Professional Documents
Culture Documents
by
J. L. Johnson
I n s t i t u t e of G a s Technology
Chicago, Illinois 60616
I
INTRODUCTION I
228
-. ~ ._ .
i
i T h e objective of t h i s p a p e r is a ) to d i s c u s s the m o d e l s which have been
developed; b) to p r e s e n t the c o r r e l a t i o n s d e r i v e d f r o m t h e s e models; and
c ) to d e m o n s t r a t e t h e c o n s i s t e n c i e s between predictions of t h e s e c o r r e l a t i o n s
and v a r i o u s e x p e r i m e n t a l gasification data obtained p r i m a r i l y with bituminous
coal c h a r s . We obtained the e x p e r i m e n t a l information u s e d i n developing the
models f r o m two m a i n s o u r c e s . Initial development of the model f o r applica-
tion to the gasification of devolatilized c o a l c h a r in hydrogen and s t e a m -
hydrogen m i x t u r e s w a s b a s e d both on data obtained i n a n extensive study
conducted a t IGT with a h i g h - p r e s s u r e thermobalance a p p a r a t u s and on
differential r a t e data obtained by i n v e s t i g a t o r s at the Consolidation Coal
Company f o r the gasification of Disco c h a r i n a s m a l l - s c a l e fluid bed. 93,' ' l9
EXPERIMENTAL
229
5
SlGt L TO
RECI DER
-WINDLASS
It
INERT
GAS
GOLD CHAIN
f
-
-
-
PRODUCT
GAS
-SAMPLE
iJ BASKET
'I
/
tREACTOR
1-112-1009
FEED REACTANT GAS
230
During a test, the d r y feed gas flow r a t e s a r e m e a s u r e d by o r i f i c e m e t e r
and the d r y product g a s flow r a t e s by a wet-test m e t e r . Periodic samples
of product g a s a r e taken to d e t e r m i n e the d r y g a s ' composition by m a s s
spectrograph. Feed and product s t e a m flow r a t e s a r e m e a s u r e d by gravi-
m e t r i c means, and the solids r e s i d u e s a r e analyzed f o r t o t a l carbon and
hydrogen.
0.7
0.E
(I
E
-
::
0
Q 0.5
\ Q
r
0
\
0
z- 0.4
?u
a
E O.?
lJl
v)
:
0
I
0.2
P TEMPERATURE = 1700'F
W
0.1
C I I I I I I
I 2 3 4 5 6 7
TIME, min
A-112-1011
231
T e h l s 1. COMPOSITION O F AIR-PRETREATED hvAb
PITTSBURGH NO. 8 COAL CHAR (Ireland Mine)
Ultimate Analysis, d r y wt %
Carbon 71. 1
Hydrogen 4.26
Oxygen 8. 85
Nitrogen 1.26
Sulfur 3.64
Ash 10.89
Total 100.00
P r o x i m a t e Analysis,
232
r e s u l t s of studies m a d e with a g r e a t e r time r e s o l u t i o n indicated that this
r a p i d - r a t e methane f o r m a t i o n o c c u r s at a r a t e which is at leas& a n o r d e r of
magnitude slower than devolatilization. 7r '' In t h i s s e n s e it o c c u r s consecu-
tively to devolatilization.
233
Volatile c a r b o n c a n be evolved s o l e l y by t h e r m a l pyrolysis, independent
of t h e g a s e o u s medium. T h e d i s t r i b u t i o n of evolved p r o d u c t s d e r i v e d f r o m
t h e volatile c a r b o n f r a c t i o n i s not defined i n t h e model. In any application
of the model t o a n integral contacting s y s t e m , the devolatilization products
a r e e s t i m a t e d by extrapolation o r interpolation of yields obtained in pilot-
s c a l e fluid o r moving-bed s y s t e m s . T h i s p r o c e d u r e c a n be applied f o r
n a r r o w r a n g e s of conditions and only f o r v e r y similar contacting s y s t e m s .
