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1 AITS-CRT-I-PCM (Sol.

)-JEE(Main)/18

FIITJEE JEE(Main)-2018
ANSWERS, HINTS & SOLUTIONS
CONCEPT RECAPITULATION TEST – I
(Main)

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS


ALL INDIA TEST SERIES

1. B 31. B 61. A
2. C 32. B 62. B
3. C 33. B 63. C
4. D 34. C 64. A
5. A 35. D 65. C
6. B 36. B 66. C
7. D 37. B 67. C
8. A 38. D 68. A
9. B 39. C 69. B
10. A 40. C 70. B
11. B 41. D 71. D
12. B 42. C 72. B
13. C 43. C 73. A
14. D 44. B 74. A
15. C 45. C 75. A
16. C 46. B 76. B
17. C 47. B 77. D
18. A 48. C 78. D
19. B 49. B 79. D
20. D 50. C 80. A
21. D 51. B 81. B
22. A 52. B 82. C
23. D 53. C 83. B
24. C 54. B 84. B
25. D 55. B 85. C
26. C 56. B 86. B
27. A 57. C 87. B
28. D 58. C 88. B
29. A 59. A 89. C
30. B 60. B 90. C

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AITS-CRT-I-PCM (Sol.)-JEE(Main)/18 2

Physics PART – I

SECTION – A

1. B
Sol. capillary rise
2T cos   
h=
r g
h r 0.4
 1  2   2:1
h2 r1 0.2

2. C
Sol. x = A sin  t  o 
At t = 0, x = 0  A sin o  0 or o = 0
Hence, x = A sin  t 
or A/2 = A sin (t)
or 1/2 = sin (t)
 1 
t = sin-1  2   6

 .T
t= 
6 6  2 
as   2 / T  t T/12 = 1/3 s

3. C
tR
E  
Sol. i 1  e L 
R 

4. D
E1 E
 1
E 4n  E2n 16n2 4n2 1
Sol.  = = constant
E 2n  En E1 E1 4

4n2 n2

5. A
10v d
Sol. f = v =  .
d 10
d
Maximum path diff. can be . Hence, number of maximum will be 6.
3

6. B
3RT
Sol. Crms = or Crms  T
M

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3 AITS-CRT-I-PCM (Sol.)-JEE(Main)/18

 Crms T T2 400
2
 = =2
 Crms T1
T1 100
(Crms) T2 = 2(Crms) T1 = 2  v = 2v

7. D
1
Sol. t = 20 min = hr
3
1 
1 km = (6)2  V 2   hr 
3 
V = 3 3 km/hr.

8. A
E0 ( 13.6)
Sol. 12.75  E0  2
 13.6 
n n12
 n4
n(n  1)
no. of lines  6
2

9. B
mv 2
Sol. qvB =
R
mv = qRB = 1.6  1021 kg m/sec

10. A
Sol: Consider the differential element of the cylinder as shown in the figure.
R2
dx l
 R   2xl ( R   )
R1
a
 R
R= ln  2 
2l  R1 
 2l 
I= ; I=
R R 
 ln  2 
 R1 

11. B
Sol. +ve slope = +ve velocity and convex graph = –ve acceleration
Concave graph = +ve acceleration

12. B
1
Sol. mv 2 = Power t = Fv t = kt
2
2kt
 V
m

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AITS-CRT-I-PCM (Sol.)-JEE(Main)/18 4

13. C
Sol: Let dq be the charge which has passed in a small interval of time dt, then dq = idt =
(4 + 2t)dt. Hence total charge passed between interval t = 2 sec and t = 6 sec
6
q =  (4  2t)dt = 48 coulomb.
2

14. D
Sol. Maximum stress on the wire will be at highest point (at the point of suspension)
weight Alg
 stress = = 
A A

 l=
g

15. C
Sol. T + f = mg sin  (Translational equilibrium)
T(R) = f(R) (Rotational equilibrium)
16. C
i
Sol. Inductor behaves like a cell of emf,  = Blv and
equivalent ckt is
R R1 R2
Blv = 
Blv
Hence, i =
R1R2
R
R1  R 2
Blv(R1  R 2 )
=
RR1  RR2  R1R2

