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PHYSICS:

+Ve - Ve No.of Total

Section Question Type

Marks Marks Qs marks

Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32

Sec – II(Q.N : 9 – 18) Questions with Multiple Correct Choice 4 -2 10 40

Matrix Matching

Sec – III(Q.N : 19 – 20) 2 -1 2 16

(+2/-1 for every match)

Total 20 88

CHEMISTRY:

+Ve - Ve No.of Total

et

Section Question Type

Marks Marks Qs marks

.n

Sec – I(Q.N : 21 – 28) Questions with Integer Answer Type 4 0 8 32

Sec – II(Q.N : 29 – 38) Questions with Multiple Correct Choice 4 -2 10 40

ha

Matrix Matching

Sec – III(Q.N : 39 – 40) 2 -1 2 16

(+2/-1 for every match)

Total 20 88

tib

MATHEMATICS:

+Ve - Ve No.of Total

Section

ra Question Type

Marks Marks Qs marks

Sec – I(Q.N : 41 – 48) Questions with Integer Answer Type 4 0 8 32

up

Matrix Matching

ad

(+2/-1 for every match)

Total 20 88

en

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PHYSICS Max Marks : 88

SECTION – I

(INTEGER ANSWER TYPE )

This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).

Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.

I) Gravitational field at all points inside a thin uniform hollow cube is zero

II) The presence of a conducting loop is not necessary to have an induced electric

et

field (due to time varying magnetic field)

.n

III) RMS value of a current i f t [f(t) is either sinusoidal or non-sinusoidal] is

ha

always greater than or equal to it’s average value

IV) Two moving charges may not exert equal and opposite magnetic forces on

tib

each other ra

V) Magnetic field on the axis of a long straight current carrying conductor whose

up

cross – section is either circular or rectangular is zero.

2. A charged particle is projected with initial velocity V 2iˆ 3ˆj 5kˆ m /s in a

ad

en

.e

3. Three point charges Q each are placed at the vertices of an equilateral triangle of

side There is a point P which is equidistant from all the three charges and

w

6 m.

the magnitude of net electric field (due to all charges) at P is equal to the

w

magnitude of electric field at P due to one of the charges. Then the distance of

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1

point P from centre of triangle is meter. What is the value of N?

N

of H atoms in ground state. Another photon beam containing various energies is

passed through a sample of Li2 ions in ground state. The two photon beams are

non – identical .Assume that excitation of electrons takes place in a single step to

Page 2

different energy levels, but de – excitation takes place in several possible steps to

ground state. Let x1 and x 2 be the number of dark lines in the absorption spectra of

H atoms and Li2 ions respectively and y1 and y 2 be the number of bright lines in

the emission spectra of H atoms and Li2 ions respectively. If x1 x 2 15, then

the minimum value of y1 y 2 14N 8. What is N ?

5. A quarter portion of a thin equi-convex lens with focal length 30 cm has been

removed by cutting it perpendicular to the principal axis as shown. A small object

et

is placed on principal axis at a large distance from lens and is moving towards the

.n

lens. At an instant, it is observed that the relative velocity between the two distinct

ha

images (corresponding to paraxial rays) is zero. The distance of object at this

instant is 5 k K 0 centimeters what is ‘k’?

tib

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up

O

ad

shown. Initial tension in each spring is F0 . The period of small oscillations of the

en

Ml

particle along a line Perpendicular to the plane containing the springs is 2 .

NF0

.e

What is ‘N’? (Neglect effect of gravity and assume that the additional force

developed in springs due to displacement is much smaller than the original tension

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F0 )

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7. The same quantity of an ideal diatomic gas is undergone for two cyclic processes

(1) and (2) as shown. 1 and 2 are the efficiencies of (1) and (2) respectively.

1 1 7x

Then . What is the value of (x + y)?

2 15 y

Page 3

2P0

1 2

P0

V0 3V0 4V0 V

2V0

et

8. Half life of a freshly prepared radioactive sample is one hour. The probability of a

.n

1 1

selected nucleus that will be decayed during second hour or fourth hour is .

16 N

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What is the value of ‘N’?

tib

SECTION – II

(MULTIPLE CORRECT ANSWER TYPE)

ra

This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,

out of which ONE OR MORE than ONE option can be correct.

up

Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.

