C2O4 CO22 e

( ) 2. 5 Fe2MnO48 H 5 Fe3Mn24 H2O KMnO4

5 KMnO4158
(A) 158 (B) 52.7 (C) 31.6 (D) 22.6 (E) 11.3
x
2. x KMnO4 5 5 x158
158

( ) 3. NaHC2O4 20 mL 0.1 M KMnO4

20 mL 20 mL 0.1 M NaOH(aq) mL
3. 1 22

(A) 20 (B) 25 (C) 50 (D) 75 (E) 100

HC2O4 MnO4 H CO2Mn2 H2O
3 4

HC2O4 MnO4
20 20
2CM 50.1
1000 1000
CM0.25M

HC2O4 OH H2OC2O42

HC2O4 NaOH
20 x
10.25 10.1 x50mL
1000 1000
( ) 4. KNO2(aq) 25 mL 50 mL 0.020 M KMnO4 4.8 mL

0.10 M FeSO4(aq) KNO2 M 4. NO2 NO3 2 e
CM2520.14.81
(A) 0.09 (B) 0.10 (C) 0.90 (D) 0.20 (E) 0.01 0.020505
CM0.09M

( ) 5.
(A) (B) (C)
(D) H (E)

5. KMnO4
210 ()
( ) 6.

(A) (B) 100
(C) (D)
(E) 2 5
2 5 99.
6. (A)(B) 6080 (C) KMnO4 (E) 10 mol CO2

*( ) 7. 1 M 100 mL H2O2 KMnO4 1 M 100 mL H2O2

MnO2
(A) KMnO4 MnO2 (B) 0.5
(C) 10 (D)
(E)

7. 5 H2O22 MnO4 6 H 5 O22 Mn2 8 H2O1 mol H2O2 1 mol O2
MnO2
2 H2O2 O22 H2O1 mol H2O2 0.5 mol O2
(B) 2

*( ) 8. 0.4 M 1 0.3 M KMnO4 0.5

KMnO4
(A) Na2SO4 (B) H2O2 (C) Ca(OH)2 (D) FeSO4 (E) BaCl2
8. KMnO4 n
0.4110 3n0.30.510 35n1.875 n 1.875 KMnO4

(A) Na2SO4 (B) H2O2 O2 2(C) Ca(OH)2 (D) Fe2 Fe3

1(E) 2 Cl Cl2 2

9. FeSO47 H2O


100 mL250 mL100 mL250 mL


1. 4.00 100 mL
2. 1 50 mL 3.0 M 30 mL

3. 0.05 M
28.25 mL
4.
48.25 mL
97.
 5 211
(1)
(2) 4
(3) 4
(4)

(1) (2)
(3) 5 Fe2MnO4 8 H 5 Fe3Mn24 H2O(4) 14

9. (2) KMnO4 Fe2

(4) 5 Fe2 MnO4 8 H 5 Fe3 Mn2 4 H2O
X
0.05M0.02 51 X0.279 50 mL Fe2
55.8
0.2792
100 13.95 14
4

( ) 1. XO X2O3 0.0150 K2Cr2O7 0.020 XO4
XO
(A) 0.0050 (B) 0.0100 (C) 0.0120 (D) 0.0150 (E) 0.0200

1. a X2O3 2a XO4

XO XO4 0.0202a XO 0.0202a
XO X2O3 K2Cr2O7
0.0202a5a80.01506
a0.0050
XO 0.02020.00500.010

*( ) 2. KMnO4 20 mL KI
0.1 M Na2S2O3 Na2S2O3 50 mL

(A) (B) KI (C) KI
(D) KMnO4 0.05 M (E) KMnO4 0.1 M
2. (A)
(B) KI
(D)(E) KMnO4 x M
KMnO4 I2 Na2S2O3
x2010 350.15010 31 x0.05M

212 ()

5-3

1 p.234

1.
2.
(1)
(2)
(3) U
KNO3NaNO3


1.0 M
1.0 M


Zn(s) Zn2(aq)2 e
Cu2(aq)2 e Cu(s)
Zn(s)Cu2(aq) Zn2(aq)Cu(s)

3.
(1)
(2)
2 2

Zn(s)Zn (aq)Cu (aq)Cu(s)

1

(A)
(B)
(C)
(D)
(E)

[]
(A)
(B)Zn Zn Zn22 e Zn
(C) Zn Cu
(D) Cu22 e Cu
(E) Zn
 5 213
2 2
[] 1. ZnZn Cu Cu

1. AgNO3 Ag
(A) NaNO3(aq) (B) KNO3(aq) (C) NH4NO3(aq) (D) AgNO3(aq) 2
Zn2 Ag Zn 2 Ag

2
Cu2 Ag Cu 2 Ag
2. Y X
(A) (B) (C) (D) (E)
X Cu Ag Zn Pb Cu
Y Fe Mg Ag Cu Ag

X Y XH2Y

2 p.236

1. reduction potentialE
V
Xn n e X ERaV EXn XaV




Y Yn n e EObV EYYn bV
2.
(1)
25
1 M 105 Pa 1 atm
E
(2) S.H.E. 0 V
2 H(aq)2 e H2(g) E0 V
(3)


0.34 V

0.34 VECu2(aq)Cu(s)0 V ECu2(aq)Cu(s)0.34 V
(4)
E E E



3.


214 ()

4.
(1) 1
Zn2(aq)2 e Zn(s) E0.76 V
Zn(s) Zn2(aq)2 e E0.76 V
(2) n

Ag(aq)e Ag(s) E0.80 V
2Ag(aq)2 e 2Ag(s) E0.80 V
(3)


2
H12FE1


1 A(s) A (aq)2 e E1
2

2 A (aq) A3(aq)e E2 H21FE2
3
H33FE3


3 A(s) A (aq)3 e E3
H1 H2
2 FE11 FE2
2 E1E2
E3 F 1 F96500 C
3
(4) E
(5) E
 5 215

2

(A) EHH20.00 V (B) 1 atm
25 1 M (C)
(D)

[]
(C)

[] E0.00 75.
(A) (B) (C) (D)

3

O22 H2 e H2O2 E0.68 V
MnO4 8 H 5 e Mn24 H2O E1.49 V

5 H2O22 MnO46 H 5 O22 Mn2 8 H2O
(A)0.81 V (B)0.42 V (C) 0.81 V (D) 0.27 V

[]
5 H2O2 O22 H2 e E0.68 V
) 2 MnO48 H5e Mn24 H2O E1.49 V
5 H2O22 MnO46 H 5 O22 Mn28 H2O E0.681.490.81V

[] Au Au33e E1.42 2 Cl Cl22 e

E1.36 2 Au3 Cl2 2Au36 Cl
80.
(A) 1.24 (B)1.54 (C)0.21 (D)0.06


2 Au3 Cl2 2 Au3 6 Cl

E1.421.360.06V
216 ()