17. C
V
Sol. E=  directed r to an equipotential surface.
r

18. A
Sol. Inside water
u = –20 cm
f = –15 cm
 v = –60 cm
v
m = –3
u
 n=3
19. B
PdV
Sol. C = Cv + ,
ndT
PV 3/2  k, PV  nRT
find relation in V and T
dV 2V

dT T
 C = Cv – 2R

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5 AITS-CRT-I-PCM (Sol.)-JEE(Main)/18

20. D
 dh 
Sol. A1V1 = A2V2  a 2gh  A   
 dt 
t 2 h
a dh
  dt   A 
A0 h1 2gh

21. D
Sol. No relative motion between source and observers.

22. A
Sol. Heat energy flowing per sec is given by
Q 
H  KA . . . (i)
t x
if dm mass of ice is increased in time dt, then
dm A dx  dx
  A..
dt dt dt
 dm 
Since, H   L
 dt 
dx
 H  A L . . . (ii)
dt
From eq. (I) and (II)
dx 
A L  KA
dt x
Rate of thickening of ice = dx/dt
dx KA  K  4  10 4  0  ( 15) 
  = = 
dt  AL x  L x 0.9  10  80  2  10 2 
3

= 4.166  106 m/s = 1.5 cm/ hour.

23. D
usin  tan 
Sol. tan  =  
eucos  e 

1 
 tan  = tan 
e
1  
 tan  = tan 
e
2 + 2 + 2 = 180°
 +  = (90 – )
tan( + ) = cot 
tan   tan  1
 
1  tan  tan  tan 
1 1
tan   2 tan 
e e 1
 
1 tan 
1  3 tan2 
e

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AITS-CRT-I-PCM (Sol.)-JEE(Main)/18 6

1 1  1
 tan2    2
  1  3 tan 
e e2  e
1 1 1 
 tan2    2
 3  1
e e e 
 
 1  e3
tan2    2
 1  1  1  1  e  e
 e e2 e3 

24. C
Sol. Let the cylinder is slightly displaced from mean position.
The total energy of the system when elongation in spring is x.
1 1 1 1 
E = kx 2  Mv 2    MR2  2
2 2 2 2 
Differentiating the above expression, we get
dx dv 1 2v dv
2kx  M2v  MR 2 2 0
dt dt 2 R dt
dv
2kx + (2M + M) =0
dt
dv  2K 
  x
dt  3M 
3M
T = 2
2k
25. D
V V V/3
Sol. Velocity of A after the collision with C, V1 = m 2m
3
B A
 Velocity of each block A and B at maximum compression
5
V2 = V
9
2
1 2 1 5 
 k x  3m  V 
2 2 9 
2
1 1 V
= mv 2  2m  
2 2 3
8m
x= V
27K

26. C
 1 2
Sol. Velocity of ball ‘A’ just after the collision V   1    u  u
 2 3
Velocity of ball ‘B’ just after the collision = 0.
u0 u
  
L L

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7 AITS-CRT-I-PCM (Sol.)-JEE(Main)/18

27. A
t
Sol. T °C where t is time in seconds.
20
d kA(T  0)

dt 
kA t
Q =  dQ  dt = 18000 J.
  20

28. D
T T 2T
Sol. v ; VAB  ; VCD 
  

29. A
4S  4S 
Sol.  4 
R1  R2 
 R2 = 4R1
4 3
R1
Required ratio = 3
4 3
R 2
3

30. B
Sol. At the level of interface
Pleft = Pright
1gh1 = 2gh2
1
  .
h

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AITS-CRT-I-PCM (Sol.)-JEE(Main)/18 8

Chemistry PART – II

SECTION – A

31. B
Sol. In H-atom, the orbitals(five 3d, three 3p and one 3s) have same energy. So, they are
called degenerate orbitals.

