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Beate Treffler
BU Additives
Technical Marketing Waxes
20.06.2013
Clariant Waxes
for PVC Processing
CONTENT
PRODUCTS
APPLICATIONS
PERFORMANCE
Public
Beate Treffler
BU Additives
Technical Marketing Waxes
20.06.2013
3 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
Montan Waxes -
Unique Lubricants for PVC Processing
Drop point Acid value
[C] [mg KOH/g]
Licowax E ~ 81 ~ 18
+
Licowax OP Ca
~ 99 ~ 12
Licolub WE 4 ~ 80 ~ 26
Licolub WM 31 ~ 74 ~ 12
Licolub WE 40 ~ 76 ~ 20
n
~ C30 ~ C18
COOH = Montanic acid COOH = Fatty acid = CO-function (polar)
Trademark registered by Clariant in numerous countries
4 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
~ 1800
Licowax PED 191 ~123 ~ 17
(140 C)
Licolub H 12 / ~ 350
~104 ~ 17
Licowax PED 521 (120 C)
Licowax C /
~ 142 - ~8
Licolub FA 1 veg. based
Montan Waxes -
Unique Lubricants for PVC Processing
Effects Benefits
Public
Beate Treffler
BU Additives
Technical Marketing Waxes
20.06.2013
8 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
5) PVC Pipe
Public
Beate Treffler
BU Additives
Technical Marketing Waxes
20.06.2013
11 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
20 GMS (FAE)
Weight: 500 mg
Surface: 3 cm FACE / FAE
18 Heating rate: 120 K/h
Atmosphere: 1 l air/min,
16
14
12
Votality [%]
10
FACE
8 Licowax E
Licolub WE 4
6
Licowax OP
4 Licolub WE 40
2
0
180 200 220 240 260 280
Temperatur [C]
12 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
0
0 2 4 6 8 10 12 14
v [cm/s]
13 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
80
Formulation:
Vinnolit S 3160 100 phr
Octyl tin stabilizer 1,5 phr
79 Processing Aid (Arcylate) 1 phr
Test product 1 phr
Parameters:
78 (according to DIN EN ISO 306)
Initial temp.: 30 C
Heating rate: 50 K/h
Method: B (50 N)
77
76
75
74
without Glycerol dioleate Mixture of Licowax E Licolub WM 31 Licocare SBW 11
fatty acid TP
complex esters
(Gl 2)
VN 107078-080
Clariant Waxes
for PVC Processing
FILM COMPOUNDS
Public
Beate Treffler
BU Additives
Technical Marketing Waxes
20.06.2013
15 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
Formulation:
30 S-PVC, k value 60 100 phr
Sn-Octyl mercaptide 1,5 phr
MBS Impact modifier 5,0 phr
PMMA Processing aid 1,0 phr
GDO 0,3 phr
25 Lubricant 0,3 phr
20
Sticking power
15
10
0
800 900 1000 1100 1200 1300 1400 Licowax E
Licolub WE 4
Time [sec.]
Licolub WM 31
16 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
Formulation:
S-PVC, k value 60 100 phr
30 Sn-Octyl mercaptide
MBS Impact modifier
1,5 phr
5,0 phr
PMMA Processing aid 1,0 phr
GDO 0,3 phr
Lubricant 0,3 phr
25
Collin Two Roll Mill
220 g, 195 C, 15/20 rpm
Sticking power
20
15
10
0 FACE/FAE
0 200 400 600 800 1000 1200 1400
Licowax E
Time [sec.]
Licocare SBW 11 TP
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
90
88
Formulation:
100,0 parts M-PVC, k value 60
86 8,0 phr MBS Impact modifier
Transparency [%]
82
80
78
76
Licowax E Licolub WE 4 Licolub WM 31 FACE/FAE
0,5 mm 2 mm
17
18 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
Two roll mill (190 C, 16,7/20 rpm) Haake kneader (40 rpm, 140C, 63 g)
20 150
16 120
Time to sticking [min.]