E x p e r i m e n t a l r e s u l t s f r o m t h e r m o b a l a n c e o r f r e e - f a l l t e s t s conducted a t
IGT indicate that the a s s u m p t i o n of a constant volatile c a r b o n f r a c t i o n is valid
f o r c o a l heat-up r a t e s a s high a s 200 " F / s . However, other studies conducted
with e x t r e m e l y rapid heat-up r a t e s ( l o 4 to l o 7 " F / s ) have shown that quantities
of c a r b o n evolved during t h e r m a l p y r o l y s i s c a n exceed t h e volatile c a r b o n
f r a c t i o n defined i n t h i s model. b* An allowance f o r the i n c r e a s e i n evolved
c a r b o n would, t h e r e f o r e , have t o be m a d e i n s y s t e m s employing s u c h high
heating r a t e s .
c; - Cb
= b a s e carbon gasified -
-
b a s e c a r b o n i n feed c o a l c h a r
c;:
234
\
where
C = b a s e c a r b o n i n coal c h a r a t a n i n t e r m e d i a t e l e v e l of
gasification, g / g feed coal c h a r
0
Cb = (1 - V - A ) ( l -y)
\
and
where
T h e r e s u l t s shown in F i g u r e 2 c a n b e i n t e r p r e t e d by the t h r e e r e a c t i o n
s t a g e s defined above. C u r v e A c o r r e s p o n d s to a t e s t i n which a i r - p r e t r e a t e d
Ireland m i n e coal c h a r w a s exposed to a nitrogen a t m o s p h e r e a t a p r e s s u r e
of 500 psig. During the f i r s t minute when t h e s a m p l e i s heating up in the
235
i
thermobalance, the weight l o s s c o r r e s p o n d s to the evolution of volatile
matter. After t h i s period, no f u r t h e r significant weight l o s s o c c u r s . The
total weight l o s s of approximately 26 % c o r r e s p o n d s closely to the volatile
m a t t e r in t h e feed coal c h a r obtained by standard proximate analysis.
Within the context of the t h r e e reaction s t a g e s defined, weight l o s s i n this
t e s t o c c u r s e n t i r e l y i n the devolatilization stage, w h e r e a l l of the volatile
carbon h a s been gasified; a l l of the b a s e carbon r e m a i n s in the devolatilized
coal char. When t h e c h a r resulting f r o m this t e s t is then exposed to hydro-
gen at 500 psig (curve B), the reaction of the hydrogen with b a s e carbon to
f o r m m e t h a n e r e s u l t s in f u r t h e r weight l o s s . T h i s reaction, which t a k e s
place a t a m u c h lower rate than devolatilization, o c c u r s i n the low-rate
gasification stage. With t h i s p a r t i c u l a r sample, t h e r e w a s no reaction in
the r a p i d - r a t e m e t h a n e f o r m a t i o n stage because the reactivity of the coal
c h a r in t h i s stage w a s destroyed during prolonged exposure to nitrogen.
