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(a) The emf of a half-cell measured relative to the standard hydrogen electrode (1)
all solutions at 1 mol dm3 concentration and gases at 1 atm pressure / 101 kPa
and at a stated temperature / 298K (1) Standalone mark
ALLOW pressure of 100 kPa 2
(b) Introducing another metal wire would set up its own p.d. / can
only measure a potential difference / need source and sink for
electrons / voltmeter requires two connections 1
(ii) E react = (+) 0.84 (V) (1)
Greater than zero therefore feasible (1) 2
(c) Cl2 is the stronger oxidising agent because Cl2 oxidises S from
(+)2 to (+)6 (1)
but l2 oxidises S from (+)2 to (+)2.50 (1) 2
3. (a) C10H8
ALLOW (C5H4)2
NOT (C6H4)2 1
0.0200 20.10
(ii) Moles MnO4 =
1000
= 0.000402 mol MnO4 (1)
5. (a) (i) Add silver nitrate (solution) (1) ACCEPT correct formula
(pale) yellow precipitate/solid(1)
OR
Add chlorine (solution)/bromine (solution) and hydrocarbon solvent (1)
Solvent goes purple/pink/violet (1)
2nd mark is dependent on 1st 2
24.0
(iii) 2.4(0) 10 4 OR 0.00024 (mol)
1000
The mark is for the answer 1
2.40 10 4
(iv) = 1.2(0) 104 (mol) OR 0.00012 (mol)
2
ALLOW TE from (iii)
The mark is for the answer 1
or
ACCEPT
Air
pump
(ii) Ereaction for the production of hydrogen is (+) 0.76 (V) (1)
smaller than reaction in (i) so is less likely (1)
OR
NO3 being the oxidised form of a redox couple with a more
positive E than E H+/ H2 (1)
OR
OH 2
H2 O OH 2
H2 O OH 2
OH 2 (1)
Both marks stand alone
[IGNORE charge] 2
[IGNORE how H2O ligand is bonded to central cation]
Accept hexaquacopper(II)
Reject formula
(iii) [Cu(NH3)4]+
OR [Cu(NH3)4(H2O)2]+ 1
Accept [Cu(NH3)2]+
Reject [Cu(NH3)6]+
Reject any 2+ complex
(ii) (If added too early) insoluble complex/black solid formed, making
titre too low
OR (If added too early) insoluble complex/black solid formed,
removes iodine from solution
OR (If added too early) insoluble complex/black solid formed,
causes inaccurate titre.
OR (If added too early) insoluble complex/black solid formed, not
all the iodine is titrated. 1
(iii) [Cu(NH3)4(H2O)2]2+ 1
Accept [Cu(NH3)4]2+
Reject [Cu(NH3)6]2+
(ii) all the others are 4s2 / have full 4s orbital (1)
Accept Cr and Cu/they do not have a full 4s orbital
Reject just only have one electron in 4s
OR
Have incomplete 4s orbital
The d subshell is more stable when either half or fully filled
OR
A specific example of chromium having half-filled or
copper having filled d sub-shell/set of d orbitals which
is more stable (1) 2
Accept sub-energy levels d shell
Reject half-filled or filled d orbital(s)
OR
amount thiosulphate for whole sample
= 0.0372 dm3 0.100 mol dm3 10
= 3.72 102 mol (1)
amount I2 = 1.86 102 mol (1)
(b) 5 1
(d) QWC
(It is acceptable because) well below the maximum safe limit (1)
Not significantly different from recommended daily dose
OR Variation in body mass means that different doses are acceptable
OR only if max 1 tablet per day is written on the bottle (1) 2
[8]
(b) (i) Zn / Iron (1) not the zinc ion or iron ion
more negative potential than -0.28V (1)
NB this mark must show evidence of use of the data
gives +E for reduction reaction (1)
consequential on second mark 3
(ii) rate too slow / activation energy too high / kinetically stable /
allow oxide layer if metal electrode specified (1)
non-standard conditions (1) 2
3. (a) (i) Use E values for reduction of Fe3+ to Fe2+ by Zn (E cell = + 1.53V) (1)
and Fe2+ to Fe by Zn (Ecell = +0.32V)(1)
They have positive E so are feasible (1) NOT will happen
OR
ALLOW Zn2+/Zn is more negative than both Fe3+/Fe2+ and Fe2+/Fe (1)
so zinc is a stronger reducing agent (1)
so zinc reducing both is feasible (1) 3
1
(ii) Reduction of Fe2+ has high activation energy / kinetically stable 1
(c) Amount MnO4 in 1st titration = 0.0182 dm3 0.0200 mol dm3
= 3.64 104 mol (1)
Amount Fe2+ in original solution = 5 above value = 1.82 103 mol (1)
Amount Fe2+ in 2nd titration = amount of Fe2+ and Fe3+ original solution (1)
= 0.0253 dm3 0.0200 mol dm3 5 = 2.53 103 mol
Amount of Fe3+ in original solution = 0.00253 0.00182 = 7.10 104 mol (1)
Amount zinc needed to reduce Fe3+ = 0.000710 = 0.000355 mol
Mass of zinc = 0.000355 mol 65.4 g mol1 = 0.0232 g (1) 2,3 or 4 SF
Consequential on their moles iron
The marks are for the following processes:
Either volume of MnO4 to moles of MnO4 (1)
Realising that 2nd titration measures total number of moles of iron (1))
Subtracting to get original moles Fe3+ (1)
Going to moles Zn then mass Zn (1)
OR
Volume MnO4 for Fe3+, which has been reduced by zinc (1) 3rd point
= 25.3 cm3 18.2 cm3 = 0.0253 dm3 0.0182 dm3 = 0.0071 dm3 (1) 4th
point
Amount of MnO4 = 0.0071 dm3 0.0200 mol dm3 = 1.42 104 mol (1) 1st
point
Amount Fe3+ reduced by zinc = 5 above value = 7.10 104 mol (1) 2nd
point
Amount zinc needed = 7.10 104 = 3.55 104 mol
mass of zinc needed = 3.55 104 mol 65.4 g mol1 = 0.00232 g (1) 5th
point 5
2
H3O+ in equation (1)
other ion in equation (1)
(Fe 2+) polarises the OH bond in ligand (1) 3
