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1. A chemical reaction that absorbs heat from the surroundings is said to be __________ and has a ΔH
which is _____________.
A) endothermic, positive
B) endothermic, negative
C) exothermic, negative
D) exothermic, positive
E) exothermic, neutral
2. The reaction
4Al(s) + 3O2(g) → 2Al2O3(s) ΔH = -3351 kJ / mol
is __________, and therefore heat is __________ by the reaction.
A) endothermic, released
B) endothermic, absorbed
C) exothermic, released
D) exothermic, absorbed
E) thermoneutral, neither released nor absorbed
3. The specific heat of liquid bromine is 0.226 J/g-K. How much heat is required to raise the
temperature of 10.0 mL of bromine from 25.00 0C to 27.30 0C? The density of liquid bromine: 3.12
g/mL.
A) 300 J
B) 10.4 J
C) 32.4 J
D) 5.20 J
E) 16.2 J
4. The value of ΔH for the reaction below is -126 kJ/mol. How much heat is released when 80.0 g of
NaOH is formed in the reaction?
2Na2O2(s) + 2H2O(l) → 4NaOH(s) + O2(g)
A) 252 kJ
B) -126 kJ
C) 7.80 kJ
D) 63.0 kJ
E) 3.9 kJ
5. The value of ΔH for the reaction below is -6535 kJ/mol. How many kJ of heat are released when 16.0
g of C6H6(l) is reacted with 65 g of O2(g) ?
2 C6H6(l) + 15O2(g) → 12CO2(g) + 6H2O(l)
A) 673 kJ
B) 2.68 x 103 kJ
C) 5.23 x 104 kJ
D) -6535 kJ
E) 1.34 x 103 kJ
6. The ΔH for the solution process when solid sodium hydroxide dissolves in water is -44.4 kJ/mol.
When a 13.9-g sample of NaOH dissolves in 250.0 g of water at an initial temperature of 23.0 0C,
what is the final temperature?
A) 14.0 0C
B) 37.8 0C
C) 40.2 0C
D) 37.0 0C
E) 35.2 0C
8. Given the data in the table below, what is the ΔH rxn for the following reaction
Ca(OH)2 + 2H3AsO4 → Ca(H2AsO4)2 + 2H2O
13. Given the following two reactions at 298 K and 1 atm, which of the statements about the ΔH°f for
NO2 is true?
N2(g) + O2(g) → 2NO(g) ΔH1
NO(g) + (1/2)O2(g) → NO2(g) ΔH2
A) ΔHf for NO2(g) = ΔH2
B) ΔHf for NO(g) = ΔH1
C) ΔH1 = ΔH2
D) ΔHf for NO2(g) = ΔH2 + (1/2) ΔH1
E) none of these
14. Using the sum of heats of formation formula and the information below, calculate ΔH°f for PbO(s).
PbO(s) + CO(g) → Pb(s) + CO2(g), ΔH° = –131.4 kJ
ΔH°f for CO2(g) = –393.5 kJ/mol
ΔH°f for CO(g) = –110.5 kJ/mol
A) –151.6 kJ/mol
B) –283.0 kJ/mol
C) +283.0 kJ/mol
D) –372.6 kJ/mol
E) +252.1 kJ/mol
Long Answers
1. Acetylene (C2H2) and butane (C4H10) are gaseous fuels. Determine the ratio of energy available from
the combustion of a given mole of acetylene to butane at the same temperature and pressure using the
following data: ΔHcomb C2H2 = –49.9 kJ/g. and ΔHcomb C4H10 = –49.5 kJ/g.
2. 25.0 mL of water is placed in a coffee cup calorimeter. The temperature of the water was 24.3 0C.
1.00 g of KCl solid was added and the maximum temperature drop was 3.8 0C. What is the molar heat
of solution of KCl?
3. A Bomb Calorimeter has a heat capacity of 10.6 kJ/0C. When 2.00 g of methane gas is burnt in the
calorimeter, the temperature went from 20.60C to 28.9 0C. What is the molar heat of combustion of
methane from this experiment?