Chemistry 7th May Part Test PDF

PHYSICAL CHEMISTRY
TARGET : JEE (ADVANCED) 2017

 

INFORMA TIO
E EST
DPPDAILY PRACTICE PROBLEMS
Course : VIJETA & VIJAY (ADP & ADR) Date : 03.05.2017

NO. 7
TEST INFORMATION
DATE : 07.05.2017 CUMULATATIVE TEST(CT)–2
Syllabus : Organic : Aromatic, carbonyl compounds, carboxylic acids & Their derivatives, Grignard Reagent
Physical : Mole & Equivalent Concept, Ionic Equilibrium, Chemical Equilibrium & Electrochemistry, Gaseous
State, Solid State, Surface Chemistry, Thermodynamics & Thermochemistry, Atomic structure, Nuclear
chemistry, Chemical Kinetics & Solution Colligative Properties.
Inorganic : Inorganic Nomenclature, Periodic Table, Chemical Bonding & Coordination Compounds, s & p-
blocks, d & f-block elements
DPP Syllabus : Atomic Structure, Nuclear chemistry, Chemical Kinetics and Solution & Colligative Properties.
DPP No. # 7
Total Marks : 173 Max. Time : 120 min.
Single correct Objective ('–1' negative marking) Q.1 to Q.9 (3 marks, 2 min.) [27, 18]
One or more correct objective (no negative marking) Q.10 to Q.22 (4 marks, 2 min.) [52, 26]
Assertion and Reason ('–1' negative marking) Q.23 to Q.25 (3 marks, 3 min.) [09, 09]
Comprehension ('–1' negative marking) Q.26 to Q.32 (3 marks, 2 min.) [21, 14]
Integer type ('–1' negative marking) Q.33 to Q.42 (4 marks, 3 min.) [40, 30]
Match the Following (no negative marking) Q.43 to Q.45 (8 marks, 6 min.) [24, 18]
1. Two first order reaction have half-lives in the ratio 8:1.Calculate the ratio of time intervals t1 : t2. The time
th th
 1 3
t1 and t2 are the time period for  4  completion of 1st reaction and  4  completion of 2nd reaction
   
respectively.
(A) 1 : 0.301 (B) 0.125 : 0.602 (C) 1 : 0.62 (D) none of these
2. The reaction A(g) + 2B(g)C(g) is an elementary reaction. In an experiment involving this reaction, the
initial partial pressures of A and B are PA = 0.40 atm and PB =1.0 atm respectively. When pressure of C
becomes (PC) = 0.3 atm in the reaction the rate of the reaction relative to the initial rate is :
1 1 1
(A) 12 (B) 50 (C) 25 (D) none of these

3. Heptene decomposes according to following reaction, C7H14  2C2H4 + C3H6
–4 –1
Rate constant was found to be 1 × 10 sec . In what time (approximately) molar ratio of heptene to
ethene in the reaction mixture will attain the value 1? [log 2 = 0.3010, log 3 = 0.4771]
(A) 68 min (B) 4055 min (C) 1736 min (D) 228 min
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Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Page No. - 1
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4. Electromagnetic radiation of wavelength 242 nm is just sufficient to ionize sodium atom. Then ionisation
energy of sodium atom :
(A) 494.73 kJ/mol (B) 494. 73 kJ/atom (C) 637.2 kJ/mol (D) 637.2 kJ/atom
5. The angular momentum of an electron in a Bohr’s orbit of H-atom is 4.2178 × 10–34 kgm2/sec. Calculate
the wavelength of the spectral line emitted when electrons falls from this level to next lower level.
(A) 1.8 × 10–5 cm (B) 1.8 × 10–4 cm (C) 1.8 × 10–4 (D) 1.8 × 10–5 m
6. The uncertainity in speed of a moving atom of mass 200 amu is 100 m/s. What is the minimum
–24 –34
uncertainity in the measurement of its position? (1 amu = 1.6 × 10 g ; h = 6.4 × 10 J sec)
(A) 1.1 × 10–10 m (B) 1.59 × 10–12 m (C) 1.01 × 10–8 m (D) 1.53 × 10–6 m
7. A solution containing large amount of A and water is steam distilled. The condensate hence obtained
contained 0.25 mole fraction of A. The external pressure at which distillation is performed is (PW ° =740
torr and temperature is same.)
(A) 760 torr (B) 791.3 torr (C) 986.67 torr (D) 886.9 torr
8. What is the % decrease in vapor pressure with respect to solution when saturated solution of Ag3PO4
is prepared
3
 3  12
Given : Ksp of Ag3PO4 =  16   10 (Assume no hydrolysis)
 