4. (a) (i) The potential (difference) / e.m.f. (of a halfcell) relative to the
standard hydrogen electrode (1)
Concentrations (of all ions) 1 mol dm3 and
(any gases at) pressure 1 atm (1)
Ignore any references to temperature 2
(ii) One from:
Can only measure a potential difference
Or
So that comparisons can be made between any half cells 1
3
5. (a) (i) Fe [Ar]
3d64s2
or 3d64s2
or 3d64s2
or 4s23d6 (1)
Fe2+ [Ar]
3d6
or 3d6
or 3d64s0 (1)
Letter d must be lower case
Any additional letters of numbers (0) 2
4
(iv) Green precipitate / solid foxy-red / red-brown / brown / orange
Both colours and precipitate / solid needed
NOT darkens 1
(b) (i) Emf of cell / potential difference of cell containing Fe2+ and Fe (1)
and standard hydrogen electrode / half cell NOT SHE
OR hydrogen electrode and 1 mol dm3 H+ and 1 atm H2 (1)
1 mol dm3 Fe2+
IGNORE temperature 3
5
6. (a) The emf of a half-cell measured relative to the standard hydrogen electrode (1)
all solutions at 1 mol dm3 concentration and gases at 1 atm pressure / 101 kPa
and at a stated temperature / 298K (1) Standalone mark
ALLOW pressure of 100 kPa 2
(b) Introducing another metal wire would set up its own p.d. / can
only measure a potential difference / need source and sink for
electrons / voltmeter requires two connections 1
(ii) E react = (+) 0.84 (V) (1)
Greater than zero therefore feasible (1) 2
6
(b) (i) Fe2+ [Ar] 3d6
Mn2+ [Ar] 3d5 (1) for both correct 1
(ii) Fe3+ is 3d5 / half filled d-subshell which is more stable than 3d6 (1)
Mn2+ is (already) 3d5 (which is more stable than 3d4) (1) 2
CN CN
NC CN
NC CN
Fe Fe
OR
NC CN
NC CN
CN CN
2
7
(ii) no. moles S 2 O 32 used = 12.5 0. 1 / 1000 = 1. 25 103 (1)
(c) Cl2 is the stronger oxidising agent because Cl2 oxidises S from
(+)2 to (+)6 (1)
but l2 oxidises S from (+)2 to (+)2.50 (1) 2
8
(b) (i) (Multiply iron half-equation by five to) cancel out electrons
OR balance electrons 1
0.0200 20.10
(ii) Moles MnO4 =
1000
= 0.000402 mol MnO4 (1)
9
10. (a) (i) uses E values to find Ereaction = (+) 1.57 (V) (1)
Reject 1.57
Zn + 2NO3 + 4H+ Zn2+ + 2NO2 + 2H2O (1) 2
Accept equation with equilibrium sign
Rejection equation with Zn on the right
(ii) Ereaction for the production of hydrogen is (+) 0.76 (V) (1)
smaller than reaction in (i) so is less likely (1)
OR
NO3 being the oxidised form of a redox couple with a more
positive E than E H+/ H2 (1)
OR
OH 2
H2 O OH 2
H2 O OH 2
OH 2 (1)
Both marks stand alone
[IGNORE charge] 2
[IGNORE how H2O ligand is bonded to central cation]
Accept hexaquacopper(II)
Reject formula
10
(b) (i) E for the reaction is 0.39 (V) (so not feasible) [value is required]. 1
Accept Cu2+ being the oxidised form of the redox couple with
the more negative E, will not oxidise I
(iii) [Cu(NH3)4]+
OR [Cu(NH3)4(H2O)2]+ 1
Accept [Cu(NH3)2]+
Reject [Cu(NH3)6]+
Reject any 2+ complex
(ii) (If added too early) insoluble complex/black solid formed, making
titre too low
OR (If added too early) insoluble complex/black solid formed,
removes iodine from solution
OR (If added too early) insoluble complex/black solid formed,
causes inaccurate titre.
OR (If added too early) insoluble complex/black solid formed, not
all the iodine is titrated. 1
11
(iii) Amount thiosulphate = 0.01655 dm3 0.1 mol dm3 (1)
= amount Cu2+ in 25.0 cm3 = 1.655 103 mol (1)
amount of Cu2+ in 250 cm3 = 1.655 103 10 (1)
mass of Cu (in sample) = 1.655 102 63.5 (1) = 1.051 g
% Cu in brass = 1.051 100/1.5 = 70 % (1)
[IGNORE sf]
[mass of 1.051g with working scores (4);
correct answer with no working scores (3).]
Mark consequentially 5
[22]
12
(c) (i) 1st mark
(simultaneous) oxidation and reduction of a (single) species/
substance/ reactant/compound/chemical
Reject oxidation and reduction occur at the same time
Or the oxidation state/number is both increased and
decreased of a (single) species/ substance/ reactant/
compound/chemical
Reject oxidation states are
Or a (single) species/ substance/ reactant/compound/
chemical both loses and gains electrons (1)
2nd mark
For a given type of atom within an ion/ molecule
Or Illustrated by a suitable example in which the
individual atom is identified (1) 2
12. (a) (i) The activation energy for the reaction is high
or to ensure that more molecules have E Ea. 1
Accept E > Ea
Reject to overcome Ea alone
Reject reactants kinetically stable;
reactants thermodynamically stable
13
(ii) protonates the alcohol (1)
Reject as a catalyst alone
providing H2O as the leaving group which is more easily displaced
by the bromide ion/is a better leaving group than hydroxide (1)
OR
reacts with NaBr (1)
to give HBr (which is the attacking reagent) (1) 2
14
(b) QWC
EITHER
Intermediate (ion) in SN1 is planar (1)
Accept intermediate carbocation is a planar molecule
intermediate molecule alone loses this mark
equal attack (by hydroxide ions) from either side (1)
produces a racemic mixture (1)
Reject attack by bromide ions
Note: Statement that the SN2 mechanism is consistent with
the information cannot score any marks.
