CHEMISTRY

SECTION – I
( SINGLE CORRECT CHOICE TYPE )
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct

1. Which of the following is a bronsted lowry acid

A. NaOH B. SO3 C. Ag  D. NH 3
2. The solubility of A 2 B3 is x mol dm 3 . Its K sp is
A. 6x 4 B. 64x 4 C. 36x 5 D. 108x 5
3. At a certain temperature, the following reactions have the equilibrium constants as shown
below :
S  s   O2  g  SO2  g  ; Kc  5
2S  s   3O2  g  2SO3  g  ; K c  10
What is the equilibrium constant K c for the reaction at the same temperature?
2SO2  g   O2  g  2SO3  g 
A. 2.5 B. 4 C. 0.4 D. 10
4. What is the ratio of concentration of CH 3COOH and its conjugate base during titration of acetic acid
6
with KOH, when the pH of the reaction mixture is 7. (Ka of CH 3COOH =10 )
A. 1:10 B. 5:1 C. 2:1 D. 1:20
5.  
Solubility of AgCl Ksp  11010 in 0.1M BaCl2 is

A. 109 M B. 5 109 M C. 5  10 10 M D. 0.05 M

6. 100 ml each of 0.25 M NaF and 0.015M Ba  NO3 2 are mixed. K sp of BaF2  1.7  10 6
A. A ppt is formed B. No ppt is formed
C. forms unsaturated solution D. Some more data are needed
7. The p H of H 2 SO4 solution is 2. Then its strength in g/lit
A. 0.49 B. 0.98 C. 1.26 D. 3
8. What is the correct relationship between free energy change and equilibrium constant of a reaction :
A. G  RT ln K B. G o   RT ln K
C. G  RT ln K D. G   RT ln K

SECTION - II
( MULTIPLE CORRECT CHOICE TYPE )
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/ are correct

9. How many of the following mixtures act as Buffer solutions

A. CH 3COOH & NaOH taken in 3:2 mole ratio
B. H 2CO3 & KOH taken in 3:2 mole ratio
C. Equal volumes of 0.5 M H 2 S & 0.25M KHS
D. Equal volumes of 0.1M H 2 S & 0.8 M KOH
10. Which of the following gaseous reactions forward reaction is /are favored by increasing pressure
A. N 2  3H 2 2 NH 3 B. PCl5 PCl3  Cl2
C. 2SO2  O2 2SO3 D. N 2  O2 2 NO
11. Which of the following aq. solutions have p  7H

A. HCl B. NH 4Cl C. CH 3COONa D. NaOH

12. An acid indicator has a K a of 3.0 105 . The acid form of the indicator is red and the conjugate basic
form is blue. Then which of the following is/or correct
A. pH is 4.05 when indicator is 75% red B. pH is 5.00 when indicator is 75% blue
C. pH is 5.00 when indicator is 75% red D. pH is 4.05 when indicator is 75% blue
13. A solution contains 0.05 M of each of NaCl and Na2CrO4 . Solid AgNO3 is gradually added to it.
Which of the following facts is true ?
Given : KSP ( AgCl )  1.7 1010 M 2 and KSP ( Ag2CrO4 )  1.9 1012 M 3
A. Cl  ions are precipitated first
B. CrO42 ions are precipitated first
C. Both Cl  and CrO42 ions are precipitated together
D. Solubility of Ag 2CrO4 is  AgCl (in water when they dissolved separately)
SECTION – III
(COMPREHENSION TYPE)
This section contains 2 groups of questions. Each group has 2 & 3 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Passage I

A solution is 0.1 M in each of KCl , KBr and K 2CrO4 . To this solution, solid AgNO3 is gradually
added. Assume no change in volume of the solution. Ksp ( AgCl )  1.7 1010
Ksp( AgBr )  5 1013 and Ksp ( Ag 2CrO4 )  1.9 10 12
14. The Sequence of Ions precipitated is in the following order
A. Cl 1 , Br 1 , CrO42 B. Br 1 , Cl 1 , CrO42
C. Cl 1 , CrO42 , Br 1 D. CrO42 , Cl 1 , Br 1
15. The concentration of the first ion precipitated when the second starts precipitating is about
A. 0.1M B. 0.03M C. 0.003M D. 3  104 M
Passage II

