SOLUTION A SOLUTION B TRIAL (sec)

Test Solution Water (mL) 0.3M KI (mL) Starch (mL) 0.02M Na2S2O3 (mL) 0.1M K2S2O8 (mL) 1
1 138 20 2 10 30 629.23
2 138 20 2 10 30 394.46
3 138 20 2 10 30 136.43
4 138 20 2 10 30 72.94
5 138 20 2 10 30 54.73

k vs Temperature
0.025

0.02

0.015
k (M-1·s-1)

0.01

0.005

0
290 295 300 305 310 315 320 325 330 335 340
Temperature (K)
TRIAL (sec) Initial Concentration
2 AVERAGE TEMPERATURE (K) 1/T K2S2O8 (M) KI (M) Rate (Molar I2/s)
736.6 682.915 293.15 0.003411223 0.03 0.015 7.32155539123E-07
381.55 388.005 299.15 0.003342805 0.03 0.015 1.28864318759E-06
154.54 145.485 313.15 0.003193358 0.03 0.015 3.4367804241E-06
88.24 80.59 323.15 0.003094538 0.03 0.015 6.20424370269E-06
56.04 55.385 333.15 0.003001651 0.03 0.015 9.02771508531E-06

ln (k) vs 1/T
0
0.0029 0.003 0.0031 0.0032 0.0033 0.0034 0.0035
-1
-2
-3
ln (k)

-4 f(x) = - 6184.7188682443x + 14.77613098

-5
-6
-7
1/T
k (M-1·s-1) ln(k) Ea (J/mol)
0.0016270123 -6.4210099 51422.6882
0.0028636515 -5.8556577
0.0076372898 -4.8747125
0.0137872082 -4.2840141
0.0200615891 -3.9089483