Professional Documents
Culture Documents
Ronald Birkhoff
Badger Licensing LLC AIChE Regional Process Technology
Conference
October 7th - 8th 2010
Galveston, TX
Badger
Research and Engineering Licensing LLC
Reducing Benzene in Gasoline Pool
1 vol %
Europe
1 vol %
1-5 vol %
range
0.62 vol % ASIA
1.5-4 vol %
Americas
range
Middle East
1-2.5 vol % Africa
range 1 vol %
Australia &
Pacific
Badger
Licensing LLC
Typical Gasoline Pool Benzene in US
Average Typical
Volume in Benzene Benzene
Components Gasoline % Level % Contribution %
Reformate ~ 30 3-11 ~ 75
Hydrocrackate ~3 1-5 ~3
Others ~ 31 0-3 ~6
Reference: EPA-HQ-OAR-2005-0036; FRL-8041-2, Table VII.F-2
Badger
Licensing LLC
Refiner’s Options
Octane
Gasoline Gasoline Hydrogen Light
Volume Pool Balance Olefin
Reformer Feed Reduced
Tailoring Production
No
Benzene Extraction change
High
Benzene Saturation consumption
No Upgrade
BenzOUT™ consumption to Mogas
Badger
Licensing LLC
BenzOUT™ Process Configuration
Light end
Products
Badger
Licensing LLC
BenzOUT™ – Reducing Benzene while
Boosting Product Value
¾ Incentives Include:
Reduced Benzene to meet regulations
¾ Commercially demonstrated
Badger
Licensing LLC
Benzene Conversion Can Be Achieved
According to Need
100
0
Olefin/Aromatic Ratio
Badger
Licensing LLC
Example of BenzOUT Boosting
Product Volume
Light end
42.3
KB/D
¾ Approx. 5% Volume Increase Based on Full Reformate
Badger
Licensing LLC
Example of BenzOUT™ Product
Properties
Product
Feed
% Evaporated
¾ Final Product Properties are a Function of Feed Composition and
Benzene Conversion
Approx. (R+M)/2 increase of 2-5
Approx. RVP reduction of 0.5 PSI
Badger
Licensing LLC
Process Demonstrated in a
North American Refinery
Light Olefin
Reformate
BenzOUT
Catalyst
Mogas Blending
Badger
Licensing LLC
Commercial Trial Results Confirmed
Pilot Plant Results
100
Benzene Conversion (%)
Olefin/Aromatic ratio
0
0 10 20 Days on
30 Stream 40 50 60
Badger
Licensing LLC
BenzOUT™ Technology Delivery
Badger
Licensing LLC
BenzOUT™ Advantages - Summary
¾ Commercially demonstrated
Badger
Licensing LLC
THANK YOU
Badger
Licensing LLC