4
ZnAg E1.4 VZnCu2 E1.1 V
(1) CuAg E V
(2) Ag e Ag 0 Cu Cu22 e E

V
2
(3) (2) ZnCu E V

[] (1) 0.3(2) 0.3(3) 1.1

(1) ECuAgEZnAgEZnCu21.41.10.3V
(2) Age Ag E0.0 ECuAg
Cu Cu22 e Ex
Age Ag E0
2
Cu2 Ag Cu 2 Ag E0.3x00.3 x0.3
(3) EZnCu2

[] 1. EPbPb20.13 VECuCu20.34 V
1.0 V ECuPb2

(A) 1.47 V (B) 0.47 V (C) 0.63 V (D)0.47 V (E)0.63 V

E

ECuPb2 0.340.130.47V

3 p.236

1.
(1)

1

F2Cl2Br2I2 F2Cl2Br2I2

2


I Br Cl F IBrClF
(2)

1 E 0

2 E 0

2. 25 1 M1 atm

(1)
(2)
(3) E
 5 217

5
XY XYZY WX WX
(A)XY (B)ZY (C)WX (D)WZ

[]
XYYZWXWXYZ
WXYZ

[] 1.
() 2 H2S3 O2 2 H2O2 SO2 () 4 HIO2 2 I22 H2O
() 2 Br22 H2O 4 HBrO2 () I2H2S 2 HIS

(A) (B) (C) (D) 1. () O2SO2() O2I2() Br2O2() I2S
Br2O2I2S


Au3(aq)3 K E4.43 V

2. Au3K (aq) 76.
3 3
(A) Au K (B) K (aq) Au (aq) (C)Au (aq) K (aq)

(D)


2. E0 KAuAu3 K

6
Fe22 e Fe(s) E0.44 Fe3e Fe2
E0.77 Cl2(g)2 e 2 Cl E1.36 Fe2 Fe3
1 M 1
(A) Fe2 Cl2 Fe3 (B) Fe3 Cl2 Fe2 (C) Fe3 Cl2 Fe(s) (D) Fe2
Cl2 Fe(s)

[]
Cl2Fe3Fe2

[] 1. Fe Fe22 e E0.44 V
2 3
Fe Fe e E0.77 V

(A) 0.44 V (B) 0.77 V
(C) 0.04 V (D) 1.21 V
2

1. FeH2Fe
E00.770.77
2.
O24 H4 e 2 H2O E1.2 X4e X3 E0.6
X3e X2 E0.1 X22 e X E1.0 2 M
X2 2 M H

(A) X3 (B) X4 (C) X (D) H2 (E) O2 2. 2 M X2 2 M H

H 2 H 2 e H2 E0.0 V

2 2
X X X e 3
E0.1 V
2 3
2 X 2 H H22 X E0.1 V0
218 ()

7

2 S2O32 S4O622 e E0.17 V

2 I I22 e E0.535 V
2
2 SO4 S2O822 e E2.05 V

(A)S4O62I2S2O82 (B)S2O32ISO42 (C) 2 IS4O62 I2
S2O32 (D) 2 IS2O82 I2SO42 (E)
E(C)(D)

[]
(A) S2O82I2S4O62(C)0.5350.170 (E) E

[] 1. Np3 Np4e E0.147 V

4 E
Np 2 H2O NpO24 He E0.75 V
Ag e Ag 0.80 V
E
I22 e 2 I 0.53 V
Np3 Np4 Np4 NpO2 2
Cu 2 e Cu 0.34 V

Ni22 e Ni 0.25 V
(A) Ag (B) I2 (C) Cu2 (D) Ni2 (E) Fe2 2
Fe 2 e Fe 0.44 V

1. 0.147E0.75

I2 Cu2

2.
(A) (B)
(C) (D)


2. (C)

10
 5 219

8
Zn | Zn21 M|| Ag1 M| Ag
(1)
(2) Na2S (2)(7)
(3)
(4) NH3
(5) NaCl
(6)
(7)

[] (1) Zn2 Ag 2 AgZn2(2) (3) (4) (5)(6)(7)

(2) ZnS [Zn2 ]E
(3)E

(4) Zn(NH3)42[Zn2 ]E
(5) AgCl E
(6) 0
(7)TE

[] CuAg
(A) (B) (C) NaCl(s)
(D) AgNO3(s) (E)
(A)
(B)


(C) Ag e Ag AgCl [Ag ]

(D) Ag e Ag Ag [Ag ]

(E) Cu2 Ag Cu2 2 Ag

1.
2.
(1)

1 EE 1E 2

ZnFe2 CuAg



ZnZn Zn22 e E0.76 V
2
FeFe 2 e Fe E0.44 V
2
CuCu Cu 2 e E0.34 V

AgAg e Ag E0.8 V
2
ZnFe 0.760.440.32 V
CuAg0.340.80.46 V
0.320.460.78 V
220 ()
(2)

1 EE 1E 2

ZnAg NiCu2



ZnZn Zn22 e E0.76 V
2
NiNi 2 e Ni E0.25 V
2
CuCu Cu 2 e E0.34 V

AgAg e Ag E0.8 V

ZnAg0.760.81.56 V
NiCu20.250.340.59 V
1.560.590.97 V
(3)
ABCD WXYZ WXYZ
ABCD
4 4!
C2 6
(4-2) ! 2!

AB CD

1 EWXYZWXYZ

2 E|WXYZ|| WXYZ |

AC BD

3 EWYXZWXYZ

4 E|WYXZ|| WXYZ |

AD BC

5 EWZXYWXYZ

6 E|WZXY|| WXYZ |

WXYZWXYZWXYZ
(a)
EWZXY
(b)AC BD AB CD
EWYXZ
 5 221

9
EZn2Zn0.76 VENi2Ni0.25 V
ECu2Cu0.34 VEAgAg0.80 V

(1)
(2) A
(3) C
(4) C KCl(s)
(5) 50

[] (1) 0.05(2) Zn Zn22 e(3) Ag Age(4) (5)

(1) E0.760.340.250.800.05V(2) ZnCu2 NiAg
(3) C (4) Ag Ag
e AgCl AgCl(s) [Ag] E (5)

[] Zn22 e Zn E0.76 V
Co22 e Co E0.28 V
2
Cu 2 e Cu E0.34 V
1 MH2 1 atm

79.

