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ISOTHERMAL
REACTOR
DESIGN
CHAPTER 4
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dt
Integrate X
t
kCAo 1 X
Example: Design of Batch Reactor
Additional information
Raw material: pure A
Required conversion:90 %
Operating condition:1000 K and 600 kPa
Reaction rate constant:0.9s-1
Initial concentration:10 mol/dm3
Design of CSTR
A exit
Stoichiometry C A C Ao 1 X
Combine
V
1 X
o k 1 X
Evaluate
k C Ao
X CA
1 k 1 k
= Damkohler Number
Space time ()
Is a characteristic time of a reactor
The time it takes for this fluid to enter
the reactor completely
Also called the holding time or mean
residence time
V
o
Damkohler Number (Da)
First order :
Second order :
Stoichiometry C C 1 X
A Ao
Rate law
2
rA kCA
Combine V X
o kC Ao 1 X
2
C Ao
C An
1 k n
1
X 1
1 k n
CSTRs in Parallel
V FA0
Vi , FA0i
n n
V FA0 X i
n n rAi
Example n equal sized CSTRs-
which is better configuration?
(Parallel or series)
o
1
V ln
k 1 X
Design of PFR
1st order reaction, gas phase, PFR
X
dX
MoleBalanc e, V FAo
0
rA
1 X
Stoichiome try , C A C Ao
1 X
RateLaw ,rA kCA
1 X
X
Combine, V FAo dX
0
kCAo 1 X
1 ln 1 X X
FAo 1
Integrate , V
kCAo
Another example for PFR
2nd order reaction, gas phase, PFR
X
dX
MoleBalanc e, V FAo
0
rA
1 X
Stoichiome try , C A C Ao
1 X
RateLaw , rA kCA
2
Combine, V FAo
X
1 X
2
dX
0 kCAo 1 X
2 2
Ao 2
X
2 1 ln 1 X X
1
Integrate , V 2
kCAo 1 X
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