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TM

JEE-MAIN TEST DATE


TARGET : JEE 2013 28 - 03 - 2013
Path to success KOTA (RAJASTHAN)
Kota | Chandigarh | Ahmedabad

FULL SYLLABUS
ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Ans. 2 2 4 1 2 3 1 3 2 1 2 2 1 3 4 4 3 1 3 2
Que. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

Ans. 2 1 4 2 4 3 2 2 1 1 3 4 4 4 2 3 1 4 2 4
Que. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Ans. 2 4 2 2 2 4 4 3 2 1 2 2 2 4 2 4 1 2 4 2
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

Ans. 2 3 1 4 1 2 3 1 4 1 3 2 1 2 4 4 4 1 1 1
Que. 81 82 83 84 85 86 87 88 89 90

Ans. 3 3 3 4 2 1 4 4 3 3

HINT – SHEET

1. µ = µ1 + µ2 T2 T2
3.  = 1 – T ; for  to be max. ratio T should be
P(2V) PV PV 1 1

RT1 = RT1 + RT2 min.


NB
2P P '  T2  T1  NA B
 RT = R  T T  A
 1 2 
mg

1
mg
cos

4.
2PT2

2  1  600 4 mg 
P' = (T  T ) = = atm
1 2 (300  600) 3
mv2
k mgcos – NA =
2. VP3 = constant = k  P = 1/ 3 R
V
mv2
k NA = mgcos –
Also PV = µRT  1/ 3 . V = µRT R
V
mv2
2/3
T1 mg – NB =
µRT  V1  R
 V2/3 = Hence   = T
k  V2  2 mv2
NB = mg –
2/3 R
 V  T
  = T  T2 = 9 T NB > NA
 27V  2

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MAJOR TEST

LEADER & ENTHUSIAST COURSE 28–03–2013


5. On platform 22. As we know current density J = nqv
2T – N – 40g = 40 × 2 ...(1)  Je = neqve and Jh = nhqv h
On man
Je n e ve 3 / 4 ne 5 ne 6
T + N – 60g = 60 × 2 ...(2)  J n n  1/ 4  n  2  n  5
Solving (1) & (2) h h h h h

T = 400N 23. Adiabatic expansion produces cooling.


6. m(vf – vi ) 25. Process CD is isochoric as volume is constant,

2 0   2g  5   process DA is isothermal as temperature con-
stant and process AB is isobaric as pressure is
= 20 N-s
constant.
v v 26. M1 = M
7.  ,   v
t1 t2   M a 2 M
t1 + t2 = t M2   
a2 16 16
t
v v t1 t2 M X  M2 X 2
 t X cm  1 1
  M1  M 2
t M a
v MO 
 16 4
X cm 
M
M
t 16
v
 a
X cm 
18. x = t(µ – 1) 64  
x1 = t(1.5 – 1) = 0.5t I 1 V
x2 = 2t(4/3 – 1) = 2t × 1/3 = t/3 = 0.33t 29. m=    u = 2v
0 2 u
x1 > x2 2cm
Distance = u + v = 45
Shifts in +y axis direction 25cm
2v + v = 45 –20cm
R –1cm
v = 15 cm
19. f' =
4  2 Position of lens x = +10 cm
30. Number of photoelectrons emitted up to
30
= t = 10 sec are
4  1.5  2
(Number of photons per unit area per unit time) × (Area × Time)
= 7.5 cm n
106
Concave mirror
1
u = 2f' = 2 × 7.5 = 15 cm  [(10)16  (5  104 )  (10)]  5  107
A•B
106
20. A Y = A • B  B• C At time t = 10s
B = A•B•B•C Charge on plate A = qA = + ne
= A•B•C = 5 × 107 × 1.6 × 10–19
C B•C = 8 × 10–12C = 8pC
n 7 n
and charge on plate B; qs = 33.7 – 8 = 25.7 pc
N 1 1 1 1 Electric field batween the plates
21.        n 7
N0  2  128  2   2 
(q B  q A )
E
After 7 half lives intensity emitted will be safe 20 A
 Total time taken = 7 × 2 = 14 hrs.
(25.7  8)  1012 N
= 12 4
 2  103
2  8.85  10  5  10 C

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JEE-MAIN 2013 28–03–2013


7 6 5 4 3 2 1
31. n=4 48. CH3 – CH = CH – CH 2 – CH – CH2 – COOH

n=3 NH2
(Pasheen)
I. region 3-Aminohept-5-enoic acid
n=2 Balmer 49. Basic strength order
(Visible)
n = 1 Lyman CH3O NH2 NH2
series
(U.V. region) +M

