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1. What is the value of standard enthalpy change when infinitely dilute solutions of CaCl2 and Na 2CO3 are
mixed? Given f H for Ca 2 (aq), CO32 (aq) and CaCO3 (s) are 129.80, 161.65, 288.5 kcal mol1
respectively. Assume CaCO3 to be completely insoluble.
(A) +2.95 kcal (B) 2.95 kcal (C) 20.95 kcal (D) data insufficient
3. Which of the following compound is ionic and contains both sigma and pi covalent bonds?
I. CaC2 II. NH4Cl III. Al4C3
IV. Mg2C3 V. NaCN
7. For an isothermal free expansion of an ideal gas into vacuum, which one of the following set of values is
correct?
(A) U 0, q 0; w 0 (B) U 0; q 0; w 0
(C) U 0, q 0; w 0 (D) U 0; q 0; w 0
8. Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals.
1 1
I. (i) n 3, 2, m 2, ms (ii) n 3, 2, m 1, ms
2 2
1 1
II. (i) n 3, 1, m 1, ms (ii) n 3, 2, m 1, ms
2 2
1 1
III. (i) n 4, 1, m 1, ms (ii) n 3, 2, m 1, ms
2 2
1 1
IV. (i) n 3, 2, m 2, ms (ii) n 3, 2, m 2, ms
2 2
The correct option is :
(A) I, II (B) II, III (C) III, IV (D) I, IV
10. If the effect of finite molecular size is dominating for a given volume then :
(A) Observed pressure is greater than pressure predicted by the ideal gas law
(B) Observed pressure is lesser than pressure predicted by the ideal gas law
(C) Observed pressure is equal to pressure predicted by the ideal gas law
(D) None of these
11. In which of the following options order of arrangement does not agree with the variation of property
indicated against it ?
I. Al3 Mg 2 Na F (Increasing ionic size)
II. B C N O (Increasing first ionization enthalpy)
III. I Br Cl F (Increasing electron gain enthalpy)
IV. Li Na K Rb (Increasing metallic radius)
The correct option is :
(A) I, II (B) II, III (C) III, IV (D) I, IV
12. One volume of a gaseous compound of hydrogen, carbon and nitrogen gave upon combustion 2 volumes of
CO 2 , 3.5 volumes of H 2 O, and 0.5 volume of N 2 , all measured at the same temperature and pressure.
What is the empirical formula of the compound?
(A) CH5 N (B) C2 H 7 N (C) C2 H14 N 2 (D) C2 H 7 N 2
14. Which of the following property of liquid is correctly related with temperature?
I. Vapour pressure of liquid increases with increase in temperature.
II. Surface tension of liquid decreases with increase in temperature.
III. Viscosity of liquid decreases with increase in temperature.
The correct choices is :
(A) Only I (B) II and III (C) I, II (D) I, II, III
17. An optically active alkyne gives optically inactive 3-ethyl hexane on catalytic hydrogenation. Alkyne is :
[X] [Y]
(A)
(B)
(C)
(D)
20. What is the expected order of reactivity of the following compounds in electrophilic nitration?
(A) I > II > III > IV (B) IV > III > II > I (C) III > IV > I > II (D) II > I > IV > III
21. Which of the following statements are correct about CO32 ?
I. The hybridization of central atom is sp3
II. Its resonance structure has one C O single bond and two C O double bonds
III. The average formal charge oxygen atom is 2 / 3 units
IV. All C O bond lengths are equal
The correct option is :
(A) I, II (B) II, III (C) III, IV (D) I, IV
22. Which of the following series contain a free radical, a nucleophile and an electrophile?
(A) Br, NH3, BF3 (B) NH3 ,H 3O , Br2
(C) H 2O, Cl, NH 3 (D) Cl, CH 4 , NH 3
23. Which of the following reaction sequence can be best applied to prepare ?
(A)
(B)
(C)
(D)
25. At a particular temperature and atmospheric pressure, the solid and liquid phases of a pure substance can
exist in equilibrium. Which of the following defines this temperature ?
I. Normal melting point II. Equilibrium temperature
III. Boiling point IV. Freezing point
The correct option is :
(A) I, II (B) II, III (C) III, IV (D) I, IV
26. Hardness of water may be temporary or permanent. Permanent hardness is due to the presence of :
I. Chlorides of Ca and Mg in water
II. Sulphates of Ca and Mg in water
III. Hydrogen carbonates of Ca and Mg in water
III. Carbonates of alkali metals in water
The correct option is :
