GTM-5

Narayana IIT Academy

INDIA
Sec: Sr. IIT_IZ Date: 04-02-18
Time: 07:30 AM to 10:30 AM Max.Marks:360

Name of the Student: ______________ I.D.NO:

IMPORTANT INSTRUCTIONS: correct response of each question. (1/4)
1) Immediately fill in the particulars on this
(one fourth) marks will be deducted for
page of the Test Booklet with Blue/Black
indicating incorrect response of each
Ball Point Pen. Use of pencil is strictly
question. No deduction from the total
prohibited.
score will be made if no response is
2) The test is of 3 hours duration.
indicated for an item in the answer sheet.
3) The Test Booklet consists of 90
6) There is only one correct response for
questions. The maximum marks are 360. each question. Filling up more than one
4) There are three parts in the question response in any question will be treated as
paper A, B, C consisting of Mathematics, wrong response and marks for wrong
response will be deducted accordingly as
Physics and Chemistry having 30
per instruction 5 above.
questions in each part of equal SYLLABUS
weightage. Each question is allotted 4 MATHS
TOTAL SYLLABUS + EXTRA SYLLABUS
(four) marks for correct response.
PHYSICS
5) Candidates will be awarded marks as
TOTAL SYLLABUS + EXTRA SYLLABUS
stated above in instruction No. 4 for
CHEMISTRY
TOTAL SYLLABUS + EXTRA SYLLABUS

MATHS
Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
1. If 4 circles touch all three lines 5. Tangents drawn from P  6,8  to a circle
x  y  3,3 x  y  7 and 2 x  3 y  5 with x 2  y 2  r 2 forms a triangle of maximum
radii a,b,c,d and a  b  c  d , then area with chord of contact, then r =
d d d
   1) 5 2) 6
a b c
3) 7 4) 4
1) 2 2) 3
6. Product of perpendiculars from any point
3) 1 4) 4
on the hyperbola 9 x 2  16 y 2  144 to its
2. In a  le ABC, A  1, 3  , B   0, 0  ,
asymptotes is k then 25k=
 1 
Incentre I   1,  then C =
 3 1) 1 2) 9
1)  5, 0  2)  4, 0  3) 16 4) 144
3)  0, 4  4)  2, 0   100 x   99sin x  
3. If distance of the plane Ax  2 y  z  d
7. Lt       (here  x  is g.i.f)
x 0
  sin x   x  
from the plane containing lines 1) 100 2) 200
x 1 y  2 z  3
  and 3)198 4) 199
2 3 4
x2 y3 z 4 8. If g  x  is inverse function of
  is 6 then d 
3 4 5
1) 6 2) 3 f  x   x 3  3 x  3 then g ' 1 

3) 2 4) 1 1) 1/6 2) 1/3
4. Distance of the point P 1, 0, 3 from 3) 1 4) 5
x 2 log 1  x 
2
the plane x  y  z  9 measured parallel
9. If  x d  tan x   
3 1
 c then
k l
x2 y2 z 6
to line   is
2 3 6 k l 
1) 6 2) 7 1) 4 2) 2
3) 5 4) 2 3) -2 4) 0

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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
10. If f : 0,    R is a continuous and 15. If  is factor of 120 then number of

increasing function and positive integral solutions of x1 x2 x3   is

x
1) 90 2) 320
f 3
 x    t. f 2  t  dt then f  6 
0 3) 160 4) 80
1) 6 2) 3 16. Consider ax  by  0, cx  dy  0 , are two
3) 2 4) 1 equations where a, b, c, d {0,1} then
11. Area bounded by curve probability that system of equations has
y   x  1 x  2  x  3 and x-axis unique solution
between lines x  0, x  3 1) 1/8 2) 1/4
1) 5 / 2 2) 11/ 4 3) 3/8 4) 1/46
3) 1 4) 3 17. Sum of first 10 terms of the series
12. Solution of differential equation 1 1
1   ......
1 2 1 2  3
dy x  1
 is a/an
dx y  1 20
1) 10 2)
21
1) Circle 2) Ellipse
20 11
3) Hyperbola 4) Straightline 3) 4)
11 20
13. If x, y , z not all zeroes and 18. Number of real roots of equation
ax  by  cz  0, bx  cy  az  0 , 2
 x  1   x  2 
2 2
 ....   x  2018   0 is
cx  ay  bz  0 then x : y : z  1) 2018 2) 1009
1) 3:4:5 2) 1:  :  2 3) 1 4) 0
3) 1 : 2 : 3 4) 1 : 3 : 7 19. Concentric circles of radii 1, 2,3....100 are
11
14. Coefficient of x 4 in 1  x  x 2  x 3  is drawn. The interior of smallest circle is
1) 990 2) 980 coloured with red and then alternatively
3) 900 4) 890
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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
with green and red then total area of 23. If a,b,c,d,p are distinct real numbers so
green region is that
1) 5050 2) 5000 a 2
 b 2  c 2  p 2  2  ab  bc  cd  p   b 2  c 2  d 2   0