Solubility product (ksp) is useful in finding the soubilities of sparingly soluble salts is different
solvents like water ‘or’ the solutions of some other compounds when the sparingly soluble salt is
dissolved in different solutions. It’s solubility is effected by the common ions if any present. It also
depends on the % dissociation of the sparingly soluble salt.
16. The solubility’s of AgCl in water, 0.01 M CaCl2 , 0.01M NaCl and
0.05 AgNO3 are S1 , S 2 , S3 , S4 respectively then which of the following relationship is correct
A. S1  S2  S3  S4 B. S1  S3  S2  S4
C. S1  S2  S3  S4 D. S1  S3  S4  S2
17. Solubility product of which of the following is 4x where ‘x’ is solubility
3

A. LiCl B. CaF2 C. AlF3 D. AgCl

18. Which of the following will influence K sp of AgCl
 
A. Hydrolysis of Ag B. Complexation of Ag
C. Addition of HCl D. Change in temperature
SECTION –IV
( INTEGER ANSWER TYPE)
This section contains 10 questions . The answer to each of the questions is a single digit integer, ranging from
0 to 9. The appropriate bubbles below the respective question numbers in the ORS have to be darkened.

KIn
19. An indicator is a weak acid and pH range is 4.0 to 6.0. Then its P is _________

20. A solution has a pH = 9, it is 1000 times more basic than the original solution. What was the pH of the
original solution

21. For the reaction 3 A( g )  B( g ) 2C( g ) , at a given temperature Kc is 9. What must be the volume of
container in litres if the mixture contains 2 moles each of A,B and C at equilibrium?

22. A maximum of 10 x moles of MgCl2 could be dissolved in one litre of a solution containing 0.1M
NH 3 and , 0.01M NH 4 without causing precipitation of Mg  OH 2 . What is the value of x?

 Ka of NH 4  108 , K sp of Mg OH 2 is 1016 

23. 10 ml of 0.1 M CH 3COOH is mixed with 990ml of 0.1 M NaCl solution.What is the change in P H
of CH3COOH solution ?

24.
The equilibrium constant K p of reaction NH 4HS(s) NH3(g)  H 2S(g) is expressed as 1  10 y .
atm2.If the equilibrium pressure of mixture is 20 atm. What is ‘y’?

25. Calculate the solubility of CaF2 in water at 298 K. K sp of CaF2 is 1.7  104 if answer is 3.5  10  x
then x = ______?

26.
A B AB K c  0.5, then Kc for AB A  B is

27. Which of the following is/are either a lewis acid or lowry Bronsted acid.
CO2 ; H 2 SO4 ; CH3 ; CH3 ' oxygen atom; SiCl4

28. Solubility product of molar aqueous solution of solute Ax B y is 6912 M 7 then x  y = ______
 MATHEMATICS
SECTION – I
( SINGLE CORRECT CHOICE TYPE )
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct

1/n
m 
29. The value of Lt  r n  n  N is __________
n 
 r 1 
1 1
A. m B. C. n D.
m n
n
  n x 1
30. If f  x   Lt     sin  where x  Q . Then f(1) = _______
n   n  1
   n 
A. 0 B. –1 C. 1 D. ½
31. If  represents the greatest integer function less than or equal to x, the value of
 100 tan x   99sin x  
Lt      x   is _________
x 0
 x 
A. 199 B. 198 C. 0 D. None
 sin x 
 
 sin x  x sin x 
32. Lt    ______
x 0
 x 
1
A. B. 1 C. e D. Does not exist
e
x(1  a cos x)  b sin x
33. Lt  1 then (a, b) 
x 0 x3
1 3 5 3 5 3 5 3
A. , B. , C. , D. ,
2 2 2 2 2 2 2 2
dy
34. If x  3cos   2cos3  , y  3sin   2sin 3  then =
dx
A. tan  B. tan  C. cot  D. cot 
2 2

y  1  x  1  x 2 1  x 4  ....... 1  x 2n 
dy
35. If then at x = 0 is
dx
A. 1 B. -1 C. 0 D. 2
 x 1 1  x  1  dy
36. If y  sec 1    sin   x  (0,1)  (1, ) then =
 x 1   x 1  dx
 x 1   x 1
A. A B.   C.   D. 0
 x 1  x 1 
 SECTION - II
( MULTIPLE CORRECT CHOICE TYPE )
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/ are correct