33. 
X(g)  2Y(g) NH 2 NO2 NH2
a
a–a 2a NO2
–I –M
MTh. 100 1
1   1   = 50.
Mobs. 75 3
4 2P T CH3  CH3
KP = =1 C2H5O Na
(1  2 ) CH3–C–CH2–Cl CH3–C–CH2–O–CH2–CH3
C2H5OH
34. Ag2 CrO4    2Ag+ + CrO4–2 CH3 CH3
In water 2s1 s1 2
Reaction followed by SN Path.
Ksp = (2s1) s1  s1 = 1.31 × 10–4
2
51.
In 0.1 M 0.1 s2 CH3
AgNO3 Ksp = (0.1) s2  s2 = 9 × 10–10
2
O3
CH3=C–CH=CH2 2CH 2=O + CH 3–C–CHO
In 0.1 M 2s3 0.1 Zn + H2O
O
Na2 CrO4 Ksp = (2s3 ) (0.1) s3 = 1.5 × 10–5.5
2
52. CH3–C– and CH3–CH– group containing
so order s2 < s3 < s1 .
O OH
35. N2H4 ( )  N2H 4(g) H = 18 kJ
compound gives iodoform test
2NH3(g) N2H4() + H2(g) H = 142 kJ 55. Ksp = [Cu+2][OH¯]2
 PH = 14  POH = 0
2NH3(g) N2H4(g) + H2(g) rH = 160 kJ  (OH¯) = 1 M
1N–N  1.0 × 10–19 = [Cu+2] [1]2
+ [Cu+2] = 10–19 M
160 = 2(3N – H) – 4 N – H
+ 0.0591
1H–H Ered = Eºred + log [Cu+2]
160 = 2 (N – H) – 1 (N – N) – 1 (H – H) 2
160 = 2 (393) – (N – N) – 436 0.0591
= 0.34 + log 10–19
EN–N = 190 kJ 2
= – 0.221 volt
37. BaCl2 + H2SO4  BaSO4 + 2HCl
0.5 mol 1 mol OH
C2H5MgBr H2SO4, 
0 0.5 mol 0.5 mol 60. C2H5–C–C2H5 C 2H 5–C–C2H 5 –H2O
H2O
38. PS = PB0 X B  PT0 X T O CH2 –CH3

 2   2 
= 120     80 
 2  2 
C 2H 5 – C – C 2H5
2  2
CH–CH3
= 100
O3 / Zn+H2O
0
P XT
T 40
X'T =   0.4 CH3–CH2–C–CH2–CH3 + CH3–CH = O
PS 100
O
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LEADER & ENTHUSIAST COURSE 28–03–2013


61. 10 100 = 2 100 , 5 100 66.
37 36
3 = 3.3 = 3.(81) = 3(80 + 1)
9 9

For divisor which are divisibly by 1090 = 290 , 9 9 9 8 9 1 9


= 3( C080 + C1.80 + ....... + C8 . 80 + C9)
5 90 atleast 90 two's and 90 five's are to be So required remainder is 3.
compulsory. 67. Since d1 = d2 = d3 = 0  D1 = D2 = D3 = 0
So 210 , 5 10 So for non-zero solution
(10 + 1) (10 + 1) = 121
a3 (a  1)3 (a  2)3
62. f'(x) > 0  xR
So function f|x| is increasing in whole domain a a 1 a2 0
R and 1 1 1
–
x f(x) < 0 
1 1 1
x   f(x) > 0
=  a a 1 a  2  0  a = –1
so exactly one real root lie in (–, )
a3 (a  1) 3
(a  2)3
6 62
63. P1 =
12    
68. .  |  ||  | cos
4
5 6
P2 = 1
11 2a  3 2b  4c  I.6.
2
P1 a + b + 2 2 C = I.3
1
P2  LHS is integer if c = 0

then   aiˆ  bjˆ which lies in xy plane

n 2 69. Since a, b, c are the roots of the equation
64. r
r 0
 S 1 + r + r +..... = S
x3 – 3x2 + x +  = 0
 a+b+c=3  a+b=3–c
1 S 1 Now area of the triangle will be
  S r =
1 r S 1 1 1 1
A  1  
 2 ab 2(a  b) 2(3  c)
2n
Now r  1  r 2  r 4  ....
r 0 dA 1
  0
dc 2(3  c) 2
1 1 S2 As A is an increasing function & c  [1,2]
=  
1  r2  S  1
2
2S  1 1
1   Amax = sq. units.
 S  2
70. Locus of variable point 'P' is a parabola with
65. Let the number are a & b.
given line as directrix and given point as focus.
Then a, A1, A2, b are in A.P. A1 + A2 = a + b Vertex is the mid point of S and foot of
a, G1, G2, b are in GP  G1G2 = ab perpendicular 'N'.
a, H1, H2, b are in HP
(3i+4j+2k)

1 1 1 1 H1  H 2 a  b
 H  H  a  b  H H  ab
1 2 1 2
N V S(4,5,8)

