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1. Put A, 2 B, 4 c
A B C 7 2
tan A tan B
sin A sin B cos C
cos A cos B cos C
But cos A B C cos A cos B cos C sin A sin B cos C
sin A sin B sin C cos A cos B cos C cos 2
cos A cos B cos C 1 1
tan A tan B 1
cos A cos B cos C cos A cos B cos C
1 1
1 1
2 4 8 2
cos cos cos sin 23
7 7 7 7
2
23 sin
7
=1-8=-7
2. z 3 3 i z 2 3z m i 0
z 3
3 z 2 3 z m i z 2 1 0
If z is a real root, then
z 3 3 z 2 3 z m 0 and z 2 1 0
z 1
z 1 m 1
z 1 m 5
cos 2 x
3. 2 4
sin 6 x cot x cos ec x dx
cot 2 x 1 cot 2 x cos ec 2 x dx
Put t cot x
I t 2 1 t 2 1 dt
t5 t3
k
5 3
1 1
A , B
5 3
8
A B
15
2ac b 2c
4. b
ac a ac
b a 3c a
ba ca
Similarly b 2a b c 3a c
c ac bc ac
b a b c 3a c 3c a 2 a c
2
ba bc ac a c
x
5. f x x 2 e t f x t dt
0
x
x t
x2 e f t dt
0
x
x 2 e x et f t dt
0
x
e x f x x 2 e x et f t dt
0
6. Multiply by y,z and x in rows 1,2 and 3 respectively and then take common y, z
and x from
column 1,2 and 3 respectively, then
3 3 3
y 1 y y
3 3 3
z z 1 z 11
3 3 3
x x x 1
3
1 0 y
3
1 1 z 11 C1 C1 C2 and C2 C2 C3
3
0 1 x 1
1 x 1 z
3 3
y 1 11 x y z 10
3 3 3 3
2
yt x t
If it passes through the centre (2,3) of the circle, then
2
t 3t 2 0
t 1,2
The point can be (1,2) or (4,4)
8. Sum of the coefficients of the terms not containing c is 38
and of the term not containing b and c both is 28, so required sum = 38 - 28 .
f ( x h) f ( x )
f ( x) lim
h 0 h
f (2 x) f (2h)
f ( x)
13. = lim 2
h0 h
f ( x) 1 ; f (2 x) 2 f ( x) -1
f ( x) 1 x
x 1 x 1
14. x 0,1 2
0; 3 0 & 2
. 3 1
1 x x 1 x x
x 1
3
x 1 2
1 1 3
tan 1 tan 1 3 tan 1 1 x x
tan
1 x2 x 1 x 1
. 3 x 4
2
1 x x
x 1 not possible
2y dy y2 1 1
15. 2
dx 1 y 2 x x 3
1 y2
y2 2y dy dt
Put t
1 y 2
1 y 2 2 dx dx
dt t 1
3
dx x x
1
t x 2 dx c
x
x 2 y 2 cx 1 1 y 2 .
2sin x cos x
16. 2sin 2 x n
2
sin 2x 2cos 2x 2n 2
5 2n 2 5
5 5
1 n 1
2 2
tan x
17. lim f x lim 1
x 0 x 0 x
1 1
lim f (x) x 2 f (x) = lim 1 x 2 f (x ) 1 form
x0 x 0
x3 2 5
x x . . .
tan x 3 15
Again, f(x) =
x x
2
= 1 x 2 x4 . . .
3 15
2
x 2
f (x) x 4 . . .