(A) I, II (B) II, III (C) III, IV (D) I, IV
27. A substance which gives brick red flame and breaks down on heating to give oxygen and a brown gas is :
(A) Magnesium nitrate (B) Calcium nitrate
(C) Barium nitrate (D) Strontium nitrate
28. Which of the following is/are the correct reasons for anomalous behaviour of lithium ?
I. Exceptionally small size of its atom II. Its high polarising power
III. It has high degree of hydration IV. Exceptionally low ionisation enthalpy
The correct option is :
(A) I, II (B) II, III (C) III, IV (D) I, IV
29. Which of the following statements is NOT CORRECT? Answer on the basis of given figure.
(A) The two bridged hydrogen atoms and two boron atoms lie in one plane
(B) Out of six B H bonds two bonds can be described in terms of 3 centre 2 electron bonds
(C) Out of six B H bonds four B H bonds can be described in terms of 3 centre 2 electron bonds
(D) The four terminal B H bonds are two centre-two electron regular bonds
30. Identify the correct resonance structures of carbon dioxide from the ones given below :
(A) OC O (B) OCO (C) O C O (D)
O C O
32. Two balls A and B are thrown with speed u and u/2 respectively. Both the balls cover the same horizontal
distance before returning to the plane of projection. If the angle of projection of ball B is 15 with the
horizontal, then the angle of projection of A is :
1 1 1 1 1 1 1 1 1 1
(A) sin 1 (B) sin (C) sin (D) sin
8 2 8 3 8 4 8
33. The horizontal range and maximum height attained by a projectile are R and H, respectively. If a constant
horizontal acceleration a g / 4 is imparted to the projectile due to wind, then its horizontal range and
maximum height will be :
H H
(A) R H , (B) R , 2 H (C) R 2H , H (D) R H , H
2 2
35. The ratio of the distance carried away by the water current, downstream, in crossing a river, by a person,
making same angle with downstream and upstream are respectively as 2 : 1. The ratio of the speed of
person to the water current cannot be less than :
(A) 1/3 (B) 4/5 (C) 1/5 (D) 4/3
37. A train is moving at a constant speed V. Its driver observes another train in front of him on the same track
and moving in the same direction with constant speed v. If the distance between the trains be x, then what
should be the minimum retardation of the train so as to avoid collision?
(A)
V v 2 (B)
V v 2 (C)
V v 2 (D)
V v 2
x x 2x 2x
38. With what velocity should a particle be projected so that its height becomes equal to the radius of the
earth?
1 1 1 1
GM 2 8GM 2 2GM 2 4GM 2
(A) (B) (C) (D)
R R R R
40. A solid uniform sphere of mass m and radius a is free to rotate about a diameter
and it is so fixed to a point O at a distance R from its centre C on a horizontal
surface that the sphere rolls without slipping along the circumference of a radius R
on the surface. The angular velocity of rotation of C is . The kinetic energy of the
sphere is :
ma2 2
m 2 5 R 2 2a 2
(A)
10 R 2 7R 2
2a 2
(B)
7
1 1 1
(C) mR 2 2 (D) mR 2 2 ma 2 2
2 2 5
41. A straight metal rod of length 3l is bent through the right angle
as shown. The bent rod is then placed on a rough horizontal
table. A light string is attached to the vertex of the right angle.
The string is then pulled horizontally so that the rod slides at a
constant velocity. Find the angle that sides 2l would make
with the string:
(A) tan1 1 / 2 (B) tan1 1 / 3 (C) tan1 1 / 4 (D) tan1 2
42. Under the action of a force, a 3 kg body moves such that x t 2 / 2 where position x is in meter and t is in
second. The work done by the force in first 3 seconds is :
(A) 13.5 J (B) 27 J (C) 81 J (D) 109 J
44. A body of mass m accelerates uniformly from rest to velocity v0 in time t0 . The instantaneous power
v0
delivered to the body when its velocity is is :
2
mv 2 mv02 mv02
(A) (B) (C) (D) None
4t0 t0 2t0
48. A block of ice at 10C is slowly heated and converted to steam at 100C. Which of the following curves
represents the phenomenon qualitatively?
A B C D
TEMP.
TEMP.
TEMP.
TEMP.