OR
SN2 involves attack from one side (1)
so configuration of the product would be inverted (1)
leading to retention of optical activity so must be SN1 (1)
Accept forms one optical isomer only
Statement that the reaction is SN1 alone scores zero. 3
15
(d) (i) Addition of barium ions pulls equilibrium to r.h.s. (1)
increases [H+] and so lower pH/the pH falls (1) stand-alone mark 2
Reject ..so gets more acidic
13. A
[1]
14. A
[1]
15. C
[1]
16. D
[1]
17. (a) B 1
(b) C 1
[2]
18. (a) (i) Fe[Ar] 3d64s2 in either order, allowing superscripts to be subscripts
Fe[Ar] 3d6 or 3d64s0 in either order, allowing
superscripts to be subscripts
Letter d must be lower case 1
Reject any other letters
16
(ii)
OH 2
H2O OH 2
2+
Fe
H2O OH 2
OH 2
OH 2 OH 2
OR H2O Fe 2+ OH 2
H2O
OH 2
OR
H2O
H2O OH 2
Fe 2+
H2O OH 2
H2O
17
(ii) QWC
Emf of hydrogen electrode is zero stated or implied
e.g. if calculate Ecell = +0.44 V (1)
Potential for the reaction is positive so reaction is feasible
OR Fe half cell has more negative electrode potential
OR H+ and ()H2 has a more positive electrode potential (1) 2
18
1. (a) 1s2 2s2 2p6 3s2 3p6 3d6 4s2/4s2 3d6 OR 3d8 (4s0) (1)
Incomplete d shell (in the ion) (1) 2
1
QWC*(b) Cr3+(aq), Cr2+(aq)(IPt) 0.41(V) (1)
[O2(g) + 2H2O(l)], 4OH(aq)(IPt) +0.4(0) (V) (1)
ALLOW a state symbol omission in each.
ALLOW half equations
Can be given in a cell diagram
by application of the anti-clockwise rule oxygen will oxidise Cr2+
OR
E0 cell = (+) 0.81(V) and this is greater than (+) 0.6 (V)
OR
Cr2+ has more negative electrode potential so will reduce oxygen /
oxygen more positive etc. (1) 3
2
3. (a) (i) Add silver nitrate (solution) (1) ACCEPT correct formula
(pale) yellow precipitate/solid(1)
OR
Add chlorine (solution)/bromine (solution) and hydrocarbon solvent (1)
Solvent goes purple/pink/violet (1)
2nd mark is dependent on 1st 2
24.0
(iii) 2.4(0) 10 4 OR 0.00024 (mol)
1000
The mark is for the answer 1
2.40 10 4
(iv) = 1.2(0) 104 (mol) OR 0.00012 (mol)
2
ALLOW TE from (iii)
The mark is for the answer 1
3
(v) 1.2 104 100 = 0.012(0) (mol dm3)
ALLOW TE from (iv)
The mark is for the answer 1
[12]
or
ACCEPT
Air
pump
4
(iv) It is a powerful oxidising agent, E = +1.51 V
OR
It is self-indicating 1
[7]
5. (a) (i) uses E values to find Ereaction = (+) 1.57 (V) (1)
Reject 1.57
Zn + 2NO3 + 4H+ Zn2+ + 2NO2 + 2H2O (1) 2
Accept equation with equilibrium sign
Rejection equation with Zn on the right
(ii) Ereaction for the production of hydrogen is (+) 0.76 (V) (1)
smaller than reaction in (i) so is less likely (1)
OR
NO3 being the oxidised form of a redox couple with a more
positive E than E H+/ H2 (1)
OR
OH 2
H2 O OH 2
H2 O OH 2
OH 2 (1)
Both marks stand alone
[IGNORE charge] 2
[IGNORE how H2O ligand is bonded to central cation]
Accept hexaquacopper(II)
Reject formula
5
(iv) ligand exchange/replacement/substitution (1)
[Cu(H2O)6]2+ + 4Cl CuCl42 + 6H2O (1)
OR
[Cu(H2O)6]2+ + 4HCl CuCl42 + 4H+ + 6H2O (1) 2
ALLOW
Accept H2CuCl4 + 2H+ for CuCl42 + 4H+
(b) (i) E for the reaction is 0.39 (V) (so not feasible) [value is required]. 1
Accept Cu2+ being the oxidised form of the redox couple with
the more negative E, will not oxidise I
(iii) [Cu(NH3)4]+
OR [Cu(NH3)4(H2O)2]+ 1
Accept [Cu(NH3)2]+
Reject [Cu(NH3)6]+
Reject any 2+ complex
(ii) (If added too early) insoluble complex/black solid formed, making
titre too low
OR (If added too early) insoluble complex/black solid formed,
removes iodine from solution
OR (If added too early) insoluble complex/black solid formed,
causes inaccurate titre.
OR (If added too early) insoluble complex/black solid formed, not
all the iodine is titrated. 1
6
(iii) Amount thiosulphate = 0.01655 dm3 0.1 mol dm3 (1)
= amount Cu2+ in 25.0 cm3 = 1.655 103 mol (1)
amount of Cu2+ in 250 cm3 = 1.655 103 10 (1)
mass of Cu (in sample) = 1.655 102 63.5 (1) = 1.051 g
% Cu in brass = 1.051 100/1.5 = 70 % (1)
[IGNORE sf]
[mass of 1.051g with working scores (4);
correct answer with no working scores (3).]