3) 4050 4) 4000 then a,b,c are in

20. Number of solutions of sin{x}  cos{x} 1) AP 2) HP
in  0, 2  is 3) GP 4) AGP
(Here {x} is fractional part of x) 24. The negation of statement: If it rains then

1) 4 2) 6 donkeys are monkeys.

3) 5 4) 7 1) If it does not rains then monkeys are

2 4 6 not donkeys
21. cos  cos  cos 
7 7 7 2) If it rains then monkeys are not
1 1 donkeys
1) 2)
2 2
3) When it rains donkeys are not
3) 1 4) – 1
monkeys
22. A balloon of radius r which is placed
4) When donkeys are monkeys then it
above the ground subtends an angle 
rains
at a point ‘P’ on the ground and angle
25. The relation between two real numbers x
of elevation of the centre of balloon at
and y is defined as xRy if x is multiple of
P is ' ' , then height of balloon above
y then relation  x, y  R
the ground is
1) equivalence

1) r cos ec .sin  2) r cos ec sin 
2 2) symmetric, transitive, but not reflexive
 3) reflexive, transitive, but not symmetric
3) r cos ec .sin 4) r sin 
2
4) Not transitive

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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
26. If a  7i  4 j  4k and b  2i  j  2k PHYSICS
then vector c along the bisector of a 31. A student performs an experiment to
and b so that c  5 6 is determine the Young’s modulus of wire,
5 5
1)  i  7 j  2k  2)  i  7 j  2k  exactly 2 m long, by Searle’s method. In
3 3
5 a particular reading, the student measures
3)  i  7 j  2k  4) i  j  k
3 the extension in the length of the wire to
27. If 2 x  3 y  6 z  14 then minimum value
be 0.8 mm with an uncertainty of 0.05
2 2 2
of x  y  z is
mm at a load of exactly 1.0 kg. The
1) 2 2) 4 student also measures the diameter of the
3) 14 4) 7 wire to be 0.4 mm with a uncertainty of
28. If vector xi  12 j  k , 2i  2 xj  k , i  k  0.01 mm. take g  9.8 m / s 2 (exact). The
forms left hand, system then x  Young’s modulus obtained from the
1)  3, 2  2)  , 4    3,   reading is
3)  2,3 4)  0,   1)  2.0  0.3 1011 N / m2
29. f : R  R defined by 2)  2.0  0.2  1011 N / m2
f  x   x 3  3 x 2  6 x  5 is 3)  2.0  0.1 1011 N / m2
1) one-one, but not onto 4)  2.0  0.5 1011 N / m2
2) onto but not one-one
32. The electron in the ground state of
3) neither one-one, nor onto
hydrogen atom is revolving in a circular
4) bijective function
orbit of radius r. If m is the mass of
30. Three sides of a trapezium are equal to
electron, e its charge and h the Planck’s
8 cm then its maximum area is
constant, the magnitude of the magnetic
1) 16 3 2) 32 3
dipole moment of the electron is
3) 48 3 4) 48

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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
eh eh ' '
1) 2) light of wavelength  Wavelength 
4 m 2 mr
(in nm) is
4 2 m 2 r
3) 4) Zero 1) 375 2) 450
eh
dN 3) 575 4) 625
33. Show a graph of Figure ln versus
dt 35. In the visible region, the dispersive
t. From the graph, the half life (in powers and the mean angular deviations
seconds) of the radioactive sample is for crown and flint glass prisms are 
'
and  and d and d ' respectively. When
10
dN 8 the two prism are combined, the
ln
dt
6 condition of zero dispersion by the