51. An ideal gas of mass m in a state A goes to another state B via three
different processes as shown in figure. If Q1, Q2 and Q3 denote the heat
absorbed by the gas along the three paths, then :
(A) Q1 < Q2 < Q3 (B) Q1 < Q2 = Q3
(C) Q1 = Q2 > Q3 (D) Q1 > Q2 > Q3
52. A number of droplets, each of radius r, combine to form a drop of radius R. If T is the surface tension,
then the rise in temperature will be : (Given density = 1 and specific heat capacity = 1)
2T 3T 1 1 1 1
(A) (B) (C) 2T (D) 3T
r r r R r R
53. A particle executes SHM between x = A and x = +A. The time taken for it go from 0 to A/2 is T1 and to
go from A/2 to A is T2 then :
(A) T1 < T2 (B) T1 > T2 (C) T1 = T2 (D) T1 = 2T2
54. In a mixture of gases, the average number of degrees of freedom per molecule is 6. The rms speed of the
molecules of the gas is c. The velocity of sound in the gas is :
c 3c 2c c
(A) (B) (C) (D)
2 4 3 3
dT
55. A body cools according to the law K (T T0 ) where K is a constant and T0 is the temperature of the
dt
surroundings. If the initial temperature of the body is 4T0, the time in the which the temperature falls to
2 T0 is :
n 3 n 2 2 n 2 2 n 3
(A) (B) (C) (D)
K K K K
56. A steel wire is suspended vertically from a rigid support. When loaded with a weight in air, it extends
by la. When the weight is completely immersed in water, the extension is reduced to lw. Then the relative
density of the material of the weight is :
la la lw lw
(A) (B) (C) (D)
la lw lw la lw la
57. Two soap bubbles at same temperature of radii a and b combine to form a single bubble of radius c
isothermally. If P is the external pressure, then the surface tension of the soap solution is :
(A)
P c3 a 2 b 3 (B)
P c3 a 3 b 3
4a 2 2
b c 2
4a 2 2
b c 2
(C) Pc3 4a2 4b2 (D) Pc2 2a2 + 3b2
58. Two pendulums begin to swing simultaneously. The first makes 9 full oscillations when the other makes 7.
The ratio of their lengths is :
(A) 9/7 (B) 7/9 (C) 49/81 (D) 81/49
59. 3 transverse waves having wave equations :
2 4
y1 A sin wt kx , y2 A sin wt kx and y3 A sin wt kx interfere to create a new
3 3
wave What is the new wave equation ?
2 2
(A) y 2 A sin wt kx (B) y A sin wt kx
3 3
2
(C) y 3 A sin wt kx (D) None of these
3
60. 2 moles of He and 1 mole of O2 is mixed. What will be adiabatic coefficient of mixture ?
7 9 17
(A) (B) (C) (D) None of these
5 7 11
61. Let P, Q, R, S and T are five sets about the quadratic equation a 5 x 2 2ax a 4 0 , a 5 such
that :
(P) : All values of a for which the product of roots of given quadratic equation is positive.
(Q) : All values of a for which the product of roots of given quadratic equation is negative.
(R) : All values of a for which the product of real roots of given quadratic equation is positive.
(S) : All values of a for which the roots of given quadratic equation are real.
(T) : All values of a for which the given quadratic equation has non-real.
Which statement is correct?
(A) P Q (B) RP
(C) P Q R' 4, 5 (D) All of these
where R' is a set of real numbers.
1
62. ai j k is equal to, where a 1 :
i 1 j 1 k 1
3 1
(A) a 1 3 (B) (C) 3
(D) None of these
a 1 a 1
2 2 2
1 1 1
63. If z z + 1 = 0, then the value of z z 2 2 ... z 24 24 is equal to :
2
z z z
(A) 24 (B) 32 (C) 48 (D) None of these
64. AB is a variable line sliding between the coordinate axes in such a way that A lies on x-axis and B lies on
y-axis. If P is a variable point on AB such that PA = b, PB = a and AB = a + b, then the equation of the
locus of P is :
x2 y2 x2 y2
(A) 2
2
1 (B) 2
2
1 (C) x 2 y 2 a 2 b 2 (D)
None of these
a b a b
65. The locus of the midpoint of the portion of the line x cos y sin p where p is a constant, intercepted
between the axes is :
(A)
p 2 x2 y 2 4 x2 y 2 (B)
p 2 x2 y 2 2 x2 y 2
(C)
4 x2 y 2 p2 x 2 y 2 (D)
2 x2 y 2 p2 x 2 y 2
66. The equation of the circle concentric with the circle x 2 y 2 6 x 12 y 15 0 and of double its area is :
(A) x 2 y 2 6 x 12 y 15 0 (B) x 2 y 2 6 x 12 y 30 0
(C) x 2 y 2 6 x 12 y 25 0 (D) x 2 y 2 6 x 12 y 20 0
67. A line segment AM = a moves in the XOY plane such that AM is parallel to the X-axis. If A moves along
the circle x 2 y 2 a 2 , then the locus of M is :
(A) x 2 y 2 4a 2 (B) x 2 y 2 2ax (C) x 2 y 2 2ay (D) x 2 y 2 2ax 2ay
68. The locus of the points from which the lengths of the tangents to the two circles, x 2 y 2 4 x 3 0,
x 2 y 2 6 x 5 0 are in the ratio 2 : 3 is a circle with centre :
(A) (6, 0) (B) 6 , 0 (C) (0, 6) (D) 0, 6
30 30 30 . . . .
69. If x log3 , then which of the following statement hold good ?
2 2 2 . . . .