(A) 6 × 10–4 (B) 1.5 × 10–4 (C) 9 × 10–4 (D) 18 × 10–4
9. The Henry’s law constant at T K for dissolution of a gas in aqueous medium is 3 × 104 atm. At what
5
partial pressure of the gas (in atm) at T K the molality of gas in aqueous solution will be ?
900
(A) 10–4 atm (B) 3 atm (C) 0.3 atm (D) 10 atm
10.* When the concentration of A is doubled, the rate for the reaction: 2A + B 2C quadruples. When the
concentration of B is doubled the rate remains the same. Which mechanism below is/are not consistent
with the experimental observations?
(A) Step I : 2A D (fast equilibrium)
Step II : B + D  E (slow)
Step III : E  2C (fast)
(B) Step I : A + B D (fast equilibrium)
Step II : A + D  2C (slow)
(C) Step I : A + B  D (slow)
Step II : A + D 2C (fast equilibrium)
(D) Step I : 2A  D (slow)
Step II : B + D  E (fast)
Step III : E  2C (fast)
st
11.* Consider the 1 order reactions :
k1 k k k
A  B ; 2A 
4
D ; B 
2
C ; D 
3
2C .
E1 E4 E2 E3
E1, E2, E3 and E4 are respective activation energies and k1, k2, k3 and k4 are respective rate constants.
Which of the following is/are correct ?
d[B] d[C]
(A)  k1[A]  k 2 [B] (B)  k 2 [B]  2k3 [D]
dt dt
k E  k 4E4
(C) Average activation energy of A  1 1 (D) None of these
k1  k 4
Page No. - 2
12.* The vapour pressure of two pure liquids X and Y which form an ideal solution are 200 and 300 mm of
Hg respectively at 300 K. A liquid solution of 'X' and 'Y' in which the mole fraction of 'X' is 0.5 is
contained in a cylinder closed by a piston on which pressure can be varied. Which of the following
is/are incorrect?
(A) Only if pressure above solution is less than 200 torr, vapour phase can exist.
(B) Only if pressure above solution is less than 300 torr, vapour phase can exist.
(C) Only if pressure above solution is more than 200 torr, liquid phase exist.
(D) Only if pressure above solution is less than or equal to 250 torr, vapour phase can exist.
13. * Initial concentration of reaction for nth order reaction is 'a'. Which of the following relations is/are not
correct about t1/2 of the reaction?
(A) n t1/2 = n (constant) – (n – 1) logea (B) n t1/2 = n (constant) – n a
(C) t1/2 n n = n (constant) + n a0 (D) n t1/2 = n n a0
14.* For a certain reaction A  products, the t½ as a function of [A]0 is given as below :
[A]0 (M) : 0.1 0.025
t½ (min.) : 100 50
Which of the following is/are true ?
1
(A) The order is . (B) t½ would be 100 10 min for [A]0 = 1 M
2
(C) The order is 1 (D) t½ would be 100 min for [A]0 = 1 M
15.* Element 'A' has principal quantum number 2 for last electron and it has 3 electron in valence shell and
element 'B' has principal quantum number 3 for last electron and it has seven electrons in the valence
shell. The atomic number of an element X is equal to sum of atomic numbers of A and B.
Which of the following statement is/are correct for X ?
(A) M shell contain 10 electrons
(B) Total number of electrons with l=1 are 12
(C) Total number of electrons with m=0 may be 14
(D) It can show back bonding in which d orbitals are involved.
16.* Which of the following do not represent ground state configuration of given element?
(A) Sc– [Ar] 3d34s0 (Z=21) (B) Si– [Ne] 3s23p2 (Z=14)
9 2 2 1
(C) Cu– [Ar] 3d 4s (Z=29) (D) La– [Xe] 6s 4f (Z=57)
17.* The magnetic moment of Xn+ is 24 BM. Hence, the species can be
2+ 2+ 2+ 3+
(A) Fe (B) Cr (C) Mn (D) Co
18.* Which one of the following statement is/are true?