3 15
(i) becomes,
x2
lim
2 1 x 0 2
x 2 4
lim x x ...
log e e
x0 f (x) e 3 15 3
18. 2ae = SS1 = 1
p1 p2 = b2, where p1& p2 are the length of perpendicular from S & S1 to the
tangent
5 4 41
. b 2 b 2 10 b 2 10 a 2 e 2 a 2 a 2
2 2 4
19. Vector perpendicular to a and lie on the plane of a & b is parallel to a b a
a.a b b.a a 9 j k 3 2i j 2k 3 2i 2 j k
a
cos a x a
cos x
I ln dx ln dx
0
sin a.cos x 0
sin a cos a x
20. a a
1
adding 2I ln dx 2 ln sin a dx 2 a ln sin a
0
sin 2 a 0
2
a c . b c 0 a.b c. a b c 0
23.
a b .c 1 a b . a b a b 1 1
1, a.b 0 a, b , a b are mutually perpendicular
2
c 1 1 1 2 2 1
2 2 2
n
24. At x = n, f n sin
n 1 n 1
f n
n 1
f n
n
sin
n
f(x) is discontinuous at all integral points.
S .D M .D
27.
P q p q p q pq p q p q
T T F F F T F
T F F T T F F
F T T F F T F
F F T T F T F
28. let O be origin and axes parallel to edges. Coordinates of A, B, C are A(a, -b, -c)
B(a, b, c) c(-a, b, -c)
Hence cos cos cos
a 2
b 2 c 2 a 2 b 2 c 2 a 2 b 2 c 2
a 2 b2 c 2
=-1
29. a b 5 means a b 0 or 1 a b 5 a b 0 ab which is possible in 10
ways. Let x, y, z represent, numbers before, in between and after a and b then
x+y+z=8, 0 y 4 and x, z 0
2
= coefficient of x8 in 1 x ......x8 1 x ......x
4
= 35
a, b, can be in any order
Total ways =2x35+10=80.
30. conceptual
PHYSICS
34. VP ,CD 2 r2 r1
VCD , AB 1r1 r2 r1
VP , AB VP ,CD VCD , AB 2 r2 r1 1r1
1
35. When deflection is reduced by , it means range of the ammeter becomes x times
x
5 I g 5 I g G
G 25
x1 25I g
x 25I g
36. Wire abc can be replaced by a straight wire ac for the computation of force.
Length of ac can be written as, l rC rA 0.5 ˆj kˆ
Required force,
F I l B 0.6iˆ .
Q
37. Electric field in between the capacitor plates is given by E , where Q is the
0 A
R12
q1 4 0
2
q2 4 R22
q1 q2 0
R120
4 4 R22 0
2
R
2
1 2
R 0
2
39. When the colliding electron remove an electron from innermost K-shell
(corresponding to n = 1) of atom and electron from some higher shell jumps to K-
shell to fill up this vacancy, characteristic X-ray of K-series are obtained
K and K X-ray are emitted when there is transition of electron between the
levels n 2 to n 1 and n 3 to n 1 respectively.
40. At resonance both bulbs will glow with same brightness. At resonance, X L X C
1
Or 2 fL
2 fC
1
Or f
2 LC
41. As inductance L2 was wound using the similar wire but the direction of winding is
reversed, so flux through L2 is zero.
L2 0
Also, L1 L3
Therefore, L1 L3 , L2 0
42. Angular fringe width is the ratio of fringe width to distance (D) of screen from the
source ie,
D
As D is taken large, hence angular fringe width of the central maximum will
decrease.
43. h G x Ly E z
x y z
M 1 L2T 1 M 1 L3T 2 M 1 L2T 1 M 1 L2T 2
x y z
M 1 L2T 1 k M 1 L3T 2 M 1 L2T 1 M 1 L2T 2
44. In equilibrium position net force acting on the object (block of mass m) is zero.
Let spring of spring constant k1 is stretched by x1 and spring of spring constant k2
is stretched by x2 , then free body diagram of the block is as shown in the figure.
GM
45. v
r
GMm
Total energy of satellite, TE E
2r
So, the energy given to satellite to escape it from gravity influence of earth is E,
so that its total energy would becomes zero.
So, change in KE, E E
mv 2f 4E 2E
So, 2E vf and v
2 m m
So, v v f v
2 1 v
46. a x 2 , vdv x 2 dx
KE x 3
48. Given graph is V-p curve, as in given graph cycle is anti-clockwise, wo in p-V
curve cycle would be clockwise and hence work is done by the system against the
surrounding.
