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O.V. Makhnenko, A.S. Milenin, A.A. Polishko, S.S. Kozlitina, L.I. Dzubak
Paton Electric Welding Institute of NAS of Ukraine, Kyiv, Ukraine
1
semifinished items of unique properties for the production of critical parts of
constructions, machines and mechanisms of energy industry, transport sector,
aircraft building. Because of the fact, that ESR involves the complex of
interdependent physical processes, those, in turn, determine the current and
residual state of ingot metal, for the optimization of technological parameters it is
of appropriate to use the up-to-date means of mathematical modeling and computer
simulation. Along with the correspondent laboratory testing of model specimens it
allows to obtain the problem-oriented program means of prediction of temperature
field kinetics, phase and chemical composition, space distribution of stresses and
strains in metal with the subsequent criterion estimation of the production quality.
One of the conventional approaches of the ESR schemes classification is
way of material supply to the melting zone. Thus, in Paton Electric Welding
Institute of NAS of Ukraine the ESR method with current-carrying crystallizer and
liquid filler metal (ESR LM) has been developed (Fig. 1 a). It allows dividing the
processes of filer metal melting and formation of liquid pool on the surface of
ingot, and, as a result, getting better control of the filler metal state. Main
disadvantage of this technology is the need of additional equipment (in addition to
ESR plant itself) and corresponding increase of power-intensity and costs of
manufacture. But for some purposes, such as production of dissimilar bimetal
ingots, ESR LM could be the most appropriate approach of electroslag remelting.
More typical method of ESR process implementation is the use of
consumable electrode (ESR CE, see Fig. 1 b) for filler material supply to the mold
[3, 4]. It also could be built by the hybrid scheme with both consumable electrode
and current-carrying crystallizer (ESR CEC, see Fig. 1 c), that allows to
redistribute the input energy more uniformly and to obtain auspicious conditions of
metal structure formation, especially, in case of large diameters of ingots under
production.
Because of the high cost of experimental investigations, the use of
mathematical modeling and computer simulation of main physical and
technological processes is reasonable. This paper presents the main algorithms of
2
simplified mathematical description of the thermal processes at ESR of large scale
steel ingots, the ways of numerical assessment of quality of metal from the point of
view of its structural state and chemical composition, susceptibility to flaws
nucleation. On the basis of their computer implementation the complex of
investigations of typical physical processes at ESR LM, ESR CE and ESR CEC of
large diameter ingots has been carried out, corresponding engineering
recommendations about optimization of their technological parameters have been
formulated.
() 1 (b) (c)
Fig. 1. Typical technological schemes of electroslag remelting: a with current-
carrying crystallizer and liquid filler metal, b with consumable electrode,
c with consumable electrode and current-carrying crystallizer
1 layer of liquid slag; 2 ingot; 3 liquid pool; 4 consumable
electrode; 5 current carrying crystallizer; 6 insulator.
U ( r , b , z ) U ( r, b , z ) U ( r, b , z )
r +
r = . (1)
r r z z t
W (r , z, t ) = (T )
+ . (2)
z
r
Thus, on the basis of calculated field of volume heat source in the liquid slag
according to solution of the problem (1) (2), the correct problem of thermal
conductivity in the system slag metal technological equipment could be
solved according to the next law [5]:
T T T
l
r + l
r + r cg
W (r , z , t ) = r (3)
r r z z t
where (), c() are the thermal conductivity coefficient and heat capacity of the
material in the point (r, z).
T
= 0,
r r =0
T
-l
z ( r ,z )P
(
=a T - T ) + e (
SF T 4 - Tcp4 ) ,
D2
III is added with the volume rate p v ( t ) could be calculated with the next
4
recursive equation:
5
p D2
X ( t)
2G ( t ) - G ( t + Dt )
+ X III 4 v( t )
Dt
X ( t + Dt ) = (4)
p D2
G ( t ) - G ( t + Dt ) +
2 v( t )
Dt
4
AK+ - AK-
AK = + -
W8 5 - W8 5
(
W8+5 -
W8 5
)
+ AK- (5)
+ -
where AK+ corresponds to the value W8 5 , AK- corresponds to the value W8 5 , AK is
+ -
unknown quantity at [W8/5], W8 5 > > W8 5 .