32. B
Sol. It is a zero order reaction.

33. B
Sol. Increasing the volume of reaction container twice, the concentration of all the species
will reduce to half.

34. C

Sol. pH  pKa  log


CH3COONa  5  log 200  0.4  5
CH3COOH 400  0.2

35. D
Sol. The observed bond angles are 120o, 180o and 90o.

36. B
Sol. 4LiNO3  2Li2O  4NO 2  O2

37. B
Sol. Peroxoborates contain peroxide linkages, which behave as bleaching agent.

38. D
Sol. In chlorobenzene, Cl exerts –I and +R effect. In other compounds, it only exerts –I effect.

39. C
Sol. Carbon should be present in the compound for giving nitrogen test.

40. C
Sol. F F

C-C
Teflon is
F F n

41. D
Sol. Ca3P2  6H2O  3Ca  OH2  2PH3

42. C
Sol. NaCl  H2SO4  NaHSO4  HCl

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9 AITS-CRT-I-PCM (Sol.)-JEE(Main)/18


2KClO3   2KCl  3O2
2HCl  O3  Cl2  O2  H2O
KCl  AgNO3  AgCl  KNO3

43. C
Sol. Due to stable t32ge g2 configuration of Fe3+ ion.

44. B
Sol. Roasting is carried out for sulphide ores.

45. C
Sol. It produces maximum number of ions as compared to other salts.

46. B
Sol. The sol becomes positively charged due to excess of Fe3+ ions.

47. B
0.0591    0.0591
Sol. E  Eo  log H   0  log10 4  0.236 V
n 1

48. C
Sol. XY3  g   X  g   3Y  g  ; H = E kJ mol–1
E
 B.E of XY = as XY3 contains three X – Y bonds.
3

49. B
Sol. For spontaneous process, G < 0.
 H - TS < 0, H < TS
H 18000
 T   300K
S 60

50. C
1200  0.4
Sol. Moles of HCl =  0.48
1000
19.2
Moles of NaOH =  0.48
40

51. B
Sol. Easily liquefiable gases should have high critical temperature(TC), which is given by
8a  8 a
TC   
27Rb  27R  b
a
TC 
b

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AITS-CRT-I-PCM (Sol.)-JEE(Main)/18 10

52. B
Sol. X = Na2SO3
Y = BaSO3
Z = BaSO4

53. C
Sol. CsCl has b.c.c. unit cell.

54. B
Sol. ‘CO’ can form carboxy haemoglobin.

55. B
Sol. Sucrolose is an artificial sweetner.

56. B
Sol. OH OCH3

CH2N2
  N2

57. C
Sol. Anti Markownikoff reaction takes place in this case.

58. C
Sol. H3C OH H3C
NH2OH/H
CH3COC2H5  
 C N + C N
H5C2 H5C2 OH

59. A
Br2
Sol. CH3 CH2CH2CONH2 
KOH
 CH3CH2CH2NH2

60. B
Sol. Due to intermolecular hydrogen bonding.

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11 AITS-CRT-I-PCM (Sol.)-JEE(Main)/18

Mathematics PART – III

SECTION – A

61. A
16
8r
Sol.  S
r 1  4r 4
1 
16
8r

r 1  2r 2

 2r  1 2r 2  2r  1 
16
 1 1 
 2  2  2 
r 1  2r  2r  1 2r  2r  1 
1 1 1 1 1 1 1   1  1088
 2      ......     2 1  
1 5 5 13 13 481 545   545  545

62. B
2
2x  x  1 ex
Sol. f ' x  f x 
x 1  x  12
2x dx 2
IF  e   e x
 
f  x  . e x
2
    x dx 1 2

2 1
 f  x  .e  x  C
x 1
At x = 0, f(0) = 5
 C=6
 6x  5  x2
 f x    .e
 x 1 
Hence, (b) is the correct answer.

63. C
   
Sol. We have r  a  b  a
  
 
r b  a  0 
  
 r  b is parallel to a
  
 r  b  a …………(i)
 
Now, r .c  0
  
 
b  a .c  0 
   
 b . c   a.c  0  
 
b.c
   
a.c

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AITS-CRT-I-PCM (Sol.)-JEE(Main)/18 12

On putting the value of  in Eq. (i), we get


 
  b.c 
rb   a
 
a.c  
Hence, (c) is the correct answer.