(A) Raoult’s law states that the vapor pressure of a component over an ideal solution of two volatile
liquids is proportional to its mole fraction in solution.
(B) The osmotic pressure () of a solution is given by the equation  = iCRT (C = molarity of solution).
(C) The correct order of osmotic pressure for 0.01 M aqueous solution of each compound is
BaCl2 > KCl > HF.
(D) Two glucose solutions of same molality prepared in different solvents will have the same boiling
point elevation.
19.* A substance ‘A’ has the following variation of vapor pressure with temperature for its solid state and
liquid state. Identify the options which are correct :
2000 1500
Given for solid A : log10P = 4– ; For liquid A : log10P = 3.5 –
T T
where P is in mm of Hg and T in K
Page No. - 3
(A) Triple point temperature of substance 'A' is 1000 K
(B) Hsub will be approximately 9.212 Kcal/mol
(C) Hfusion will be approximately 9.212 Kcal/mol
(D) Hvap will be approximately 6.909 Kcal/mol
20.* An ideal binary liquid solution of A and B has a vapour pressure of 900 mm of Hg. It is distilled at
2
constant temperature till of the original amount is distilled. If the mole fraction of ‘A’ in the residue and
3
mole fraction of B in the condensate is 0.3 and 0.4 respectively and vapour pressure of residue is 860
mm of Hg, then which of the following is/are correct options :
(A) The initial mixture taken should be an equimolar mixture of A and B.
(B) The first vapors formed will have more moles of A as compared to moles of B.
(C) PA° = 1000 torr
(D) The vapor pressure above the condensate is 920 torr at same temperature.
21.* 10 ml of FeC2O4 solution requires 30 ml of 0.4 M KMnO4 solution in acidic medium for titration. 25 ml of
the same FeC2O4 solution is mixed in some water to make a solution containing 900 g of water. Which
of the following is/are true for this solution ?
(Kf for water = 1.8/K kg/mol)
(A) Freezing point of the solution is 0.2 K
(B) The RLVP of the solution is 2×10–3
(C) Osmotic pressure of the initial FeC2O4 solution is 49.2 atm at 300 K.
(D) Osmotic pressure of the initial KMnO4 solution (without acid) is 19.68 atm at 300 K.
22.*
0.1M urea and 0.1M NaCl aqueous solutions of same volume are separated by semi–permeable
membrane. Identify the true correct statement(s).
(A) No water flow across the membrane (B) Water will net flow from I to II
(C) Water will net flow from II to I (D) Both solutions will be isotonic in the end
23. Statement-1 : For zero order reaction (AB), successive half life of reaction decreases with the
progress of reaction.
Statement-2 : Rate of zero order reaction remains unchanged with the progress of reaction.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
24. Statement-1: The maximum degeneracy of an electron for which azimuthal quantum number is l is
(2l + 1).
Statement-2 : For a given value of l , the magnetic quantum number (m) can have any integral value in
the range of –  -------0--------+  .
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True
Page No. - 4
25. Statement-1 : At ice water equilibrium, on increasing the pressure freezing point of water
decreases.
Statement-2 : Ice have low density so equilibrium shift in forward direction when pressure is increased.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
Comprehension # 1
Definition valid for single electron System :
Z2 th
En =–13.6 2 eV/atom (Energy of electron in n orbit of hydrogen like species having atomic number Z)
n
(i) Ground state : Lowest energy state of any atom or ion is called ground state of the atom It is n = 1.
(ii) Excited State : States of atom other than the ground state are called excited states :
n=2 first excited state
n=3 second excited state
n=4 third excited state
n=n+1 nth excited state
(iii) Ionisation energy (E) : Minimum energy required to move an electron from ground state to
n =  is called ionisation energy of the atom or ion.
(iv) Excitation Energy : Energy required to move an electron from ground state of the atom to any other
state of the atom is called excitation energy of that state.
Excitation energy of 2nd state = excitation energy of 1st excited state = 1st excitation energy = E2 – E1
(v) Binding Energy ‘or’ Seperation Energy :
Energy required to move an electron from any state to n =  is called binding energy of that state.
Binding energy of ground state = .E. of atom or on. The third excitation energy of a hydrogen like
species is 204 eV.
26. Identify the hydrogen like species.

