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Instructions:
1. The question paper has four parts: A, B, C and D. All parts are compulsory.
2. Write balanced chemical equations and draw labeled diagrams wherever required.
3. Use log tables and the simple calculator if necessary.
(Use of scientific calculators is not allowed)
PART – A
I. Answer ALL of the following. (Each question carries 1 mark) 10 x 1 = 10
1. Define ebullioscopic constant.
2. A solution of an ester in benzene freezes at 0.84 K temperature below the freezing point of the
3. Write the cell reaction of the Lead storage battery when it is discharged.
4. Express the rate of the reaction in terms of different reactants and products.
2 N2O5 ( g ) 4 NO2 O2 ( g )
8. Why is the solubility of haloalkanes in water is very low although they are polar in nature?
9. Give reason; aldehydes are more reactive than ketones.
10. Mention the bonding helps in stabilising the helix structure of proteins.
PART – B
II. Answer any FIVE of the following. (Each question carries 2 marks) 5 x 2 = 10
11. Classify the following into P-type and n-type semiconductors.
(a) Ge doped with In
(b) Si doped with Boron
12. What is specific conductivity? Mention its SI unit.
13. Show that the rate of first order reaction is doubled when the concentration of the reactant is
doubled.
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Subject Topic Practice Paper - 1 Date
PART – C
III. Answer any FIVE of the following. (Each question carries 3 marks) 5 x 3 = 15
19. How is metal copper extracted from low grade ore of it. (3)
20. (a) Why does nitrogen dioxide dimirise? (1+1+1)
(b) Complete the following equation.
PCl5 H 2O
22. (a) Explain the action of chlorine on slaked lime. Give the equation. (2+1)
(b) Give reason: The electron gain enthalpy of fluorine is less than that of chlorine.
23. (a) Complete the following equations. (2+1)
26. (a) Give the example for inner orbital complex and outer orbital complex. (2+1)
(b) Give the example for neutral didentate ligand.
PART – D (i)
IV. Answer any THREE of the following. (Each question carries 5 marks) 3 x 5 = 15
27. (a) Calculate the packing efficiency in cubic close packing (ccp) lattice.
(b) Mention the most disordered and ordered crystal system (3+2)
28. (a) How will you determine the molecular mass of solute from Relative lowering of vapor
pressure
(b) Ethyl glycol (molar mass 62 g / mol ) is a common automobile antifreeze. Calculate the
water. (3+2)
29. (a) The molar conductivity of 0.025molL1 methanoic acid is. Calculate its degree of disassociation
H 349.6 S cm2 mol 1 and HCOO 54.6 S cm2 mol 1
30. (a) The rate constant of a Zero order reaction in ‘A’ is 0.0030 mol L1S 1 . How long it will take for
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Subject Topic Practice Paper - 1 Date
PART – D (ii)
V. Answer any FOUR of the following. (Each question carries 5 marks) 4 x 5 = 20
32. (a) Define the following terms:
(i) Retension of configuration
(ii) Inversion of configuration
(iii) Recemization (3+2)
(b) Write the chemical reaction in which diazonium group in diazonium salt replaced by iodine
ion.
33. (a) Write the reactions taking place in the preparation of Ethanol from Molasses. (2+3)
(b) Arrange the following compounds in the increasing order of acidity and give reason.
Phenol, o – nitro phenol, o – cresol
34. (a) Write the chemical equations for the following conversions. (3+2)
(i) Ethanol to But – 2 - enal
(ii) Carbonyl group of ketone to CH 2 group.
Fe / HCl HNO C H OH
C6 H5 NO2 A
2 B
6 5
C
273K 278K
(b) Arrange the following amines in the decreasing order of their Basic strength.
C6 H5 NH 2 , C2 H5 NH 2 , C2 H5 2 NH