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Study of Self-Purification Capacity in the


Semi-Arid Zones: Case of Wadi Cheliff,
(Northern Algeria)

Article in Current World Environment December 2014


DOI: 10.12944/CWE.9.3.05

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Current World Environment Vol. 9(3), 584-590 (2014)

Study of Self-Purification Capacity in the Semi-Arid Zones:


Case of Wadi Cheliff, (Northern Algeria)
Mokadem Maamar1*, Achour Djillali2 and Cherif El Amine3

Department of Hydraulics,University of Sciences and Technology MB of Oran


1,3

P.O. Box 1505, El-Mnaouer,Oran 31000, Algeria.


2
University of Hassiba Ben Bouali,P.O. Box 151 Hay Es-Salem, Chlef 02000, Algeria.

http://dx.doi.org/10.12944/CWE.9.3.05

(Received: September 10, 2014; Accepted: October 23, 2014)

Abstract

The aim of this paper was to study and predict the self-purification capacity of wadi Cheliff
(in the section Oum Drou Chlef). This was done primarily by measuring the Dissolved Oxygen (DO)
downstream of a pre-selected pollution discharge point on wadi Cheliff and then predicting the same
using the modified Streeter-Phelps equations. Twelve sampling stations are chosen, on a section
of approximately 8.5 km of the wadi Cheliff (Oum Drou - Chlef), to collect data with knowing the
Biochemical Oxygen Demand (BOD), pH, stream velocity, stream depth and distance. Predicted DO
deficit trend lines were first fitted by retaining the original re-aeration coefficient component, k2, of
the modified Streeter-Phelps equation (United States Geological Survey equation) and subsequently
by substituting it with our reaeration coefficient model. It was found that the latter displayed better
predictive capacity. Results also demonstrated that the self-purification capacity of the river which
is already limited by the relatively low DO saturation level is further threatened by the wastes being
discharged into it at varying intervals. Some of these wastes are non-biodegradable which slows
down the self-purification processes of the wadi. To preserve the underground layers of the area and
to ensure a water of good quality for the irrigation, the Wadi Cheliff must be, necessarily, to protect
from any pollution.

Key words: Surface Water Quality, Pollution, Dissolved Oxygen, reaeration coefficient,Wadi Cheliff.

Introduction sedimentation, adsorption, dispersion, the advection


and of the re-aeration of the atmosphere (Fischer et
Water quality modeling has been shown to al. 1979; Koussis 1983; Koussis et al. 1983, 1990;
be a useful tool in strategic water quality management McBride and Rutherford 1984). at the same time
(Fan et al. 2009). The literature contains very few one increased, on the one hand, the difficulties
studies on the water quality modeling for small rivers, of using them in practice (Snowling and Kramer
and such studies as have been published are fairly 2001) and on the other hand the error between
limited in scope (Giorgio M., Gaspare V. 2010) and simulations and the total sensitivity of the model
especially for the arid and semi-arid areas. increases and consequently the most complex model
is not necessarily the most useful (Lindenschmidt
The aim of models self-purification is 2006).
predict, at the space-time forecast, the effects
of an organic matter rejection on the dissolved Reliable model calibration requires an
oxygen content of the receiving medium, by taking extensive array of water quality data that are generally
account of its characteristics and those of the rare and resource-intensive, both economically and
rejection. Progressively of progress of the scientific in terms of human resources, to collect (Mannina
research, the models were become more complex by and Viviani 2010).
integrating a growing number of factors like dilution,
585 Maamar et al., Curr. World Environ., Vol. 9(3), 584-590 (2014)