(A)ZnZn2H2HCuCu2CoCo2
(B)ZnZn2CuCu2H2HCoCo2
(C)ZnZn2CoCo2CuCu2H2H
(D)ZnZn2H2HCoCo2CuCu2

ZnCoH2Cu
ZnCo H2Cu
222 ()

5 () p.239

1.
(1)
G. Leclanche18391882
(2)


(3)

Zn(s) Zn2(aq)2 e

2 NH4(aq)2 e 2 NH3(g)H2(g)
2 MnO2(s)H2(g) Mn2O3(s)H2O(l)
Zn2 (aq)2

NH3(g)2 Cl (aq) [Zn(NH3)2Cl2](aq)
2 MnO2(s)2 NH4Cl(aq)Zn(s) Mn2O3(s)[Zn(NH3)2Cl2](aq)H2O(l)

1

(4)

1

2 1.5 V

2.

3.
(1) 30
(2)
Pb(s)SO42(aq) PbSO4(s)2 e
PbO2(s)4 H(aq)SO42(aq)2 e PbSO4(s)2 H2O(l)

PbO2(s)Pb(s)2 H2SO4(aq) 2 PbSO4(s)2 H2O(l)

 5 223
(3)
PbO2(s)Pb(s)2 H2SO4(aq) 2 PbSO4(s)2 H2O(l)
F96500 1
2 mol

1 Pb1 molPbO21 molH2SO4 2 mol

2 PbSO4 2 molH2O 2 mol

PbSO4Pb96
PbSO4PbO264
196 36 160
(4)

1 2.0 36 612

2 Pb PbSO4PbO2 PbSO4[H2SO4]

10

(A) (B) Zn Zn22 e (C) MnO2NH4Cl ZnCl2
(D) (E)

[]
(A)
(E) 2 MnO2H2 Mn2O3H2O

[]
95.
(A) (B) (C) (D) (E)



(C) 2 NH4 2 e 2 NH3H2 NH4 H21 0
NH4Cl (E) Zn2 MnO22 NH4Cl Zn(NH3)2Cl2MN2O3H2O
MnO2 Mn2O34 3 MnO2
224 ()

11
77.
2 4 2
(A) PbO2 (B) Pb Pb (C) SO4 (D)

[]

PbSO42 PbSO42 e Pb Pb2 PbSO4
PbO24 HSO422 e PbSO42 H2O PbO2 Pb2 PbSO4

PbPbO22 H2SO4 2 PbSO42 H2O
SO4 H2SO4 H2O
2

[]

96.
(A) (B) (C) (D)
(E) (F)

(A)(C)
(F)

12
1000 32.8 2
48250 S32Pb207PbO2239PbSO4303
(1)
(2)
(3)

[] (1) Pb(s)PbO2(s)2 H2SO4(aq) 2 PbSO4(s)2 H2O(l)(2) 48 32 (3) 25

2F
(2) PbPbO22 H2SO4 2 PbSO42 H2O
248250
x y
96500
x mol3032070.59648
y mol3032390.56432
(3) Q2 48250 96500 1
H2SO4 98 9818
10000.32898
100 25
100080
[] 1.0 Pb208
S32O16
(A) 96500 (B) 304 (C) 64 (D)
98 (E) 36 2 965002
Pb PbSO4 96

PbO2 PbSO4 64
2 H2SO4 2H2O 160
196 36
 5 225

*

( ) 1.
K Ca Na Mg Al Mn Zn Fe Pb Cu Hg Ag

(A) (B)
(C)
(D)
1. (A)
(B)
(C) 2 Na2 H2O 2 NaOHH2Mg

( ) 2. A2 B3 2 B2A2E0
C22 B2 2 B32 CE0
AC2 A22 CE0
2 D3 3 A 2 D3 A2 E0

(A) CA2D (B) DAC (C) AC2B2
(D) C2B3D3 2.

AB2 C B2 AC DA

DAC B2
3 2
B C2A D3

( ) 3. 25 1 atm 1 M

(A) CuCl2F2 (B) CuCl2Zn (C) CuCl2Ag (D) CuCl2AgNO3
3. (A) F2Cl2CuCl2F2 CuF2Cl2(B) ZnCuCuCl2Zn
ZnCl2Cu(D) CuCl22 AgNO3 Cu(NO3)22 AgCl

( ) 4.
(A) (B) (C)
(D)II
4. (A) Mg (B)AgFe(D)

( ) 5.
()
()
()
()
(A) (B) (C) (D) 5. () ZnAg() CuAg()
ZnH2() H2Cu()()

e H2CuAg
226 ()
( ) 6. ENiAg1.55 V EAlZn20.96 V ECuAg
0.46 V EAlNi21.41 V EAlCu2 V
(A) 0.32 (B) 2.50 (C) 3.42 (D) 1.46 (E) 2.92
6. EAlCu2 EAlNI2

ENiAg ECuAg
1.411.550.462.50V

( ) 7. A(s)B(s) 1 M A21 M B2
A B
EA EB
(A) EA0EB0 (B) A B (C) A21MB B21MA
(D) AB A

EAEB 7. A EAA2 EA0

B EBB2 EB0
(B) A (C)

(D) EAB2 EAEB

( ) 8.
Pb(s)2 H2SO4(aq)PbO2(s) 2 PbSO4(s)2 H2O(l) 40 H2SO4(aq)
1 1 96500

(A) 11 (B) 22 (C) 33 (D) 44
8. 1 H2SO4 98 H2SO4
80
10000.498
10033
100080

( ) 9.
Fe22 e Fe(s) E0.44V
Fe3 e Fe2

E0.77V
2
Ni 2 e Ni E0.23V
(A) 1 M Fe3 1 M Fe2 (B)
2 3
1 M Fe 1 M Fe (C) 1 M Fe3
1 M Fe2 (D) 1 M Fe3 1 M Fe2

9. Ni Ni2 2 e E0.23 V

Fe2 2 e Fe E0.44 V

Fe2 Ni Ni2 Fe E0.21 V


Ni Ni2 2 e E0.23 V
3 2
Fe e Fe E0.77 V

Ni2 Fe3 Ni2 2Fe2 E1 V

 5 227
*( )10.
Zn(s)2 H(aq) Zn2(aq)H2(g)Zn2(aq)2 e Zn(s) E0.76

2H (aq)2 e H2(g) E0.00
(A) (B) (C)
(D) pH
(E) 25 H2 1 atm[Zn2]1.0 M[H]2.0 M
93.
10. (A) Zn E0.76 VH2 E0 VZn H2

(C) E0.760(D) Zn2 H Zn2 H2

pH [H ](E) [H ] 1.0 M

*( )11. 3 100.
(A) (B)
(C) (D)
(E)
11. (C)(D)

*( )12.
(A) (B) (C) 1.5 (D)
(E)
12. (C) 2.0 (D)

*( )13.
(A) (B) (C) (D) (E) 13.