(e x  1) 4
f ( x)  ( x  0) and f (0)  8 continuous at x  0 then  
37.  x2   x2 
sin  2  log 1  
   2

A. 2 B. 1 C. -1 D. -2
 x3 x 1

38. f ( x)   x 2 3 x 13 is
   x 1
4 2 4
A. continuous at x = 1 B. continuous at x = 3
C. Differentiable at x = 1 D. Differentiable at x = 3

39. If f ( x)  x3  6 x 2  11x  6 then f is not differentiable at x =

A. 1 B. 0 C. 2 D. 3

x x2 x3
40. If f ( x)  1 2 x 3 x 2 then which of the following are true
0 2 6x

1
A. f 1 (0)  0 B. f 1 (1)  -6 C. f 1 (2)  24 D. f 1    3/2
2

41. If f ( x)  x3  x 2 f 1 (1)  xf 11 (2)  f 111 (3) x  R then

A. f (0)  f (2)  f (1) B. f (0)  f (3)  0

C. f (1)  f (3)  f (2) D. f (1)  2 f (2)

SECTION – III
(COMPREHENSION TYPE)
This section contains 2 groups of questions. Each group has 2 & 3 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Passage I

f ( x)  sin 1 x   cos1 x  x [0,1] ([.] is greatest integer less than or equal to x)

42. Number of points of discontinuity of f(x)
A. 0 B. 1 C. 2 D. 3
43. Number of points f(x) is not differentiable is
A. 3 B. 2 C. 1 D. 0
Passage II

dy
The Derivative of y  f ( x) with respect to ‘x’ is given by  f 1 ( x)
dx
 4x   2  3x  dy
44. If y  tan 1  2 
 tan 1   then 
 1  5x   3  2x  dx
3 4 5
A. B. C. D. 0
1  9x 2 1  4x 2 1  25x 2
45.  
If f ( x)  sin  [ x]  x 2  where x  (2,3) and [x] is greatest integer less than or equal to x then
3 
  
f 1   =
 3 
 
A.  B. C. 0 D. does not exist
3 3
 a cos x  b sin x  dy
46. If y  tan 1   , then =
 b cos x  a sin x  dx
1 1 1
A. B. C. -1 D.
1  x2 1  x2 1  x2

SECTION –IV
( INTEGER ANSWER TYPE)
This section contains 10 questions . The answer to each of the questions is a single digit integer, ranging from
0 to 9. The appropriate bubbles below the respective question numbers in the ORS have to be darkened.

sin  cos x 
47. Lt  __________ ( [.] is greatest integer less than or equal to x)
x 0 1  cos x 

48. 1 f (50)f 1 (50)

f(x) = x  then  __________
1 50
2x 
1
2x 
2x  .....

dy
49. f(x)= 2x 2  1 and y  f (x 2 ) then at x = 1 is ______
dx

dy y
50. If xy  (x  y) n and = then n = _________
dx x

dy
51. If sin(x  y)  e x  y  2 and  k then k 2  k  ___________
dx

 y2  4 
2
 dy 
52. If x  sec   cos  and y  sec   cos  and    n k  2
n n
 then k = ________
 dx  x 4
 d  1 x2  x4 
53. If    ax  b then a-b = __________
dx  1  x  x 2 

dy
54. If xe xy  y  sin 2 x then at x = 0,  _________
dx

 4  dy k
55. If y  sin 1  x  x 3  and  then k = ____
 27  dx 9  x2

 1  1
56. The derivative of sec 1  2  with respect to 1  x 2 at x  is _______
 2x  1  2
 PHYSICS
SECTION – I
( SINGLE CORRECT CHOICE TYPE )
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct

57. In a vertical plane inside a smooth hollow thin tube a block of same mass as that of tube is released as
shown in figure. When it is slightly disturbed, it moves towards right. By the time the block reaches
the right end of the tube then the displacement of the tube will be (where ‘R’ is mean radius of tube).
Assume that the tube remains in vertical plane.
m
m
R

