Professional Documents
Culture Documents
MATERIAL
Alec N. Tobias
Researcher
1
ABSTRACT
The study aims to find another use of Milkfish locally known as “Bangus”
(Chanoschanos) scales were regarded as waste materials which produced unpleasant odors
and clogged canals. Scales of this fish is abundant in Navotas City (Fishing Capital),
Philippines.
Hence, it gives the idea to come up this project and thought that these fish scales can
be used as a raw material in making fish scale mold as an alternative instructional tool.
As the results of study, gives a clear indication that the fish scales can be used as an
additive for resin products to make it unique, attractive, harder and durable.
Also, the by-products or samples toys were submitted for extractable lead (Pb) test at
Department of Science and Technology, Industrial Technology Development Institute
Standards and Testing Division. The products passed the lead standard requirement of 90
mg/kg.
A successful study of this research would reduce the waste materials in the market
that causes unpleasant smell and clogged canals, its most important feature is its usefulness
as an instructional material and it could be a source of income for Navoteños.
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Table of Contents
Title Page 1
Abstract 2
Table of Contents 3
Acknowledgement 4
Introduction and Background of the Study 5-8
Statement of the problem
Significance or purposes of the study
Definition of terms Scope and limitations
Review of literature on the areas relevant to the study
Research Method and Process 9 - 15
Survey
Collection
Soaking and Drying
Boiling, Grinding and Drying
Pounding and Pulverizing
Silicon Mold Making
Mixing of Formulations
Casting
Physical Performance Test
Water Absorption
Compressive Strength
Flame Resistance
Freezing Resistance
Extractable Lead (Pb) Testing
Computation of Expenses and Market Value
Test for Effectiveness and Usefulness of the Material
Results and Findings 16 - 22
Conclusions & Recommendation 23
References 24
Appendices 25 – 38
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ACKNOWLEDGEMENTS
H. Bion (Division Chief), and Ms. Sonia A. Jalandoon (OIC Chemistry Laboratory) for
testing the chemical content of the pulverized Milkfish scales and to Mr. Elyson Keith P.
Encarnacion OIC, Inorganic Chemistry Section and Rosario T. Fuertes, MSc, RCh, for testing
the Extractable Lead (Pb) of fish mold under the Industrial Technology Development Institute
making resin figurines and helped me to complete my project, thank you very much.
To the fish vendors in San Roque Market and Malabon Market who willingly gave us
the fish scales which are the main concern of this project, I give my greatest thanks to you.
for this opportunity and always there to guide me. To all my teachers and our beloved
principal Dr. Maria Cristina A. Robles for the moral support. Thank you so much.
4
Introduction
Navotas is known as the Fishing Capital of the Philippines. Locals heavily rely on seawater
and the city has been developed into a Marine Industrial Estate. One of the most abundant
product brought and caught is Milkfish, Chanos chanos, locally known as “bangus” or
“bangos”.
This study aims to give usefulness to Milkfish scales since they are regarded as wastes
that produce unpleasant odors and may end up clogging canals.
We wanted to use milkfish scale as an additive to resin, that can create different shapes
as an alternative instructional tool, and to be used in Kindergarten pupils to enhance the
learning skills and improve its competency in science or mathematics.
A great impact of the study is the production of the instructional materials that can be
used for education and business which may end up reducing the waste present in our
environment.
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Significance of the Study
The product intents to promote a concern for health. In a sense of decreasing the pollutants
that are present in our environment. If fish scales aren’t disposed properly they produce
unpleasant odors. It takes years for the scales to decompose and in due time these may become
a contributor in clogging of canals.
We have made these in forms of different shapes that have been used for educational
purposes. These interactive molds were given to children in the kindergarten and were used
in the teacher’s lesson, it proved to be effective and fun.
Not only does it lessen waste but can also be a source of income. A cheaper alternative to
pure resin figures. They are manipulative and can be molded into different shapes.
It aims to innovate the use of fish scales that are thrown away or pollutes the economy’s
environment. To make use of them and create a material both durable and useful.
Definition of Terms
Resin - a sticky flammable organic substance, insoluble in water, exuded by some trees and
other plants (notably fir and pine). Compare with gum.
Synthetic - (of a substance) made by chemical synthesis, especially to imitate a natural product
Viscous - having a thick, sticky consistency between solid and liquid; having a high viscosity
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Scope and Limitation
In this research, the researcher used the scales of Milkfish locally known as Bangus
(Chanoschanos) as an additive in resin. No other part of the said fish was used in this study.
This research was focused only on how this fish scales can be used as an additive in making
resin figurines and to produce alternative instructional materials, other things, results, and
effects which are produced and came up on the researcher research were not given much
attention and significance.
