Appendix Property Data Bank ‘The listing of compounds is by the total carbon number. Within each car- bon number class, subgroups are indexed by the number of hydrogens and, further, by additional atoms in alphabetical order. The symbols and equations used are shown below. The enthalpy and Gibbs energy of formation at 298.2 K (DELHF and DELGF) are for the ideal-gas state. The reference states chosen for the elements are as follows: Ideal gases at one atmosphere: Ar, Clo, Ds, F;, He, Ho, Kr, Ne, O2, Rn, T,, and Xe. Al (crystal); As (crystal); B (crystal); Br, (liquid); C (graphite); Hg (liquid); Ip (crystal); P (solid, red); S (crystal, rhombic); Se (crystal); Si (crystal); Ti (crystal, alpha); U (crystal). MolWt = molecular weight, g/mol Tip = normal freezing point, K jormal boiling point (at 1 atm), K. tical temperature, K ritical pressure, bar ritical volume, cm®/mole Zc = critical compressibility factor, PeVe/ATC ‘Omega = Pitzer's acentric factor Dipm = dipole moment, debyes 656Property DataBank 657 CPVAP A, CPVAP B, CPVAP C, CPVAP D = constants to calculate the isobaric heat capacity of the ideal gas, with Cp in J/(mol-K) and T in kelvins: Cp = CPVAP A + (CPVAP B)T + (CPVAP C)T? + (CPVAP D)T® DELHF = standard enthalpy of formation for the ideal gas at 298.2 K, J/ mol (Gee note above on reference states.) DELGF = standard Gibbs energy of formation for the ideal gas at 298.2 K and 1 atm, jj mot (See note above on reference states.) Vapor pressure: Pvp = vapor pressure, in bars Pe = critical pressure, in bars critical temperature, in kelvins T = temperature, in kelvins There is a choice of equations as noted in the tables: Equation (1): In (Pvp/Pc) = (1 — x)~1[(VP Alx + (VP B)x'5 + (VP Cx? + (VP D)x®] x=1-T/Te Equation (2): In Pvp = VP A — (VP B)/T + (VPC) In T + (VP D\Pvpy/T? Equation (3): In Pvp = VP A — (VP BY/[T + (vP.C)] LDEN = liquid density, g/om? TDEN = temperature for LDEN, KO70 zez"0 L4Z70L'SZE— TSE TRUS BTOEE«E*HUZ © 86B"59T piyo[yres9ag uori[ts SPL. 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