H1  H 2 A1  A 2
  (–1,2,7)
H1 H 2 G1G 2
Let N be (–1 + 3,2+4, 7+2)
G1G 2 A1  A 2 
 H H  H H SN  (5  3)iˆ  (3  4) ˆj  (1  2)kˆ
1 2 1 2 
SN.(3iˆ  4ˆj  2k)
ˆ  0   1
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MAJOR TEST

JEE-MAIN 2013 28–03–2013


N  (2,6,9)
dy (x  1)2  y  3 y3
 11 17  74.   (x  1) 
 V   3, ,  dx x 1 x 1
 2 2
2 2 dy dY
 2x  3y  5   3x  2y  1  Putting x + 1 = X, y – 3 = Y, 
    dx dX
71.  13   13  1
the equation becomes
4 1
dY Y dY 1
x2 y2 X or  .Y = X [L.D.E.]
which is equivalent ot   1 with a = 2, dX X dX X
a 2 b2
b=1 1
I.F. = e 
( 1/ X) dX
 Area of ellipse = .2.1 = 2 = e–log X =
X
72. Let P(h, k) be the point from which two tangents
are drawn to y 2 = 4x. Any tangent to the  the solution is
parabola y2 = 4x is
 
1 Y.   c   X   dx  c  X
y  mx  X X
m
If it passes through P(h, k), then
1  y  3)
or  c  x 1
k = mh +  m2 h – mk + 1 = 0 (x  1)
m
Let m1, m2 be the roots of this equation. Then,
0 3
k 1 x = 2, y = 0   c  2 1
m 1 + m 2= and m1m2 = 2 1
h h  c = –4
k 1  the quation of the curve is
 3m 2 = and 2m 2 2 = [ m 1 =
h h
2m2(given)] y 3
 x  3 or y = x2 – 2x.
2
x 1
 k 1
 2     2k 2  9h 78. USE DL
 3h  h
a a
Hence, P(h, k) lies on 2y2 = 9x L = a (1 + na) and M = a

1 + na = 2
x tan x
73. I=  sec x  cosx dx a=e
0
f(  h)  f(0) h  1  1

(   x) tan(  x) 79. LHD = lim = lim =1
h 0 h h 0 h
 I=  dx
0
sec(   x)  cos(   x)
f(h)  f(0) cosh  1

(  x) tan x RHD = lim = lim =0
 I=  dx h 0 h h 0 h
0
sec x  cos x
Not differentiable but continuous.
 /2
tan x dx tan x dx
 2I =    2 
0
sec x  cos x 0
sec x  tan x
(-6,10)
80.
/2 B 10
sin x 4
 I=  
0
1  cos2 x
dx –5 P(2,5) BP'=17

0 –6 A 2
dt 1 1 2
 I =    [tan t]0  p'(2,–5)
1
1  t2 4

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MAJOR TEST

LEADER & ENTHUSIAST COURSE 28–03–2013


88. Statement-2 is clearly true.
Z1  2Z 2   
85. 1 Since OM  OD  d
2  Z1 Z 2
Now points A, B, C and M are coplanar
 Z1  2Z 2   Z1  2Z 2          
 [a b c]  [m a b]  [m b c] [m c a]
so  2  Z Z   2  Z Z   1
 1 2  1 2       
= [ d a b]  [ d b c] [ d c a]
|Z1|2 2(Z1 Z 2  Z1 Z 2 ) + 4|Z2|2   
[a b c]
          
= 4 – 2 (Z1 Z 2  Z1 Z 2 ) + |Z1|2 |Z2|2 [d a b]  [d b c] [d c a]
|Z1|2 (1 – |Z2|2) – 4 (1 – |Z2|2) = 0 and therefore Statement-1 is also true.
(1-|Z2|2) (|Z1|2 – 4) – 4) = 0 89. x2 + y2 = 1
 |Z2|  1 so |Z1| = 2 and (x – 1)2 + y2 = 1
86. ax + by = 0 are symmetrical about x-axis
cx + dy = 0 Solving these,
homogenesous system
It always have atleast one solution so St–2 is y
A
correct. y2
For unique solution x
O C D

a b B
= 0 x2+y2=1 (x–1)2+y2=1
c d
C is (1/2,0), also D is (1, 0).
1 0 0 1 1 1 1 1 0 1 1 0
, , , , ,  Required area
0 1 1 0 1 0 0 1 1 1 1 1

6
these are 6 possible probability = 4 
6 3

= 2 
0
1/ 2
1  (x  1)2 dx  
1

1/ 2 
1  x 2 dx
2 16 8
so St-1 is also true but St-2 is not a correct  2 3
explanation of St-1. =  3  2  sq. units.
 
90. Statement-1 is correct statement-2 is false.

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