Mark consequentially 5
[22]
7
If formula wrong but sulphate/ SO4 is present scores 1 (out of 2) 2
Accept Cu2SO4(OH)2
Accept Cu2(OH)2SO4
Accept (CuOH)2SO4
Reject HSO4 instead of SO4
(iii) [Cu(NH3)4(H2O)2]2+ 1
Accept [Cu(NH3)4]2+
Reject [Cu(NH3)6]2+
8
(v) (At high pressure) all active sites are occupied/full
OR
(At higher pressures) rate controlled by availability of sites. 1
Accept reverse argument for low pressure
[20]
(ii) all the others are 4s2 / have full 4s orbital (1)
Accept Cr and Cu/they do not have a full 4s orbital
Reject just only have one electron in 4s
OR
Have incomplete 4s orbital
The d subshell is more stable when either half or fully filled
OR
A specific example of chromium having half-filled or
copper having filled d sub-shell/set of d orbitals which
is more stable (1) 2
Accept sub-energy levels d shell
Reject half-filled or filled d orbital(s)
9
(iii) [Cr(H2O)6]3+ + OH [Cr(H2O)5OH]2+ + H2O
OR
[Cr(H2O)6]3+ + 2OH [Cr(H2O)4(OH)2]+ + 2H2O
OR
[Cr(H2O)6]3+ + 3OH Cr(OH)3 + 6H2O
OR
[Cr(H2O)6]3+ + 3OH [Cr(H2O)3(OH)3] + 3H2O
First mark is for the correct Cr product
Second mark is conditional on the first and is for the rest
of the equation correct and balanced 2
(c) (i) Check working correct answer can be obtained by not dividing
by 2 for 2nd mark and not multiplying by 2 for 4th mark
amount thiosulphate in titre = 0.0372 dm3 0.100 mol dm3
= 3.72 103 mol (1)
3.72 10 3
amount I2 = (1) = 1.86 103 mol
2
2nd mark cq on amount thiosulphate
amount dichromate in 25 cm3
1.86 10 3
= (1) = 6.2 104 mol
3
3rd mark cq on amount I2
10
OR
amount thiosulphate for whole sample
= 0.0372 dm3 0.100 mol dm3 10
= 3.72 102 mol (1)
amount I2 = 1.86 102 mol (1)
8. (a) B 1
(b) C 1
[2]
9. C
[1]
10. D
[1]
11. D
[1]
11
12. (a) (i) Fe[Ar] 3d64s2 in either order, allowing superscripts to be subscripts
Fe[Ar] 3d6 or 3d64s0 in either order, allowing
superscripts to be subscripts
Letter d must be lower case 1
Reject any other letters
(ii)
OH 2
H2O OH 2
2+
Fe
H2O OH 2
OH 2
OH 2 OH 2
OR H2O Fe 2+ OH 2
H2O
OH 2
OR
H2O
H2O OH 2
Fe 2+
H2O OH 2
H2O
12
(b) (i) QWC
Emf of cell/ potential difference of cell containing Fe (1)
dipping into a 1 mol dm3 Fe2+ solution (1)
And standard hydrogen electrode/half cell
OR hydrogen electrode and 1 mol dm3 H+ and 1 atm
H2
OR description of standard hydrogen electrode (1)
IGNORE temperature 3
RejectSHE
(ii) QWC
Emf of hydrogen electrode is zero stated or implied
e.g. if calculate Ecell = +0.44 V (1)
Potential for the reaction is positive so reaction is feasible
OR Fe half cell has more negative electrode potential
OR H+ and ()H2 has a more positive electrode potential (1) 2
13
3d 4s
1. (a) 2
Mn [Ar]
2+
Mn [Ar]
= 4.925 104mol
1
2. (a) (i) The potential difference between a standard hydrogen electrode
and the (half-) cell (1)
all concentrations measured at 1 mol dm3 and any gases are at 1 atm pressure (1)
2
(ii) Fluorine or F2 (1) 1
3. (a) Sc [Ar]
Cr [Ar]
Cr 3+ [Ar]
Ligand electrons
2
Correct electron structure for complex ion (1)
ligand electrons identified (1) 6 pairs identified stand alone mark
Consequential on structure of Cr3+
2
3+
(ii) OH2
H 2O OH 2
Cr
H 2O OH 2
OH2
(b) (i) Zn / Iron (1) not the zinc ion or iron ion
more negative potential than -0.28V (1)
NB this mark must show evidence of use of the data
gives +E for reduction reaction (1)
consequential on second mark 3
(ii) rate too slow / activation energy too high / kinetically stable /
allow oxide layer if metal electrode specified (1)
non-standard conditions (1) 2
5. (a) An element that has at least one of its ions has an incomplete d shell (1) 1
3
(b) (i) Coloured ions / compounds/ complexes/ solutions (1)
variable oxidation states (1) 2
(c) (i) Cr Cl H2 O 2
19.5 / 52 40 / 35.5 40.5 / 18 (1)
0.375 1.127 2.25
0.375/0.375 1.127/0.375 2.25/0.375 (1)
1 3 6
NB 2 method marks
6. (a) (i) 1
(ii) 1
4
(c) d orbitals/subshell/energy level split (in energy by
ligands)/diagram to illustrate (1)
Electron transitions/jumps from lower to higher energy level (1)
Absorbs light in visible region/reference to white light (1) 3
If imply or state that emission is occurring, only the first
marking point is available
[11]
(b)
OH2
H2 O OH 2
Ni
H2 O OH 2
OH2
(1)
Shape mark
Must be 3D ie wedges or dashes
labelled covalent between OH OR arrow to H2Oand labelled covalent
bond (1)
labelled dative covalent between O atom and ion (1) 3
5
8. (a) (i) Use E values for reduction of Fe3+ to Fe2+ by Zn (E cell = + 1.53V) (1)
and Fe2+ to Fe by Zn (Ecell = +0.32V)(1)
They have positive E so are feasible (1) NOT will happen
OR
ALLOW Zn2+/Zn is more negative than both Fe3+/Fe2+ and Fe2+/Fe (1)
so zinc is a stronger reducing agent (1)
so zinc reducing both is feasible (1) 3
(c) Amount MnO4 in 1st titration = 0.0182 dm3 0.0200 mol dm3
= 3.64 104 mol (1)
Amount Fe2+ in original solution = 5 above value = 1.82 103 mol (1)
Amount Fe2+ in 2nd titration = amount of Fe2+ and Fe3+ original solution (1)
= 0.0253 dm3 0.0200 mol dm3 5 = 2.53 103 mol