4
combination is
2 1)  d   'd '  0
0 2)  ' d   d '  0
1 2 3 4 567
t  in s   3)  d   ' d '  0
2 2
ln  2  4) d    ' d '   0
1) 2) ln  2 
2
36. A plane electromagnetic ware travelling
3) 2ln  2  4) 4ln  2 
in a non-magnetic medium is in given by
34. The angular width  of the central E   9 108 NC 1  sin  9 108 rad S 1  t   6m1  x 
maximum in the diffraction pattern of
where x is in meter and t is in second.
a slit illuminated by light of
The dielectric constant of the medium is
wavelength 500 nm is measured. The
1) 5 2) 4
angular width of the central maximum
3) 3 4) 2
is found to increase by 25% when the
same slit is illuminated by another
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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
37. An L-R circuit connected to a battery e

of a constant emf E. The switch S is

closed at time t  0 . If ’e’ denotes the
induced emf across the inductor and ‘i’
the current in the circuit at any time t,
which of the graphs represents the 0 i
4)
variation of e with i ?
L R 38. A charge Q is uniformly distributed over
the surface of non-conducting disc of
radius R. The disc rotates about an axis
perpendicular to its plane and passing
S
through its centre with an angular
E
e
velocity  . As a result of this rotation a
magnetic field B is obtained at the centre
of the disc. If we keep both the amount
of charge placed on the disc and its
0
1) i
angular velocity to be constant and vary
e
the radius of the disc, then the variation
of the magnetic field at the centre of the
disc will be represented by which of the
0
2) i
following figures.
e

0
3) i

1) R

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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
When a current I is passed in the coil as
B shown, the coil will experience
1) no net force and no net torque
2) a net force F = 2BIa which will move
R 
2) it in the direction of B but no net torque
3) a net torque  = BIab which will rotate
B
it but no net force
4) a net torque   BI  a 2  b 2  which will

3) R rotate it in the anticlockwise sense and

also a net force F  BI  a  b  which will
B 
be parallel to B .
40. A current carrying (from Q to P)

R cylindrical conductor PQ is lying along

4)
39. A rectangular coil PQRS of length
PQ = a and breadth SP = b is
suspended with its plane parallel to a
horizontal magnetic field B
the x-axis with its end P at x  0 . The
cylinder has a uniform cross-section and
it is made of an alloy whose resistivity
varies with x as   ax  b . Where a and b

are positive constants. Which of the

B graphs represents the variation of
S R
I potential (V) with x? (Assume potential

I at P to be zero Volt)
I

P Q
I

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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
V 41. The electrostatic potential inside a
charged spherical ball is given by
  ar 2  b where r is the distance from

the centre; a,b are constants. Then the

charged density inside the ball is
O x
1)
1) 24 a 0 r 2) 6 a 0 r
V
3) 24 a 0 4) 6a 0
42. The transverse displacement y  x, t  of a

wave on a string is given by

1/2
 
  ax 2  bt 2  2 abxt 

x
y  x, t   e  
. This
2) O

V represents a
1) Wave moving in x direction with
a
speed
b

b
2) Standing wave of frequency
a

3) O x 3) Wave moving in x direction with

V a
speed
b
1
4) Standing wave of frequency
b

43. An insulated box containing a diatomic

gas of molar mass M is moving with a
O x
4)
velocity  . The box is suddenly stopped.

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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
The resulting change in temperature is T

0
(R is the gas constant)
M 2 M 2
1) 2) 0 t
2R 3R 4)
M 2 2M  2 45. Which of the graphs shown in the figure
3) 4)
5R 5R
44. If a piece of metal is heated to correctly represents the variation of

temperature  and then allowed to     dV / dp  / V with p for an ideal gas

cool in a room which is at temperature
at constant temperature?
0 , the graph between the temperature

T of the metal and time t will be

closest to 
T

0

1)

0 t
1)
T 

0


0 t
2)
2)
T

0


0 t
3)

3)
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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
47. Two bodies of masses M 1  m and
M 2  4m are placed at a distance r. The

gravitational potential at a point on the
line joining them where the gravitational