W8 5
T
For the cooling curve < 0 for the some part of ingot under consideration
t
st e
on the basis of digitized CCT-diagram the data about the temperatures T j and T j ,
st e
mass fraction of the phase at start and end of phase transformation V j , V j could
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be determined and current mass fraction at the temperature T(t) ( T j > T ( t ) > T j )
st e
T jst - T ( t ) t stj - t st
V je
V j ( t ,T ) = + st e + V j (6)
2 T jst - T je tj -tj
T
For > 0 the next condition should be fulfilled:
t
Vj
= 0 at < 800
t (7)
V j A 0, VA = 1.0 at 800
V
volume growth rate of new phases at given temperature [8]:
t j A
V V ( t)
=- A = k(T)
VA ( t ) (8)
t j A t
where k(T) is the temperature function.
DV ( t ) = C -k ( T )
exp
( t - t0 )
(9)
7
where integration constant is determined for temperature 1 and moment of time
Analysis of state of stresses and strains of the ingot during ESR within the
framework of this investigation has been carried out on the basis of nonstationary
thermoplastisity problem solution with numerical tracing of elastic-plastic
deformations from the start of remelting up to complete cooling of the ingot.
Relation between the components of stress tensor ij and strain tensor ij is
determined with Hooke law and plastic flow associated law on the assumption of
the next expressions [9, 10]:
1
( ij - d ij m ) + d ij ( K m + De ) - ( m) + ( K
*
m ) (10)
*
De ij = Y ij - d ij
2G
n G=
1- 2 E
where K = ,
E ( 1 + n ) , E is Young modulus, is Poisson ratio, m is a
2
1
Y= , if i < T
2 G
(11)
1
Y> , if i = T
2 G
where i is a stress intensity; is a yield stress.
T ( T , V j ) = T( j ) ( T )
Vj ( T ) , (12)
j
8
where T( j ) is the yield stress of jth structure component as a temperature function.
9
12Kh13 0.15 0.22 0.22 0.05 12.2 0.01 0.03
38KhN3MFA 0.35 0.47 0.06 2.7 1.9 0.53 0.08
30CAD6-12 0.28 0.49 0.32 0.050 0.012 0.13 1.65 0.22 1.050
28NiCrMo74 0.30 0.46 0.24 0.025 0.030 2.06 1.44 0.37 0.20 0.001
30NCD12 0.30 0.40 0.30 0.016 0.015 3.20 0.86 0.40 0.17
2
2
1
() (b)
Fig. 2. Appearance () and template (b) of test bimetallic ingot (1 steel 12Kh13,
2 steel 38KhN3MFA) of the diameter D=180 mm, that has been produced
with ESR LM technology
10
Fig. 3. Temperature distribution at ESR LM of bimetallic (12Kh13 and
38KhN3MFA) ingot of the diameter D=180 mm in the transition dissimilar
region (0z is the axis of symmetry)
11
(a)
(b)
(c)
Fig. 4. Numerically assessed axial distribution of the alloying elements concentrations
C along the bimetallic (12Kh13 and 38KhN3MFA) ingot of the diameter
D=180 mm: a Ni, Cr; b C, Mo, Mn; c V, Si
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of insulator position ins, that allows raising the heat source concentrator above the
surface of the ingot and to redistribute Joule energy more uniformly. This
hypothesis has been checked with the developed software on the example of the
ESR LM of the ingot of the diameter D=700 mm. As it could be seen in Fig. 5, the
increase of ins makes the process under consideration more power-intensive, but
the liquid pool becomes more plane and its depth is sufficiently lower. This
approach gives an opportunity to optimize these parameters for ESR LM of the
ingot of the diameter D=1200 mm: as the numerical data have shown (see Fig. 6),
with ins = 300 mm, W0=6240 kW and the height of liquid slag layer about 400 mm
it is possible to achieve the melting of all end surface of the ingot and to avoid
sufficient overheating of its periphery.
