Samrat Ashok Technological Institute (Engg. College), Vidisha (M.P.

)
Petrochemical Engineering Department
Maximum Marks Allotted Contract
Hrs. per
V-SEM Theory Practical
BE Subject Subject Name / weeks Total
Petrochemical Code Title Credits
End Mid Quiz End Lab L T P
Sem Assign
Sem Sem Work
MST ment
Materials of
PCE- Construction in
70 20 10 30 20 3 1 2 6
1751 Chemical
Industry

UNIT I
Properties and behavior of materials useful in structure, machines and equipments, atomic arrangements
and imperfections elasticity, micro elasticity and phase transformation. Materials of construction and their
technology with reference to application in chemical industry Cast iron, mild steel, high carbon steel,
stainless steel, high silicon steel, molybdenum and tungsten steel, heat treatment of plane steel. Theory of
alloying, constitutional diagrams, their construction and applications.

UNIT II
Non-ferrous metals Copper, aluminum, lead, chromium, tin, brass, bronze, Nickel, silver, and monel.

UNIT III
Non-metallic Materials Non-metals Glass, Enamels, graphite, wood, plastics, rubber, ebonite lining
materials, composite materials: fiber reinforced plastic composite material, concrete, asphalt and asphalt
mixture, ceramic mixture and silicates, structure and properties, polymeric material.

UNIT-IV
Chemical and Corrosive Environments Overview ,Corrosion by Water and Steam, Corrosion by Soil
,Atmospheric Corrosion, Oxidizing Acids, Reducing Acids ,Carbon Dioxide, Corrosion in Alkaline
Environments, Ammonia and its Compounds ,Salts ,High-Temperature Phenomena.
Practical Materials Selection Procedure: General Strategy, Liquid-solvent Temperatures, High
Temperatures, Low Temperatures.
Materials Protection Techniques: Overview, Coatings, Changing the Environment.

UNIT-V
Piping Materials Selection and Applications The Piping Material Engineer ,Process Industry Codes and
Standards, Materials, Piping Components, Joints for Process Piping Systems, Bolts and Gaskets, Valves,
Glossaries and Abbreviations.

Reference Books:
1. T.C. Pharris1 and R.L. Kolpa2,Overview of the Design, Construction and Operation of Interstate
Liquid Petroleum Pipelines
2. By PETER SMITH, Piping Materials Selection and Applications.
3. Prof.dr.ir. Walter BOGAERTS, Materials Engineering for the Chemical Process Industries.
 Samrat Ashok Technological Institute (Engg. College), Vidisha (M.P.)
Petrochemical Engineering Department
Maximum Marks Allotted Contract
Hrs. per
V-SEM Theory Practical
BE Subject Subject Name / weeks Total
Petrochemical Code Title Credits
End Mid Quiz End Lab L T P
Sem Assign
Sem Sem Work
MST ment
Chemical
PCE-
Reaction 70 20 10 30 20 3 1 2 6
1752
Engineering- I

UNIT I
INTRODUCTION TO CHEMICAL KINETICS: General Mole balance equation, Homogeneous and
Heterogeneous reaction rates, rate constants, stoichiometry, reactor mass balance, temperature and
concentration dependence of rate of reaction, Constant-volume and varying-volume systems, search for a
reaction mechanism and consequent deduction of rate expression.

UNIT II
BATCH REACTORS:Constant pressure and volume batch reactors, Interpretation of batch data,
Differential and integral methods of analysis, Regression analysis in fitting kinetic models.

UNIT III
CONTINUOUS REACTORS:CSTR & PFR, Performance equations, Space velocity & space time,
Comparison between Batch reactors, CSTR & PFR, Recycle reactor, Tubular reactors.

UNIT IV
ENERGY BALANCES FOR REACTORS:Energy balance equation, Non-isothermal reactions, Qualitative
discussion of optimum temperature progression, simultaneous solutions of material and energy balances for
reactor design, and multiple steady states of adiabatic CSTR.

UNIT V
BASICS OF NON IDEAL FLOW:Residence Time Distribution (RTD), RTD of ideal reactors, Earliness
of mixing, Conversion in non ideal flow reactors, tanks in series models.