*( )14. Cr2 Cr3e E0.41 VSn2 Sn42 e E0.15 V

2 2 3
Cu Cu e E0.15 VFe Fe e E0.77 V
2
Hg Hg 2 e E0.78 V
2
SO22 H2O SO4 4 H2 e E0.17 V
SO2 14. (A) E0.410.170
3 3 4 2 2 (B) E0.770.170
(A) Cr (B) Fe (C) Sn (D) Cu (E) Hg (C) E0.150.170
(D) E0.150.170
(E) E0.780.170
228 ()
*( )15.
94.
(A) (B) (C) (D)
(E)

15. (A)2 Ag Cu Cu2 2 Ag
(B)(C)(D)
21(E)
1 mol Cu 64 g 2 mol Ag 216 g

*( )16. Cu2(aq)Zn(s) Cu(s)Zn2(aq) E1.1

83.
(A) (B) (C)
(E) Cu2 2 e CuE0.34

0 (D)
2 Cu24 e 2 CuE0.68

16. ZnCu2 Zn2 Cu

0(B) Cu2 2 e Cu Zn Zn2 2 e
(E)

( ) 1. X Y
(A) X Y Z H2SO4 (B) X Y Z CuSO4
(C) X Y Z AgNO3 (D) X Y Z
AgNO3 1. Y X (A) H2

( ) 2.
() Cu | Cu21 M|| Ag1 M| Ag () Cu | Cu21 M|| Ag0.5 M| Ag
() Cu | Cu2 0.5 M|| Ag 1 M| Ag () Cu | Cu2 0.5 M|| Ag 0.5M| Ag

(A) (B) (C) (D)
2
2. Cu2Ag Cu 2 Ag E

0.059 [Cu2 ]
E E log 2
2 [Ag ]

E [Ag ]
0.059 1
E E log
2 0.52
0.059 0.5
E E log 2
2 1
0.059 0.5 0.059 1
E E log E log
2 0.52 2 0.52
 5 229
( ) 3. M
M2(aq)e M(aq) E0.60 VM4(aq)2 e M2(aq) E0.40 V

(A)M2(aq)M4(aq) (B) M2(aq) M(aq) M4(aq)
M2(aq) (C) M4(aq)3 e M(aq) E0.07 V (D) M2(aq)
M(aq) M4(aq)

3. (A)M4 M2 (B) E

(C) M4 3 e M E 3 E20.4

10.6 E0.07 V(D) 3 M2 2 M M4
E0.60.41.00

SARS

4.5. 92.
( ) 4.

ClO(aq)H2O(l)2 e Cl(aq)2 OH(aq) E 0.89 V

O2(g)4 H (aq) 4 e 2 H2O(l) E 1.23 V
H2O2(l)2 H(aq)2 e 2 H2O(l) E 1.77 V
(A) (B) (C)
(D) (E)
4. (A) O2 H2O2 ClO

(B) H2O2(l)2 H (aq)2 e 2 H2O(l) E1.77 V
(C) 21
(E)(D)
(D)(D)

( ) 5.
400 nm

OHHe H2O E2.79 V

(A) OH (B)
(C) 3.2 eV (D)
(E)

9 C
5. (A)OH (B)1 10 m(C) Ehv


3108
34 19
4.9710 19 19
6.62610
9 4.9710 J 3.1eV1 eV1.60210 J
40010 1.60210 9

(D)(E)OH 7 OH
OH
230 ()

5-4

1 p.246

1.



2 H2O(l)2 e H2(g)2 OH(aq) E0.414 V
1
H2O 2 O22 e2 H E0.815 V

1
H2O(l) H2(g) 2 O2(g) E0.815 V0.414 V1.23 V

E0 1.23

2.

3.
(1)



1

Al2O3x H2O NaOH

CO2H
Fe2O3
NaAl(OH)4(aq) Al(OH)3

Al2O3(s)

Na3AlF6
Al2O3(l) Al O2

2 Na3AlF6 2015

Na3AlF6 1000
 5 231

3

(2)
99
Cu2O(s)C(s) 2 Cu(s)CO(g)


1

Cu(s) Cu2(aq)2 e
Cu2(aq)2 e Cu(s)
(a)

(b)
(3)

1 3

2 Cl(aq) Cl2(g)2 e
2 H2O(l)2 e H2(g)2 OH(aq)
2 H2O(l)2 Cl(aq) H2(g)2 OH(aq)Cl2(g)
2 H2O(l)2 NaCl(aq) H2(g)2 NaOH(aq)Cl2(g)
232 ()

2

OH

(1)

H2(g)Cl2(g)
2 HCl(g)

(2)

Cl2(g)2 OH (aq) ClO (aq)Cl (aq)H2O(l)

4.
(1)







1 2 H2O(l) 4 H (aq)O2(g)4 e E0.815 V


2 2 I I22 e E0.53 V

2


1 2 H2O(l)2 e H2(g)2 OH (aq)E0.414 V


2 K e KE2.92 V

(2)

1 Ag CuAg

M(s) Mn(aq)n e


2 Cl Br I

Cl2Br2I22 X X22 e
3 F NO3 SO42 PO43


O2 H
1
H2O(l) 2 O2(g)2 H(aq)2 e
 5 233


1

2 Al3


H2 OH
2 H2O(l)2 e H2(g)2 OH(aq)
(3) PtAuC

1
22
Na3AlF6 1000
(1)
(2) 950

(3)
(4) 27
27.01 96500

[] (1) Al2O3(2) (3) 2 Al2O3(l) 4 Al(l)3 O2(g)(4) 51 g289500 C

(4) Al33 e Al
27 Al 1 3 396500289500
1
2 Al2O3 51

[] 81.
(A) (B) (C) (D)


(A)(B) Al2O3
234 ()

2


(A) HCl
(B) H2 Cl2
(C)
(D)

[]
(A) NaOH(B) Cl2 OH(C) Cl2

[] 1.
(A) NaCl
(B)
(C)O2
(D)
(E)


