7/25/2010

Manila Review Institute, Inc.

Chemical Engineering Review

DISTILLATION
Dr. Servillano Olano, Jr.

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Theory and Equations

Phase Equilibria in Distillation

A = more volatile
Gibbs Phase Rule
B = less volatile

For binary system: TA < TB

φ=2–2+2=2 pA > pB

Two degrees of freedom is needed to define equilibrium, e.g.

specifying temp and press will fix the compositions

specifying pressure and composition will fix temperature, etc

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he boiling point of A is that at which

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Rayleigh’s Equation

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For abnormal Solutions

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Next

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