The conventional method for the analysis Study area


of the water pollution is based on the equation of The watershed of Cheliff occupies a surface
Streeter-Phelps (Streeter and Phelps 1925, 1936; of 47.269 km2. It extends between the meridian lines
Cox 2003; Lin and Lee 2007; Omole and Longe 2012; 0 and 330' Eastern and between the latitudes 34
Omole et al. 2012) this model does not introduce and 36 Northern. It covers four under watersheds:
the decantable component of the DBO (Tyagi et al. Cheliff upstream of Boughezoul, the high and the
1999). Bhargava considered that the DBO includes/ middle Cheliff, Lower Cheliff, the Mina and the coastal
understands a decantable part and another dissolved one. It is limited to North by the Mediterranean, in the
(Bhargava 1983; Velz and Gannon 1962) added a West by the Oranais watershed, the South by the
factor to the constant of DBO rate, k1, exponential high plains and the East by the of Algiers watershed
form of kinetics of first order to explain the reduction (Fig. 1).
in DBO by the phenomenon of sedimentation.
The area is characterized by a semi-arid
Thomann and Mueller (1987) carried climate with very hot summers and cold winters
out an important modification in the model of (Boulaine, 1957). The considerable variation (18
Streeter and Phelps, by the separation of DBO in C) between the maximum temperature recorded
two carbonaceous and nitrogenized components in July (29 C) and the minimal one in January (11
because these two elements have a rate of different C) a continental climate marked, in spite of the
deoxygenation and reaeration. However oxygen proximity of the sea; indeed, the mounts of Dahra
dissolves remainder the same one, it is supplemented form a barrier isolating from the watershed Cheliff of
with a dependence of the temperature. the regulating influence of the Mediterranean over a
70 km length (Bettahar et al. 2009).
In Algeria, the water resources of surface
are very limited and difficult to exploit, this is why any MATERIALS AND METHOD
risk of contamination or of pollution deserves to be
underscored, forwarded and modeled. The model is applied to a section of the
Wadi Cheliff length approximately 8.5 km delimited
The wadi Cheliff, one of the most important by the section upstream to the level of the town of
rivers in Algeria, par excellence constitutes a Oum Drou until the section swallows taken on the
vector of pollution for the underground layers and level of the center of the town of Chlef.
the irrigation. To know the quality of this water is
essential for the management of this resource and Twelve (12) sampling stations were selected
its environment. on the level of this section (Fig. 2). The distance of
the stations compared to the first station (Oum Drou)
The wadi Cheliff is a concrete example is defined in table 1.
of the width of a pollution of any kind to knowing
physical, chemical and bacteriological following the The data measured on the level of these
excessive rejections of urban or industrial nature stations are the DBO5analysis were stored in a
which it receives with the length of the year without series cooled incubator at a controlled temperature
any preliminary treatment. Thirty-two (32) production of 20C, water velocity was measured using a reel
units are established in the watershed of the wadi current meter, the ambient and water temperature
Cheliff and generate a pollution of about 410.000 data were obtained using a portable conductimeter,
populationequivalents (ABHCZ 2005). water pH was obtained using a handheld pH-meter,
the dissolved Oxygen evaluated using a portable
The model considered here for the first O2-meter. The total distance of the segment and
time is a simulation of the Oxygen dissolved in the the global position of each sampling station were
courses in Algeria. A comparison between this model obtained with the Garmin Handheld GPSMAP
and the linear model of Streeter and Phelps will be 78S.
carried out on a section of the Wadi Cheliff.
Maamar et al., Curr. World Environ., Vol. 9(3), 584-590 (2014) 586

Theory This dissolved oxygen deficit, will be at least filled by


The model of Streeter and Phelps (1926), the reaeration of water by gas transfer. After a certain
for the river Ohio, described the space-time evolution distance (time), water in the stream, including waste
of the concentration of dissolved oxygen and BOD water, is again saturated or almost with dissolved
to the downstream after pollution discharges, was oxygen, C H Cs (Curve A). Curve B presents a case
proposed: where the pollution leads to the river becoming septic
(Anaerobic).
(dD(t))/dt=k_1 b(t)-k_2 D(t) ...(1)
The concentration of saturation out of
oxygen Cs in water is calculated, according to the
D=(Cs-C) ...(2)
temperature T, the formula empirical (Fair et al. 1968;
Bowie et al. 1985) following is used:
Where, D = Dissolved Oxygen deficit, b
= Ultimate first stage BOD of mix at the point of
discharge in mg/l, k1 = deoxygenation coefficient, Cs=14.64-0.41T+0.008T2 ...(5)
k2 = re-aeration coefficient, t = time in days, C =
concentration of OD, Cs = concentration of saturation The coefficient of reaeration k2 is determined
of DO. by the following relation (Metcalf 1972):