2 Cl Cl22 e
1. NaCl(aq)
2 H2O2 e H22 OH
(D) H2O(g)

2. 99.95 CuSO4(aq)
(A)
(B)
(C) Cu2(aq)2 e Cu(s)
(D)

2. (B)(C) Cu Cu2 2 e
(E) (D)


 5 235

3
E
Cu Cu22 e E0.34 V
2 H2O(l) O2(g)4 H(aq)4 e E0.82 V
2
S2O822
2 SO4 e E2.05 V

H2(g)2 OH (aq) 2 H2O(l)2 e E0.41 V
2
H2SO32 H2O(l) 2 SO4 4 H (aq)2 e E0.17 V
(1) Cu CuSO4(aq)
(2) Pt CuSO4(aq)

[] (1)Cu Cu22 e Cu22 e Cu

(2)2 H2O O24 H4 e Cu22 e Cu E0.48
(1) ECuCu20.34 VEH2OO20.82 V
ESO42S2O822.05 V
Eox Cu Cu22 e Cu22 e Cu
ECu2Cu0.34 VEH2OH20.41 V
Ered
(2) 2 H2O O24 H4 e
Cu22 e Cu
|0.820.34||0.48 |0.48

[] 1.0 M X 1.0 M Y2

Xe X E0.80 VY22 e Y E0.13 V

(A) H2 (B) X (C) Y (D) O2
X e X

4
1.0 M
(A) KI NaOH (B) MgCl2 Na2SO4 (C) NaOH NaF (D) CuSO4 MgF2 (E) KBr
H2SO4

[]

(A) (B) (C) (D) (E)

KI NaOH MgCl2 Na2SO4 NaOH NaF CuSO4 MgF2 KBr H2SO4
I2 O2 Cl2 O2 O2 O2 O2 O2 Br2 O2
H2 H2 H2 H2 H2 H2 Cu H2 H2 H2

[]
93.
(A) (B) (C) (D) (E)

(A) CuSO4(aq) O2 Cu(B) AgNO3(aq) O2 Ag(C) KI(aq) I2(I3 )

H2(D) NaCl(aq) Cl2 H2(E) H2SO4(aq) O2 H2

236 ()

5
pH
(A) AgNO3 (B) NaCl (C) NaOH (D) K2SO4 (E) CuSO4

[]
H O 1 O 2 H2 e
(A) AgNO3(aq) 2
2 2
Ag e Ag

[HNO3]

2 Cl Cl22 e
(B) NaCl(aq)
2 H2O2 e H22 OH
NaOH
2 OH 1 O H O2 e
(C) NaOH(aq) 2 2 2

2 H2O2 e H22 OH

[NaOH]
H O 1 O 2 H2 e
(D) K2SO4(aq)
2
2 2
2 H2O2 e H22 OH

1.
H O 1 O 2 H2 e H2SO4NaOHNa2SO4
(E) CuSO4(aq)
2 2
2
Cu2 2 e Cu

H2O 12 O22 H2 e
AgNO3
Age Ag

2 I I22 e
KI }
2 H2O2 e H22 OH

2 I I22 e
2. KI(aq)
2 H2O2 e H22 OH
(A) I2
(B)
(C) I2 CCl4
(D) Fe(OH)3
(E)

[] 1. H2SO4NaOHNa2SO4AgNO3KI

(A) 5 (B) 4 (C) 3 (D) 2

2. 0.1 M
(A) (B) (C)
CCl4(l) CCl4 (D) FeCl3(aq)
(E)


 5 237

2 p.251

1.
(1) W


QIt

(2) M
n
2. WQM
n
W Q
n M F

F
96500 Cmol

6
10.0 96.5 15.6
1 96500 Cr52.0 89.
(A)2 (B)3 (C)4 (D)6

[]
Mn ne M

57900 15.6
QIt1096.56057900 96500 52/n n2

[]
93.
2 3 4
(A) Ag (B) Cu (C) Al (D) Pt


Ag 0.25 2 1
2
Cu 0.25 4 2
3
Al 0.50 6 3
4
Pt 1.00 6 4

QIt96500n n It n
It
It96500CMV n CM
V n
12 2 24 4
(A) Ag CM 8(B) Cu2 CM

16
0.251 0.25 0.252 0.25
36 3 46
(C) Al3 CM 12(D) Pt4 CM

6
0.503 0.25 14
238 ()

7
5.00 1.00 M CuSO4(aq) 500 Pt
Cu 0.635 Cu63.5
(1)
(2) pH
(3) STP
(4) [Cu2] M

[] (1) 386 (2) 1.4(3) 112 (4) 0.98 M

(1) Cu2 2 e Cu
0.635 2
63.5 1 0.02
0.02965005.00t t386
(2) 2 H2O O24 e4 H
4
nH0.02 4 0.02
0.02
[H] 0.044102M
0.5
pH2log 422 log 21.4
1
(3) 0.02 22.40.112112
4
1.000.50.01
(4) 0.98M
0.5

[] 1. 4 M
1 3.6 M Cu
Cu64 1. H2SO443.610.4
(A) 6.4 (B) 12.8 (C) 19.2 (D) 25.6 0.4 0.2 Cu
0.26412.8

2. 10 NaOH 109 STP 8.4

(A) 0.5 (B) NaOH 10.4 (C) NaOH 10 (D)
0.5 (E) 4.5


1
2. NaOH(aq) H2O(l) H2(g) 2 O2(g)
8.4
0.375
22.4
2 1
nH20.375 3 0.25nO20.375 3 0.125n2O0.25
1 2
(A) Q0.2520.5(B)0.25184.5NaOH
10910
100 10.4 (C) NaOH 1091010.9(D) 0.252
1094.5
0.5(E) 0.25184.5
 5 239

3 p.253

1.


2.

3.