9. The figure given below is the apparatus of photoelectric effect in which the light

energy falling on emitter plate per unit time remains constant, but its frequency

ad

can be changed. I 1 and I 2 are the photo currents registered when the light has

f

en

2

f

less than . The values of I 1 and I 2 (in above two cases) can be varied between

.e

2

zero and their saturated values by changing the magnitude and polarity of applied

w

voltage V.

light

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A

emittor collector

A) A positive value of V can exist so that I 2 2I1

B) A negative value of V (reversed polarity) can exist so that I 1 I 2

C) A negative value of V (reversed polarity) can exist so that I 1 2I 2

D) I 2 I1 for V 0

Page 4

10. A rigid square loop is dipped in a wetting liquid and is taken out. A loop of light

inextensible thread of total length 15 units is gently put on the liquid film formed

in the square frame. Now a hole is pricked inside the thread loop. Take the length

of side of square frame is 4 units. Surface tension of liquid is S. Neglect any

friction between square frame and thread. What will be the final surface area of

liquid film on one side of square frame after the hole is pricked?

1 1 31 31

A) units B) units C) units D) units

16 4 15 4 16 15

11. The graph shows the current versus voltage in a series RLC circuit at a fixed

frequency. The arrow indicates the direction that this curve is drawn as time

progresses. Which of the following conclusion(s) can be made?

et

current

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voltage

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A) Voltage leads current by p / 2

tib

B) Impendence is equal to reactance and it is greater than 1

C) Reactance of circuit is less than 1

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D) Power factor of circuit is zero

up

12. A uniform resistive rod AB of length 3m is sliding with constant velocity 2 m/s on

ad

two long horizontal, parallel and resistanceless rails which are separated by 2m.

The resistance of rod AB is 3 . The rails are connected with 6 resistance at one

en

end. A uniform vertical magnetic field 2T exists as shown. Then select correct

.e

statement(s)

A

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w

6 >

> v = 2 m/s

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> >

B

B) emf induced between the ends of rod is 10 V

C) Potential difference between the ends of rod is10 V

D) Potential difference between the ends of rod is 6 V

Page 5

13. An ideal gas is enclosed in a chamber and is undergone for a thermodynamic

process. In this process, Q represents the net heat transfer to the gas and U

represents the net change in internal energy of the gas. Select the incorrect

statement/s

A) If Q 0 , then the process must be adiabatic

B) If U 0 , then the process must be isothermal

C) If Q U , then the process must be isochoric

D) Q U 0 , then a particular state may be repeated twice or more

14. In the circuit given below, each resistance is 3 . Select the correct statement.

et

C D

>

>

>

>

.n

>

>

>

>

>

>

>

>

>

>

>

F

ha

E >

>

>

>

>

>

>

tib

ra 12V

A) The current in the branch CD is 3A towards right

up

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D) The current in the branch EF is 1A towards right

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15. A pan balance has a container of water with an overflow spout on the right-hand

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pan as shown. It is full of water up to the overflow spout. A container on the left-

hand pan is positioned to catch any water that overflows. The entire apparatus is

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lowered into the water, but not allowed to rest on the bottom of the container.

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Water

Page 6

A) Water overflows and the right side of the balance tips down.

B) Water overflows and the left side of the balance tips down.

C) Water overflows but the balance remains balanced.

D) Water overflows but which side of the balance tips down depends on whether

the brass weight is partly or completely submerged.

16. Choose the correct statement/s regarding the nature of image (I) corresponding to

a virtual object in case of a thin lens

A) If the lens is concave, then I may be real, enlarged and erect

et

B) If the lens is concave, then I may be virtual, enlarged and inverted

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C) If the lens is concave, then I may be virtual, diminished and inverted

D) If the lens is convex, then I may be real, enlarged and erect

ha

17. A large vacuum chamber of volume ‘V’ is connected to a narrow cylindrical pipe

which is initially filled with an ideal gas 1.4 at temperature T0 , pressure P0

tib

and volume V0 V . The gas is enclosed by a light insulating piston (which is

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free to move) and the air outside is at constant pressure P0 . Now the gas in the pipe

is slowly allowed to leak into the vacuum chamber through a small opening as

up

shown. All the walls are insulated. The final pressure ‘P’ and temperature ‘T’ of

the gas are given by

ad

V

en

vaccum piston

gas Air

P0, V, T0

.e

0 P0

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w

P0 V0 1.4 P0 V0

A) P B) T T0 C) P D) T 1.4 T0

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V V

18. A disc with a hole is given some initial motion and released so that it rolls without

slipping on the ground. There is sufficient friction. C is geometric centre of disc.

At the instant shown in figure, the hole is at its upper position. Considering the

motion of disc till it makes half rotation,

Page 7

A) Angular momentum of disc is conserved w. r. t the point of contact.