2R 4R R
A. B. C. D. R
  2
58. Two men ‘A’ and ‘B’ are standing on a plank. ‘B’ is at the middle of the plank and ‘A’ is the left end
of the plank. The surface between plank and ground is smooth. System is initially at rest and masses
are as shown in figure. ‘A’ and ‘B’ starts moving such that the position of ‘B’ remains fixed with
respect to ground. Then the point where A meets B is located at :
40kg 60kg
A B

smooth
40 kg

120cm
A. the middle of the plank
B. 30 cm from the left end of the plank
C. the right end of the plank
D. None of these
59. A mud ball at rest origin explodes into three fragments of masses in the ratio 1 : 2 : 1. The two equal
masses move with velocities 2iˆ  5 ˆj  6kˆ and 4iˆ  3 ˆj  2kˆ. The velocity of the third mass is
A. iˆ  4 ˆj  2kˆ m / s B. iˆ  4 ˆj  2kˆ m / s
C. 2iˆ  8 ˆj  4kˆ m / s D. none of these
60. A uniform square sheet has a side length of 12 cm. If one of the quadrants is removed, the shift in the
centre of mass

A. 1cm B. 3 cm C. 2 cm D. 2 cm
61. Two persons of masses m1 and m2 are standing on a smooth surface facing each other holding a
massless rope in their hands. If they pull each other with a force ‘F’ they meet each other (d is the
initial distance between them)

2m1m2 d
A. After seconds at the centre of mass
F (m1  m2 )

2m1m2 d
B. After seconds at the mid point
F (m1  m2 )

m1m2 d
C. After seconds at the centre of mass
F (m1  m2 )

m1m2 d
D. After seconds at the mid point
F (m1  m2 )

62. A train of mass M is moving on a circular track of radius ‘R’ with constant speed V. The length of
the train is half of the perimeter of the track. The linear momentum of the train will be
2MV
A. 0 B. C. MVR D. MV

63. Three particles of masses 1 kg, 2 kg and 3 kg are places at the vertices A, B and C of an equilateral
triangle ABC. If A and B lie at (0,0) and (1,0) m, the co-ordinates of their centre of mass are

 3 7  7 3  7 3   7 7 
A.  m and m  B.  m and m C.  m and m  D.  m and m 
 2 6  6 4   12 4   12 12 

64. Three particle each of 1kg mass are placed at corners of a right angled triangle AOB, ‘O’ being the
origin of coordinate system (OA and OB along the x-direction and +ve y-direction). If OA = OB =
1m, the position vector of centre of mass (in metres) is

i j i j 2(i  j )
A. B. C. D. i j
3 3 3

SECTION - II
( MULTIPLE CORRECT CHOICE TYPE )
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/ are correct

65. Assuming potential energy ‘U’ at ground level to be zero. All objects are made up of same material.
Solid Cube Solid Cone Solid Cylinder
Solid sphere
S
R
Q
P
D

u=0
D D D

U P = Potential energy of solid sphere

U Q = Potential energy of solid cube
U R = Potential energy of solid cone
U S = Potential energy of solid cylinder
 A. U S  U P B. U Q  U S C. U P  U Q D. U S  U R
66. A bag of mass M hangs by a long thread and a bullet (mass m) comes horizontally with velocity v and
gets caught in the bag. Then for the combined system (bag + bullet) :
A. Momentum is mMv/(M + m) B. KE is (1/2) Mv 2
C. Momentum is mv D. KE is m2v 2 / 2( M  m)
67. The centre of mass of system of particle is at the origin. It follows that
A. The number of particles on x – axis should be equal to the number of particle on y – axis
If there is a particle on the positive x – axis there must be at least one particle on the negative x –
B.
axis.
The total mass moment of one side of particles about the origin is equal to total mass moment of
C.
other side
D. Moment of mass of all particles about the origin is zero.
68. P is the centre of mass of four point masses A,B,C and D, which are coplanar but not collinear.
Choose correct option.
A. P may or may not coincide with one of the point masses
B. P must lie within the quadrilateral ABCD
P must lie within or on the edge of at least one of the triangles formed by taking A,B,C and D,
C.
three at a time
D. P must lie on a line joining two of the points A,B,C and D
69. A man ( m1 ) with a bag (m2 ) in hand falls vertically from a height h above the ground. After falling
through a height y0 , man throws bag horizontally with a velocity u0 towards his right
2 y0
A. Centre of mass is at a height (h  y0 ) at the end of time
g
2h
B. Centre of mass strikes the ground at the end of time
g
C. Centre of mass experiences a uniform acceleration
D. Centre of mass changes its path when man throws the bag.
SECTION – III
(COMPREHENSION TYPE)
This section contains 2 groups of questions. Each group has 2 & 3 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Passage I