The model uses the coefficients k 1 k2=.vn/hm ...(6)


and k2 which is dependent respectively on the
waste characteristics alone while the re-aeration Where, h = depth of the river in m, v = velocity of the
coefficient k2, is dependent on such factors as water river in m/s, , n, m = empirical coefficients.
temperature, velocity and depth of the river.
Results and discussions
The equation 1, after integration (Waite et al. 1977;
Kiely 1998; Longe and Omole 2008) gives: Just before the rejection of the waste water
(S1), the water of the wadi is rich in dissolved oxygen
with a value of 7.7 mg/l which is very close to the
saturated dissolved oxygen, at this period of the year,
...(3) level of 8.4 mg/l correspondent at a temperature
of approximately 24C. This concentration, which
Where: D = the predicted DO deficit in mg/l is highest of the values measured in the sampling
after time t; L0 = Ultimate first stage BOD of mix at the stations, starts to decrease up to a minimal value of
point of discharge in mg/l; D0 = Initial DO deficit of the 6.2 mg/l (S3). At this place relatively high speed (1.04
mix at the mixing point in mg/l; k1= De-oxygenation m/s) to support a good reaeration and consequently
coefficient for the effluent; k2=Re-aeration coefficient good self-purification and the OD take a value of 7.5
for the stream; t = time. mg/l (S4).
f = Self-purification factor defined by Eq. (4)
The section between S5 and S6 is
f= k2/k1 ...(4) characterized by low slopes (0.6 to 3 ) which
generate low velocity of flow (thus a relatively high
The variation of the dissolved oxygen deficit time of travel) which favor the oxygen consumption
D is described by a curve spoon shaped (Fig. 3) by the bacterial activity. It takes a value of 7.1 mg/l
which can be interpreted as follows: With the starting to start to increase up to the value of 7.6 mg/l (S7).
point, and before the pollution discharges, water is This increase is stopped by a rejection of waste
rich in oxygen; the dissolved oxygen deficit is low. water without treatment of the agglomeration of
After the introduction of waste water, a biochemical Chega and the cycle of the process of biological
decomposition of this last with dissolved oxygen breakdown repeats i.e. a reduction in the OD (6.7
starts according to the equation N1. A dissolved mg/l at the S9 station) then an increase (7.5 mg/l at
oxygen deficit is established and increases gradually. the S10 station). Another rejection of waste water
587 Maamar et al., Curr. World Environ., Vol. 9(3), 584-590 (2014)

(of the Eastern part of Chlef) comes to stop, again,


the phenomenon of the self-purification of the wadi
Cheliff and the OD decreases up to the value of 6.8
time of Oxygen
deficit
(mg/l)

0.130 1.62
4.25
3.80
3.14
3.18
1.05
2.51
1.40
0.86
1.17
0.63
1.45
mg/l.

It remains to be announced that the pH of


the water of the wadi Cheliff is slightly acid, its median
Velocity travel

0.005
0.014
0.022
0.032
0.053
0.060
0.071
0.077
0.102
0.117
(d-1)

value is of 5.77 this is due to the bio-degradation of


part of the organic matters in anaerobic medium
Table. 1: Sampling Stations and corresponding hydraulic and physico-chemical characteristics

especially in the dry season.


Mean

(m/s)

5.7 0.63
1.45
0.91
1.04
0.93
0.70
1.39
0.68
1.25
0.43
0.68
0.47
From this a k2 model for Wadi Cheliff is
calculated from experimental results using Eq. (7)
5.8
5.6
5.6
5.5
5.6
5.8
5.6
5.1
6.0
7.2
5.7
pH
(mg/l)
(C)


Water DO BOD

...(7)
24
10

18
12
16
14
34
10
18

14
8

Where, D up= initial DO deficit at the


upstream; Ddown= DO deficit at any downstream
point; t = time of travel between two points
bed temperature (mg/l)

7.8
6.8
7.4
7.6
7.2
8.2
7.6
5.8
6.8
7.4
6.8
7.2

successive.

To find the relationship between the


calculated values of k 2a non-linear regression
23.9
23.7
23.7
23.6
23.6
23.7
23.7
24.0
23.7
23.7
23.6
23.5

analysis could be used, the stream velocity and


stream depth by obtaining the constants of the
relationship which are also known as the coefficients
Mean Elevation Wadi

100.2
97.4
95.9
94.7
93.8
93.0
90.4
89.6
88.0
87.8
87.3
87.2
(m)

of regression b1, b2, b3 using Eq. (8):

k2=1 V2 /H3 ...(8)


91.5

90.5

89.5
101
(m)

98
97
96
95

91

90

89
88
(m)

Where, V = stream flow velocity, in meters


per second and H = Hydraulic Radius, in meters.
depth

0.8
0.6
1.1
1.3
1.2
0.9
0.6
0.9
1.1
1.1
1.7
0.8

The k2 model for wadi Cheliff (Eq. 9) was


developed while determining the parameters b1, b2
and b3. These parameters are the unknown values
Sampling Cumulated Width

of the function that must be determined. Since b2


10.1
(m)

