1. Calculate Gibbs free energy () for the next reaction at 1 atm and 25 C.

4() + 22() 2() + 22 ()

Answer.
*This information was recovered from Langes Handbook by James G. Speight
(Chapter 6, tables 6.1, table 6.3)
Calculate ()

( ) =


( ) = .


( ) = .


( ) = .

=

= (. ) + (. ) ( (. )

= .

Calculate ()

( ) = .


( ) = .


( ) = .


( ) = .

=

= (. ) + (. ) ( . )


+ ( . )


= .


= .

Calculate ()

= . (. . )

= .

2. Zyanya was thinking in a reaction that she read at her chemistry book, she
was really interested on thermodynamic equilibrium so she asked herself if
she could calculate the temperature (T) of equilibrium of the next reaction:
3() 2() + ()
Could you help Zyanya to know the temperature of equilibrium?
Answer.
*This information was recovered from Langes Handbook by James G. Speight
(Chapter 6, tables 6.1, table 6.3)
Assumption: =
Calculate ()

( ) = .


( ) = .


( ) = .

=

= (. ) + (. ) ( (. )

= .
Calculate ()

( ) = .


( ) = .


( ) = .

=

= (. ) + (. ) ( (. )


= .


= .

Calculate (T)

=

.
=

.
 = .

Phase Diagram.

1. One winter night of December Diana parked her new car and she went bed
because she was tired, at morning she remembered that she left her phone
at her car. When she saw her car, she was surprised because it had ice at
her windshield and she had no idea what happened. A) Explain the process.
B) Calculate entropy of water at her normal sublimation point ( =

44.0 ). C) Describe with a phase diagram what happened.
Answer
A) Air contains water vapor so it crystalized, it means that it had an inverse
process of sublimation.

B) =

44.0
=
273.15

= 0.1610

C)
 2. Mike was not sure if his Cengel thermodynamics tables were trustworthy so
he asked to her thermodynamics teacher how he could show that her
thermodynamics tables were not fake tables, so she just said, Maxwell
Relations.

So he decided to use a Maxwell relation that says () = ( ) , and he
used refrigerant 134a at 50 C and 0.7 mPa to show that his tables were

correct. Show Cengel thermodynamics tables are right using: () = ( ) .

Answer
*Values were used from Thermodynamics an engineering approach 8th edition by
Cengel and Boles tables A-13.

( )50 = ( )700

@0.9 @0.5 @70 @30

( ) =50 = ( )0.7
(900 500) (70 30)

3
(0.9661 1.0309) (0.036373 0.029966)

( )50 = ( )0.7
(900 500) (70 30)

Assumption =kPa*m^3, and K=C JUST FOR TEMPERATURE differences.

4
3 4
3
1.62110 1.60210

In conclusion Cengel Tables satisfied Maxwell relation.