1.

The ratio of radius of trigonal void to the radius of the spheres in closest packed arrangement is

1) 0.414 2) 0.155 3) 0.225 4) 0.732

2. Consider the tube of cross sectional area 1cm^2.the bottom of the tube is closed with semipermeable
membrane .1 gm of glucose is placed in it. Closed end of tube is immersed in pure water. What is the
osmotic presser at equilibrium at 25 degree Celsius? (Density may be taken 1 gm/cm^2)

1) 78.999 Kpa 2)32.77 Kpa 3) 36.7 Kpa 4)34.77Kpa

3. 5 mole of an ideal gas expand isothermally and reversibly from a pressure of 10 atm to 2 atm at 300 K.
What is the largest mass which can be lifted through a height of 1 metre in this expansion?

1)2048.46kg 2) 2000kg 3) 2500kg 4) 2100kg

4.the molal freezing point constant for water os 1.86k. molarity ^-1. If 34.2 g of cane sugar are dissolved
in 1000g of water ,the solution will freeze at

1) -1.86 C 2) 1.86 C 3) -3.92 C 4) 2.42 C

5. Calculate the amount of work done by 2 mole of an ideal gas at 298 K in reversible isothermal
expansion from 10 litre 20 litre.
1) 3434J 2)-3434.9J 3) 3434.9 J 4) 3032J

6. 1 mol of NH3 gas at 27C is expanded under adiabatic condition to make volume 8times ((gamma) =
1.33). Final temperature and work done respectively are:
(A) 160 K, 900 cal (B) 150K, 400 cal (c) 250 K, 1000 cal (D) 200 K, 800 cal

7) 50.0 mL of 0.10 M HCl is mixed with 50.0 mL of 0.10 M NaOH. The solution temperature rises by3.0C.
Calculate the enthalpy of neutralization per mole of HCl.
(A) 2.5102 kJ (B) 1.3102 kJ (C) 8.4101 kJ (D) 6.3101 kJ

8) For which of the following change H E?

(A) H2 (g) + I2 (g)-> 2HI (g) (B) HCl (aq)+ NaOH(aq) -> NaCl(aq) + H2O(l)
(C) C(s) + O2(g) -> CO2(g) (D) N2 (g)+ 3H2(g) -> 2NH3(g)

9) rH of which of the following reactions is zero?

(A) H2(g) -> 2H+ (g) + 2e (B) 2H(g) + aq -> 2H+(aq) + 2e
(C) 2H(g) -> 2H+(g) + 2e (D) H2(g) + aq -> 2H+(aq) + 2e
10) Which of the following compounds gives iodoform with I2 + NaOH
1)CH3CH2OH 2) CH3CH2CH2OH 3)CH3OH 4) CH3COOH

11) The compound formed by reaction of 1,1dichloropropane with Zn can also be prepared by the
following reaction
[1] 3, 4Dibromohexane with zinc [2] 3Bromohexane with alcoholic KOH
[3] both of the above [4] None of above

12) In Zerewittnoffs method Grignards reagent reacts with the following

[1] A primary amine [2] a primary alcohol [3] Acetylene [4] All of above

13) Among the alkenes which one produces tertiary butyl alcohol on acid hydration
A (CH3)2C = CH2

B CH3 CH = CH CH3

C CH3 CH2 CH = CH2

D CH3 CH = CH2

14) Among the following, which is least acidic?

A phenol

B o-cresol

C p-nitrophenol

D p-chlorophenol

15. An organic compound A containing C, H and O has a pleasant odour with boiling point of 78C. On
boiling A with concentrated H2SO4, a colourless gas is produced gas is produced which decolourises
bromine water and alkaline KMnO4. The organic liquid A is
A C2H5COOCH3

B C2H5OH

C C2H5Cl

D C2H6

16. The correct order of decreasing acid strength of trichloroacetic acid (A), trifluoroacetic acid (B),
acetic acid (C) and formic acid (D) is
A) A > B > C > D B) A > C > B > D
C) B > A > D > C D) B > D > C > A
17) Which of the following reactions will not result in the formation of carbon-carbon bond?

A) Reimer-Tieman reaction B) Friedel Crafts acylation

C) Wurtz reaction D) Cannizzaro reaction

18) Which of the following has most acidic hydrogen?

A) 3-Hexanone B) 2, 4-Hexanedione
C) 2, 5-Hexanedione D) 2, 3-Hexanedione

19) The product formed in Aldol condensation is

A) a beta-hydroxy aldehyde or a beta-hydroxy ketone B) an alpha-hydroxy aldehyde or ketone

C) an alpha, beta unsaturated ester D) a beta-hydroxy acid

20) Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc. HCl is called
A) Cope reduction B) Dow reduction
C) Wolff-Kishner reduction D) Clemmensen reduction

21) Which one of the following statement is incorrect about enzyme catalysis?
A) Enzymes are denaturated by ultraviolet rays and at high temperature B) Enzymes are least reactive
at optimum temperature
C) Enzymes are mostly proteinous in nature D) Enzyme action is specific

22) Gold numbers of protective colloids A, B, C and D are 0.50, 0.01, 0.10 and 0.005 respectively. The
correct order of their protective powers is
A) B < D < A < C B) D < A < C < B
C) C < B < D < A D) A < C < B < D

23) Identify the correct statement regarding enzymes:

A) Enzymes are specific biological catalysts that cannot be poisoned.

B) Enzymes are normally heterogeneous catalysts that are very specific in action
C) Enzymes are specific biological catalysts that can normally function at very high temperature (T -
1000K).
D) Enzymes are specific biological catalysts that possess well defined active sites.

24) Which of the following acids does not exhibit optical isomerism?

A) Lactic acid B) Tartaric acid

C) Maleic acid D) -amino acids

25) An oxygen containing organic compound upon oxidation forms a carboxylic acid as the only organic
product with its molecular mass higher by 14 units. The organic compound is

A) a ketone B) an aldehyde
C) a primary alcohol D) a secondary alcohol