TEXT BOOKS:
1. Octave Levenspiel, Chemical Reaction Engineering, 3rd edition, John Wiley & Sons, 2003
2. Fogler H S, Elements of Chemical Reaction Engineering, Prentice Hall, India, 1997.
3. Smith J M, Chemical Engineering Kinetics, 3rd edition, McGraw Hill, 1981.
LIST OF PRACTICALS:

1 Find out kinetic constant and study conversion of a given reaction in a batch reactor
2. Find out kinetic constant and study conversion of a given reaction in a plug flow reactor
3. Find out kinetic constant and study conversion of a given reaction in a CSTR
4. Study and operation of an adiabatic batch reactor
5. Study of a reversible reaction in a batch reactor
6. To determine energy of activation of reaction of ethyl acetate with sodium hydroxide
7. Find out specific rate contant and activation energy of a reaction in a plug flow reactor
8. To determine reaction equilibrium constant of reaction of acetic acid with ethanol.
9. To determine changes in free energy, enthalpy and entropy for the reaction of potassium
iodide with iodine.
10. Study and operation of a cascade CSTR
 Samrat Ashok Technological Institute (Engg. College), Vidisha (M.P.)
Petrochemical Engineering Department
Maximum Marks Allotted Contract
Hrs. per
V-SEM Theory Practical
BE Subject Subject Name / weeks Total
Petrochemical Code Title Credits
End Mid Quiz End Lab L T P
Sem Assign
Sem Sem Work
MST ment
PCE-
Mass Transfer-I 70 20 10 30 20 3 1 2 6
1753

UNIT-1
DIFFUSION IN FLUIDS: Ficks law of diffusion, equimolecular counter diffusion, diffusion in stationary
gas, maxwells law of diffusion. Inter phase mass transfer, mass transfer equilibrium, diffusion between
two phases. Local mass transfer coefficients, Local and average mass transfer coefficients. Simultaneous
heat and mass transfer.

UNIT-2
DISTILATION-I:Basic concepts of distillation, principles, Classification, types, total reflux, minimum
reflux ratio, optimum reflux ratio, Raoults law, Henrys law, multistage continuous rectification.

UNIT-3
DISTILLATION-II: Design calculations by McCabe-Thiele and Ponchon-Savarit methods, continuous
contact distillation tower design: extractive & azeotropic distillation, low pressure distillation: Steam,
reactive & membrane distillation, calculation of actual number of stages, NTU & HTU calculations.

UNIT IV
LIQUID-LIQUID EXTRACTION: Liquid-Liquid extraction: Liquid-liquid equilibrium, Different types of
extractors: selection, construction, sizing & operations. Calculation with and without reflux for immiscible
and partially miscible system.

UNIT-5
EQUIPMENTS FOR GAS-LIQUID OPERATIONS: Sparged vessel/Bubble column, Mechanically
agitated vessels for gas liquid contact, Tray towers, type of trays, flow arrangements on tray, tray
efficiency. Venturi scrubbers, wetted wall tower, spray tower, spray chamber, packed tower, Mass transfer
coefficients for packed tower, types of packing.

REFERENCE BOOKS:
1. R E Treybal- Mass Transfer Operations 3rd edition Mc Graw Hill 1980.
2. J M Coulson and J F Richardson- Chemical Engineeing Vol I & IIELBS Pergeman Press 1970.
LIST OF PRACTICALS: (Mass Transfer-I Laboratory)

1. To carry out Steam distillation.

2. To study different types of plates and packing.
3. Studies on the Sieve plate distillation unit.
4. Studies on Bubble cap distillation column.
5. To study the absorption of a gas in a packed column and calculation of NTU and HTU.
6. To study Batch distillation.
7. To study Continuous distillation.
8. Study of Venturi Scrubber.
9. Study of Differential distillation
 Samrat Ashok Technological Institute (Engg. College), Vidisha (M.P.)
Petrochemical Engineering Department
Maximum Marks Allotted Contract
Hrs. per
V-SEM Theory Practical
BE Subject Subject Name / weeks Total
Petrochemical Code Title Credits
End Mid Quiz End Lab L T P
Sem Assign
Sem Sem Work
MST ment
Industrial
PCE-
Chemical 70 20 10 30 20 3 1 2 6
1754
Technology

UNIT I
INTRODUCTION TO CHEMICAL INDUSTRY:Chemical industries facts and figures, concept of unit
operations and unit processes. General principle involved studying a chemical industry, manufacture and
applications of fuel gases and industrial gases- producer gas, water gas, coke oven gas, Carbureted gas or
oil gas, Natural gas and LPG, Synthesis gas, Acetylene.

UNIT II
ACIDS & ALKALIS:Manufacture of soda ash, caustic soda, chlorine, sulphuric acid, hydrochloric,
phosphoric acid, nitric acid.

