Professional Documents
Culture Documents
Combustion
Products
Fuel Air CO2
CO
Carbon
Hydrogen
Sulfur
Oxygen
Nitrogen
+ Oxygen
Nitrogen
Water vapor
SO2
Residual O2
Ash
NOx
Water CO2 Water vapour
Fuel residue
Ash
Flue gas
The Combustion Process
The term combustion refers to the exothermic oxidation of a fuel, by air
or oxygen occurring at a sufficiently rapid rate to produce a high
temperature (heat), usually with the appearance of a flame (light)
As most of the fuels contain carbon or carbon and hydrogen, the
combustion involves the oxidation of carbon to carbon dioxide and
hydrogen to water
Sulphur, if present, is oxidized to oxides of sulphur while the mineral
matter forms the ash
Combustion of complex fuels like coal:
When heated organic matter of coal is pyrolyzed, and then evolves as
volatile. The reaction between the char and oxygen is a gas-solid
heterogeneous reaction. The gaseous oxygen diffuses to, and into, the
char particle, being absorbed, and reacting on the pore surface of the
particle. Coal Coke (or Char) + Coal gas
The Combustion Process (Contd.)
The combustion process is complete if all the combustible
components in the fuel are burned to completion
The combustion process is complete if all the carbon in the
fuel burns to CO2, all the hydrogen burns to H2O , and all the
sulfur (if any) burns to SO2
Insufficient oxygen (also insufficient time, insufficient mixing,
and dissociation) causes incomplete combustion, unburnt
fuel, C, H2, CO, or OH would be in the products.
At ordinary combustion temperatures, nitrogen behaves as
an inert gas and does not react with other chemical elements.
Combustion
chamber
The Combustion Process (Contd.)
Complete combustion of a fuel is possible only in the presence
of an adequate supply of oxygen or air
The minimum energy is required to ignite a fuel air mixture.
Ignition will take place only when the ignition energy balances
the heat loss by conduction
In practice, excess oxidizers are supplied to ensure complete
combustion of the fuel
Rapid fuel oxidation results in large amounts of heat
Solid or liquid fuels must be changed to a gas before they will
burn
Usually heat is required to change liquids or solids into gases
Fuel gases will burn in their normal state if enough air is
present
Various Types of Flame
Based on the mixing mode of the fuel and oxidizer they are classified as
Liquid fuel
penetration
length
Nozzle
Source:Heywood
DI Combustion Stages
Ignition Delay
Period between start of injection to the start of
combustion
Physical delay (injection characteristics,
atomization, vaporization, mixture formation etc.)
Chemical delay (pre flame chemical reaction)
Premixed combustion
Fuel which has mixed with air within the
flammability limits during delay period burns
rapidly in few crank angle degree
High heat release rates characteristics
DI Combustion Stages (Contd.)
Diffusion combustion
The burning rate is controlled by the rate at
which mixture becomes available for the
burning
Rate of burning is primarily controlled by the
fuel vapor-air mixing process
Late combustion
Heat release (from small fraction of remaining
fuel, soot and fuel-rich combustion product etc.)
continues at a lower rate well into the expansion
stroke
Combustion Characteristics – Understanding
Schematic of a Diesel Spray and Transport Process
In-cylinder Processes in CI Engine
Parameter Value
Fuel n-heptane
Intake 21% O2
Load 4.6 bar IMEP
Intake T 153°C
Intake P 1.80 bar
SOI -10° ATDC
Speed 1200 rpm
Engine rc 10.75
Window 100 mm diam
Framing 7200 fps
Effective Camera Gain 1
Filter 500 nm SWP
High engine-out and tailpipe PM and NOx
emissions (3-way catalyst does not work)
Peak thermal efficiency typically 40-45%,
full load range possible
Pollutant Formation
HC, CO
NOx / PM Trade-off
critical diesel
tuning
PM
NOx
Combustion Characteristics – Understanding
Lower initial comb. Temp.
PM reduction, Good
economy
RoHR
Low NOx-PM
Combustion
Regime
HC, CO
Entire P rise in Combustion chamber takes place at Constant Volume i.e. at TDC.
Stages of SI Combustion – Ricardo’s
Theory
I II III
A – Passage of Spark
B – Beginning of P rise
C – Maximum pressure
I – Ignition Lag
II – Flame Propagation
III – After Burning
In order to reduce the heat loss, burn time (s) to be small (high flame velocity)
accomplished by either increasing
a) laminar burning velocity, or
b) turbulence intensity.
Highest laminar burning velocity is achieved for slightly rich mixtures (for
isooctane maximum Sl = 26.3 cm/s at f = 1.13
Spark Timing
Spark timing relative to TDC affects the pressure development and thus the
imep and power of the engine.
Want to ignite the gas before TDC so as to center the combustion around TDC.
motored
Maximum Brake Torque Timing
If start of combustion is too early work is done against piston and if too late
then peak pressure is reduced.
The optimum spark timing which gives the maximum brake torque, called
MBT timing occurs when these two opposite factors cancel.
Engine
Speed Piston
Speed Turbulent
Intensity Turbulent
Burning
Velocity
Engine Speed
Temperature
& Pressure
Factors:
• Self Ignition Temperature – High
• Ignition Lag Period – High
Piston damage by Knock
Effects:
• Severe pressure pulse is generated.
• Vibration and noisy operation.
• Increased loss of heat.
• Loss of power.
• Life of engine components reduces.
Abnormal Combustion
Surface Ignition
Power Output of
Time Factors Engine
Spark Advance
Composition
Factors Supercharging /
Turbocharging
Effect of Engine Variable on
Knock
Temperature
Compression Ratio
Factors
Mass of inducted
Density Factors Charge
Inlet Temperature
of mixture
Time Factors
High Load Demand
Composition Supercharger /
Factors Turbocharger
Effect of Engine Variable on
Knock
Temperature
Turbulence
Factors
Engine Speed
Density Factors
Flame Travel
Distance
Engine Size
Time Factors
Combustion
Chamber Shape
Composition
Location of Spark
Factors Plug
Effect of Engine Variable on
Knock
Temperature
Factors
Octane Number
Time Factors
Humidity of
entering air
Composition Molecular
Factors Structure
Anti Knock additives
Engine
Emissions
Exhaust Non-exhaust
Emissions Emissions
Particulates
Soot and Smoke
Effect of Equivalence Ratio on Emission
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