Modern figurines, particularly those made of plastic are often referred to as figures.
Sometime a plastic called Polyvinyl chloride is used with figures often referred to as a PVC
figure and sometimes if it's a collection a PVC set. They can encompass modern action figures
and other model figures as well as Precious Moments, Mr. Stubbs and Hummel figurines,
Bobbleheads and all kinds of memorabilia. Two companies which produce figurines are
Royal Doulton and Lladró. (The Chinese Neolithic: Trajectories to Early States, 2004,
Cambridge University Press, 328 pages by Li Liu)
Resin is a natural or synthetic compound which begins in a highly viscous state and
hardens with treatment. Typically, resin is soluble in alcohol, but not in water. There are a
number of different classes of resin, depending on exact chemical composition and potential
uses. There are numerous applications for resins, ranging from art to polymer production, and
many consumers interact with products which contain resin on a daily basis.
Natural resin comes from plants. A classic example is pine sap, which has the
characteristic sharp odor of terpene compounds. Substance is very viscous but hardens
overtime.
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Plant resin can be clear to dark brown in color, and it varies in opacity and hardness.
Some plant resin is also extremely volatile, since it contains unstable compounds.
For the most part, polymers made with “resins” are actually made with synthetic resin,
which is cheaper and easier to refine. Synthetic resin is much more stable, predictable, and
uniform
Most resin figurines are small, lightweight and detailed sculptures in sizes ranging
from 5 to 8 inches in height and weighing between 1 to 4 lbs. However, different types of
resin sculptures which are much larger and come with their own display stands. (By Tatyana
Ivanov, eHow Contributor)
The study was conducted for the intention to promote a concern for health. In a sense
of decreasing the pollutants that are present in our environment.
This research aims to innovate the use of fish scales that are thrown away or pollutes
the environment. To make use of them and create a material both durable and useful. To create
colorful and durable shapes for pupils to use and enhance their basic skills.
The number of respondents that were involved were 10 vendors. These respondents
were the ones who sell fish, specifically milkfish and resides in either the marketplaces of
Navotas or Malabon. The researcher chose to retrieve 10 respondents because it felt that the
said number is big enough and that it was the number that was manageable at the given time
frame. A series of questions regarding their knowledge about wasted fish scales were asked
in the survey and was required to be answered by all respondents that would participate,
although the inclusion of their names was optional.
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The results of the survey were analyzed through using different graphs attained from
the results of the survey. It provided the researcher to easily show the behavior of the results.
Ø Fish scales
Ø Resin
Ø Lime
Ø Sodium Hypochlorite
Ø Silicon
Ø Blender
I. Survey
1. How many fishes are you able to sell in a day?
2. How long does it take until every fish has been sold?
3. How many of these fish’s scales, do you think are being wasted?
4. Where are these fish’s scales being thrown out?
5. Who collects these thrashes?
6. Who is the person responsible for taking the trash out?
II. Procedures
1. Collecting of milkfish scale from the market
Fish used in the study is milkfish (Chanoschanos). Fish scales were gathered at Tres,
and Tangos marketplace in Navotas City and Bayan marketplace in Malabon City.
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2. Washing the fish scale with running water
Milkfish scales were washed with tap water until the scales are thoroughly clean.
3. Soaking
Create a mixture consisting of water, lime (apog), and sodium hypochlorite. The scales
were soaked for 3 hours. This makes the scales turn white.
4. Drying
Fish scales were air-dried for three days to prevent them from deteriorating before the
process begins.
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5. Boiling, Grinding, and Drying
The fish scales were boiled for an hour at 100 . After boiling the scales were blended
and chopped into fine pieces. Let it dry until crisp.
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8. Mixing of Formulations
Combine the pulverized fish scales and polyester resin. Stir and make mixture even.
(50g pulverized scales: 50g polyester resin + 2ml catalyst) Add toner to colorize the
shapes
9. Casting
Pour the mixture into the silicon mold. Let it dry for about 30 minutes or until product
hardens.
III. Testing
Sample Tiles
Pure resin, consists of 100% resin
Formulation one, consists of 50% resin and 50% pulverized scales
Formulation two, consists of 40% resin and 60% pulverized scales
Formulation three, consist of 30% resin and 70% pulverized scales
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A. Test for Water Absorption
The four sample tiles were soaked in 300 grams of water for three hours.
13
D. Test for Freezing Resistance
The four sample tiles were positioned in a freezer for three hours.
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Results and Findings
Survey
kilograms
per day.
15
Table 1: Thickness, length and width and volume of samples with different formulation
Same data were used to compare the different tests done to the different formulation
of the samples.