(A) He+ (B) Li2+ (C) Be3+ (D) B4+
27. What is the binding energy of efrom second state in the given species?
(A) 13.6 eV (B) 54.4 eV (C) 122.2 eV (D) 17 eV
28. If ionisation energy is 'a' eV then ionisation potential is 'a' V. Using this information, find the ionisation
potential of given species.
(A) 54.4 V (B) 217.6 V (C) 122.4 V (D) 13.6 V
Comprehension # 2
A definite volume of H2O2 undergoing decomposition required 22.8 mL of standard KMnO4 solution for
titration. After 10 and 20 min, the volumes of permanganate required were 13.8 and 8.25 mL,
respectively.
228 2280
Given ln  0.5 and ln  1.01
138 825
29. Find order of reaction.

(A) 1 (B) 2 (C) 3 (D) 3/2
30. Calculate the time (in. min) required for the decomposition to be half completed.
(A) 1.8 (B) 7.6 (C) 13.7 (D) 20.4
Page No. - 5
Comprehension # 3
Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when
solute molecules are added to get homogeneous solution. These are called colligative properties.
Application of colligative properties are very useful in day-to-day life. One of its example is the use of
ethylene glycol and water mixture as anti-freezing liquid in the radiator of automobiles
A solution M is prepared by mixing ethanol and water. The mole fraction of water in the mixture is 0.9
Given : Freezing point depression constant of water (Kfwater) = 1.86 K kg mol–1
Freezing point depression constant of ethanol (Kfethanol) = 2.0 K kg mol–1
Boiling point elevation constant of water (Kbwater) = 0.52 K kg mol–1
Boiling point elevation constant of ethanol (Kbethanol) = 1.2 K kg mol–1
Standard freezing point of water = 273 K
Standard freezing point of ethanol = 155.7 K
Standard boiling point of water = 373 K
Standard boiling point of ethanol = 351.5 K
Vapour pressure of pure water = 32.8 mm Hg
Vapour pressure of pure ethanol = 40 mm Hg
Molecular weight of water = 18 g mol–1
Molecular weight of ethanol = 46 g mol–1
In answering the following questions, consider the solution to be ideal dilute solutions and solutes to be
non-volatile and non-dissociative.
31. The freezing point of the solution M is

(A) 354.4 K (B) 261.52 K (C) 234.2 K (D) 150.9 K
32. The difference in the vapor pressure of solution M and N is :

(solution N is prepared by adding ethanol in water till mole fraction of ethanol becomes 0.9)
(A) 5.76 torr (B) 6.48 torr (C) 36 torr (D) 32 torr
33. Difference between nth and (n + 1)th Bohr’s radius of H-atom is equal to its (n–1)th Bohr’s radius. The
value of n is :
34. For zero order reaction A  3B plot of concentration vs time is as follows.
B
Conc.
0 2 4 6 8
t(min)
Find half life period in minutes if the initial concentration of A be 1 M.
12 139
35. Find the total number of alpha particles and neutrons emitted when C is bombarded on 57 La to
147
produce 63 Eu .(Assume no other particles are produced)
1
36. Calculate the maximum total number of electrons in Gallium, with spin + and which occupy orbitals
2
having minimum one radial node.
37. Consider the first order parallel reactions, starting with 1 M of A.