236
C o r r e l a t i o n s f o r Rapid-Rate Methane F o r m a t i o n Stage
where
\
= hydrogen p a r t i a l p r e s s u r e , a t m
PH2
= r e l a t i v e reactivity f a c t o r f o r r a p i d - r a t e methane formation
fR
dependent on the p a r t i c u l a r c a r b o n a c e o u s solid. (Defined a s
unity f o r a i r - p r e t r e a t e d I r e l a n d m i n e c o a l c h a r . )
237
07
TEMPERATURE RANGEF: GAS
0 1550- 1600
06 A 1700
-a 0 1750
v 1600
X
0 1600- 1650
? 05
z
0
I-
V
3
(L
04
z
0
4
I-
03
00
' > IO 20 30
HYDROGEN PARTIAL PRESSURE,atm
40 50 60 70
A-112- 1006
238
0 10 20 30 40
HYDROGEN PRESSURE, atm
A-112-1005
a
X
/
Y
2 0.8
2-
0
I-
U 0.6
Z
3
LL I A A S L O P E = 0.0105 atm-'
0 1470
A 2190
0 20 40 60 80 100
HYDROGEN PRESSURE, otm-l
1-112-1008
0.8I
::
- 0.7
.- -
In
0
0
al 0.6 -
L
al
m
\
m 0.5 -
NITROGEN-PRE-
z TREATED COAL
0
,=
V
0.4 - CHAR, H20 AT
U
U
LL
0 I 2 3
TIME,
4
min
5 6 7 8
i
A-112-IOZ2
240
Although the effects of p r e t r e a t m e n t t e m p e r a t u r e on reactivity in the
r a p i d - r a t e methane formation stage have not been systematically studied i n
this investigation, s o m e indication is apparent f r o m the r e s u l t s given i n
F i g u r e 7. It shows total weight l o s s e s f o r m a t e r i a l s subjected to different
p r e t r e a t m e n t s i n nitrogen obtained a f t e r gasification of air - p r e t r e a t e d coal
char in hydrogen f o r 1 hour. Below 1000"F, no effect of the nitrogen p r e -
t r e a t m e n t is apparent on subsequent weight l o s s i n hydrogen. Above t h i s
t e m p e r a t u r e , however, the total weight l o s s f o r m a t e r i a l s initially exposed
to nitrogen tends to d e c r e a s e with increasing t e m p e r a t u r e , and above
approximately 1500 "F, no r a p i d - r a t e methane formation o c c u r s with these
materials.
i
24 1
E
c
0
q m
242
\
A. -+ A*
A* -4 B
A*
b a s e c a r b o n t hydrogen- methane (9)
T h i s model, which i s qualitatively similar to one p r o p o s e d by Mosely and
Patterson, l3 a s s u m e s that the coal c h a r initially f o r m s a n active i n t e r m e d i a t e ,
A,, (Equation 7 ) which c a t a l y z e s the r e a c t i o n between b a s e c a r b o n and
g a s e o u s hydrogen t o f o r m methane (Equation 9). T h i s reaction, however,
c o m p e t e s with a r e a c t i o n i n which A , deactivates to f o r m the inactive s p e c i e s ,
B (Equation 8).
The following e x p r e s s i o n is a s s u m e d t o d e s c r i b e t h e r a t e of r e a c t i o n in
Equation 9:
where
= concentration of s p e c i e s , A, m o l / m o l of b a s e carbon
NA*
t = time
r NAO
= concentration of s p e c i e s , Ao, m o l / m o l base carbon
24 3
Combining Equations 10 and 11 l e a d s to the expression -
= - fR +$+ pH:l - X)2h exp(-aX2) (12)
a
244
o c c u r p a r t i c u l a r l y a t gasification t e m p e r a t u r e s l e s s than 1600 OF. At t h e s e
lower t e m p e r a t u r e s , specific p r e t r e a t m e n t conditions such a s g a s a t m o s -
p h e r e and time of p r e t r e a t m e n t produce somewhat complex effects during
subsequent gasification f o r b a s e c a r b o n c o n v e r s i o n s of l e s s than 10 %.
T h e s e limitations have no p r a c t i c a l significance in using the simplified
model developed to d e s c r i b e coal c h a r gasification kinetics at higher t e m -
p e r a t u r e s , o r f o r b a s e carbon c o n v e r s i o n l e v e l s sufficiently g r e a t e r than
10 %.
f L = fo exp (8467/To)
k1 -
- (17 1
t-16.35
246
-
kLI =
1t P
exp(2.67;i
H2
- 33,076/T) (1
I
I ' \
kIII =
ff = '
-
~
$2
H2
P
H2O
exp(12.4463 - 44,544/T)
i 1 t e x p ( 4 . 6 6 9 6 t 15,198/T) P
52.7 PH
/-:
0. 521
H 7.
PH
7.