4 30
0 0
FACE/FAE/ Licowax OP FACE/FAE/ Licowax OP
Ca-Soap Ca-Soap
19 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
Formulation:
30 S-PVC, k value 60 100 phr
Ca/Zn Stabilizer 3,0 phr
MBS Impact modifier 5,0 phr
PMMA Processing aid 1,0 phr
GDO 0,3 phr
25 Lubricant 0,3 phr
20
Sticking power
15
10
0 Licowax E
800 1000 1200 1400 1600 FACE/FAE
time [sec.] Licolub WE 4
20 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
Transparency is excellent
Clariant Waxes
for PVC Processing
PROFILE / PIPES
COMPOUNDS
Public
Beate Treffler
BU Additives
Technical Marketing Waxes
20.06.2013
22 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
300
250
200
150
100
Formulation: phr
S-PVC, k value 68 100,0
50 CaCO3 (90T) 15,0
Ca/Zn Core stabilizer 1,18
0 Test products 0,35
0.085
0.08
0.075
0.07
150
100
50
0
p1 p2 p3 p4 p5
Extrusiometer E 30 M
1 phr Hydrocarbon wax 1 phr Licocene PP 6102 D= 30 mm, 25 L/D
n= 30 rpm,
180-185-190-200-210C
1 phr Licocene PE 4201 0,7 phr Licocene PP 6102 round-section die: 215C
25 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
8 0,04
E-value [kWh/kg]
Output [kg/h]
6 0,03
4 0,02
2 0,01
0 0
02
02
01
x
wa
61
61
42
on
PP
PP
PE
rb
Extrusiometer E 30 M
e
e
e
ca
en
en
en
ro
D= 30 mm, 25 L/D
oc
oc
oc
yd
ic
ic
ic
n= 30 rpm,
rH
rL
rL
rL
180-185-190-200-210C
ph
ph
ph
ph
0,
26 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
150
45 75 Formulation:
Dosage: 0,3 phr Dosage: 0,2 phr S-PVC k-value 68 100 phr
Ca/Zn-Stabilizer compound 2,4 phr
70 Impact modifier 7 phr
40 Processing aid 1 phr
65 TiO2 4 phr
Output [kg/h]
Chalk 6 phr
Torque [%]
Di stearyl phthalate 0,5 phr
35 60 Calcium stearate 0,5 phr
Oxidized PE-wax 0,2 phr
Test product 0,2 - 0,3 phr
30 55
50
25
45
Output
20 40
standard PE Licocene PP Licocene PE Licocene PP Licocene PE Torque
wax 6102 4201 6102 4201
28 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
Formulation:
S-PVC k-value 68 100 phr
200 Ca/Zn-Stabilizer compound 2,4 phr
Impact modifier 7 phr
Processing aid 1 phr
TiO2 4 phr
180 Chalk 5 phr
Di stearyl phthalate 0,4 phr
Torque [Nm]
140
120
100
without 30 rpm without 45 rpm WE 40 30 rpm WE 40 45 rpm
Formulation:
S-PVC k-value 68 100 phr
Ca/Zn-Stabilizer compound 2,4 phr
0.095 Impact modifier 7 phr
Processing aid 1 phr
e - Value [kWh/kg]
TiO2 4 phr
Chalk 5 phr
Di stearyl phthalate 0,4 phr
Oxidized PE-wax 0,15 phr
PE Wax 0,20 phr
0.09 Test product 0,3 phr
0.085
0.08
without 30 rpm without 45 rpm Licolub WE 40 Licolub WE 40
30 rpm 45 rpm
Weber CE 3Z, D= 52 24 mm, n= 30 rpm, Temperature: 185-185-185-185C, flat die: 190 C (VN99498ff)
30 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
300 18
16
250
14
200 12
10
150
8
Basic formulation:
S-PVC, k value 64, impact mod, 100,0 phr
100 Ca-Stearate 0,5 phr 6
Zn-Stearate 1,0 phr
Hydrotalcit 1,0 phr 4
-Diketone 0,6 phr
50 Di-Trimethylol Propane 0,5 phr
Phenolic Antioxidant 0,1 phr 2
0 0
0,3 phr FACE 0,3 phr Licolub WE 40
+ 0,2 phr Licowax PE 520 + 0,2 phr Licowax PE 520 Output
Fusion time
Extrusiometer
(70-180-190-195C, Brabender Plastogram
screw 5/2, die 75/5, 60 rpm) (35 g, 150C, 40 rpm)
31 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013
Public
Beate Treffler
BU Additives
Technical Marketing Waxes
20.06.2013
33 Public, Clariant Waxes for PVC - General
Beate Treffler, BU Additives, Technical Marketing Waxes, 20.06.2013