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MODEL OF ATOM
Proton
Shell
Neutron
Electron
COMPOSITION OF ATOMS
Electron
Has a negative (-) charge
Has a relative mass of 0 (zero)
Determines the ion
Found outside the nucleus
Bohr model electrons are in specific
energy levels
Electron cloud model electrons are in a
random cloud
Nucleus center of the atom
Home of Protons and Neutrons
Proton
Has a positive (+) charge
Has a relative mass of 1
Determines the atomic number
Found inside the nucleus
Neutron
Has no (0) charge
Has a relative mass of 1
Determines the isotope
Isotopes are two of the same
element with different masses
Found inside the nucleus
Number of protons = atomic number
Atomic number, Z
the number of protons in an atom
2 13 238
1H 6
C 92 U
3 14
1H 6
C
Light travels through space as a wave.
E = h
= hc /
where h = Plancks constant = 6.63 x 10-34 Js
27
Main postulates of Bohrs atomic theory are:
CONSTANT ENERGY CONCEPT
Energy of an electron is constant in one of its
allowed orbits. As long as an electron remains in its
orbit, it neither absorbs nor radiates energy.
CONCEPT OF ENERGY LEVELS
Electrons revolve around the nucleus of atom in
circular orbits in which energy of electrons is
constant. These circular paths are known as
"energy levels" or "stationary states".
RADIATION OF ENERGY
If an electron jumps form higher energy level to a
lower energy level, it radiates a definite amount
of energy.
ABSORPTION OF ENERGY
If an electron jumps from lower energy level to a
higher energy level, it absorbs a definite amount of
energy.
When excited, the Emission: The atom
electron is in a higher gives off energyas Upon emission, the
energy level. a photon. electron drops to a
lower energy level.
Excitation: The atom
absorbs energy that is
exactly equal to the
difference between two
energy levels.
Called subshells
n l Suborbital notation
1 0 1s
2 0 2s
1 2p
0 3s
3
1 3p
2 3d
0 4s
1 4p
4
2 4d
3 4f
Describe the orientation of the orbital in space.
Function: determine:
- direction of orbital ( x, y, z axis)
- determine number of orbital
if l = 0 (s orbital), ml = 0
if l = 1 (p orbital), ml = -1, 0, or 1
if l = 2 (d orbital), ml = -2, -1, 0, 1, or 2
Name, Symbol
(Property) Allowed Values Quantum Numbers
Angular
momentum, l 0 to n-1 0 0 1 0 1 2
(shape)
0 0 0
Magnetic, ml
-l,,0,,+l -1 0 +1 -1 0 +1
(orientation)
-2 -1 0 +1 +2
Function : determine spin (direction)
of the electron
Question :
1. Between 2s and 3s, which one will be filled first
by the electron?
2. How many 2p orbitals are there in an atom?
3. How many electrons can be placed in the 3d
subshell?
Fill up electrons in lowest energy orbitals (Aufbau principle)
? ?
B 5 electrons B 1s22s22p1
Be 4 electrons Li 1s22s1
Li 3 electrons Be 1s22s2
He 2 electrons He 1s2
H 1 electron H 1s1
CHM081/chapter5/ZMH
Order of orbitals (filling) in multi-electron atom
1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p < 5s < 4d < 5p < 6s
Outermost subshell being filled with electrons
A maximum of two spin paired electrons may be placed in
each orbital
No two electrons in an atom can have the same set of
quantum number (n, l, ml and ms)
Example:
n = 1, l = 0, m = 0, s = -1/2
n = 1, l = 0, m = 0, s = +1/2
One electron is added to each degenerate (equal energy orbital)
before a second electron is added
n=3 l = 1
n=3 l = 0
n=2 l = 1
n=2 l = 0
n=1 l = 0
Two general methods are used to denote configurations.
a) The subshell ( sub-energy level) notation, uses ;
- numbers to designate the principal energy levels or principal
shells
- the letters s, p, d, and f to identify the sublevels.
- superscript number following the letter indicates the number of
s in the designated subshell.
Scientist :
Antoine Lavoiser (1789)
J.W. Dobreiner (1829)
John Newlands (1864)
Dimitri Mendeleev
The elements are arranged based on atomic number
1 ns1 1
2 ns2 2
3 ns2 np1 3
14 ns2 np2 4
15 ns2 np3 5
16 ns2 np4 6
17 ns2 np5 7
18 ns2 np6 8
Valence electron configurations and number of valence electron for group of elements
A periodic table of partial ground-state electron configurations
CHM138/Chapter5/NMH
Horizontal row
Electron configuration :
1s2 2s2 2p6 3s2 3p6 4s1 or [Ar] 4s1
(19 electrons)
3 4 5 6 7 8 9 10
2 Li Be B C N O F Ne
6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18
11 12 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
3 Na Mg IIIB IVB VB VIB VIIB ------- VIII ------- IB IIB Al Si P S Cl Ar
22.99 24.31 3B 4B 5B 6B 7B ------- 8 ------- 1B 2B 26.98 28.09 30.97 32.07 35.45 39.95
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.47 58.69 63.55 65.39 69.72 72.59 74.92 78.96 79.90 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.62 88.91 91.22 92.91 95.94 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba La* Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.9 137.3 138.9 178.5 180.9 183.9 186.2 190.2 190.2 195.1 197.0 200.5 204.4 207.2 209.0 (210) (210) (222)
87 88 89 104 105 106 107 108 109 110 111 112 114 116 118
7 Fr Ra Ac~ Rf Db Sg Bh Hs Mt --- --- --- --- --- ---
(223) (226) (227) (257) (260) (263) (262) (265) (266) () () () () () ()
58 59 60 61 62 63 64 65 66 67 68 69 70 71
Lanthanide Series* Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.1 140.9 144.2 (147) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0
90 91 92 93 94 95 96
CHM140/chapter2/NorainiMH
97 98 99 100 101 102 103 f block
Actinide Series~ Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.0 (231) (238) (237) (242) (243) (247) (247) (249) (254) (253) (256) (254) (257)
s block : elements in Group IA and IIA, include H & He
because a maximum of 2 electrons can occupy the single
orbital in an s-subshell.
f block : elements include all the elements in the 2 rows at the bottom of
the periodic table
because a maximum of 14 electrons can occupy the seven
orbitals in a f-subshell.
Atomic size
Ionization energy
Electron affinity
Decreasing groups: ATOMIC SIZE INCREASE
WHY????
Na: 1s22s22p63s1
Outermost orbital n = 3
Across period: ATOMIC SIZE DECREASE
The atomic radius decrease because the valence electron
and effective nucleus charge increase
CHM138/Chapter5/NMH
Atomic radii of the main group and transition elements.
CHM138/Chapter5/NMH
Ionic radius/radii is the radius of a cation or an anion.
If atom forms an anion, its size or radii increases,
because the nuclear charge remain the same but the
repulsion resulting from additional electrons enlarge the
electron cloud.
Cations are smaller than anions.
Example : Na+ is smaller than F-
Both ions have the same number of
electrons, but Na (Z = 11) has more proton
than F (Z = 9). The larger the effective
nuclear charge of Na+ results in a smaller
radius.
Tendency of element to become more positive by
removing electron
The first electron is more readily removed than the second, etc.
I1 < I2 < I3 < I4
The 1st IE increase from left to right because atomic radius decrease,
the outer electrons are more tightly held to the nucleus.
o The 1st IE decrease moving down a group because the atomic radius
increase from top to bottom.
ability to accept one or more electrons
Answers:
Decrease
CHM138/Chapter5/NMH
THE END
THANK YOU
Q&A
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