B) The speed of point C will decrease

C) The mechanical energy of disc is conserved.

et

D) A backward friction acts on the disc.

.n

ha

SECTION - III

(MATRIX MATCHING ANSWER TYPE)

This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and four statements (P, Q, R and

tib

S) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. For

example, if for a given question, statement B matches with the statements given in Q and R, then for the particular question darken the

bubbles corresponding to Q and R in the OMR sheet. For each correct matching will be awarded +2 marks ONLY and 0 if not

attempted and -1 in all other cases.

ra

19. The figure shows the displacement versus position of particle in a longitudinal

harmonic wave which is traveling in air along ve x – direction. P, Q, R and S are

up

Match Column – I with Column – II

ad

y

en

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P Q

w

x

w

S

R

w

Column – I Column – II

(A) The points of compression (P) P

(B) The points of rarefaction (Q) Q

(C) The points at which pressure is increasing (R) R

(D) The points at which pressure is decreasing (S) S

Page 8

20. Consider a circular loop of radius ‘R’ in XZ-plane with centre at origin. The

magnitude of B.d l is to be evaluated along this loop due to a semi infinite

current (I) carrying straight wire in XY-plane. Column – I represents the position

of wire and Column – II represents the magnitude of B.d l

Column – I Column – II

A) Wire extends from (-R, R) to along the line y = R P) Zero

m0 I

et

B) Wire extends from (0, R) to along the line y = R Q) equal to

2

.n

m0 I

C) Wire extends from (0, R) to along the line y x R R) less than

2

ha

R R m0 I

D) Wire extends from , 0 to along the line y x S) greater than

2

tib

2 2

ra

up

ad

en

.e

w

w

w

Page 9

CHEMISTRY Max Marks : 88

SECTION – I

(INTEGER ANSWER TYPE )

This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).

Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.

21. A cell designed below contains one litre of buffer mixture of acetic acid and

sodium acetate each 1M in two compartments using platinum electrodes. Pka of

acid is 4.74. The emf of the cell at 298 K is ; (neglecting the liquid junction

potential if present)

et

Pt / H 21atm / (CH3COOH1M CH3COONa1M ) / / (CH 3COOH1M CH 3COONa 1M ) / H 21 atm / Pt

.n

22. Gaseous COF2 is passed over a catalyst at 10000 C and comes to equilibrium

ha

CO2 g CF4 g . The pressure under equilibrium = 10 atm. A sample of

2COF2g

tib

the equilibrium mixture is quickly “fronzen” i.e., cooled to a low temperature.

This prevents any change in the equilibrium concentrations. Analysis of 500 ml

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(STP) of the equilibrium mixture shows that the combined volumes (STP) of

up

ad

23. In a hydrogen atom the wavelength of ‘m’th line of balmer series is approximately

4102 A0 . What is the value of ‘m’

en

24. If 3-bromo-4-methyl hexane is treated with ethanolic KOH solution, how many

.e

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25. C6H4Br2 (P) is a dibromo benzene and it is the less polar isomer of its two polar

w

isomers. If P is treated with conc. HNO3 and conc. H2SO4 mixture, theoretically,

w

26. The sum of oxidation states of all the ten N atoms in the following compounds of

nitrogen is N3 H , NH 2OH , NH 2 NH 2 , N 2O , N 2O4

27. The sum of stereo isomers of complex A, complex B and complex C in the

following sequence of reactions is

3 2NH3 NH 3 Br

CoCl6

2Cl

A complex

Cl

Bcomplex

Cl

C complex

Page 10

28. The number of minerals in which ‘Ca’ is present

1. Aragonite 2. Calcite 3. Fluorospar

4. Dolomite 5. Brucite 6. Fluoro apatite

SECTION – II

(MULTIPLE CORRECT ANSWER TYPE)

This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,

out of which ONE OR MORE than ONE option can be correct.

Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.