PCH4PC0
E l
PH,PH,OKIII -/
pCH4
t 0.85PC, t 18.62 p__
. _
\'
T = reaction t e m p e r a t u r e , "R
'H,' 'H20'
fO
= r e l a t i v e reactivity f a c t o r f o r low-rate gasification
dependent on the p a r t i c u l a r carbonaceous s o l i d
247
individual exceptions t o t h i s t r e n d exist.
M(X) =/,
=/, xR
The t e r m i A R
ex +cwXz dX =CR
tfLkTt
---- Values have been obtained
which r a n g e f r o m 0. 3 f o r a low-volatile bituminous c o a l c h a r to about 10 f o r
a North Dakota lignite. T h e r e a c t i v i t y of the Disco c h a r u s e d i n gasification
studies conducted by t h e Consolidation C o a l Company9*
+Jx
XR
‘9 is fo = 0.488.
M(X) =lo X
= fLkT t
248
2.0
3 95
\ 09
1. 1.5
T
- X
X
-
- z
2
&
m
-
I1
X
08 :
I-
LL
I z
z 0
fn
2 a
L 1.0 07 9z
z
3 0
LL V
z z
2 0
m
t
-I
06 a
a
w V
a W
a fn
8 35 2
0.5
/ PRESSURE =35.0otm
34
0 1700
53
A 1800
0 1900
32
31
0 3
0 2 4 6 8 IO 12 14
TIME,min
A-112-1007
249
0.9 x
..
z
0 I
2 2.0 6a
z- e
LL
i
0 3.8
I-
U
z 1.6 0
v)
3
LL
e
W
>
z z
0 1.2 0.7
GJ z
W 0
E
c
o.8
PRESSURE = 35.0 otm
3.6 m
3.5
LL
a
TEMPERATURE, OF W
v)
0 1700 1.4 a
0.4 m
A 1800 1.3
0 1900 1.2
1.I
0 1
0 20 40 60 80 too I20
TIME, min
8-112-1003
250
I'
4.c
\, 1.9
\
3s X
i
X 0
Y
I-
z O
a
CK
z- LL
0 z
I-
O
z 0
3 1.8
2.( W
>
z z
Q 8
G-I z
W 0
CT m
CT CK
a
8 O
w
v,
a
).6
TIME, min
A-112-1002
25 1
I
Carbon gasification r a t e s w e r e d i r e c t l y m e a s u r e d i n the fluid-bed t e s t s
conducted with Disco c h a r , 9 * and values of f k and O! can be obtained
I9
L T
dX/dt
graphically by plotting v a l u e s of I n v e r s u s Xz. Such a plot i s
x 13 dX/dt
illustrated in Figure I1,where the value of #(- a t X = 0 is equal
to fLkT and the slope of a given line is equal to 01. Generally, the c o r r e l a -
tions p r e s e n t e d a r e consistent with v a l u e s of fLkT and IY obtained f o r the
gasification of Disco c h a r at t e m p e r a t u r e s of 1600 and 1700 " F and p r e s s u r e s
of 1, 6, and 30 a t m o s p h e r e s f o r gasification with pure hydrogen and with
v a r i o u s steam-hydrogen m i x t u r e s . The c o r r e l a t i o n s a r e a l s o consistent
with individual r a t e s of methane and c a r b o n oxide formation r e p o r t e d in the
investigations conducted with Disco c h a r f o r initial l e v e l s of c a r b o n conver -
sion. Although the relative r a t e s of methane to carbon oxide f o r m a t i o n
w e r e r e p o r t e d to i n c r e a s e somewhat with i n c r e a s i n g conversion level,
a t r e n d not accounted f o r in the m o d e l developed in t h i s study, i n v e s t i g a t o r s
a t t h e Consolidation Coal Company have suggested that t h i s effect w a s
caused by a catalytic reaction d o w n s t r e a m of the fluid-bed r e a c t o r em-
ployed, in which some of the c a r b o n monoxide produced in the r e a c t o r was
converted t o methane.