Amount of Fe3+ in original solution = 0.00253 0.00182 = 7.10 104 mol (1)
Amount zinc needed to reduce Fe3+ = 0.000710 = 0.000355 mol
Mass of zinc = 0.000355 mol 65.4 g mol1 = 0.0232 g (1) 2,3 or 4 SF
Consequential on their moles iron
The marks are for the following processes:
Either volume of MnO4 to moles of MnO4 (1)
Realising that 2nd titration measures total number of moles of iron (1))
Subtracting to get original moles Fe3+ (1)
Going to moles Zn then mass Zn (1)
6
OR
Volume MnO4 for Fe3+, which has been reduced by zinc (1) 3rd point
= 25.3 cm3 18.2 cm3 = 0.0253 dm3 0.0182 dm3 = 0.0071 dm3 (1) 4th
point
Amount of MnO4 = 0.0071 dm3 0.0200 mol dm3 = 1.42 104 mol (1) 1st
point
Amount Fe3+ reduced by zinc = 5 above value = 7.10 104 mol (1) 2nd
point
Amount zinc needed = 7.10 104 = 3.55 104 mol
mass of zinc needed = 3.55 104 mol 65.4 g mol1 = 0.00232 g (1) 5th
point 5
7
(d) (i) White precipitate /solid /suspension (1) NOT powder
Colourless solution (in excess ammonia) NOT clear (1) 2
(ii) [Zn(H2O)6] + 2NH3 [Zn(OH)2(H2O)4]+ 2NH4
2+ +
Or
[Zn(H2O)6]2+ + 2OH [Zn(OH)2(H2O)4]+ 2H2O
Or
[Zn(H2O)6]2+ + 2OH Zn(OH)2 + 6H2O
Or
[Zn(H2O)6]2+ + 2NH3 Zn(OH)2 + 2NH4+ + 4H2O (1)
[Zn(OH)2(H2O)4] + 4NH3 [Zn(NH3)4(H2O)2]2+ + 2OH + 2H2O
Or
Zn(OH)2 + 4NH3 [Zn(NH3)4]2+ + 2OH
(1) for cation formed
(1) for balancing equation with the correct species (2) 3
(e) (i) d-(sub) shell / orbitals are full / 3d10 arrangement of electrons (1)
No jumps of d-electrons /no d-d transitions (1)
Any mention of e falling back down or no splitting of d-orbitals and
second mark is not awarded 2
(ii) Cr is a transition metal / Cr can have d-d transitions /CrO42 is
yellow / Cr(+6) or Cr(VI) is yellow 1
[16]
8
(ii) The mark is for the shape
9
(b) (i) Emf of cell / potential difference of cell containing Fe2+ and Fe (1)
and standard hydrogen electrode / half cell NOT SHE
OR hydrogen electrode and 1 mol dm3 H+ and 1 atm H2 (1)
1 mol dm3 Fe2+
IGNORE temperature 3
11. (a) (i) Forms ions which have partially filled d-orbitals
OR
Forms ions which have a partially filled d-subshell 1
10
(c) Shape (1)
Bonding to correct atoms (1)
(4) (4)
CN CN
NC CN
NC CN
Fe Fe
OR
NC CN
NC CN
CN CN
2
11
(ii) no. moles S 2 O 32 used = 12.5 0. 1 / 1000 = 1. 25 103 (1)
(c) Cl2 is the stronger oxidising agent because Cl2 oxidises S from
(+)2 to (+)6 (1)
but l2 oxidises S from (+)2 to (+)2.50 (1) 2
3d 4s
13. (a) [ Ar ] (1)
3d 4s
[ Ar ] (1)
12
(ii) [Ni(H2O)6]2+ + 2NH3 [Ni(OH)2(H2O4)] + 2NH +4
OR
[Ni(H2O)6]2+ + 2NH3 Ni(OH)2 + 4H2O + 2NH +4
OR
[Ni(H2O)6]2+ + 2OH [Ni(OH)2(H2O4)] + 2H2O
OR
[Ni(H2O)6]2+ + 2OH Ni(OH)2 + 6H2O
IGNORE state symbols
IGNORE missing square brackets in any formula 1
13
1. (a) (i) *CH(CH3) (1) 1
(ii) (the three) OH groups (1)
allow adrenalin to form more hydrogen bonds with water
(than does benzedrine) (1) 2
(b) (i) 1
CH 2 CH(CH 3 )NH3 +(Cl )
(ii) 1
CH 2 CH(CH 3 )N C CH 3
(1)
H O
O
(iii)
CH 3 C CH 2 CH(CH 3 ) N C CH 3
O H
substitution(s) in ring at any position(s) (1)
production of amide (1) 2
(d) R NHCH 3 R H 2
C C C C
H H H NHCH 3
2. (a) (i) The enthalpy / heat / heat energy change / released when 1 mol of benzene is
formed (1) from its elements (1) under standard conditions 2
(ii) The enthalpy / heat / heat energy change when 1 mol of benzene burns (1) in
excess oxygen / burns to form carbon dioxide plus water / is completely oxidized
under standard conditions (1)
The second mark is not awarded if standard conditions are not mentioned in part
(i) or (ii). 2
1
6C + 3H 2 C6 H6
(b)
H1 H2
6CO 2 + 3H 2 O
For correct cycle shown (1) or equivalent equations
H1 = 6 (394) + 3 (286) = 3222 kJ (1) for either showing calculation or
answer
Hf = 3222 (3273) = +51 kJ mol1 (1) 3
(c) Benzene has electrons delocalised (1) Therefore bond energy NOT that of CC or
C=C
localised (1)
+51
6C(s) + 3H 2 (g)
2
3. (a) CH3CO+ (1)
Candidate may not identify electophile but may score this mark if they use the
correct electrophile in the mechanism
CH3COCl + AlCl3 CH3CO+ + AlCl4 (1) 2
AlCl 4-
(1)
+ H
OCCH 3
COCH3
(1)
(1)
COCH3
+ HCl
(b) Notes: The arrow for the first mark should start inside the ring and
go to the carbon of the CO group.
The arrow for the last mark should start on the bond and finish inside the ring.
AlCl 4-
(1)
+ H
OCCH 3
COCH3
(1)
(1)
COCH3
+ HCl
3
(c) There are several routes through this; all can score full marks
CN
CH3 O
C CH3 C OH
(1)
(1)
+ HCN
Dilute HCl (1) Heat 9under
reflux) (1)
Slightly acidic / slightly alkaline / or
buffered at name pH between 5 Dilute NaOH (1) followed
and 9 / mixture of KCN and acid. / by acid (1)
HCN plus KCN (1) CO 2 H
CH3 C OH
5
[10]
(c) (i) Sodium nitrite + aq / conc / dilute HCl / hydrochloric acid (1)
any temperature between 0 and 10 C or a range between 0 & 2
10 C (1)
4
+
N N(Cl) + OH
(iii)
N N OH + H + (Cl or HCl)
3 structures (2)
2 structures (1)
Balance (1)
It is not necessary to show the full structure for the diazo compound
e.g C6H5N2+ is acceptable.