KAg(CN)2(aq)

Ag(s) Ag (aq)e Ag (aq)e Ag(s)

[Ag ]
4.
(1)
electroless plating


1

RCHO(aq)2 [Ag(NH3)2](aq)3 OH(aq) RCOO(aq)2 Ag(s)4 NH3(g)2 H2O(l)

2 NaH2PO2

(a)H2PO2(aq)3 OH(aq) HPO32(aq)2 H2O(l)2 e E1.65 V
(b)Ni2(aq)2 e Ni(s) E0.257 V
(2)

8

(A) (B)
(C) (D)
(E)

[]
(A)(B)(D)

[] Cu CuSO4(aq)
(A) (B) (C) (D)
2
Cu Cu 2 e

Cu2 2 e Cu

Cu Cu

Cu2
240 ()

9

(A) (B) (C)

(D) Ag Ag

[]
(C)

*

( ) 1. 0.1 M
(A) H2SO4 (B) NaOH (C) NaCl (D) Na2SO4
1. (A)(B)(D)2 H2O 2 H2(g)O2(g)


(C) 2 NaCl2 H2O Cl2(g)2 NaOHH2(g)

( ) 2. 27 1 atm 0.5 A 32 10
mL 66.
(A) 61.5 (B) 123 (C) 615 (D) 1230
0.5( 326010 )
2. ne 0.01mol
96500

2 H2O O24 H 4 e
1 1
nO ne 0.010.0025mol
2 4 4
V
PVnRT 1 0.00250.082300
1000
V61.5mL

( ) 3.
(A) (B)
(C)| E| (D)
3. (B)
 5 241
( ) 4. 1.3

Cd(s)2 NiO(OH)(s)2 H2O(l)
Cd(OH)2(s)2 Ni(OH)2(s)

5.0 2.0
112.41
96500 97.
(A) 0.6 (B) 1.0 (C) 1.2 (D) 2.4 (E) 3.6
It
4. moln
96500
2x6060 5
x 2 x1.2 hr
96500 112.4

( ) 5.
1 1 1
5. 632
1 2 3
(A) 321 (B) 631 (C) 123 (D) 632

( ) 6. pH
(A) H2SO4 (B) NaCl (C) Na2SO4 (D) NaI 6. (A)[H2SO4]pH

( ) 7.
(A) (B) (C) (D)


2 2 2
Ni (aq) Ni (aq) Cu (aq) Cu2(aq)

7. Ni2 (aq) Ni

( ) 8. 2.0 M
1.6 O
16S32Cu64 77.
(A) 9650 (B) 4825 (C) 2412 (D) 1206 2 Q
8. Cu2 2 e Cu
1 1.6
( )
64
Q0.050.05965004825
242 ()
( ) 9.
Mn22 e Mn E1.18 V 9. Eox Ered

2I I22 e

2 H2O2 e H22 OH E0.83 V 2 H2O2 e

H22 OH

2 H2O2 I I2H22 OH
I22 e 2 I E0.53 V

O24 H 4 e 2 H2O E1.23 V
MnI2
(A) MnI2 (B) MnO2 (C) H2I2 (D) H2O2 (E) MnH2

( )10.
96500 88.
(A) 11 (B) 10.5 (C) 0.50.5 (D) 0.50.25
1 1
10. H2O(l) H2 O2 1 1
2 2
96500 1
2 H2 0.5O2 0.5
296500 2
0.25
( )11.
PbSO42 PbSO42 ePbO2SO424 H2 e PbSO42 H2O
CuSO4 0.635 CuCu
63.5
(A) O2 STP 0.224 (B) 0.635 (C)
0.01 (D) 0.01 (E) 1
2
965 Cu 2 e Cu
11. CuSO4(aq) nCu2nO
2 H2O O24 H 4 e 2
0.635 0.01
(A) 20.02 O2 22.4
63.5 2
0.112(B) Cu0.635 (D) H2SO40.02

*( )12. 81.
(A) (B) FeCl3
(C) (D) (E)


12.2 I I22 e I2I I3

2 H2O2 e 2 OH H2 (A)(B) Fe3 I2 2 Fe3 2 I 2 Fe2 I2 I2

KI(aq)(C)(D) I3 I2I I3

(E) K I
 5 243
*( )13.
(A) F Y X A (B) A (C) C
(D) D (E) E
13.


A Zn ZN2 2 e
2
B Cu 2 e Cu
1
C H2O O22 H 2 e
2

D 2 e 2 H2O H22 OH
2
E PbSO4 PbSO42 e

F PbO22 e 4 H SO42 PbSO42 H2O
A BEF
CD
A X Y F F
Y X A

*( )14. H2(g)
(A) NaCl(l) (B) NaCl(aq) (C) NaOH(l) (D) NaH(l) (E) NaNO3(aq)

14. (A)(C)(D) Na e Na

pH
15.16. 93.
pH 2 7 8 10

*( )15.

(A) (B) (C) (D)

15. 2 H2O2 e 2 OH H2
pH7pH10

2 H2O 4 e 4 H O2
pH7pH2
244 ()
*( )16.




(A) (B) (C) (D) (E)
16.

2 H2O 4 e 4 H O2


2 H2O2 e 2 OH H2
pH7pH10

*( )17. 22

Al27.01 96500
(A) (B) Al2O3 (C)
2 Al2O3(l) 4 Al3 O2 (D) 27
51 (E)(D) 289500
1 1 27
17. (D)Al2O3 Al 0.5 1020.5 51
2 2 27
3
(E) Al 3 e Al 3Al 3 965003 289500

18.

(1)
(2) A

(3) A


(1) 2 H2O2 e 2 OH H2 (2) (3) Cl2 H2O HOClHCl

18. (1) Na

(2) 2 Cl Cl22 e
(3) HOCl
 5 245
19.

E
2
Ca (aq)2 e Ca(s) 2.76
2 H2O(l)2 e H2(g)2 OH(aq) 0.83

MnO4 (aq)2 H2O(l)3 e MnO2(s)4 OH (aq) 0.58
3 2
Fe (aq)e Fe (aq) 0.77
Cr2O72(aq)14 3

H (aq)6 e 2 Cr (aq)7 H2O(l) 1.33
Cl2(g)2 e 2 Cl(aq) 1.36
2
MnO4 (aq)8 H (aq)5 e Mn (aq)4 H2O(l) 1.49
(1)
(2) CaCl2
(3)
(4) 84.

(1) Ca(2) H2(3) (4) 0 19. (1)

(2) Ca2 2.76H2O0.83
H2O H2

*( ) 1. NaOH(aq) KI(aq)ABC
D Pt 10 10 NaOH(aq)
2 1 M KI(aq) 25 1 atm 32
10 10A
(A) B C (B)
19.2 (C) NaOH(aq) 9.8 (D)
pH 13
(E) AB C 6.125

( ) 2. NaOH(aq) 5 100
10 NaOH(aq) 100 t NaOH(aq) 11
t NaOH401 96500 26.8
NaOH10
(A) 54.2 (B) 27.1 (C) 10.8 (D) 5.40 2. 10 100
H2O90
1. (A) Pb PbO2 CB 11 NaOH 10
(B)0.1969.6 10 1000

2e 1 11 11
(C) H2O H2 O2
2 1000 100
0.1 0.2 100
11 11
1 193010 2e
1
NaOH

12 e mol 0.2 H2O H2 O2
101.8 96500 2
0.12 2 1 It2

(D) 2 H2O2 e H22 OH [OH ] 0.1 M 100
2
pH13(E) 0.25 mol 6.125 11
5t3600 296500 t5.40
18
246 ()

p.29

1.