252
U
a
U m Nmm o d m m m + e m 9 NN-Ilnoa -e* 0
d a -4- m a e a r - e e m e omr?m-lm m - 4 N
-i 0 --e 0 " N W " NNNN o-lmmma fua* m
L-
A.
2
U
-i
0
0
. . . 0
0 0 0
0 0 0
. 0. 0. 0. 0. . . . . 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 O d O d O 0
0 0 0 0 0 0 0
. . .
0 0 0
.
0
0
c d
c1 L)
Y
c
rd
-
I
Y c
z
.A
0
E
U
0
Y
rd
W
a
0
e-r-
- 4 - 0 ' .
-4-0
a e a N m d*eN
o a e m e a e m e
.-ANN- NNNN
l n o o o o N-a
r-lnmoo N V -
-4mNme N a v
-
. . . .
0
Q\
0: 0
0
. . . . . . . . . . . .
0 0 0
0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0 0
0 0 0 0
0 0 0 0 0 0
d0OdO
0 0 0
0 0 0
0
0
_-
c
0
*
4
-IN*
*G-m
o\*ooo m m o
a m e m m \ o a -
0
m m a O-4m-N
W
0
. . . 0. 0. 0. 0.0. 0 0 0 d o d d ~ d d0 0 0
0 0 0
NNO\ 03
0
I I l l I 1 . 1 I I I l l 1 I I I I I I l l I
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
m
m
u
L w e e
In
. . . . . . .
* * + N
m m a m
\c) aaa
-lm mm mmmm
J'
0 0 0 0 0 0 0 0 0
* 0 0 0 0
0 m m m 0 0 0 0 0 lnmmln
a a a er-eer- 4
e e e e
2 3 4 3 - 4 4
- 4 - d -
253
I
I
. . . . . . . . . . . 0. 0. 0. 0.
00000000 0 0 0
0ddodododdddd
. . . . . . . .
00000000
1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
o o o o o o o o o o m m m
*** 00000000
*. *. *.
ddd 000
I
**
. . I
N O N
. . .
I C O N It-t-m
* m 4 * m
z
o)
rd
F
0000000000000
* ** 000 0000
***
0000000000000 000 0000
r-I-Fbr-r-Fr-t-I-bFt- COCOm mmmm
4 4 4 3 4 H 4 4 4 4 - 4 4 4 4-44 3 4 4 r l
254
\DU'\DdmclWN \OW- O N m r l a 4 a m * N F mmC0r.m
m o o o * m o m o m m m o ~ ~ a m r n 4 c o a ~ 0r \ -4 c4 o 4 +
0 0 0 0 0 0 0 0 0 O N 0 * 4 4 4 O V N N 4 N M 4 O m m N 4
0
0
. . . . . . . . . . . .
0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0
000
0 0 0
000000040000 0 0 0 0 0
ddddddoooooo
. . . . . . . . . . . 0 0 0 0 0
0
N N m a m a m ocoao N V 4 O O
* N0 0+ 0
In
0
a N a H N * a * m
0 0 0 N * O N O
04000
Nmm
O N 0
p
N
~ * a ~ 4 a * o r n m m
- I 4 4 4 m N O N 4 , 4 4
4 0 r - m ~ -
O W F N 4
d d d d d d o. o. o. o.o.o. . . . . .
o oooooo+oooo 00000
0
0
. 0. 0. 0. 0. 0. 0. 0.0. . . .
0 0 0 0 0 0 0 0 0 0 0
0 0 0 00000
+ ommm3acoa m m a
+ m*mNr-omF N O N
0
. . . . . . . . . N. +. * . d d d d d d d d o. o. o.o. . . . . .
N 4 - 3 N m - I N 3
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
I I I I I I I I I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 l l I I
o o o o o o o m m m m m ooooo
0 0 0 0 0 0 0 0 0 0 0 0
*. *. *. *. *.
0 0 0 0 0
N comco+mcooa a m m
m N m m 4 m m r - *
dddddd\dAd o o m
...
NNN
. . . . . . . . . . . .