64. A
Sol. Replacing f (x) by x, we f (x) = x2
 ffff (x) = x16 also (f (x4))2 = x16.

65. C
1
Sol. Since coefficient of x2 + ax + 1 are symmetrical so roots will be ,

 1  1
sin  x    x      x    x   
lim

sin x 2  ax  1  = lim    . 
x 1/   x  1 x 1/   1   x  1

 x   x  
 
1

= lim
x     
1  2
x 1/    2

66. C
Sol. If u = f(cos x) and v = g (sinx)
du  f (cos x) sin x
 
dv g(sin x) cos x
 1 
 f    tan
 2 3 2
At x = ,  =  3 = 3
3  3 2
g 
 2 
 

67. C
Sol. Given that f (x) = |1  x|
 x  1, x  1

1  x, 0  x  1
 f (|x|) = 
1  x, 1  x  0
  x  1, x  1
Clearly the domain of sin1 (f |x|) is [2, 2].
 It is non differentiable at the points { 1, 0, 1}.

68. A
Sol. y = x touches y = x2 + bx + c
1=1+b+cb+c=0 ……(1)
dy
 2x  b (1, 1)  2  b  1  b  1, c = 1.
dx
(b, c) = (–1, 1).

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13 AITS-CRT-I-PCM (Sol.)-JEE(Main)/18

69. B
 2 tan x
x   
Sol. e   tan2  x    dx
 1  tan x  4 
     
  e x  tan  x    sec 2  x    dx
  4  4 
 
 e x tan  x    c .
 4

70. B
dx dx
Sol. ( 2 7

x)  ( x)  1 
( x )7  1  5 
 ( x) 
1
Put =y
( x )5
dy 5
=–
dx 2( x )7
 
2dy 2 2  1 
I=  = – ln |1 + y| + c = + ln  
5(1  y) 5 5  1 1 
 ( x )5 
 
2 5
a= ,k= .
5 2

71 D
 
 cot   x  
        
Sol.  ln  cos   x   dx =  cot  4  x  .ln cos    x  dx
0  4  0
 /4
     
 cot     0  x   ln cos     0  x   dx
0 4 4  4 4 

1 2 
=  cot x.ln  sin x  dx  2 ln sin x  
= not defined.
0

72. B
10 1 1 1
3x
dx = 20  3 x  [x] dx  20  3  dx  20  3 x dx
x
Sol.  3 x
10 0 0 0
1
 3x  40
= 20    .
 ln3  0 ln3

73. A
Sol. The distance between (2, 2m) and ( 5, 5m) is less then 5.
 ( 5 –2)2 +( 5m – 2m)2 < 25

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AITS-CRT-I-PCM (Sol.)-JEE(Main)/18 14

 9m2 < 16
2
4 4 4
m2 <      m  .
3 3 3
74. A
Sol. Let A denote the event that a sum of 5 occurs, B the event that a sum of 7 occurs and C
the event that neither a sum of 5 nor a sum of 7 occurs. We have
4 1 6 1
P A   , P B   
36 9 36 6
26 13
P C   
36 18
Thus, probability that A occurs before B is
P  A or  C  A  or  C  C  A  or ....
 P  A   P  C  A   P  C  C  A   .....
2
 P  A   P  C  P  A   P  C  P  A   ......
2
1  13  1  13  1
     .....
9  18  9  18  9
1/ 9 2
 
1  13 / 18 5

75. A
n1  n 
Sol    k Cr 1 
r 1  k 1 
n1  n 
 
r 1  k 1
 k 1
Cr k Cr  

n 1

r 1
 n 1
Cr 1 Cr  2n1  2
76. B
1
Sol. b2 
1  b1
1 1 1  b1 b1  1
b3    
1  b2 1  1 b1 b1
1  b1
b1  b3  b12  b1  1  0
1
 b1   or 2  b 2    or 2
1 
2001 2001 2001

 br 2001    
r 1 r 1
2001
  1 = –2001
r 1

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15 AITS-CRT-I-PCM (Sol.)-JEE(Main)/18

77. D
      
Sol.  
Let the plane r . i  2 j  3k  17 divide the line joining the points 2i  4j  7k and
  
3i  5j  8k in the ratio t : 1 at point P.
Therefore, point P is
3t  2  5t  4  8t  7 
i j k
t 1 t 1 t 1
This lies on the given plane
3t  2 5t  4 8t  7
 1   2    3   17
t 1 t 1 t 1
Solving, we get
3
t
10