Conditions phenol in alkali (1) yellow / orange / red ppt (1) 5
CH 3 CO + COCH 3
(1)
+ H (1)
(AlCl 4)
(1)
(ii)
COCH 3
+ HCl (+ AlCl 3 )
Marks:
formation of electrophile
attack on electrophile from ring
intermediate
removal of proton 4
5
O
CH 3 C O
(1) 2
OH OH OH
(c) (i) OH
OH
OH
Three correct 2 marks. 2 correct 1 mark 2
(ii)
O O
O O C CH 2 C
6. (a)
H
O C H
H
H C H
C C
C C
H C H
H
Fully displayed showing all C, H and circle or kekul structure. 1
6
(b) Understanding of electrophile positive/electron deficient entity
ACCEPT Species that accepts a lone pair of electrons (1)
Understanding of substitution exchange/replace for another entity / atom /
hydrogen (1) 2
(c)
OCH3
NO2
(d) C7H7OBr )
C7H6OBr2 ) Any two
C7H5OBr3 )
HBr ) 2
7
(ii) HNO3 + H2SO4 H2O + HSO4 + NO2+ (1)
Can be shown in two stages
Or
HNO3 + 2H2SO4 H3O+ + 2HSO4 + NO2+ (1)
NO 2+ NO 2
NO 2
(+ H + )
(b) 3
NO 2 NO 2 NO 2
NO 2
NO 2 NO 2 O2 N NO 2
NO 2
(1) (1) (1)
Vertical/right hand substituents must be shown with C to N bond
[Mark consequentially on structural formula given for
nitrobenzene in (a)(ii)]
8
(d) (i) H H 1
N C C H
O H
Allow:
NH C CH3
O
9
(d) (i) (polymer formed by) elimination/ removal of a small molecule/ water
(between two monomers) 1
(ii) any CIOC***COCl (1) and H2N*CH2*NH2 (1) 2
(iii) structure consequential on answer to (ii) showing amide link (1)
and extension of the chain (1) 2
(iv)
H H H H
N C C N C C N C C
H CH 3 O CH3 O H CH 3 O
CONH drawn out (1)
Show 3 units (1) 2
[16]
10
(b) (i) AlBr3/ AIC13 / FeBr3 / Fe
Formula must be correct; no names 1
(ii) Ignore curly arrows in this first step; mark species only
(consistent with catalyst)
+
Br 2 + AlBr 3 Br + AlBr4 (1)
Br
Br
+ +
Br + +H
Br BrAlBr3
10. (a) 6
solution X Y
Sodium fizzing/ effervescence/ no reaction /
carbonate bubbles (1) no bubbles (1)
Bradys reagent no change/ yellow /orange / orange-red or
(2,4-dinitro (stays) yellow/orange (1) yellow-orange precipitate /
phenyl hydrazine) (crystalline) solid (1)
Potassium no change Goes from orange to green/
dichromate + /(stays) orange (1) brownish green/dull green (1)
sulphuric acid
11
(b) (i) 1
(ii) 1
12
11. (a) (i) Fuming sulphuric acid / conc.sulphuric acid & sulphur trioxide (1)
Warm/(heat under) reflux/ hot/ high temperature (1)
[fuming/conc. could appear as a condition]
OR
concentrated sulphuric acid
(heat under) reflux for several hours (1) 2
(ii) SO3/ SO3H+ 1
13
12. (a) (i) C6H5ONa+ / C6H5ONa / C6H5O 1
Do not allow covalent O-Na
(ii)
1
No other Isomer allowed
OR
IGNORE bond to H of OH
(iii)
1
No ring substitution allowed
14
(ii)
15
(b) (i)
16
NOT reduction
NOT partial oxidation 1
(e) Any 2
set them on fire/heat (1)
both burn with a sooty flame (1)
add sodium (1)
both give off bubbles of gas /hydrogen/fizz/effervesce/sodium will
disappear/white solid forms (1)
add PCl5 (1)
misty fumes of HCl (1)
nitric and sulphuric acid (1) NOT nitration
produces yellow/brown/red products (1) NOT brown gas disappears
If they describe esterification to produce oily drops of the same ester
max 2
NOT reagents which produce no reaction eg. Bradys reagent
NOT decolorise bromine water
NOT decolorise bromine and iron / iron bromide 4
[19]
17
(ii)
Mark independently
ALLOW other three, four and five membered ring structures
ALLOW fully/partially displayed formulae
NOT open-chain structure with 2 C=C NOR C6H10Br2, open
chain with one C=C 2
(b)
18
15. (a) Delocalisation / -systern (1)
due to overlap of six p-orbitals
OR
Due to overlap of p-orbitals around the ring (1)
Confers stability / benzene at a lower energy level / more energy needed to break
bonds compared with having three separate / double bonds / cyclohexatriene,
Kekule structure (1) Standalone mark 3
19
(ii) AlBr3 + CH3CH2Br CH3CH2+ + AlBr4 (1)
ALLOW C2H5+ in this equation only
2 3
+
CH 2 CH 3 H
(1) for arrow Intermediate (1)
CH 2 CH 3 CH 2 CH 3 + HBr + AlBr3
Br AlBr3
H
OR
CH 2 CH 3
+
CH 2 CH 3 H
(1) for arrow Intermediate (1)
CH 2 CH 3 CH 2 CH 3
+
+ H
H
20
(ii) Naphthalene is more/very stable than double bonds suggest (1)
Must be a comparison for the 1st mark
Therefore the electrons/bonds may be/are delocalised
(over the ring system)
OR it is a delocalised system (1)
No TE from (i)
Delocalised mark can be given if delocalisation mentioned in (iii) 2
(iii) No
because it is likely to react like benzene / delocalised structure /
no double bonds
OR bromine not a strong enough electrophile without a catalyst
OR yes but only if bromine [NOT bromine solution] and a catalyst 1
21
(ii)
OH OH
Br Br
+3Br2 +3HBr
Br
2,4,6-tribromophenol (1)
rest of equation if for formation of a tribromophenol (1)
C6H5OH + 3Br2 C6H2Br3OH + 3HBr scores (1) 2
(iii)
O
O C
CH 3
C = O in ester must be shown 1
(b) Sn and conc hydrochloric acid (accept conc HCl) OR Fe and conc
hydrochloric acid (accept conc HCl)
IGNORE any references to NaOH
IGNORE references to Fe or Sn as a catalyst 1
22
(iii)
N=N OH
OR O
instead of
OH group 1
(b) Reduction
ALLOW redox 1
(d) (i)
OH ONa
(+ 2NaOH) (+ CH 3 CO 2 Na + H 2 O)
NHCOCH 3 NH 2
Organic formula fully correct (2)
Only one group reacting (1) 2
23
(ii) No because, phenol is not a strong enough acid to react with sodium
carbonate (1)
NOT because phenol is a weak acid 1
(e) (i) Van der Waals and (permanent) dipole (permanent) dipole, and
QWC hydrogen bonds (1)
Van der Waals between aromatic rings / everywhere / anywhere (1)
(Permanent) dipole force between carbonyl / C=O groups (1)
Hydrogen bonds eg between NH and O=C (1) 4
BUT must make it clear which atoms are involved
(ii) Van der Waals total forces in paracetamol are too strong
QWC OR
Hydrogen bonds in water are too strong
ALLOW carbon chain too long / large
ALLOW because of benzene ring 1
24
19. (a) (i) Conc(entrated) / fuming sulphuric acid / sulphur trioxide / SO3 (1) 1
Accept oleum (1)
Reject sulphuric acid / H2SO4
(b) (i) To avoid losing too much vanillin (in the filtrate when
crystallisation occurs) OWTTE 1
Accept to maximise the yield
Reject answer only referring to saturation
25
(ii) Cl2 2Cl (1)
PhCH3 + Cl PhCH2 + HCl (1)
PhCH2 + Cl2 PhCH2Cl + Cl (1)
any one of:
2 PhCH2 PhCH2CH2Ph
PhCH2 + Cl PhCH2Cl
2 Cl Cl2 (1)
[IGNORE curly arrows]
If the initiation or propagation steps are wrong, only the
termination step can score consequentially on any two of their
radicals. 4
Dot must not be on Ph penalise once
P instead of Ph penalise once
(iii) flask and vertical condenser need not be shown as separate items
(1) [Ignore direction of water flow; penalise sealed condenser]
gas entry into liquid in flask (1) [allow tube to go through the side
of the flask, but tube must not be blocked by flask wall]
Allow the gas to be bubbled down a tube coaxial with the
condenser bore.
