EXPERIMENTAL VLE DATA 1,2 dichloroethane (1) n-heptane (2) 343.15 K P1sat 486.41 P2sat 302.

87
NEGATIVE DEVIATION A-Model RAOULTS LAW CALC.
x1 y1 Ptotal gam1 gam2 ln(gam1) ln(gam2) gam1/gam2 ln(h) Gexcess A value ln(gam1) ln(gam2) gam1 gam2 p.p1 p.p2 pt y1 ln(h) Ptotal' P.P 1 y1' y2' X Y
0 0 302.87 #DIV/0! 1 #DIV/0! 0 #DIV/0! #DIV/0! 0 #DIV/0! 1.104972 0 3.01914 1 0 302.87 302.87 0 1.104972 302.87 0 0 1 0 0
Chart Title
0.0911 0.2485 372.62 2.089641 1.017238 0.736992 0.017092 2.054229 0.719901 235.8663 2848.599 0.912816 0.00917 2.491329 1.009213 110.3957 277.8146 388.2102 0.284371 0.903646 319.5905 44.31195 0.138652 0.861348 0.1 0.1
1.5
0.1979 0.4174 429.28 1.861422 1.0295 0.621341 0.029073 1.808083 0.592267 417.3379 2629.139 0.7109 0.043276 2.035822 1.044226 195.9693 253.6758 449.6452 0.435831 0.667624 339.1926 96.26054 0.283793 0.716207 0.2 0.2
0.2867 0.5052 466.48 1.68992 1.068401 0.524681 0.066163 1.581729 0.458518 563.8004 2756.928 0.562206 0.090825 1.754539 1.095078 244.6771 236.5775 481.2545 0.508415 0.471381 355.4909 139.4537 0.392285 0.607715 0.3 0.3 1
0.3674 0.559 491.02 1.535923 1.130192 0.429131 0.122388 1.358992 0.306744 670.6865 2885.7 0.442191 0.149152 1.556113 1.16085 278.0882 222.4136 500.5019 0.555619 0.293039 370.3026 178.707 0.482597 0.517403 0.4 0.4
0.4467 0.6078 509.4 1.424955 1.192201 0.35414 0.175801 1.19523 0.178339 728.8299 2948.829 0.338277 0.220487 1.402529 1.246684 304.7406 208.9167 513.6573 0.593276 0.11779 384.8573 217.2793 0.564571 0.435429 0.5 0.5 0.5
0.5044 0.6535 520.41 1.386161 1.201327 0.326538 0.183427 1.153858 0.143111 729.2485 2917.22 0.271403 0.281126 1.311803 1.324621 321.8446 198.8287 520.6733 0.618132 -0.00972 395.4476 245.3452 0.620424 0.379576 0.6 0.6
0
0.5733 0.6646 525.71 1.252917 1.364364 0.225474 0.310689 0.918315 -0.08521 747.0024 3053.637 0.201185 0.363174 1.222852 1.437886 341.003 185.8247 526.8277 0.647276 -0.16199 408.0935 278.8589 0.683321 0.316679 0.7 0.7 0 0.2 0.4 0.6 0.8 1 1.2
0.6578 0.7089 533.44 1.181882 1.498275 0.167108 0.404314 0.788829 -0.23721 708.3308 3146.75 0.129393 0.478122 1.138137 1.613043 364.159 167.1792 531.3382 0.685362 -0.34873 423.6026 319.9605 0.755332 0.244668 0.8 0.8 -0.5
0.7644 0.7696 536.58 1.110648 1.732549 0.104943 0.549593 0.641049 -0.44465 598.272 3322.024 0.061334 0.645643 1.063254 1.907213 395.3304 136.0914 531.4219 0.743911 -0.58431 443.168 371.8118 0.838986 0.161014 0.9 0.9
0.8132 0.7877 535.78 1.066958 2.010497 0.064812 0.698382 0.530694 -0.63357 522.5542 3439.989 0.038557 0.730712 1.03931 2.076558 411.0977 117.4836 528.5813 0.777738 -0.69215 452.1247 395.5486 0.874866 0.125134 1 1 -1

0.8603 0.8201 530.9 1.040464 2.25731 0.039667 0.814174 0.460931 -0.77451 421.8528 3510.061 0.021565 0.817808 1.021799 2.265527 427.5805 95.85659 523.4371 0.816871 -0.79624 460.7695 418.4585 0.908173 0.091827 1.1 -1.5
0.893 0.8458 524.21 1.020749 2.494305 0.020537 0.91401 0.409232 -0.89347 331.3372 3467.648 0.012651 0.881159 1.012731 2.413695 439.8941 78.22083 518.1149 0.849028 -0.86851 466.7712 434.3641 0.930572 0.069428 1.2
0.9332 0.89 515.15 1.010058 2.800875 0.010008 1.029932 0.360622 -1.01992 222.9267 3576.111 0.004931 0.962278 1.004943 2.617654 456.1614 52.95962 509.1211 0.895978 -0.95735 474.1495 453.9178 0.957331 0.042669 1.3 -2
0.9572 0.9253 505.15 1.003917 2.910991 0.003909 1.068494 0.344871 -1.06458 141.1451 3445.239 0.002024 1.01241 1.002026 2.752227 466.535 35.67667 502.2117 0.928961 -1.01039 478.5545 465.5917 0.972913 0.027087
0.9812 0.9537 498.04 0.995213 4.049777 -0.0048 1.398662 0.245745 -1.40346 61.58492 3338.558 0.000391 1.063816 1.000391 2.897405 477.4519 16.4977 493.9496 0.9666 -1.06343 482.9594 477.2655 0.98821 0.01179
1 1 486.41 1 #DIV/0! 0 #DIV/0! #DIV/0! #DIV/0! 0 #DIV/0! 0 1.104972 1 3.01914 486.41 0 486.41 1 -1.10497 486.41 486.41 1 0
3152.429
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