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Adsorption of Isotherm.
B. Objectives
isotherm from Freundlich in adsorption process of acetic acid on the active carbon.
C. Background
solute in the liquid with which it is in contact. There are basically two well
established types of adsorption isotherm the Langmuir adsorption isotherm and the
In a modified form it can also describe a bi-layer deposition. The shape of the
isotherm (assuming the (x) axis represents the concentration of adsorbing material in
the contacting liquid) is a gradual positive curve that flattens to a constant value. The
Freundlich isotherm curves in the opposite way and is exponential in form. It often
isotherm is not common, most adsorption processes are best described by the
assumption the the absorbent have a heterogeneous surface and each molecules have
expressed as
or
Where:
x = mass of adsorbate
m = mass of adsorbent
K and 1/n are constants for a given adsorbate and adsorbent at a particular
shoul be get gradient n and intercept k. from this isotherm, will be knowing the
absorbent capability to absorb the water. This isotherm using in the experiment
1. Sotherm curve will tendence flat, it means isotherem which using to absorb in the
2. Isotherem curve which sheer, it means the adesorbtion capacities increasing with
by the object surface absorbance, where occur a chemical bonding and physical
between substances and its absorbance. Adsorption process viewing as the molecules
process leaving the solution and adhere on the absorbent surface caused by physical
and chemical bonding. So that way, adsorption always classifying as the tertiary
solution from a solute of molecules in its surface caused by the disbalancing forces in
monomolecular layers, in the surface undergo the forces from valence residue on the
capillary from solids. Generally, elements with molecular weight which more big will
standard materials that was used. It means with activating, atreatment to the active
carbons which have objectives to making a big pores with cutting a hydrocarbon
bonding or oxidation the surface of molecules. So that the active carbons get a
changes of properties. Both of physical and chemical are the surface wide adding and
become biggest, as well as it was influence the absorption occurs (author. 2010).
1. Apparatus:
d. Drops pipette
f. Spraying bottle
g. Shaker
h. Stopwatch
i. Stove
j. Analytical balance
k. Spoons
l. Funnel, 6 pieces
m. Porseline dish
n. Clamp.
2. Chemicals:
c. Phenolphthalein indicators
e. Aquadest
f. Tissues.
E. Instructions
1. The charcoals was activated by using a stove to make it hot and we trying to
2. The active carbons was measured 1 grams and directly input on the shaper
Erlenmeyer flask. Each one time of balancing. So that, the total are six active
3. About 100mL of each concentration of acetih acid was put on the shaper
4. The acetic aced was mixtures with the active carbons and it was silently as 10
minutes, and it was shaking as 1 minutes in the shaker. Its treatment was
5. The six Erlenmeyer flask with containing a mixtures acetic acid and active
7. The NaOH 0.1N was input on the burette as 50mL and directly titrated with
various volume:
a. 0.5000M = 10mL,
b. 0.250M = 10mL,
c. 0.125M = 25mL,
8. The volume of NaOH that was used to titrated then write down in the tables.
F. Result
black mixtures 30 minutes each 10 minutes getting shake in the
shaker transparent (filtrate) various volume.
10 mL H2C2O4 0.1M NaOH, V = 20.00 mL.
M1V1 = M2V2
(0.1M)(10mL) = M2 (20.00mL)
(0.1)(10)
M2 = (20.00)
= 0.05 M
a. Concentration of CH3COOHlast
(.)
M =
3
(0.05)(80.5)
= (10)
= 0.4025 M
mmole = (M.V)CH3COOH
= (0.5000M)(100mL)
= 50 mmole
mmole = (Mlast.V)CH3COOH
= (0.4025M)(100mL)
= 40.25 mmole
= (50-40.25)mmole
= 9.75 mmole
e. Adsorbed Concentration
M = 3
9.75
= 100
= 0.0975 M
= 5.85 mg
= 0.585 g
g. Its x/m
.
= .
= 0. 468
3. CH3COOH 0.250M, VCH3COOH = 100mL
a. Concentration of CH3COOHlast
(.)
M =
3
(0.05)(36.9)
= (10)
= 0.1845 M
mmole = (M.V)CH3COOH
= (0.250M)(100mL)
= 25 mmole
mmole = (Mlast.V)CH3COOH
= (0.1845M)(100mL)
= 18.45 mmole
= (25-18.45)mmole
= 6.55 mmole
e. Adsorbed Concentration
M = 3
6.55
= 100
= 0.0655 M
= 393 mg
= 0.393 g
g. Its x/m
.
= .
= 0. 338
a. Concentration of CH3COOHlast
(.)