(A) 0 x 1 (B) 1 x 2 (C) 2 x3 (D) x2
cos x cos 2 x 3
70. The value of , where x , is equal to :
2 cos x 1 cos x 1 4
(A) 0 (B) 1 (C) 2 (D) 3
x k x 2012 1
71. The integral value of k for which the quadratic equation 0 has integral roots :
2013 x
(A) 2010 (B) 2011 (C) 2014 (D) None of these
72.
Let f x cos x 2 x where [.] represents greatest integer function, then :
(A) f (x) is neither odd nor even (B) f (x) is non periodic function
(C) Range of f (x) is 1, 1 (D) f x f x for all x
f4 x
f2 x f3 x 1
73. If f1 x 2 , where f 2 x 2012 , where f3 x ,
2013
where f 4 x log 2013 log x 2012 , then the range of f1 x is :
(A) 2, (B) 2012, (C) 0, (D) ,
74. Let the least positive value of x satisfying the equation sin e x 0 is then :
n 4 n 4
(A) is a rational number (B) is negative integer
n 4 n 4
(C) is an odd integer (D) is a prime number
75. If one diagonal of a square is along the line x 2 y and one of its vertex is (3, 0), then its sides through this
vertex are given by the equations :
(A) y 3x 9 0, x 3 y 3 0 (B) y 3 x 9 0, x 3 y 3 0
(C) y 3 x 9 0, x 3 y 3 0 (D) y 3x 9 0, x 3 y 3 0
76. The locus of the mid points of the chords of the circle x 2 y 2 ax by 0 which subtend a right angle at
a b
, is :
2 2
(A) ax by 0 (B) ax by a 2 b2
a2 b2 a 2 b2
(C) x 2 y 2 ax by 0 (D) x 2 y 2 ax by 0
8 8
77. Words are formed by letters of word ENGINEER :
I. Number of 5 letters word containing all vowels is 120
II. Number of 5 letters word containing all vowels is 60
III. Number of words by using all the letters, in which exactly two Es are together is 15 5!
8!
IV. Number of words by using all letters, in which all vowels appear before consonants is
3!2!
The correct option is :
(A) FTTF (B) FTTT (C) FFTF (D) TFFT
5
1
78. Let 1 , 2 , 3 , 4 , 5 are roots of 6 z 5 5 z 4 4 z 3 3z 2 2 z 1 0 , then value of 1 i is :
i 1
13 10 4 17
(A) (B) (C) (D)
3 3 3 3
Let P n 1
n
1n k .k n 1 ! then the value of P 7 P 8 P 9 1 is :
79.
k 0
k 1 k! n 1 k !
31 29 20 20
(A) (B) (C) (D)
20 20 31 29
80. If 2 8 is at an end of a focal chord of the parabola y2 = 32x then other end of the chord is :
(A) (32, 32) (B) 32 32 (C) 2 8 (D) None of these
81. The normal at a point P on the ellipse x 2 4 y 2 16 meets the X axis at Q. If M is the mid-point of the
line segment PQ, then the locus of M intersects the latus rectum of the given ellipse at the points :
3 5 2 3 5 19 1 4 3
(A) (B) (C) 2 3 (D) 2 3
2 7 2 4 7 7
x2 y2
82. If the latus rectum of the hyperbola 1 subtends a right angle at the centre, then the eccentricity
a2 b2
of the hyperbola is :
5 1 2 3 3 2
(A) (B) 3 1 (C) (D)
2 2 2
2
83. Number of distinct common solutions of | z i 1 | 2 and z 3 2 z 4 0 is :
(A) 0 (B) 1 (C) 2 (D) 3
2
(A) 0 (B) tan1
3
2 2
(C) tan1 (D) tan1
3 3
1 10
85. The sum C0 10C1 2 . 10C2 22 10
C3 . . . . 29 . 10C10 is :
2
1 1
(A) (B) 0 (C) . 310 (D) 1
2 2
86.
The coefficient of x9 in the expansion of 1 x 1 x 2 1 x3 ...... 1 x100 is :
(A) 9 (B) 8 (C) 7 (D) 10
87. From the point (15, 12), three normals are drawn to the parabola y 2 4 x . The centroid of the triangle
formed by the feet of the normals is :
26 16
(A) 0 (B) (4, 0) (C) 0 (D) (16, 0)
3 3
88. If the tangent to the ellipse x 2 4 y 2 16 at the point ' ' is a normal the circle x 2 y 2 8 x 4 y 0
then is equal to:
(A) (B) (C) (D)
2 4 3 4
x2 y2
89. The product of the slopes of the common tangents of the ellipse 1 and the circle x 2 y 2 3
4 1
is:
(A) 1 (B) 2 (C) 3 (D) 1
90. In the decimal system of numeration the number of 6-digit numbers in which the sum of the digits is
divisible by 5 is:
(A) 180000 (B) 540000 (C) 5 103 (D) None of these