4) field is zero is
46. Water is filled up to a height h in a
4Gm
1) Zero 2) 
beaker of radius R as shown in the r
6Gm 9Gm
figure. The density of water is  , the 3)  4) 
r r
surface tension of water is T and the 48. A disc of mass M and radius R is rolling
atmospheric pressure is P0 . Consider a with angular speed  on a horizontal
vertical section ABCD of the water plane. The magnitude of angular
column through a diameter of the momentum of the disc about the origin O
beaker. The force on water on one side is
of this section by water on the other Y

side of this section has magnitude

M


O X

1
1) MR 2 2) MR 2
2
3
2
3) MR 2 4) 2MR 2
1) 2 P0 Rh   R  gh  2 RT 2
2) 2 P0 Rh  R  gh2  2 RT
3) P0 R 2  R  gh 2  2 RT
4) P0 R 2  R  gh 2  2 RT

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Narayana IIT Academy
49. The potential energy U of a particle of
mass m  3kg moving in the
x  direction is given by
3
U  3  x  1   x  3 when U is in joule
and x is in meter. Which of the graphs
best represents the variation of the
acceleration A of the particle with
position x ?
A horizontally, striking the ground 10 m
04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
A
O
x
4)
50. A body whirls a stone in a horizontal
circle of radius 1.25 m, by means of a
string 2m above the ground. The string
breaks and the stone files off
away (horizontal displacement). What is
the magnitude of the centripetal

O acceleration during circular motion?

x
1) Take g  10 ms 2

A 1) 100 ms 2 2) 200 ms 2
3) 300 ms 2 4) 400 ms 2
51. A soap bubble of radius r is blown up to
O
x form a bubble of radius 2r under
2)
isothermal conditions. If  is the surface
A tension of soap solution, the energy spent
in doing so is.
2 2
O 1) 3  r 2) 6  r
x
2 2
3) 3) 12  r 4) 24  r

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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P

52. When the temperature of a thin copper

wire is increased by T , its length L
increases by 0.1% . If the temperature

of a thin square copper plate of side L

is increased by T , its surface area
4
increases by 1) 2) 2
9
1) 0.1% 2) 0.2% 8
3) 4) 18
3
3) 0.3% 4) 0.4%
55. Which of the following has the highest
53. A simple pendulum of bob of mass m
magnetic permeability?
is oscillating with an angular
1) Paramagnetic substances
amplitude  m (in radians). The 2) Diamagnetic substances
maximum tension in the string is 3) Ferromagnetic substances
1) mg 2) mg  m 4) Vacuum

4) gm 1   m 
2
2
3) mg  m 56. A series LCR circuit connected to a
variable frequency 200 V source. L = 5
54. A battery of internal resistance 4 is
H, C  80 F and R  40 . What is the
connected to the network of
resistances. In order that maximum source frequency which drives the circuit

power can be delivered to the network, at resonance?

the value of R in ohm should be

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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
25
1) 25 Hz 2) Hz

50
3) 50 Hz 4) Hz

57. A body of mass m, having momentum
p, is moving on a rough horizontal
surface. If it is stopped in a distance x ,
Output is:
the coefficient of friction between the
body and the surface is given by
p2 p2 1)
1)   2)  
2 gm 2 x 2mgx
p p
3)   4)  
2mgx 2 gm2 x 2)
58. An audio low frequency signal of
frequency vm is superposed on a high
3)
frequency carrier wave of frequency vc
. The resultant amplitude modulated 4)
wave has components of frequencies. 60. In a transistor. A change of 8.0 mA in the
1) vm and vc emitter current produces a change of
2) vm , vc and  vc  vm  7.8 mA in the collector current. What
3) vm , vc and  vc  vm  change in the base current is necessary to
4) vc ,  vc  vm  and  vc  vm 
produce the same change in the collector
59. The logic circuit shown in the figure
current?
has the input waveforms ‘A’ and ‘B’
1) 50  A 2) 100  A
as shown. Pick out the correct output
3) 150  A 4) 200  A
waveform.
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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
CHEMISTRY 62. The oxidative cleavage of compounds
61. The end product of the following Glucose (A) and Fructose (B) with HIO4
reaction is
leads to the formation of acids and
OH
Excess aldehydes. The ratios of formic acid to
CHCl3/NaOH/
formaldehyde for (A) and (B)