M =
3
(0.05)(57.1)
= (25)
= 0.114 M
mmole = (M.V)CH3COOH
= (0.125M)(100mL)
= 12.5 mmole
c. Last mmole of CH3COOH
mmole = (Mlast.V)CH3COOH
= (0.1142M)(100mL)
= 11.42 mmole
= (12.5-11.42)mmole
= 1.08 mmole
e. Adsorbed Concentration
M = 3
1.08
=
100
= 0.0108 M
= 64.8 mg
= 0.064 g
g. Its x/m
.
= .
= 0. 0462
a. Concentration of CH3COOHlast
(.)
M =
3
(0.05)(48.75)
= (50)
= 0.04875 M
mmole = (M.V)CH3COOH
= (0.0625M)(100mL)
= 6.25 mmole
mmole = (Mlast.V)CH3COOH
= (0.04875M)(100mL)
= 4. 875 mmole
= (6.25-4.875)mmole
= 1.375 mmole
e. Adsorbed Concentration
M = 3
1.375
= 100
= 0.01375 M
= 82.5 mg
= 0.0825 g
g. Its x/m
.
= .
= 0. 0615
a. Concentration of CH3COOHlast
(.)
M =
3
(0.05)(24.95)
= (50)
= 0.02495 M
mmole = (M.V)CH3COOH
= (0.0313M)(100mL)
= 3.13 mmole
c. Last mmole of CH3COOH
mmole = (Mlast.V)CH3COOH
= (0.02495M)(100mL)
= 2.495 mmole
= (3.13-2.495)mmole
= 0.635 mmole
e. Adsorbed Concentration
M = 3
0.635
=
100
= 6.35x10-3 M
= 38.1 mg
= 0.0381 g
g. Its x/m
.
= .
= 0. 0278
a. Concentration of CH3COOHlast
(.)
M =
3
(0.05)(14.95)
= (50)
= 0.01495 M
mmole = (M.V)CH3COOH
= (0.0156M)(100mL)
= 1.56 mmole
mmole = (Mlast.V)CH3COOH
= (0.01495M)(100mL)
= 1.495 mmole
= (1.56-1.495)mmole
= 0.065 mmole
e. Adsorbed Concentration
M = 3
0.065
= 100
= 6.5x10-4 M
= 3.9 mg
= 3.9x10-3 g
g. Its x/m
.
= .
= 2.8x10-3
Active Concentration of
No. carbons CH3COOH (M) X(g) Log C
mass(g) First Last
1. 1.25 0.5000 0.4025 0.585 0.468 -0.329 -1.010
Y-Values
1
0.5
0
-0.515 -0.924 -0.987 -1.455 -1.73 -1.844
Series 1
-0.5
-1
-1.5
H. Discussion
This experiments was done to know the adsorption occurs in the acetic acid by
active carbons, where using the various concentration of acetic acids to made it
comparison in the result. Active carbon have an adsorptions ability define by the
surface wide of particles and this ability can be more high if the active carbon get
m2/g ant its relating with interval pores structure which cause the active carbons
have properties as an adsorbent. The activating done to made the pores getting
bigger with cutting the hydrogen bonding or oxidizing the surface molecules and
must be pouring before, because as small the pores of active carbons, the wide
carbons that should be using to know how many CH3COOH will be adsorbed by
its carbon actives. The volume of NaOH after done titration same with how many
According to the data, as high the concentration of CH3COOH made the NaOH
volume is high also, with a little bet range of active carbons weight. When the
it become pink solution and the work of indicators where the equivalent point was
and CH3COOH achieve, with changes the color of CH3COOH from transparent
In this experiment, adsorption that was used namely carbons active, where its
containing both of air or in the water. Acetic acid would be adsopbed at the first
in not pure become more pure because another substances which is followed in
done after addition of active carbon was pourposed to adsorb the color of
effective it. The using of shaper Erlenmeyer is avoid the distributed from outside
and ovoid the Ch3COOH got contaminated by another substances which can be
When added by indicators, it was indicated when the color chaged. This indicator
functioning to know when the titrane addition must be stopped and know the
equivalent point are amount of titrane same with the titrated amount. Also to
determining the last point where titration must be stopped because the colors got
change. Indicator that was used here namely phenolphthalein. Where when in acid
1. Conclusion
which needs to titration, and its vise versus as high the concentration,
c. Amount of naOH which needs to titrated the acetic acid which was
1) 0.5000M is 0.5850 g,
2) 0.2500M is 0.3930 g,
3) 0.1250M is 0.0648 g,
4) 0.0625M is 0.0815 g,
5) 0.0313M is 0.0381 g,
6) 0.0156M is 3,9x10-3 g.
2. Suggestion
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Bibliography
1. Qualigfication:
a. Physical adsorption:
b. Chemical adsorption:
2. Reaction is currently
carcoals.
3. With heating process, the particles and wide serface of carbons becomes
more big so that the adsorption ability molre big if compare with not heating
the carcoals.
5. Because freundllich equation get from empirical without basic theory, for the
high pressure is not used while Langmuir based on the theory from layer
form.