(a) (b)
Fig. 5. Temperature distribution at ESR LM of bimetallic (12Kh13 and 38KhN3MFA)
ingot of the diameter D=700 mm in the transition dissimilar region (0z is the
axis of symmetry): a ins=50 mm; W0=1000 kW; b ins=110 mm;
W0=1200 kW
13
Fig. 6. Temperature distribution at ESR LM of bimetallic (12Kh13 and
38KhN3MFA) ingot of the diameter D=1200 mm in the transition dissimilar
region (0z is the axis of symmetry): ins=300 mm; W0=6240 kW
14
(a)
(b)
(c)
Fig. 7. Temperature distribution at ESR CEC of ingot of the diameter D=1200 mm
for different electrode diameters: a 1100 mm; b 550 mm; c 275 mm.
15
As it could be seen in Fig. 8 a, nonstationary regime of ESR at the start of
technological cycle is characterized with somewhat higher efficiency of ingot
formation, and with the height of the ingot more than 50 mm Q becomes near to
constant, that linearly depends on De (see Fig. 8 b).
(a) (b)
Fig. 8. Dependence of the ESR CEC production efficiency at remelting of the
ingot of diameter D=1200 mm on the current height of ingot h (a) and on
the fill factor kf (b)
16
those are an alternative to noninterruptible schemes with constant or adjustable
input power. With the use of developed numerical approach, these schemes have
been studied form the point of view of power intensity and the quality of transition
zone. As it could be seen in Table 2, the most cost-effective scheme is the one with
adjustable power, which is caused with control of heat balance through the natural
heat loss to the environment and technological accessories. But noninterruptible
schemes are characterized with sufficient depth of liquid pool (up to 320 mm, see
Fig. 10), whereas the building-up on the cold ingot allows diminishing the fusion
in this region to ~40 mm, that provides favourable conditions for metal
crystallization and phase transformations.
Less typical problem, which could be considered within the limits of
numerical analysis, is the assessment of the metal susceptibility to cold cracking.
This optimization task could be set, for example, in case of sufficient difference of
the chemical compositions of steels of dissimilar steel ingot. As a result, in
dissimilar transition zone undesirable stable and metastable phases could form and
prevent obtaining the bimetal structural elements of high exploitation capabilities.
One of the ways to ensure high quality of metal is the use of intermediate filler
metal within the limits of ESR LM technology. Adequate choice of filler material
allows achieving the gradual transition from one metal to another and guaranteeing
the absence of crack-like flaws nucleation.
It is known, that prerequisite for cold cracks nucleation in certain region of
structure is simultaneous presence of tensile stresses, martensite structures and
diffusion hydrogen [11, 12]. For typical problems of technological cycle
optimization it is sufficient to avoide one of these factors for to ensure the metal
continuity. For studying of these phenomena within the framework of this
investigation, the process of ESR of bimetal ingots (SAE2330 and 28NiCrMo74,
see Table 1) has been simulated. As the most appropriate technological
implementation, the noninterruptible scheme of ESR LM with adjustable input
power has been chosen (see corresponding line in Table 2).
17
(a) (b) (c)
Fig. 9. Temperature distribution at ESR CE of the ingot of the diameter D=800 mm at different values of consumable electrode
diameter De: a De=72 cm; b De=64 cm; c De=56 cm
18
Table 2. Technological schemes of multistep ESR of ingots of large diameter
Operation Consumed Dissimilar
Scheme Power
time energy zone length
building-up on Preheating ~40 mm
the cold ingot power 120 kW 600 sec 0.5 kilowatt-hour
with constant Remelting
power power 120 kW 2125 sec 71 kilowatt-hour
total 162.5
kilowatt-hour
building-up on Preheating ~40 mm
the cold ingot power 400 kW 175 sec 19.4 kilowatt-hour
with sufficient Remelting
power of surface power 120 kW 2125 sec 71 kilowatt-hour
preheating total 161.4
kilowatt-hour
Preheating ~40 mm
power 600 kW 137se 22.8 kilowatt-hour
Remelting
power 120 kW 2125 se 71 kilowatt-hour
total 164.8
kilowatt-hour
noninterruptible Remelting ~320 mm
schemes with power 120 kW 4275 sec 142.5 kilowatt-
constant power hour
noninterruptible Remelting ~250 mm
schemes with power 50 kW 4275 sec 59.4 kilowatt-hour
adjustable input Power at
power (cooling cooling 40 kW 438 sec 4.9 kilowatt-hour
after first step of total 135.3
remelting) kilowatt-hour
19
(a) (b) (c)
Fig. 10. Temperature field profile in the steel ingot of the diameter D=1200 mm for different schemes of ESR:
a continuous remelting with constant power 120 kW;
b continuous remelting with controlled power 4050 kW (cooling after melting of first part of ingot);
c building-up on the cold ingot with constant power 120 kW
20
Steel grades 30NCD12 and 30CAD6-12 have been considered (see Table
2) as the possible filler materials for the fusion zone. With the application of
developed finite-element algorithm for assessment of state of stresses and strains
with concomitant prediction of phase transformation kinetics, the possibility of
excess martensite in the region of tensile stresses in ingot metal has been studied.