2. e e
3.
A.
(1) 0.050 M

(2)
(3) 25.0 mLVR()
(4) 2 M 30 mL 50 mL
70 90 ()
(5)
()

() () ()
B.
(1) 0.01 g
(2) 2 M 30 mL 50 mL
(3)

(4) (2)(3)
(5) Fe55.9

1

(A) (B)
(C)
25 (D)

[]
(C)
 5 247

( ) 1. Fe2 0.1 M KMnO4 0.1 M K2Cr2O7
X Y X Y
86.
5 3 6 5 1. 1MV50.1X1MV60.1Y
(A) 3 (B) 5 (C) 5 (D) 6 X 6

Y 5

( ) 2.
(A)
(B)
(C)
(D) MnO2 Fe2O3

2. (A)(B)(D) Mn2 Fe3

( ) 3. 100.0 g 100 mL Fe2 10 mL

0.10 M KMnO4 KMnO4 40 mL
Fe56
(A) 12.5 (B) 15.8 (C) 8.4 (D) 11.2
1
Fe2

Fe3

3. 5
MnO4 MN
2

x 10
x Fe100 0.1x
100 100
0.1x 40
0.15 x11.2
56 1000
1

4. 0.201 Na2C2O4134
KMnO4 83.
(1) 19.6 mL KMnO4 KMnO4 KMnO4
158
(2) 0.105 FeSO4 KMnO4 mL

(1) 0.03 M(2) 700 mL 0.201
4. (1) nmolnMV2 5M19.610 3 M0.03
134

(2) nmolnMVFe2 Fe3 n110.10550.03V
V0.7L700 mL
248 ()

p.37

1.
2.
(1)

(2)
(3)

(4)
CHO

RCHO(aq)2 [Ag(NH3)2]2(aq)3 OH(aq) RCOO(aq)2 Ag(s)4 NH3(g)2 H2O(l)

[Ag(NH3)2]
3.
A.
(1) 3.5 100 mL 50 mL 2.5 g

(2)
(3) 20
(4)
(5)

B.
(1) 100 mL 90
(2) 1 mL

(3)

(4) 90



 5 249

*

( ) 1. Cu2()Ag() Ni2()
Cu63.5
Ag107.9Ni58.7 72.
(A) (B) (C) (D)
W 1t n
1. n t
M 96500 M
2 1 2
() () ()
63.5 108 58.7

*( ) 2. Cu63.55Zn
65.39
(A)
(B)
(C)
(D)
(E)
2. (A)(B)
(D)

*( ) 3.
(A) (B)
(C) (D)
(E)
3. (A)(B) Ag2O

*( ) 4.

(A)
(B)
(C) P
(D)
(E) 4. (C) P Q
(E)
250 ()

( ) 1. KMnO4
71.
(A) (B) (C) (D) 1. (C) KMnO4

( ) 2. 0.1 M 2 mL 0.1 M
5 mL

93.
(A) (B) (C)
(D) (E)


2. (1) Cu2 2 I CuI2 (2) 2 Cu2 2 I 2 Cu I2
(1)(A)(B)

CuI(C) I2I I3
(D) I2 (E) I2

I I3 I2I I3

( ) 3. ZnAg 1.56 ZnCu 1.10

Cu2(aq)2 e Cu(s)E0.00 Ag(aq)e Ag(s) E
95.
(A) 0.23 (B) 0.46 (C) 0.80 (D) 1.10 (E) 1.56
3. EZnEAg1.56EZnECu1.10 ECu0 EAg0.46
EAg0.46

( ) 4. 2.0 M Au(NO3)3

93.
(A) (B) (C) (D)
(E)
4. 2 H2O O24 H 4 e

Au3 3e Au
 5 251
( ) 5.

CO2H2O 99.
(A) 11 (B) 12 (C) 13 (D) 23 (E) 31

5. CH3OHH2O CO26 H 6 e
1 4 e 4 H O2 2 H2O
2

23 e H2O mol 13
1 2

( ) 6. 99.
(A) (B) (C)
(D)
(E)
6. (B)
(C)(D)(E)

( ) 7.
100.
(A) HF (B) HNO3 (C) HClO4 (D) H2SO4 (E) H2S2O3
7. (A) HF (B)(C)
(E) KMnO4

( ) 8. 6 1
1

6 CLie
LiC6

3.0 0.30

(A) 14 (B) 2.4 (C) 1.5 (D) 0.24 (E) 0.15 100.
W 336000.3
8. C mole mol 61 W2.4
12 96500

( ) 9. NO3(aq)N2(g)MnO2(s) 101.

NO3 (aq)4 H (aq)3 e NO(g)2 H2O(l) E0.96 V

N2(g)5 H (aq)4 e N2H5 (aq) E0.23 V
Mn2(aq)2

MnO2(g)4 H (aq)4 e H2O(l) E1.23 V

(A) MnO2(s)N2(g)NO3(aq) (B) N2(g)
NO3(aq)MnO2(s) (C) N2H5(aq)NO(g)Mn2(aq) (D)
Mn2(aq)NO(g)N2H5(aq) (E) NO(g)N2H5(aq)
Mn2(aq)
9.


(1) NO3 N2MnO2 Ered 0.96V0.23V1.23V MnO2NO3
2
N2(2)(1) N2H5 NOMn
252 ()
( )10. Cu | CuSO41.0 M
0.46 Zn | ZnSO41.0 M 1.56
103.


Zn2 (aq)2e Zn(s) 0.76

Cu2 (aq)2e Cu(s) 0.34
H21.0 atm| HCl1.0 M

(A) 1.10 (B) 0.80 (C) 0.76 (D) 0.42 (E) 0.34
10.