Pure resin 0%
The samples were soaked in 300 grams of water for 3 hours. The data shows that all of
the formulations did not absorb water.
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Table 3: Compressive Strength
The compressive strength of the different formulation was compared to the pure resin. The data
shows that results are almost the same with one another.
Formulation Porosity %
Pure resin 0%
After soaking the samples in 300 grams of water for 3 hours, the volume of the all the
samples did not change.
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Table 5: Flame Resistance
Formulation Changes
50% Pulverized fish scale + 50% resin released an odor same with frying a
Milkfish and it did not burn easily,
little portion of the sample was
damaged
60% Pulverized fish scale + 40% resin released an odor same with frying a
Milkfish and it did not burn easily, the
fire did not flare up, a little portion of
the sample was damaged
70% Pulverized fish scale + 30% resin released an odor same with frying a
Milkfish and it did not burn easily, the
fire did not turn big and it seems like it
will stop, very little portion of the
sample was damaged
The results showed that all of them released odor and burned.
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Table 6: Freezing Resistance
Formulation Changes
The results showed that all of the samples did not show any changes at all.
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Effectiveness and Usefulness Results
To test the effectiveness and usefulness of the Manipulative Instructional Materials, the
researcher used the said materials in Kindergarten II-Yellow class. With the help of the teacher-
in -charge the pre-test and post-test were administered.
The researcher noticed that only 5 out of 22 pupils got the perfect score and three (3)
pupils got the lowest score during pre-test. In order to enhance the skills of the students and
develops the fine-motor skill and hand-eye coordination. After the pre-test, the researcher and
the teacher- in- charge applies the Instructional materials on her discussion and gives group
activity in the class. During discussion and activity, the researcher found out that the pupils
were interested. They love sorting and matching the chunky shapes.
Then, the post-test was given to the same pupils. Based on the comparative analysis of
the test results, the Mastery level both pre-test and post-test gained 62.50% and 97.73%
respectively.
The improve performance of the students is relevant to the features of the materials,
because of its size is fit enough, easy to grasp and feature rounded corner and edges. That the
reasons why most of the pupils were interested and active during activity.
Hence, the researcher concluded that the products are effective and useful as
manipulative instructional materials.
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COMPARATIVE ANALYSIS OF THE TEST RESULTS
(FORMATIVE TEST)
120
100
80
Standard Deviation
60
Mastery Level
40 Mean
20
0
Pre- Post
Test Test
Based on the test results the Post Test got 97.73% Mastery Level compared with Pre-
Test gained 62.50% ML. This implies that the Instructional Materials used is effective and
useful for the pupils.
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CONCLUSIONS AND RECOMMENDATION
The researcher concluded that we can minimize the waste material in market through
segregation of fish scales. Based on the results and findings of the study, the white granulated
texture of the pulverized Milkfish scales could be used as an additive and filler in resin. The
by-products are comparable with pure resin product. The production of figurine and different
shapes of toys as an alternative instructional material is cheaper and comparable with the
commercial resin figurine in terms of durability, flame and freezing resistance.
The researcher concluded that the 50-50 formulation is best among the three resin
bonded formulations. This formulation gives an indication that the quality of the product is still
equal. By using the 50-50 formulation the production of resin using 1 Kg of resin would be
doubled without changing the quality of the products.
To test the effectiveness and usefulness of the Manipulative Instructional Materials, the
researcher used the said materials in Kindergarten II- Yellow class. During activity, noticed
that the pupils were interested and loved sorting and matching the chunky shapes. The features
of the products can help the students to be active in the class. The size is enough and fit, these
are easy to grasp and has a feature rounded corner and edges. Most of the pupils are really
interested and active during activity. In addition to this the said products also passed the
required lead content standard for toys. Thus, the toys are safety to use.
The Comparative Analysis of test results indicates the good performance of the pupils.
The results show the highest increment of 35.23%. The Mastery level in pre-test and post-test
was 62.50% and 97.73% respectively.
Hence, the researcher concluded that the said products are effective and useful as
manipulative instructional materials. It can help the pupils to develop their fine-motor and
hand-eye-coordination. Also, to enhance students’ skills and improve teaching and learning
process.
Therefore, the researcher would like to recommend the use of the pulverized Milkfish
scales or other fish scales as an additive and filler in resin to produce different shapes and use
in making instructional Materials with good quality and enough quantity, with cheaper retailing
price and easy production. The researcher also believed that this study would help Navoteños
(residence in the Navotas City, Philippines) to earn extra income and has good impact to our
environment. It can help to lessen waste materials in the market.
22
References and Resources
Storer, Tracey I., Usinger, Robert L., Stebbins, Robert C., and Nybakken, James W.