As is shown in Fig. 11, the use of steel 30NCD12 as filler material leads to
formation of region of martensite phase that is axially tensile. So, it could be
conclude, that possibility of cold crack formation is inadmissibly high. As for
another considered filler material (see Fig. 12), the volume fraction of martensite is
too low (down to zero for the most critical parts of ingot), that means the rational
combination of technological parameters and typical physical processes in metal
from the point of view of final quality of the ingot under production.
Conclusions.
1. For the numerical analysis of ESR of homogeneous and bimetallic
ingots of large diameter complex of mathematical models and computer means of
their implementation were developed. In particular, models of electric potential
field in layer of liquid slag for different schemes of ESR (ESR LM, ESR CE, ESR
CEC) and corresponding models of temperature field kinetics were implemented.
On the basis of numerical assessed temperature field corresponding approaches of
prediction of chemical and phase composition of ingot metal as well as its current
and residual properties were fulfilled. Analysis of state of stresses and strains of the
ingot during ESR within the framework of this investigation was carried out on the
basis of finite-element solution of nonstationary thermoplastisity problem by
means of numerical tracing of elastic-plastic deformations from the start of
remelting up to complete cooling of the ingot.
2. On the basis of laboratory test ESR LM of bimetallic ingot of
D=180 mm diameter the verification of the developed approach of ESR numerical
simulation was done. Postprocessing of this bimetal ingot section and visualization
21
of the form of liquid pool in the transition dissimilar region demonstrated the
inaccuracy of calculation of about 4 %.
3. The influence of the value of fill factor kf on the liquid pool form and the
rate of ingot built-up Q at ESR CE (ESR CEC) of cylindrical ingot has been
studied. It was shown that nonstationary regime of ESR at the start of
technological cycle is characterized with somewhat higher efficiency of ingot
formation, and with the height of the ingot more than 50 mm Q becomes near to
constant, that linearly depends on kf. The change of kf at ESR CE of at ESR CEC of
ingots leads to the consequent transformations of temperature field and the form of
liquid pool, namely, in case of big value of kf the temperature field is more
homogeneous in radial direction.
4. With the use of developed numerical approach, different ESR schemes
have been studied form the point of view of power intensity and the quality of
transition zone of ingots of large scale. It was shown that the most cost-effective
scheme is the one with adjustable power, which is caused by control of heat
balance through the natural heat loss to the environment and technological
accessories. Noninterruptible schemes are characterized with sufficient depth of
liquid pool (up to 320 mm), whereas the building-up on the cold ingot allows
diminishing the fusion in this region to ~40 mm, that provides favourable
conditions for metal crystallization and phase transformations
5. The influence of intermediate filler steel grade on cold cracking
susceptibility of the ingot metal was studied by the example of ESR LM of
bimetallic ingot. It was shown that nonoptimal choice of filler material could lead
to formation of excessive volume fraction of martensite in transition dissimilar
zone, which is characterized with tensile axial stresses and, therefore, highly
susceptible to cold cracking.
22
() (b) (c)
Fig. 11. Distribution of circumferential () and axial (b) stresses and martensite volume fraction (c) in cross section of bimetal
cylindrical ingot made of steels SAE2330 and 28NiCrMo74 with filler metal 30NCD12 after ESR LM
() (b) (c)
Fig. 12. Distribution of circumferential () and axial (b) stresses and martensite volume fraction (c) in cross section of bimetal
cylindrical ingot made of steels SAE2330 and 28NiCrMo74 with filler metal 30CAD6-12 after ESR LM
23
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