UNIT III
NATURAL PRODUCT PROCESSING:Production of pulp, paper & rayon. Manufacture of sugar, starch
& starch derivatives. Fermentation processes for production of ethyl alcohol. Refining of edible oil & facts,
fatty acids. Soaps & detergents.

UNIT IV
FERTILIZER & CEMENT INDUSTRIES:Nitrogen fertilizers- synthetic ammonia- Urea- Ammonium
chloride- CAN- Ammonium sulphate- Phosphorous fertilizers- Phosphate rock- Super phosphate- Triple
Super phosphate- MAP & DAP, Cement-Types of Portland cement, methods of production.

UNIT V
COAL, COAL CHEMICALS & PETROLEUM:Occurrence- coking of coal, distillation of coal tar,
gasification of coal, hydrogenation of coal. Petroleum- occurrence & chemical composition. Petroleum
refinery products. Types of refineries. Refining processes- physical changes & chemical changes like
pyrolysis & cracking, reforming, polymerization etc.

REFERENCE BOOKS:
1. R. Gopala Rao and M. Sitting Drydens- Outlines of Chemical Technology 3rd edition. Affiliated
East West Pub. 1990.
2. S D Shukla and G N Pandey Text book of Chemical Technology Vol. I 1977.
LIST OF PRACTICALS: (Industrial Chemical Technology Laboratory)

1. To determine BOD and COD of given water sample.

2. Preparation of acetic acid from ethyl alcohol
3. To find out the sucrose content in aqueous solution by polarimeter.
4. To evaluate the viscosity of molasses.
5. To determine percentage of formaldehyde in the formalene.
6. To determine iodine value of the given oil sample.
7. To determine the acetic acid, ethanol concentration in aqueous solutions.
8. To prepare azodye and finding the yield.
9. Prepare a standard phenol solution and estimate the % of phenol in the given unknown sample of
phenol.
10. Analysis of fertilizers- determination N, P amounts.
11. Cement analysis.
12. Preparation of soap.
13. Preparation of detergents.
14. Preparation of starch.
 Samrat Ashok Technological Institute (Engg. College), Vidisha (M.P.)
Petrochemical Engineering Department
Maximum Marks Allotted Contract
Hrs. per
V-SEM Theory Practical
BE Subject Subject Name / weeks Total
Petrochemical Code Title Credits
End Mid Quiz End Lab L T P
Sem Assign
Sem Sem Work
MST ment
PCE- Process
70 20 10 - - 3 1 - 4
1754 Instrumentation

UNIT I
INTRODUCTION TO INSTRUMENTS AND ITS CHARACTERISTICS Introduction to Instruments and
their representation: Introduction, Elements, Classification, Standards, Calibration procedures Static and
Dynamic Characteristics of Instruments, Specification of static characteristics, Selection of instruments.

UNIT II
TEMPERATURE, PRESSURE AND LEVEL MEASUREMENTS Temperature measurement:
Temperature scales, Non electrical methods, Electrical methods, Radiation methods
Pressure measurement: Moderate pressure measurement, High pressure measurement, vacuum
measurement
Level measurement: measurement techniques for Liquids and slurries, advance measurement techniques

UNIT III
FLOW MEASUREMENTS AND STUDY OF VALVES Flow measurement: Introduction, Review of
Venturimeter, orifice meters, rotameters, Pitot tube, electromagnetic flow meters
Introduction to Advanced flow measurement techniques: Hot Wire anemometer, Laser Doppler
anemometer, Ultrasound
Study of Valves: Types of Valves, Actuators, Positioners, Valve characteristics

UNIT IV
INTRODUCTION TO QUALITY CONTROL AND ANALYTICAL TECHNIQUES Need for Chemical
analysis in Petroleum industry. Crude Assay. Standard Test Methods. Introduction to principles of
Analytical techniques: electrochemical analysis, thermal analysis, electrophoresis, calorimetery, Hybrid
techniques

UNIT V
MISCELLANEOUS MEASUREMENTS AND ANALYSIS Density, viscosity, Refractormeter, pH and
redox potential measurements. Thermal conductivity gas analyzers. Oxygen determination. Orsat analysis

REFRENCE BOOKS
1. Patranabis, D, Principles of Industrial Instrumentation , 3rd Edn, Tata McGraw Hill, 2010.
2. Nakra and Chaudhary, Instrumentation measurement and analysis, 3rd Edn, Tata McGraw Hill, 2009.
3. Liptak Bela, Instrumentation Engineers Handbook, Vol- IV CRC Press, 2003