(1)Cu n Cu E0.46x0.34 x0.80

(2)Zn n Zn E1.56x0.76 x0.80
n
(3)H2 H2 E0.800.800.00

( )11.
(1)ATiO2 A (2)
I3I(3)
1ATiO2 A*TiO2

2A*TiO2 ATiO2e

3I3 2 e 3 I
42ATiO23 I 2ATiO2I3
103.
(A) (B)
(C) 1 (D) 3
(E)
11. (C) 1 (E)

( )12. X Y Cl
XY Cl2 X Cl2Y Cl22X Cl2 2X Cl3 Y2X Cl3 YCl22X Cl2


(A) XCl3 (B) XCl2 (C) Cl2 (D) Y (E) YCl2 98.
XYCl2 XCl2Y
12.
X0 2YCl2XCl2
Cl22 XCl2 2 XCl3 Y2 XCl3 YCl22 XCl2
XCl2 2 3 Y 0
Cl2XCl3 2XCl3XCl2
 5 253
( )13. C176
C 0.200 M 1.76 g C
50.00
C
C 101.
(A) (B) (C)

(D) (E)

13.
C

V I2 I 2
1.76 50.00
V0.200 2V2
176 1000
2
C OH 1

2 OH
2 OH 2

*( )14.

95.
(A) (B)
(C) (D)
(E)
14. (A)(B)
(E)

*( )15. 1 M

95.
(A) 0.1 M Na2SO4 (B) 3 M (C)
3 M (D) 3 M (E)

15. (A)Zn(s) Zn2 (aq)2 e (B) Zn2 OH 2 H2O Zn(OH)42 H2(C)(D) Zn(s)2 H (aq)

H2(g)Zn2 (aq)(E)
254 ()
*( )16. U
0.1 M
2 101.
(A) (B) (C)
(D) 2
(E) 2
1 5

16.(A)(C)H2 OH (E) I2

*( )17. 16O 18O

2 FeO24 H218O 2 Fe(18OH)22 H2O
97.
(A) (B)
(C) (D) (E)
17. H218O 18O Fe
Fe(18OH)2 H218O H2O

40


O2(g)4 H(aq)4 e 2 H2O(l) E1.23
CO2(g)8 H(aq)8e CH4(g)2 H2O(l) E0.17
2 H(aq)2 e H2(g) E0.0
WnFE W F
96500 En 1
18.19. 96.
*( )18.
(A) 1.0 2.0 (B)
1.40 (C) 1.23 (D) 1.0
W409 (E) 1.0
W237 18. P.257
 5 255
W
*( )19. H
H
286 890

(A) (B) 83
(C) 92 (D)
90 (E)
W 237 W 818
19.(B) 83(C)
H 286 H 890
W
92(D) 90(E)
H

*( )20. 0.095 g FeSO4 152 20

0.5 M 0.001 M KMnO4 25.00
KMnO4
MnO4(aq)5 Fe2(aq)8 H(aq) Mn2(aq)5 Fe3(aq)4 H2O(l)

101.
3 2 2
(A)[Fe ] 5[Mn ] (B)[Fe ] 5[MnO4 ] (C)
20 (D)()
(E) 1 M HCl(aq)

20.MnO4 Fe2 15
0.095x
0.00125.0010 35

1 x20.0
150
(A)

[Fe3 ]5 [Mn2 ](B) Fe2 0 M(D) H2SO4

H (E) HCl(aq) Cl MnO4

*( )21. Na2S2O3
Na2S2O3x Cl2y H2O 2 NaHSO4z HCl
xy z 102.
(A) z2x (B) xyz (C) Cl2 (D) S 2 4 (E)
21.Na2S2O3Cl2
Na2S2O3(aq)4 Cl2(g)5 H2O(l) 2 NaHSO4(aq)8 HCl(aq)
x4y5z8Na2S2O3 Cl2

(A) z2x8(B) Cl2 Cl (D) Na2S2O3 2
NaHSO4 6(E)
256 ()

*( )22. Zn(s) | Zn2+(aq)Ag+(aq) | Ag(s)

104.
(A) Zn(s)2 Ag+(aq) Zn2+(aq)2 Ag(s) (B)
(C) (D) Ag+
Ag Ag+(aq) |Ag(s) (E)

22.(A)(B)(D)

(C)(E)

23. WXYZ X Y
Z

1 W

2 78

3 WXY Q

4 Q 6 42 82

5 Z2


6 Z2 Z Z3

(1) W Z
(2) X Y
(3) Q
(4) 0.1 M Z3 0.1 M Q
104.
(1) 1H53I(2) SO2SO3(3) H2SO3
(4) I3 I2I I2H2SO3H2O 2 ISO424 H+
I3H2SO3H2O 3ISO424 H+

23.(1) W 1 3 1HZ 5 53I

(2) X X Y 2 781HXY53I78 XY24 xX(x+8) Y24XY

x 8 2644 24xx824 x8 X 8O
Y 16S SO2SO3
(3) 3 WXY HOS Q H2SO382H2SO498 4 Q 6

42 82 H2SO3
2 I3 H2SO3H2O 3 I SO42 4H+

(4) 1 I3 2 I2H2SO3H2O 2 I SO42 4 H+
I2I 1
 5 257

1M



Cl(AgCl)
92.

AgCl(s)e Ag(s)Cl (aq) E0.22 V
2
Cu (aq)e Cu (aq) E0.15 V

Cl(AgCl)e Cl (aq) E3.80 V

Cu (aq)e Cu(s) E0.52 V
Ag(aq)e Ag(s) E0.79 V
1.2.
( ) 1.
(A) (B) (C) (D) Cu2
(E) A B
1. AgCl
3.8 V0.15 V

Cl(AgCl)Cu Cl Cu2 E3.65 V0 Ag

AgCl Cu Cu2 B A

( ) 2.


(A) AgCl AgCl (B) AgCu AgCu (C) ClCu ClCu2
(D) AgCu2Cl AgClCu (E) AgCl2 Cu AgClCu2Cu

2.

AgClCu Cu2 AgCl

Ag AgCl

(A) AgCl Ag Cl Ag

(B) AgCu Ag Cu E0.27 V

(C) ClCu Cl Cu2 Cl

(E) AgCl2 Cu Ag Cl Cu2 Cu Ag

18.

O2(g)4 H (aq)4 e 2 H2O(l) E1.23 1

CH4(g)2 H2O(l) CO2(g)8 H (aq)8 e E0.17 2

2 1 2 CH4(g)2 O2(g) CO2(g)2 H2O(l)

E1.230.171.06


O2(g)4 H (aq)4 e 2 H2O(l) E1.23 3

H2(g)2 H (aq) 2 e E0.0 4

3 4 2 2 H2(g)O2(g) 2 H2O(l)

E1.23
(A) 1.0 1 4.0 1 2.0 (B)
8965001.06
1.06 (C) 1.23 (D) WnFE 818
1000
2965001.23
(E) WnFE 237
1000
258 ()