0 0 0 0 0 0 C O P N O O N
255
............
000000000000 ddddddoooooooo
........... 4 0 4
............
000000000000 ddodddddddddd; Ad;
. . . . . . . . . . . . 0. 0.0.0.0.0.0.0.~ .0 4
000000000000
. 0. -. 4. -.0-40
4
...
1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 l l I 1 1 1
mmmmmmmmmmmm mmmmmmmmmmmmmm mmm
. . * * *. *. *.*.*.*.*.*.*.* .* .* .*0.0
*****e******
..........
000000000000
*.*.
0
d 0 O O O O O O O O O O O O
............
mNmm***NNm4-
00-4000000000
256
500
TEMPERATURE=1700°F
4 00
IO
II I I
61
I I
0 0.2 0.4 0.6 0.8 I13
X2
a - 1 1 2 - 1004
s
W 0.06
2l
K
D
W
5 0.04
1
3
J
V
a
0.02 TEMPERATURE RANGE 1600'-1900'F
PRESSURE RANGE 1-70 otm
0. 1 4
0 ' 0.02 0.04 0.06 0.08 0.10 0.12
EXPERIMENTAL RATE CONSTANT, rnin-l
I
~-IIZ-IOIO
/
A COAL CHAR INITIALLY DEVOLATILIZED
O.Io - IN NITROGEN, OR PARTIALLY GASIFIED
WITH STEAM AND HYDROGEN
IN A FLUID BED
I-
2 0 0 / 0 A
CQ
v,
0.08
z
8
IX
0
5W 0.04.
J
3
Ya
u 0.02. RANGE : 1700.- 1800.F
RANGE : 3 5 - 7 0 aim
Ol/ I I I 1 I
(a)
W
5
0.4 -
n
W
G1
2 0.2- TEMPERATURE RANGE:
Y
a
1700'- I90O0F
PRESSURE RANGE:
V
35-70 aim
A-112-1016
(b)
p
GASIFIED WITH STEAM AND
HYDROGEN IN A FLUID BED
a
004
TEMPERATURE RANGE
1550*-1900'F
a 002
V PRESSURE RANGE
3 5 - 7 0 atrn
0
0 002 004 006 008 010 012
EXPERIMENTAL RATE CONSTANT, rnin-'
A , I 2 101)
(4
16
/
COAL CHAR INITIALLY DEVOLATILIZED
IN NITROGEN OR PARTIALLY GASIFIED
- 14 WITH STEAM AND HYDROGEN IN A
I
FLUID BED
5
E
/
12 TEMPERATURE RANGE :
I-- 170Oe-200O0F
z
a
IO
z
s 08
W
t
(r
0.6
0
W
l-
a
J 04
3
Ya
02
0
0 0 2 04 06 08 IO I2 14 I6
EXPERIMENTAL RATE CONSTANT, min-'
.-112-1018
F
( b)
F i g u r e 14. COMPARISON O F EXPERIMENTAL AND CALCULATED
RATE CONSTANTS FOR LOW -RATE GASIFICATION O F
AIR-PRETREATED IRELAND MINE COAL CHAR LN SYNTHESIS GASES
239
i
(1
260
0.572
lo=
fR: 0.694
w.
aE
L
r
1
0.10 -
PRESSURE i 140 otrn
X I
AV G
0 1252 0.0029
A 1291-1317 0 0029
0 1347-1376 0.0029
V 1440 0.0029
0 1485 0.0095
Z 04-
E
0
V 0.3 - FEED SOLIDS
COAL CHAR
WITHOUT
COAL CHAR VOLATILE
WITH MATTER
I VOLATILE (PARTIALLY
FEED GAS MATTER GASIFIED)
0
SYNTHESIS GAS . .A , . v .
