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International Scholarly and Scientific Research & Innovation 4(2) 2010 213 scholar.waset.org/1307-6892/731
World Academy of Science, Engineering and Technology
International Journal of Chemical and Molecular Engineering
Vol:4, No:2, 2010
and 5:5 by volume; the stirring intensity, 1500 rpm; the but not for crude oil B. For 20-80 % w/o emulsion, crude oil B
mixing time, 5 min and prepared at room temperature (27oC). displays the viscosity is not correlated with shear rate. The
The prepared emulsions were checked for o/w or w/o type of crude oil can be a good reason for behavior of crude
emulsions using tube test and filter paper. Only w/o types was oil. Crude oil B has lower viscosity and light crude oil
chosen for further study. The emulsion was measured the compared with crude oil A and C.
refractive index using refractometer to identified type of As the dispersed phase function (water) of dispersion is
prepared emulsion. increased, the dispersion rheology changes significantly due to
The rheological measurements for all the samples was the frequency of droplet interaction increases. Therefore, as
carried out with Brookfield Rotational Digital Rheometer the results coalescence faster in high cut, the number of the
Model LV/DV-III with UL adaptor and spindles 31 in droplets in an aggregates change with time. Since any change
measuring viscosity, shear rate and shear stress. in the dependence of the viscosity on rate of shear could not
The droplet diameter of each emulsion (20-80 % and 50- be observed, the decreased in viscosity would be brought
50% w/o) was observed through Carl Zeiss research about the broadening of the droplet size distribution.
microscope before connected with digital camera and
determined by AxioVission AC software. The effect of 700
crude oil A
refractive index (R.I) in emulsion was examined using crude oil B
refractometer from Mattler Toledo. 600 crude oil C
International Science Index, Chemical and Molecular Engineering Vol:4, No:2, 2010 waset.org/Publication/731
viscosity (cP)
A. Effects of Phase Ratios 400
It has been reported that the phase ratio persuaded the
droplet size distribution [2]. As change the ratios, the viscosity 300
also altered and affected the stability, thus effects the droplet
size distribution. The droplet size distribution for 50-50 % and 200
20-80 % w/o were measured and illustrated.
100
2 4 6 8 10 12 14 16 18
shear rate (1/s)
140
(a) (b)
120
Fig. 1 Droplet size distribution at (a) 50-50 w/o emulsion and (b) 20-
viscosity (cP)
International Scholarly and Scientific Research & Innovation 4(2) 2010 214 scholar.waset.org/1307-6892/731
World Academy of Science, Engineering and Technology
International Journal of Chemical and Molecular Engineering
Vol:4, No:2, 2010
D (ρ )
temperature viscosity droplet viscosity droplet
=
g
2
W
− ρ O
(oC (cP) diameter (cP) diameter
v m
18μ (1)
(µm) (µm)
obtained from Eq. (1). Both phase ratios show the decreasing
Which at 50-50 % w/o emulsion, the emulsion is expected
of viscosity as increasing temperature. However at 90oC (in
from non-Newtonian because of the content of water cut and
50-50 % w/o), crude oil B acquired the increasing temperature
near to the phase inversion point. In case for 20-80 % w/o
and this is expected due to phase inversion point is reached.
emulsion, they were followed Newtonian behavior because the
viscosity of emulsion is no longer a unique function of the
1400 phase ratio because droplet size distribution plays as dominant
factor.
1200
crude oil A
The value of RI as following temperature from ambient
1000
crude oil B (25oC), 50, 70 and 90oC were 1.4495, 1.50, 1.5038 and
crude oil C
1.5046, correspondingly. The RI obtained increasing as
decreasing the droplet size distribution.
Viscosity (cP)
800
600
600
500
400
crude oil A
200 400 crude oil B
viscosity (cP)
crude oil C
0 300
20 30 40 50 60 70 80 90
temperature (oC)
International Scholarly and Scientific Research & Innovation 4(2) 2010 215 scholar.waset.org/1307-6892/731
World Academy of Science, Engineering and Technology
International Journal of Chemical and Molecular Engineering
Vol:4, No:2, 2010
200
150
100
50
0
500 1000 1500 2000
stirring speed (rpm)
60
50-50 % w/o emulsion
20-80 % w/o emulsion
50
40
30
20
10
500 1000 1500 2000
stirring speed (rpm)
IV. CONCLUSION
This paper shown the viscosity is affected on droplet size
distribution for Newtonian and non-Newtonian behavior; the
International Scholarly and Scientific Research & Innovation 4(2) 2010 216 scholar.waset.org/1307-6892/731