5.3

7.3
6.4
8.5

7.8
12

15

10
5

8
(m)

and b3 are in a non-linear position with respect to


the defined relationships, a non-linear regression
was done to determine the parameters.
distance

1341
2051
2881
4153
4906
5569
6180
7122
7978
8535
615
0

Following the calibration of the model


is obtained by plotting the dispersion plot of k 2
(measured) and k 2 (computed), and the non-
stations

linear regression analysis of data using the


Mathcadsoftware:
S10
S11
S12
S1
S2
S3
S4
S5
S6
S7
S8
S9

k2=21.56V1.372/H0.0683 ...(9)
Maamar et al., Curr. World Environ., Vol. 9(3), 584-590 (2014) 588

Following the non-linear regression The re-aeration coefficient proposed by


analysis, the model output passed with the following Streeter et al.(1936) is defined thus:
statistics: Error Sum of Squares, SSE = 8.561;
Coefficient of determination, R2 = 0.942; and a Root k2=5.026V0.969/H1.673 ...(10)
Mean Square Error, RMSE = 1.723.

Fig. 1: Watershed of wadi Cheliff

By substituting equation 9 into equation 3,


S1 the broken curve in Figure 4 was obtained. However,
S2 when the equation 3 was used with the re-aeration
S4 coefficient proposed by Streeter et al.(1936) (Eq. 10),
S5 S3
the predicted DO deficit curve that was obtained is
S6 presented in Figure 5.
S7 Legend

S8 Furthermore the plot of DO along the path


S9 River Path of the wadi (Fig. 4) displayed a marked difference
S11 S10 Sampling Station
from the expected normal spoon-shaped DO curve
(Fig. 3). The DO curve along wadi Cheliff displayed
Scale
S12 sinusoidal tendencies which suggest that the
0 1 Km 2 Km progressive recovery process was being interrupted
at several intervals in the section.
Fig. 2: The Sampling and measurement
stations on wadi Cheliff By comparing the results of these deficits of
dissolved oxygen simulated by the model suggested
Pollution of the wadi Cheliff, the Streeter-Phelps model and
Dis measurements of the analysis, one notes: the results
sol Oxygen saturation level
of the model suggested approach those measured
ve D0
do better that those provided by the model Streeter -
xy D Phelps.
ge A
n
B
Conclusion
0
Anaerobic conditions After this study; we can say that the Wadi
Time
Cheliff has a capacity normal but limited to purify
itself from many pollutants mainly the rejections of
Fig. 3: The Oxygen Sag Curve domestic or industrial waste water (agro-alimentary)
589 Maamar et al., Curr. World Environ., Vol. 9(3), 584-590 (2014)

Fig. 4: DO deficit trend line against sampling and measurement stations using Cheliff model

Fig. 5: DO deficit trend line against sampling stations using Streeter-Phelps model

especially in the dry season; on the one hand the and/or of management; this to be used like a tool
flow is low generating low velocity of flow; on the of forecast and assistance for management such
other hand the temperature, during this time of the as the designation of the zones of intake of water
year, exceeds the 29C what decreases the solubility for the irrigation and the knowledge of the quality
of the OD (crucial factor to the bio-degradation of of water of the wadi in every point of the section.
the organic matters) in water. The DO curve along This forecast makes it possible to each time avoid
wadi Cheliff displayed sinusoidal tendencies which the recourse to expensive analyzes. Cheliff model
suggest that the wadi self-purification processes is therefore recommended for application in future
are being interrupted at several intervals in the reaeration studies on wadi Cheliff.
section.
To Safeguard the public health and to
The development and validation of protect the groundwater of pollution transported by
Cheliff model has been carried out; This model is the wadi Cheliff require measurements to improve
suggested to study the quality of the wadi Cheliff the capacity of self-purification of this last. Among
and its capacity of self-purification requires, for its these measurements, the construction of the
application, only knowledge that hydraulic properties waste waterpurification plants for the waterside
of the wadi and characteristics physico-chemical of agglomerations; to activate the police force of water
water, this is very important and useful especially so that the regulations of environmental protection
for developing countries which miss data, means are respected.
Maamar et al., Curr. World Environ., Vol. 9(3), 584-590 (2014) 590

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