29. 0.56 gm CaO is dissolved in 100 ml of water and a solution is prepared

et

k w

13

10 . The correct statements are

.n

A) Concentration of OH 0.2 M

ha

B) Conc. H would be = 51013 M

C) Degree of dissociation of water in the solution 91015

tib

D) If 1.12 gm of CaO added to 100 ml at same temperature then conc. OH is

= 0.4 M ra

30. 0.1 M solution of KI reacts with excess of H 2SO 4 and KIO3 solutions, according to

up

equation 5I IO3 6H 3I 2 3H 2O; which of the following statement(s) is/are

correct

ad

B) 100 ml of the KI solution reacts with 0.006 mole of H 2SO 4

en

Molecular weight

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5

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31. Choose the conclusions which are apropriate for the observations

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w

Observation Conclusion

A) z = 1(at all ‘p’) i) The gas need not be showing the ideal behaviour

B) z > 1 ii) on applying pressure the gas will respond by increasing

volume

C) z < 1 iii) The gas has the ability to get liquified

D) z 1 (for low ‘p’) iv) The gas is approaching ideal behaviour

Page 11

32. Major product (Y) PhCH

Br O Ph CH 2 Br major product (X)

2

CF3 CH 2 OH DMF

A) ‘X’ is O-alkylated product and Y is C-alkylated product

B) Both X and Y are C-alkylated products only

C) Mixture of X and Y can be separated by dil NaOH

D) Product ‘Y’ can react with sodium metal

et

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33. Chose the correct statements

ha

A) C-Cl bond of chloroethene is stronger than in chloroethane.

tib

B) C=C double bond in ethene is shorter than the same in CH2=CH-OCH3

ra

C) CH3SH is weaker acid than CH3OH

up

D) CH3CH2NH2 is stronger base than CH2=CH-NH2

ad

34. The correct combinations of names for isomeric alcohols with molecular formula

en

C4H10O is/are

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O

|| AlCl3

+ CCl

(excess)

35.

Mixture of products are formed in the above reaction, which of the following

products are expected.

Page 12

O

A) B)

O

CO

CH3

et

C) D)

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36. The planar Molecules/ions among the following

A) N SiH3 3 (N and its immediate atoms) B) KIF4

ha

C) KXeF5 D) BF3

tib

37. Which of the following reactions does not produce ammonia?

ra Zn dust

A) NH 4 NO3 KOH aq. B) NaNO3 KOH

C) AlN dil.HCl D) NH 4 NO2 s

up

white P4 NaOH aq ? ?

ad

en

B) It is a disproportion reaction

C) One of the products is NaH 2 PO3

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SECTION - III

w

This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and four statements (P, Q, R and

w

S) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. For

example, if for a given question, statement B matches with the statements given in Q and R, then for the particular question darken the

w

bubbles corresponding to Q and R in the OMR sheet. For each correct matching will be awarded +2 marks ONLY and 0 if not

attempted and -1 in all other cases.

A) NaCl P) Body diagonal length is 2r 2r

B) CsCl Q) Coordination no of cation is 8

C) ZnS R) Alternate tetrahedrals are filled

D) CaF2 S) No. of formula units per unit cell is 4

T) Diamond follows the similar arrangement of particles

Page 13

40. Properties of major product formed in List – I is given in List – II.

Match the following List – I with List – II

List – I List – II

OH

NH2

A) P) Product has atleast two enolisable

NaNO 2 HCl

major product hydrogens

OH

NH2

et

B) Q) Product can react with CH 3MgBr

NaNO 2 HCl

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major product and forms 20 alcohol

OH

ha

tib

NH2

C) ra R) Product can give positive tollen’s test

NaNO2 HCl

major product

up

OH

ad

NH2

D) S) Product can give 20 alcohol when

NaNO 2 HCl

major product treated with LiAlH 4

en

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Page 14

MATHS Max Marks : 88

SECTION – I

(INTEGER ANSWER TYPE )

This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).

Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.

41. The number of ordered pairs x, y where x, y 0,10 satisfy us

1

sin 2 x sin x

2

2 1 is 2K where K

sec2 y

x4

et

42. Let f : R R defined as f x 8 . Also let and be

x 2 x 6 4 x 4 8 x 2 16

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maximum and minimum values respectively of f x . Then 12 ______

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43. The normals of parabola y 2 4 x drawn at the end points of its latus rectum are

2 2

tib

tangents to x 3 y 2 a 2 . Then the value of a 2

ra

such that r b c b and r .a 0 then r .b

up

a b

45. Let R A : a , b, c {0,1,2,3,4} be set of 2 2 matrices.

ad

c a

Then number of A in R such that A is either symmetric or skew-symmetric or

en

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4

1

x 4 1 x A B A 2B

46. 0 1 x 2 dx C C 3 __________ ( where A, B & C are natural

w

w

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47. Of the three independent events A, B and C the chance that only A occurs is e 1;

the chance that only B occurs is e2; the chance that only C occurs is e3. The chance

that none of them occurs is and satisfies e1 2e2 e1e2 and

P occurenceof A

___________

P occurenceof C

Page 15

a 2 b2 c 2 2abc 3 ______

SECTION – II

(MULTIPLE CORRECT ANSWER TYPE)

This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,

out of which ONE OR MORE than ONE option can be correct.

Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.

et

x 1 y 2 z 1

L1 :

.n

3 1 2

ha

x 2 y 2 z 3

L2 : then

1 2 3

tib

i 7 j 5k

A) Unit vector perpendicular to both L1 & L2 is

ra 5 3

17 2

B) Shortest distance between L1 & L2 is

3

up

17

C) Shortest distance between L1 & L2 is

5 3

ad

1 2 2

50. Let the complex numbers and lie on circle x x0 y y0 r 2 and

en

2 2 2

x x0 y y0 4r 2 respectively. If z0 x0 iy0 satisfies 2 z0 r 2 2 then

.e

is smaller than

1 1 1

w

A) 1 B) C) D)

2 3 10

w

w

tangent to H and S at P intersects the x-axis at point Q. If ,r is centroid of

PQC then the correct expression (s) among the following is ( are) _________

d 1 dr

A) 1 2 : 1 B) : 1

d 3 d 3 2 1

d 1 dr 1

C) 1 2 : 1 D) : 0

d 3 d 3

52. Let A and B be two 3 3 non-zero matrices such that AB BA . Further if A B 2

and A2 B 4 O (Where O is null matrix )then

Page 16

A) determinant of A2 AB 2 0

B) there is a 3 3 non-zero matrix C such that A2 AB 2 C is zero matrix

C) determinant of A2 AB 2 1

D) For a 3 3 matrix C if A2 AB 2 C equals the zero matrix then C is zero

matrix

53. Natural numbers are divided into groups as follows

S1 1 , S2 2,3 , S3 4,5,6 , S4 7,8,9,10.......... and so on..

A) Last number in S50 is 1275

B) First number in S100 is 4951

et

C) Sum of numbers in S70 is 7500

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D) Sum of middle two numbers in S80 is 4000

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54. Which of the following statement (s) is (are) incorrect ?

A) Common tangent to y 2 28 x and x 2 28 y 0 can’t be x y 7 0

tib

B) Angle between y 2 4 x and xy 32 is / 2

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C) Normals drawn at ends of latus rectum of y 2 8 x meet on y 2 0

up

2

D) A parabola y 2 4 x and a circle x 1 y 2 3 cut in 4 points

ad

3 3 3 3

en

A) a B) a 3 C) 3 a 5 D) 0 a

3 3

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correct ?

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5

coordinate axes is tan units

12

5

C) Maximum distance from centre on any normal is cos units

12

D) area is 2 3 sq units

57. Let f : 0, 0,1 be a differentiable function such that f 0 0, f 1, then

2 2

Page 17

2

A) f 1 f for all 0,

2

2

B) f for all 0,

2

1

C) f f for at least one 0,

2

8

D) f 2 for at least one 0,

2

x

e

58. Let f x and g x f ' x then

1 x2

et

A) g x has four points of local extremum

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B) g x has two points of local extremum

C) g x has a point of local minimum at x=1

ha

D) g x has a point of local maximum at some x 1,0

tib

SECTION - III

(MATRIX MATCHING ANSWER TYPE)

This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and four statements (P, Q, R and

ra

S) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. For

example, if for a given question, statement B matches with the statements given in Q and R, then for the particular question darken the

bubbles corresponding to Q and R in the OMR sheet. For each correct matching will be awarded +2 marks ONLY and 0 if not

up

attempted and -1 in all other cases.

ad

Column – I Column – II

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integer coefficients) of degree 2 satisfying p 0 0 and

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p x dx 1 is ________

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0

B The number of points is the interval 13, 13 at which Q) 6

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w

_____

C /2 R) 1

s in x

0

cos x

sin x

cos x cot x ln sin x dx ___

1 1 1

_________

a b c

Page 18

Column – I Column – II

A) c P) 1

The normal at ct1 , to the curve xy c 2 meets it

t1

c

again at ct2 , c, t1 , t2 0 then t13 t21 ______

t2

B) Maximum distance from centre of ellipse Q) 0

3x 2 4 y 2 12 from any of its normals is ________

C) Number of solution pairs x, y for the equations R) 3

et

x y 1 and sin x sin y sin x y is __________

.n

D) A variable plane makes with 3-dimensional co-ordinate S) 6

axes, a tetrahedron of constant volume 64k 3 . Then

ha

locus of centroid of this tetrahedron is xyz 2 k 3

where _

tib

ra

up

ad

en

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Page 19

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