NH2
respectively are

OH 1) 5/1, 3/2 2) 5/2, 3/1

OHC 3) 3/2, 5/2 4) 4/2, 5/1
63. Consider the following first order
1) OHC
reactions:
NH2
k2
OH
k1
X  A  B and Y  CD
OHC Cl If 50% of the reaction of ‘X’ has been

2) completed when 96% of the reaction of

‘Y’ was completed, then the ratio of their
C N
rate constants (k2/k1) is (log0.698)
OH
1) 2.34 2) 0.215
Cl
3) 1.1 4) 4.64
3) 64. An unknown compound, X, has the
NH2 CHO molecular formula C7 H 12 . On catalytic
hydrogenation 1 mole of X absorbs 2
OH moles of H 2 and yields 2-methylhexane.
OHC Cl
When X is treated with a solution of
4) Ag ( NH 3 ) 2 OH , a precipitate forms; an
NC
analysis of the precipitate shows that it
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contains silver, and treatment of the 2) HClO3  H 3BO3  H 3PO 4
precipitate with dilute HNO3 3) H3PO 4  HClO3  H3BO3
regenerates X. Which compound 4) H3BO3  HClO3  H 3PO 4
represents X?
1) CH 3CH 2CH 2 CH 2 CH 2  C  C  H
CH3
|
2) CH3  C  C  CH 2  CH  CH3
CH3
| 67.
3) CH 2  CH  CH  CH  CH  CH3
CH3
|
4) CH3  CH  CH 2  CH 2  C  C  H
65. Arrange the following in the increasing
order of resonance energies

S N O
1)
I III H V
II IV

1) I > II > III > IV > V

2) II > I > III > V > IV 2)
3) V > IV > III > II > I
4) IV > V > II > I > III
66. When the acids HClO3 , H 3BO3 , H3 PO4
3)
are arranged in order of increasing
strength, which order is correct ?
1) H3BO3  H 3PO 4  HClO3
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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
H 71.
CH3
CH 3
*
NBS Mg (i) CO 2
A B + C
H 2 2 CH NH CCl4 Et2O (ii) H
4)
68. The order of acidity of positions X, Y
The End Prodcut ‘C’ Is
and Z is
*
F HOOC CH3 OHC CH3

z
NO2
1) 2)
*
HO HOH2C CH3 HOOC CH3
x y

F
3) 4)
1) x > y > z 2) y > x > z
72. One mole of a substance is cooled at rate
3) z > x > y 4) x > z > y
of 0.4 kJ min–1 during freezing. What
69. During process of electro refining of
would be the entropy of fusion (in JK–1
Cu some metals present as impurity
mol–1) for this substance using data from
settle as anode mud. These are:
the following graph?
1) Sn and Ag
800
2) Pb and Zn
3) Ag and Au 400

4) Fe and Ni Temp. (K)

70. The number of identical P-O bonds 1 4

4 Time (in minute)
P2O6
1) 2 2) 3
1) Four 2) Six
3) 4 4) 5
3) Five 4) three
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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
73. Determine the major product of the OH

following: COOH

OH

COOH 4) Br
Br2 74. A compound (A) has the molecular
H2O
formula C5H9Cl. It does not react with

OH bromine in carbon tetrachloride. On

Br Br treatment with a strong base it produces a

single structural isomeric compound (B)
Compound (B) has the molecular

Br
formula C5H8 and reacts with bromine in
1)
carbon tetrachloride Ozonolysis of
OH
compound (B) produces a compound (C)
COOH
with molecular formula C5H8O2. The
structure of compound (A) would be