From 1st law of thermodynamics, Q dU W
xcm
m 35 3 4 4 1 / 3
3m
ycm 6 1/ 3 .
54. Let mi be the amount of water that gets freezed out of M g of water at 0C due to
evaporation.
Now, mi 80 M mi 580
mi 580
0.878
M 660
r
2
56. As the lens rotates by , the OA also rotates by as shown in figure. Primed
letters in figure are corresponding to rotated position of lens.
The object distance along the OA in rotated position of lens is u ' 2 f cos .
2 f cos
v' as is small so v ' comes out to be +ve.
2 f cos 1
Where t
For 2 rad , and cos 1
90 90
4 f
vimage 90 4 f m / s along BA.
2
2 1 90
T
The velocity of this position is, V
kx 2
dx T
dt kx 2
L t T
x dx dt
0 0 k
L2 T
t
2 k
k L2
t
T 2
59. Intensity at a distance r from the isotropic point source of sound having power P
is given by
P
I
4 r 2
I P
SL 10 log 10 log 2
log I 0
I0 4 r
a b log r
V l b h
60.
V l b h
0.1 0.1 0.1
10 20 5
0.7
20
V 0.7
Percentage 100 3.5%
V 20
CHEMISTRY
2
61. PtCl4 is dsp 2 and square planar
P P
HO O OH
OH OH
65.
hot HI CH 3 CH CH 2 CH 2 CH 2 I
KOH / EtOH CH 3 CH CH CH CH 2
O
I
2) FeCl3 .6 H 2O 6SOCl2 FeCl3 12HCl 6SO2
67.
H 2 / Pt
(Chiral)
(Achiral)
O3 / H 2O2
COOH
COOH
(Chiral)
rc
68. For octahedral void 0.414
ra
rc 0 .414 ra
0.414
4
2
400 pm 4ra 2a
58.54 pm
d 58.54 2 117.16 pm
T T
nR 2 1 2 R T2 30 ---- (1)
P2 P1
w U q 0
70.
MnO2 2 KOH KNO3 K 2 MnO4 green KNO2 H 2O
71.
O OH
O O
H 3O
CH 3 C H CH 3 C CH 2 CH 2 OH
CH 2COOH
CH 2COOH
H 3O
OH
72. Basic nature p-toulidine > m- toulidine > o- toulidine (due to ortho effect)
73. A g
2B g C g
90 0 0 (t = 0 min)
90-x 2x x (t = 10 min)
Total pressure after 10 minutes ; P 90 2 x 180
x 45 mm
1 P 1 90
k ln 0 ln 0.0693 min1 1.5103 sec 1
t P0 x 10 45
M 2 M1 190 106
74. nOCH3 2
42 42
75. PCC
F2CH 3 CH 2 CH 2 OH NH 2 CONHNH 2
CH 3 CH 2 CHO
Positive tollen ' s test
CH 3 CH 2 CH N NH CO NH 2
76.
NH 2 NH 2 F
N 2 BF4
Br Br Br
Br Br Br
Br2 / H 2 O
1 NaNO2 HCl
2 HBF4
Br Br Br
77. Anomers differ at hemi acetal or acetal carbon but epimers differ at any one of the
other stereogenic centre.
H
2
log
0.06
78. EE 0
Ag
2
2
1 1
0.62 0.8 0.06 log log 3 Ag 103 mol / L
Ag
Ag
% of Ag = 1.
PA0 x A 440 / 5
79. yA 0.478
PA xA PB xB 440 / 5 120 4
0 0
5
Ni s
80. (a) Vegetable oil solid fat (heterogeneous)
Fe s
(b) N 2 g 3H 2 g
2 NH 3
(heterogeneous)
NO2 g
(c) 2SO2 g O2 g
2SO3 (homogeneous)
V2 O5 s
(d) 2SO2 g O2 g
2SO3
(heterogeneous)
Pb 2
K sp 1.7 105
1.7 103
Cl 2 0.1
2
h 6.6261034
89. x .P h / 4 V 31 10
5.7910 6 m / s
4m x 43.14 9.1110 0.110