78. D
Sol. Vector perpendicular to the face OAB is
 
  
OA  OB  ˆi  2ˆj  kˆ  2iˆ  ˆj  3kˆ 
 5iˆ  ˆj  3kˆ
Vector perpendicular to face ABC is
 
  
AB  AC  ˆi  ˆj  2kˆ  2iˆ  ˆj  kˆ 
 ˆi  5ˆj  3kˆ
Since the angle between the face = angle between their normal, therefore
5  5  9 19  19 
cos       cos1  
35 35 35  35 
79. D
   P(1, 1, –1)
Sol. V1, V 2 , PS are in the same plane
   
 2iˆ  ˆj  3kˆ  3iˆ  kˆ .  x  2  ˆi   y  1 ˆj  zkˆ  0  V2  2iˆ ˆj 3kˆ V1 3iˆ kˆ

R (–2, 1, 0)
Q (3, 0, 2)

S (x, y, z)
80. A
sin  xy 
Sol. y
cos  xy 
 sin  xy   xy
 xy  0
 x  0 or y = 0
But x = 0 is not possible
 y = 0 and x = 1, i.e. (1, 0)

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AITS-CRT-I-PCM (Sol.)-JEE(Main)/18 16

81. B
y
Sol.
y = 2x – x2
1

x
O  
2 y= In sin x

–1
/2

–2

–3

–4

In sin x   x  x  2 
  3 
Graphs of y  In sin x and y   x  x  2  meet exactly two times in   , 
 2 2
82. C
A
c 2  b2 a 2
Sol. In ABC, AD2  m12  
2 4
2
a
2
AD  c 2  
2
In ABD, AE2  m22   
2 4
[Apollonius Theorem]
2
a
2
AD  b 2  
2
In ADC, AF2  m23   
2 4 B E C
D F
2 2
b c a2
m22  m23  AD2  
 2 8
2 2 2
a a a
 m12    2m12 
4 8 8
2
a
 m22  m32  2m12 
8

83. B
 n12
Sol. We know that adj  adj A   A
 n12
 adj  adj  adj A    adj A
 n13
 A  28  256

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17 AITS-CRT-I-PCM (Sol.)-JEE(Main)/18

84. B
Sol. The total number of third order determinants is 9! Since the number of determinants is
even and in which there are 9!/2 pairs of determinants which are obtained by changing
two consecutive rows,
n
So  Di  0 .
i1

85. C
2
Sol. A 1
BA   A 1

BA A 1BA
 A 1 B  AA  BA
1

 A 1BIBA  A 1B2 A
3
A 1
BA   A 1 2

B A A 1 BA 

 A 1B2 AA 1 BA 
 A 1B3 A and so on
n

 A 1BA   A 1Bn A

86. B
Sol. Let f (x) = ax2 + x + c – a
f (1) = c + 1 > 0 ( c > –1)
 Given expression is positive for every x  R
 1 a 1
So, f   > 0   + c – a > 0  4c – 3a + 2 > 0
2 4 2
 4c + 2 > 3a.

87. B
Sol. Let  be a common root then 3  2a  2  0 and  4  2a 2  1  0
i.e.  4  2a 2  2  0 ….(i)
4 2
  2a  1  0 …(ii)
1
From (i) and (ii) 2  1  0   
2
3
 1 1 1 1 17
So,    2a  2  0   a  2  0  a  2    .
2 2 8 8 8

88. B
Sol. First, 6 distinct digits can be selected in 10C6 ways. Now the position of smallest digit in
them is fixed i.e. position 4. Of the remaining 5 digits, two digits can be selected in 5C2
ways. These two digits can be placed to the right of 4 th position in one way only. The
remaining three digits to the left of 4th position are in the required order automatically.
So n(S) = 10C6  5C2 = 210  10 = 2100.

89. C

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AITS-CRT-I-PCM (Sol.)-JEE(Main)/18 18

Sol. Clearly p = 6! 7P4


q = 7! . 4!
p
5
q

90. C
n
C4
Sol. When 4 points are selected we get one intersecting point. So probability is n
.
( C2 n)
C2

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