Y
TEMPERATURE RANGE : 1590" 1880' F
PRESSURE RANGE : 15- IO3 atm
fo' 1.0
- f,= 1.0
FEED SOLIDS
qO& CHAR
WITHOUT
COAL CHAR VOLATILE
WITH MATTER
VOLATILE (PARTIALLY
FEED GAS MATTER GASIFIED:
H 2 0 OR H2/H20 0 0
SYNTHESIS GAS b v
L
/
r
0.5 - TEMPERATURE RANGE : 1602'- 1816' F
- PRESSURE RANGE: 4.1 - 9.5 otrn
\
E
-0 to ~ 0 . 4 8 8
E 0.4 -
N
0
V
+ 0.3 -
D
W
5 0.2 -
3
FEED GAS
V
J
a
V
0.1 -
.
' t
2
V
0.06
TEMPERATURE RANGE
PRESSURE RANGE. 4.1-9.5otm
: 1602'-1816'F
,"
I o.031
1
0
w
t+ 0.02
I y o
V
1 FEED GAS
9 0.01 0 HzO. H20/N2
0
, p
A H20/H2
HzO~H2
,
0 001
0.01 002
0.02 003
0.03 0 .00 4
0 4 005
0.05 C 16
L EXPERIMENTAL CH4, mol/rnol C-hr
*-1,2-1012
263
TOTAL PRESSURE,
GRAPHITE
0.3mol C IN GAS
BASIS:
mol F E E D H z 0
0.001
264
SUMMARY OF NOTATION
b a s e c a r b o n in c o a l c h a r a t a n i n t e r m e d i a t e gasification
level, g / g feed c o a l c h a r
cV
volatile c a r b o n in feed coal, g / g feed coal c h a r
fO
relative reactivity factor f o r l o w - r a t e gasification
dependent on the p a r t i c u l a r carbonaceous solid
fL r e l a t i v e reactivity f a c t o r f o r l o w - r a t e gasification
dependent on the p a r t i c u l a r carbonaceous solid and
pretreatment temperature
k r a t e constants, m i n - ’
*(T)’ k3(T)
r a t e constants f o r Reactions I, 11, and ILL, min-’
kI’ kII’ kIII
E E E
equilibrium constants f o r Reactions I, 11, and I11
K, ’ KII’ KIII considering c a r b o n a s graphite
concentration of s p e c i e s A, a t a n y t i m e , m o l / m o l b a s e
carbon
265
t = time, m i n
T = r e a c t i o n t e m p e r a t u r e , OR
= p r e t r e a t m e n t t e m p e r a t u r e , "R
TO
wO
= weight of f e e d c o a l c h a r , g
X = total b a s e c a r b o n conversion f r a c t i o n
= b a s e c a r b o n conversion f r a c t i o n a f t e r r e a c t i o n in
xR r a p i d - r a t e m e t h a n e f o r m a t i o n s t a g e is completed
G r e e k Symbols
B = k,(T)/k,(T) r a t i o
ACKNOWLEDGMENT
.f
T h e w o r k conducted i n t h i s study w a s s p o n s o r e d by t h e A m e r i c a n G a s
Association, the U . S. D e p a r t m e n t of t h e I n t e r i o r , Office of Coal R e s e a r c h ,
and t h e F u e l Gas A s s o c i a t e s . T h e author w i s h e s to e x p r e s s his appreciation
f o r the p e r m i s s i o n of t h e s e g r o u p s to publish this paper.
REFERENCES CITED
266
4. Blackwood, J. D. and M c G r o r y , F . , "The Carbon-Steam Reaction a t
High P r e s s u r e , I' Aust. J. Chem. 11,
16-33 (1958) F e b r u a r y .
267
16. Wen, C. Y. and Huebler, J., "Kinetic Study of Coal-Char Hydrogasifi-
17.
cation -
Rapid Initial Reaction, I' Ind. Eng. Chem. P r o c e s s Des. Dev. 2,
147-54 (1965) April.
19.
action of Hydrogen With L o w - T e m p e r a t u r e C h a r a t 1500 to 1700 "F,
Eng. Chern. 47, 820-25 (1955) April.
.J
268