3k
A  B
2k
A   2C
k
A  3D
If [C] is x M, find 100 x.
Page No. - 6
58
38. Zn decays by two paths. By path (I), it produce daughter nuclide 'X' along with a positron and proton.
By path(II) it produce daughter nuclide 'Y' along with a positron. Find the sum of neutrons in X and Y.
39. The hydration of ethylene oxide (C2H4O) in aqueous solution proceeds with first order kinetics such that
ethylene glycol is formed. The kinetics of the equation is determined by measuring the change in
volume of the liquid system. The change in volume is noted by measurement of height at various
instants in a thin capillary tube. From the data, calculate the rate of disappearance of ethylene oxide at
an initial concentration of 22 g/L. Express answer in terms of M/day.
Time 0 3600 
Height (mm) 11 10 1
1
e
40. 20 g of naphthoic acid (C11H8O2) is dissolved in 50 g of benzene (Kf = 1.72 K kg mol–1). If the Van't Hoff
factor (i) of naphthoic acid is 0.5 then the value of depression in freezing point (in K) will be :
238 b 238
41. 92 U is bombarded with aX particle to produce 93 Np and two neutrons. The Np thus formed is
238
unstable and decays to produce 94 Pu along with a particle dc Y .
Find a + b + c + d
K1 K1
42. A reversible reaction which is Ist order in both direction A B. For which value of following
K2 K2
graph will be correct (where a is initial amount of reactant A)
43. Match the following :

En = total energy
th
n = angular momentum in n orbit
Kn = K.E. , Vn = P.E.
Tn = time period, rn = radius of nth orbit
Column () Column ()
1
(A) En–y  rn then y, for a given Z, is (p)
2
(B) n  nx then x is (q) – 2
En
(C) is (r) – 3
Vn
Zt
(D) Tn  , t and m respectively are (s) 1
nm
Page No. - 7
44. Match entries in column-I with those in column-II for a radioactive sample:
Column-I Column-II
(A) Activity of sample (p) varies with time
(B) Half life of sample (q) varies with temperature.
(C) Number of radioactive nuclei (r) is a constant for a given species at any time
and temperature
(D) Decay constant (s) its log vs time graph is a straight line
45. 1 mole of A is added in 1 kg water. Volume is nearly 1L. To this mixture , small amount of B is added
such that it act as limiting reagent. Match the effect of addition of B in Column I with entries in column II
Column-I Column-II
A B
(A) KCN + AgCN(s) (p) Boiling point increase
(B) CuS(s) + Conc. HNO3 (q) Freezing point does not increase
(C) CH3COOH + Ba(OH)2 (r) Osmotic pressure is unchanged
( < 0.1)
(D) HgI2 + KI (s) Vapor pressure decreases
ANSWER KEY
DPP NO. # 6
1. (B) 2. (A) 3. (C) 4. (C) 5. (C)
6. (C) 7. (C) 8. (A) 9. (C) 10. (B)
11. (ABCD) 12. (ACD) 13. (ABC) 14. (BC) 15. (AC)
16. (ABD) 17. (ABC) 18. (BC) 19. (ABD) 20. (BCD)
21. (BD) 22. (A) 23. (C) 24. (B) 25. (C)
26. (C) 27. (B) 28. (C) 29. (B) 30. (C)
31. (D) 32. (B) 33. 3 34. 4 35. 2
36. 6 37. 4 38. 3 39. 5 40. 3
41. 70
42. (A)  q, s; (B)  q, r, s ; (C)  p; (D)  q,s
43. (A)  q ; (B)  p ; (C)  s ; (D)  r
44. (A)  p, r, s; (B)  p, r, t ; (C)  q ; (D)  p, s
45. (A)  p,t ; (B)  q,r,s,t ; (C)  q,r,s ; (D)  s,t
Page No. - 8

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PHYSICAL CHEMISTRY

TARGET : JEE (ADVANCED) 2017

Course : VIJETA & VIJAY (ADP & ADR) Date : 03.05.2017

18.* Which one of the following statement is/are true?

26. Identify the hydrogen like species.

29. Find order of reaction.

31. The freezing point of the solution M is

32. The difference in the vapor pressure of solution M and N is :

34. For zero order reaction A  3B plot of concentration vs time is as follows.

37. Consider the first order parallel reactions, starting with 1 M of A.

43. Match the following :

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