(1979) General Zoology Sixth Edition McGraw-Hill Book Company, USA
Hickman C Jr., Roberts L., Larson A.,Ober C., and Garrison C. (2006) Integrated
Principles of Zoology Wm. C. Publishers
Charles Weichert and William (1979) Elements of Chordate Anatomy Fourth Edition
McGraw-Hill Inc.
Kumagai, S., Bagarinao, T. U., & Unggui, A. (1985). Growth of juvenile milkfish
Chanos chanos in a natural habitat. Marine Ecology Progress Series, 22(1), 1-6.
Pauly, Daniel, and Rainer Froese 2001. Fish Stocks. In: Simon Levin (ed.). Encyclopedia
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APPENDICES
Appendix 1. Measurement:
Table 1: Thickness, length and width and volume of samples with different formulation
Pure resin 0.5 inch (12.7 4 inches 1 inch (25.4 2 inch3 (32, 25 g
mm2)
50% Pulverized 0.5 inch (12.7 4 inches 1 inch (25.4 2 inch3 (32, 25 g
resin mm2)
60% Pulverized 0.5 inch (12.7 4 inches 1 inch (25.4 2 inch3 (32, 25 g
resin mm2)
70% Pulverized 0.5 inch (12.7 4 inches 1 inch (25.4 2 inch3 (32, 25 g
resin mm2)
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Table 2: Water Absorption
2 0% 0% 0% 0%
3 0% 0% 0% 0%
Table 3: Porosity
2 0% 0% 0% 0%
3 0% 0% 0% 0%
25
Appendix 2. Computation
Pure Resin
50-50 Formulation
1. 25-25x 100% = 0 1. 25-25x 100% = 0
25 25
2. 25-25x 100% = 0
2. 25-25x 100% = 0 25
25
3. 25-25x 100% = 0
3. 25-25x 100% = 0 25
25
26
B. Computation for the Mean Water Absorption
0 0
0 0
+ 0 + 0
0 0
0= 0% 0= 0%
3 3
0 0
0 0
+ 0 + 0
0 0
0= 0% 0= 0%
3 3
27
C. Computation for Compressive Strength
$%.' $$.)
2. = 0.5348 Kg/cm2 2. = 0.4456 Kg/cm2
().'*+, ().'*+,
$%.' $$.)
3. = 0.5348 Kg/cm2 3. = 0.4456 Kg/cm2
().'*+, ().'*+,
-.( +.-
1. = 0.3565 Kg/cm2 1. = 0.2674 Kg/cm2
().'*+, ().'*+,
+.-
2. = 0.2674 Kg/cm2
-.( ().'*+,
2. = 0.3565 Kg/cm2
().'*+,
+.-
3.
-.(
= 0.3565 Kg/cm2 3. = 0.2674 Kg/cm2
().'*+,
().'*+,
28
D. Computation for the Mean Compressive Strength
29
E. Computation for Porosity
Pure Resin
50-50 Formulation
1. 25-25x 100% = 0 1. 25-25x 100% = 0
25 25
2. 25-25x 100% = 0 2. 25-25x 100% = 0
25 25
3. 25-25x 100% = 0 3. 25-25x 100% = 0
25 25
30
F. Computation for the Mean Porosity
Pure 50-50
Resin Formulation
0 0
0 0
+0 +0
0 0
0=0%/3 0=0%/3
60-40 70-30
Formulation Formulation
0 0
0 0
+0 +0
0 0
0=0%/3 0=0%/3
Page | 31
Appendix 3. UTILIZATION OF THE INSTRUCTIONAL MATERIAL.
Page | 32
After Pre-Test the teacher in charge used the instructional material in the class.
Page | 33
Appendix 4. Sample Activity
Name: ____________________________________Date: _______________ Score:
_______
Directions: Encircle your ANSWER. Choose the correct shape and color from
Column B and match this in Column A.
Column A Column B
Page | 34
Appendix 5. Survey Questionnaires:
Survey
___________________________________________________
2. How long does it take until every fish has been sold?
___________________________________________________
3. How many of these fish’s scales, do you think are being wasted?
___________________________________________________
4. Where are these fish’s scales being thrown out?
___________________________________________________
5. Who collects these trashes?
___________________________________________________
6. Who is the person responsible for taking the trash out?
___________________________________________________
Page | 35
Appendix 6. Test Report of Extractable Lead (Pb)
Page | 36
The researcher conducted an interview in three marketplaces
The researcher removing scales from milkfish Collector of fish scales and entrails
Fish scales that are waste which produce unpleasant odors and pollutes the market
Page | 37
Fish Scale Mold as an Alternative Instructional Material
Page | 38