A(2n  1) identical bricks, each of length L and height h are arranged, with n bricks above and n
bricks below the central brick AB, as shown in the figure for n = 3. Each brick is displaced with
respect to the one in contact by L /10 . The x-y axes are defined with respect to the lowest brick as
shown.
Y

A B

X
70. The y-coordinate of the centre of mass of the system is
1  1 nh 1
A. ( L  h)n B.  n   h C. D. (n  1)h
2  2 2 2
71. The x-coordinate of the centre of mass for the arrangement shown in the figure is
16 29 22 35
A. L B. L C. L D. L
45 50 35 44
Passage II

One particle of mass 1kg is moving along positive x-axis with velocity 3m/s. Another particles of
mass 2 kg is moving along y-axis with 6 m/s. At time t = 0. 1kg mass is at (3m,0) and 2 kg at (0,9m).
x – y plane is the horizontal plane.
72. The centre of mass of the two particles is moving in a straight line
A. y  x  2 B. y  4 x  2 C. y  2 x  4 D. y  2 x  4
73. If both the particles have the same value of coefficient of friction   0.2 . The centre of mass will stop
at a time t = ____________ sec.
A. 1.5 B. 4.5 C. 3 D. 2
74. Co-ordinates of centre of mass where it will stop finally are
A. 2m, 14.25 m B. 2.25 m, 10 m C. 3.75 m, 4m D. 1.75 m, 12m
SECTION –IV
( INTEGER ANSWER TYPE)
This section contains 10 questions . The answer to each of the questions is a single digit integer, ranging from
0 to 9. The appropriate bubbles below the respective question numbers in the ORS have to be darkened.

75. Two bodies of masses 2kg and 4kg are moving with velocities 20 ms 1 and 10 ms 1 towards each
other due to mutual gravitational attraction. The velocity of their centre of mass is _____

76. Mass is non uniformly distributed over the rod of length “ l ” . Its linear mass density varies linearly
kl
with length as   0 x. The position of centre of mass is given by where k = __
3

77. There is a uniform circular disc of radius R and a concentric disc of radius r (where r < R) is cut off
from it. The distance of the new position of centre of mass of hollow disc from the centre of disc
is__________

78. When a ice cube of side ‘a’ and mass ‘M’ is kept on a tray of mass ‘m’. The centre of mass of system
Ma
descends by when ice completely melts then k is________
k (m  M )

79. A cylinder of cross sectional area 1m 2 is filled with water at a rate of 2 m3 / sec , rate of displacement
of centre of mass is ________ m/sec

80. Two persons starting from the centre of a long trolley move with speed v in opposite direction with a
speed v relative to the trolley (consider all the mass to be same). If the velocity of the trolley is v and
coincides with motion of one of the persons, then velocity of COM of system is kv where k =
_______
81. A solid cone of height h and radius r is mounted on a solid cylinder of same height and radius. The
7h
centre of mass of the system lies at a distance of : (Assume the same density for both the bodies)
8k
above the base of the cone, where k =_________

82. If acceleration of 3 particles are  j  3k , i  j , and 2i  k . If the masses of three are in the ration 1 : 3
13i  y j  2k
: 5, then acceleration of centre of mass is ; Where y = ______
9

83. Two bodies of masses 1 kg and 2 kg are moving with velocities 2i  3 j and (3i  4 j ) m/s
xi  11 j
respectively. Then velocity of centre of mass of the system is where x is ________
3

84. Consider a system of two particles P and Q of mass m and 4m respectively. If speed of particle Q is 1
m/s with respect to centre of mass of P and Q, then what will be speed (in m/s) of particle P with
respect to centre of mass of P and Q ?