Bubbling gas into a beaker OR other vessel without a
condenser 0 (out of 3)
heating from a electric heater/heating mantle/sand bath/water
bath/oil bath (1) diagram or words
labelling of diagram not necessary
[IGNORE uv source] 3
Reject just heat, Bunsen
[10]
1
Accept alternative substitution products with
SO3H group on other ring positions
SO3 H+
Accept multiple substitutions
Accept Displayed Formulae
Reject bonding to ring through H or O atom
26
(b) (i) (conc.) nitric acid (1)
Accept HNO3
Reject dilute, HNO3 (aq)
(conc.) sulphuric acid (1) Mark independently 2
Accept H2SO4
Reject H2SO4(aq)
Reject incorrect formula in conjunction with name
(ii) NO2+ 1
Reject NO2+
(d) Oxidation 1
Accept partial oxidation
Reject redox
Reject full oxidation
27
(e) sodium/ potassium dichromate((VI)) (1)
Accept Na2Cr2O7/ K2Cr2O7
sulphuric acid (1)
or
Potassium manganate ((VII)) (1)
Accept H2SO4
dil. or conc.
acidified dichromate = 1
or
KMnO4
Sulphuric acid (1) 2
Accept H2SO4
acidified manganate = 1
OR
Potassium manganate ((VII)) (1)
Sodium hydroxide (1)
Reject incorrect oxidation numbers
Reject incorrect Formula in conjunction with correct name
[12]
H C H
+
H N H
H
Positive charge must be on the N atom
The minus charge must be on the O in the CO if no
delocalisation shown 1
Accept delocalised carboxylate group with a negative charge
shown
Reject compressed structural formula
28
(ii) (H+ from) COOH (group) protonates the NH2(group) 1
+
(b) (i) NH3CH2COOH / +H3NCH2COOH / +H3NCH2COOH
OR written right to left
OR
O OH
H C H
+
NH3 1
Accept CO2H
OR
NH3+Cl
Or NH3Cl
Reject molecular formula
29
(ii) NH2CH2COO / NH2CH2CO2 /
O O
H C H
NH2 1
Accept COONa
or
COONa+
Reject molecular formula
(iii) CH3CONHCH2COOH/
O OH
H C H
H N
C O
H C H
H 1
Accept CH3CONHCH2CO2H
OR no reaction (1)
Reject molecular formula
(iv) NH2CH2COOCH3 /
H
O O C H
C
H
H C H
H N H 1
Accept NH2CH2CO2CH3
30
(c) (i) (Glutamic acid molecule) has four different groups attached
to a C (atom)
Or
(Glutamic acid molecule) has four different groups attached
to a chiral centre
Accept contains an asymmetric carbon (atom)
Or
molecule has no plane of symmetry
Reject just has a chiral centre
Or
Just the molecule is asymmetrical
OR
has mirror images which are not superimposable 1
(ii) (the isomers) rotate the plane (or polarisation) of (plane-) polarised
light (1)
Accept .rotate plane polarised light
in opposite directions (1)
Reject just in different directions
Ignore any reference to polarimeter 2
HO C(CH 2)4 C OH
COOH(CH2)4COOH
Or COCl(CH2)4COCl
[13]
31
23. (a) (i)
SO3 H
(b) (i)
SO3 H
H3 C CH 3
Allow TE from (a)(i) 1
Accept
SO3 H
CH 3 CH 3
Formula for 2,6-dimethyl benzene sulphonic acid
32
(ii) Reagent X: CH3Cl (1)
Catalyst Y: AlCl3 (1)
Allow TE from (b)(i) e.g. CH3CH2Cl if an ethylbenzene 2
Accept CH3Br / CH3I (1)
Accept Al2Cl6/AlBr3/AlI3 (1)
One correct name and one correct formula (2)
Names for both answers (1 max)
(ii) Hydrogen bonding interactions between dettol and water are weaker
than those between water molecules
OR
Hydrogen bonding interactions between dettol and water are weaker
thatn the van der Waals forces in dettol
Look for good use of scientific language. Answer must include a
specific type of intermolecular force 1
Accept hydrogen bonding between dettol and water is weak
Reject dettol molecule is too big
Accept dettol can only form one H-bond with water/only has
one OH group to H-bond with water
Reject arguments based on lone pairs of electrons on OH group
being delocalised into the ring
[10]
33
(ii)
CH 3 CHCH 3 + AlCl 3 CH3 CHCH3 + AlCl 3 Br (1)
Br
H CH 3
CH 3 CHCH 3 + CH
+
(1) (1) CH 3
( Br AlCl 3 ) CH 3
H CH 3
CH
+ CH + (H +/ HBr + AlCl3 )
CH 3
(1) CH 3
OR
CH 3
H CH 3
H C Br AlCl 3
+ CH + Br AlCl 3
CH 3
(1) (1) (1) CH 3
( Br AlCl 3 ) CH 3
H CH 3
CH
+ CH + (H +/ HBr + AlCl3 )
CH 3
(1) CH 3
34
OR
CH3 CHCH 3
+ AlCl 3 CH 3 CHCH 3 + Br AlCl 3
Br +
+ H
CH 3 CHCH 3 CH(CH 3 )2
+
+HBr + AlCl 3
+ H Br AlCl 3
CH(CH 3 ) 2
CH(CH 3 ) 2
Accept C2H5CH2+
Reject C3H7+
35
(c) (i) First mark
sodium nitrite /sodium nitrate(III)/NaNO2 (1)
Second mark
hydrochloric acid / HCl(aq) (1)
IGNORE concentration of acid
2nd mark is conditional on NaNO2 or HNO2 2
Reject HNO2
Reject HCl/hydrogen chloride
(iii)
N N
OH
N=N link, can be shown linear (1)
IGNORE other atoms
Remainder correct (1) 2
IGNORE position of OH group.