1) 2)
2) Br
OH
3) 4)
Br COOH

75. S1 : For an electron, the given set of

3) quantum numbers is not possible:
1
n  4,   1, m  0, s  
2

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Narayana IIT Academy
S2 : The total number of orbitals in a
subshell is 2  1 , where   Azimuthal
quantum number.
S3 : For the same element , the cation
with greater positive charge will have
larger radius because of the lesser
attraction of the electrons by the
nucleus.
S4 : First ionization enthalpy of
Potassium is lesser than that of
Calcium, but the order of second
ionization enthalpy is just the reverse.
1) FTTT 2) TTFT
3) FTFT 4) FFFF
76. In PBr3F2, the Br—P—F angle is:
o o
1) 90 2) 120
o o
3) 180 4) 109.5
77. Three isotopes of an element have
mass numbers M, (M + 2) and
(M + 4) If the mean mass number is
(M + 0.75), then which of the
following ratios may be accepted for
the M, (M + 2), (M + 4) in that order
1) 1 : 1 : 1 2) 4 : 1 : 1
3) 5 : 2 : 1 4) 6 : 1 : 1
Sec: Sr.IIT_IZ
04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
78. If the limiting slope of density vs
pressure plot for air at 0°C is 1.27 x 10-5
kg m-3 Pa-1, the molar mass of air would
be
1) 14.42 x I0-3 kg mol-1
2) 23.89 x 10-3 kg mol-1
3) 28.82 x 10-3 kg mol-1
4) 32.89 x 10-3 kg mol-1
79. Two liquids A and B have vapour
pressure in the ratio p0A : pB0  1: 2 at a
certain temperature. Suppose that we
have an ideal solution of A and B in the
mole fraction ratio A : B = 1 : 2 the mole
percent of A in the vapour in equilibrium
with the solution at the given temperature
is
1) 20 2) 25
3) 35 4) 75
80. A certain transition in the hydrogen
spectrum from an excited state to the
ground state in one or more steps gives
rise to a total of ten lines How many of
these belong to the visible spectrum?
1) 3 2) 4
3) 5 4) 6
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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
81. The iodide content of a solution was (I) AmO22 / AmO2 (II) AmO22 / Am24
determined by titration with cerium (III) Am4 / Am2
(IV) sulfate in the presence of HCl, in 1) (I) only 2) (II) only
which I is converted to ICl. A 250 ml 3) (I) and (II) only 4) (I), (II) and (III)
sample of the solution required 20 ml 84. The enthalpy of fusion of ice is 6 kJmol-1
of 0.05 N Ce4+ solution. What is the The heat capacity of water is 4.2J g-1 °C-1
iodide concentration in the original What is the smallest number of ice cubes
solution in g/litre (atomic mass of at 0°C, each containing one mole of
I=127) water that are needed to cool 500 g of
1) 0.254 g/Iitre liquid water from 20° to 0° C?
2) 2.54 g/litrc 1) 1 2) 7
3) 0.508 g/litre 3) 14 4) 125
4) 5.08 g/litre 85. Which of the following does not give
82. Calcium crystallizes in a face-centered Hoffmann bromamide reaction?
cubic unit cell with O NHBr
a = 0.556 nm Suppose this sample of
Ca contained 0.1%. Frenkel defects in O

the crystal. The density of the crystal

1) changes by 0.05% 1) 2) H3C NH2

O NH2 O NHCH3
2) changes by 0.1%
3) changes by 0.15%
4) does not change
83. For which of these redox couple 3) 4)
electrode potential vary with pH?

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Narayana IIT Academy 04-02-18_Sr.IIT_IZ_Ph-I_Jee-Main_GTM-5_Q.P
86. In the reactions,

CH3  CH  CH2 
H
D O
(A)
2

CH3  CH  CH2 
D
H O
(B)
2 89.
the compounds (A) and (B) are
1) CH3  CH(OH)CH2D and
CH3 CH(OD)CH3

2) CH3CH(OD)CH3 and CH3CH(OD)CH2D

3) CH3CH2CH2OD and CH3CH(D)CH2OH 1) 2)

4) CH3CH(OD)CH3 and CH3CH(OH)CH2D

87. Physiosorption increases with
1) raise in temperature
2) decrease in temperature 3) 4)
3) decrease in pressure
90. Which of the following is most acidic?
4) decreasing the surface area of the
adsorbent

88. MnO 2  K 2CO3  air  (X) ;
Green

1) 2)
(X)  Cl2 
 (Y)
pink

The compounds (X) and (Y) are

1) K 2Cr2O2 ,KMnO4
2) K 2MnO4 ,KMnO4 3) 4)
3) KMnO4 ,K 2MnO4
4) MnCO3 ,MnCl2
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