Accept ONa or O instead of OH
Reject N=NO
36
(d) (i) QWC
First two
add 2,4-dinitrophenylhydrazine/Bradys reagent (1)
orange/yellow ppt (1)
Allow this second mark if the name of the reagent is
slightly incorrect e.g. 2,4-diphenylhydrazine
Accept 2,4-dnp(h)
Accept any combination of yellow and orange
Must be ppt
Reject just Red ppt
Reject solid for ppt
OR
IR absorption due to C=O stretch (1)
at 1700 cm1 (1)
Third mark
Does not give a silver mirror with ammoniacal silver nitrate
(or Tollens reagent)
Accept no change with Tollens
OR
no red ppt/stays blue with Fehlings or Benedicts solution
Reject Iodoform
OR
H+/Cr2O72 does not change from orange to green/stays orange
OR
H+/MnO4 does not change from purple to colourless/stays purple (1) 3
(ii) the C=O group is polar and the nucleophile attacks the + carbon (1)
whereas C=C is non-polar/electron-rich, the double bond/-bond
is attacked by electrophiles (1)
OR
C=O is polar and C=C is nonpolar (1)
Nucleophile attacks the + carbon in C=O and
electrophiles attack the /double bond in C=C, which
is electron rich/non-polar (1) 2
37
(iii)
H3 C H3 C O:
C O C
H3 C H3 C CN
:CN
H3 C O: H CN H3 C OH
C C + :CN
H3 C CN H3 C CN
both curly arrows in 1st diagram, attack by cyanide, arrow
must start from C or ve charge on C not N and ve charge
must be present somewhere on ion; lone pair not essential.
Arrow must start from bond between C and O
and point towards the O (1)
Accept curly arrow from O to H+
Intermediate lone pair not essential but negative charge is
essential (1)
Arrow from O (lone pair not needed) or negative charge to HCN
or H+, this can be shown on the diagram of the intermediate (1)
If HCN is used the arrow from HCN bond is required
Any other ketone or aldehyde, max (2) 3
[22]
25. (a) (i) The activation energy for the reaction is high
or to ensure that more molecules have E Ea. 1
Accept E > Ea
Reject to overcome Ea alone
Reject reactants kinetically stable;
reactants thermodynamically stable
38
(iii) H-bonding between water and the alcohol not strong
enough to overcome hydrophobic interactions /effect of
alkyl group (1)
acid and alcohol form ionic species/C4H9OH2+ which
is more soluble (1) 2
Accept butyl group
39
(b) QWC
EITHER
Intermediate (ion) in SN1 is planar (1)
Accept intermediate carbocation is a planar molecule
intermediate molecule alone loses this mark
equal attack (by hydroxide ions) from either side (1)
produces a racemic mixture (1)
Reject attack by bromide ions
Note: Statement that the SN2 mechanism is consistent with
the information cannot score any marks.
OR
SN2 involves attack from one side (1)
so configuration of the product would be inverted (1)
leading to retention of optical activity so must be SN1 (1)
Accept forms one optical isomer only
Statement that the reaction is SN1 alone scores zero. 3
40
(d) (i) Addition of barium ions pulls equilibrium to r.h.s. (1)
increases [H+] and so lower pH/the pH falls (1) stand-alone mark 2
Reject ..so gets more acidic
(ii) Step 1
(electrophilic) substitution (1)
Accept sulphonation
Reject Nucleophilic substitution
Step 2
neutralisation or acid-base (1) 2
41
(ii) Reagent
C12H25Cl
OR
C12H25Br (1)
Accept (1-)chlorododecane
C12H25I
Catalyst
AlCl3 (1) 2
Accept Al2Cl6
Accept Aluminium chloride
Reject AlCl4
Reject AlCl4
[8]
42
(c) Note: although many candidates have calculated the empirical formula,
this is not required.
Molecular formula of ibuprofen = C13H18O2 (1)
Allow if given at end
Allow marks for masses and number of moles if answers are
rounded to 2 SF in OR but method is correct.
EITHER
Mr = 206 (1)
1
1g= mol = 4.854 103 mol
216
mass CO2 produced from 13 C
= 13 44 4.854 103 = 2.78 g (1)
mass H2O from 18 H
= 9 18 4.854 103 = 0.787 g (1)
OR
(2.78 12)
Mass C = = 0.758g
44
(0.786)
Mass H = = 0.0873g (1)
9
(0.758)
Moles C = = 0.0632
12
Moles H = 0.0873 (1)
Ratio C:H = 0.0632: 0.0873 = 13:18 (1) 4
(d) (i) (Aspirin and ibuprofen) both contain same (types of)
bond(s)(so absorb at same frequency/wavenumber) 1
Accept list of at least 4 bonds which are present in both
Reject groups for bonds
43
(iii) 57 in Ibuprofen
C4H9+ /CH3CH(CH3)CH2+/CH(CH3)2CH2+
OR
C2O2H+/CCO2H+ (1)
Accept structural or displayed formulae
Do not allow lines at
15 (CH3+)
76 (C6H4+)
43 (C3H7+ or CH3CO+)
45 (COOH+)
as present in both
Aspirin
59 (1) OCOCH3+ /C2H3O2+ (1)
OR
121 (1) C6H4CO2H+ (1)
OR
180 (1) C9H8O4+ (parent ion) (1)
OR
137 (1) C6H4(CO2H)O+ (1)
Penalise no/wrong charges once only 3
[14]
28. A
[1]
29. B
[1]
30. D
[1]
31. B
[1]
44
32. A
[1]
33. B
[1]
34. C
[1]
35. D
[1]
36. (a) B 1
(b) B 1
(c) A 1
(d) D 1
[4]
45
(ii)
+
Br Br (1)
Br Br (1)
Br Br
Br
(1)
Br 3
(b) (i)
Br
+ Br 2 + HBr
1
46
(ii) QWC
Cyclohexene
Addition of Br does not involve bond breaking
/results in more exothermic reaction than loss of H+ (1)
Benzene
No Br available in benzene reaction (1) Stability of
ring regained by loss of H+ (1) 3
(d) Three / 3 1
[17]
47