Document Title: Duplex Stainless Steel Requirements as per Industry Practice Project No.

124033

4.4 Technical Sheet: Duplex 22Cr Stainless Steel Forgings

Technical Sheet 4.4: Duplex 22Cr Stainless Steel Forgings

Product Form Forgings.

Material 22Cr ferritic/austenitic stainless steel - often referred to as duplex stainless steel. This
Technical Sheet is not applicable to HIP components. For requirements for HIP
components, consult Company.

Manufacturer’s Materials supplied in accordance with this standard shall only be supplied by Company
Approval qualified manufacturers.

Specification ASTM A 182 / A 182M.

Grade(s) F51 (UNS S31803) and F60 (UNS S32205).

Supplementary S2
Requirements

Heat Treatment All materials shall be delivered in the solution annealed (followed by water quenching)
condition.

Chemical Analysis A product chemical analysis shall be carried out for all heats.
and Pitting
Resistance PRE = Cr + 3.3Mo + 16N. The PRE shall be greater than or equal to 34.0.

Equivalent (PRE)

Hardness Per ASTM standard specified in this Technical Sheet. If no hardness is specified by the
ASTM standard, then the maximum hardness shall be HRC 28, HB 271 or HV10 310.

Impact Testing Charpy V-notch testing shall be in accordance with ASTM A 370;

1. Required test temperature shall be -46 deg C (-50.8 deg F) or lower.

2. Absorbed energy is minimum 48 J (36 ft-lbf) average and 36 J (27 ft-lbf) for single
value or corresponding energy level.
3. Materials originally tested by manufacturer at lower temperature or equivalent than
item (1) and (2) above are acceptable. No re-testing is required.

Document No. MYTZ-WE-LSZZZ-170001 Revision: CC Page 19 of 49

Document Title: Duplex Stainless Steel Requirements as per Industry Practice Project No. 124033

Technical Sheet 4.4: Duplex 22Cr Stainless Steel Forgings

Ferrite Content ASTM E 562 or ASTM E 1245 shall be used for manual point count or AIA respectively
as follows:

1. Ferrite count shall be between 35% and 55%.

Metallographic 1. Samples shall be etched using ASTM E 470 etchant number 98-K3Fe(CN)6 or with
Examination KOH or NaOH.

Test Sampling 1. Test samples shall be taken from an actual (sacrificial) test forging or from a
prolongation of the actual part.
2. Test sample shall be from a location which is representative of the thickest section
of the production forging.
3. The test sample from parent forging shall accompany the actual production forgings
through all heat treat ad quench cycles.

Extend of Testing All testing shall be conducted on each heat for each heat treatment load.

Inspection 1. 20% of forgings shall be examined by PT.

2. Acceptance criteria shall be in accordance with ASME Section VIII Div.1, Appendix
8 “Methods for Liquid Penetrant Examination (PT)”.

Non Destructive 1. All forgings shall have ferrite content determined in a minimum of two locations,
Ferrite Measurement including both the thickest section and the thinnest section using a Fischer
Feritscope ferrite scope.
2. Ferrite content shall be between 35% and 55%.

Repair of Defects Weld repairs shall not be allowed.

Document No. MYTZ-WE-LSZZZ-170001 Revision: CC Page 20 of 49

Document Title: Duplex Stainless Steel Requirements as per Industry Practice Project No. 124033

4.5 Technical Sheet: Duplex 22Cr Stainless Steel Plates

Technical Sheet 4.5: Duplex 22Cr Stainless Steel Plate

Product Form Plate (for pressure-containing components such as vessel shells or for fabricated
components such as plate type heat exchangers and tanks.)

Material 22Cr ferritic/austenitic stainless steel - often referred to as duplex stainless steel.

Manufacturer’s Materials supplied in accordance with this standard shall only be supplied by Company
Approval qualified manufacturers.

Specification ASTM A 240 / A 240M.

Grade(s) UNS S31803 and UNS S32205.

Supplementary S1
Requirements

Heat Treatment All materials shall be delivered in the solution annealed (followed by water quenching)
condition.

Hot and Cold 1. If material is cold worked at any location in the product into a radius of curvature to
Working thickness ratio of 18:1 or less, or to a plastic strain of 2.5% or more, then material
shall be solution annealed after cold working has been completed.
2. A separate solution annealing and water quenching shall be required for material
that has been hot formed. Testing shall be carried out on material after completion
of all forming and heat treatment activities.

Chemical Analysis A product chemical analysis shall be carried out for all heats.
and (PRE)
PRE = Cr + 3.3Mo + 16N. The PRE shall be greater than or equal to 34.0.

Hardness Per ASTM standard specified in this Technical Sheet. If no hardness is specified by the
ASTM standard, then the maximum hardness shall be HRC 28, HB 271 or HV10 310.

Impact Testing Charpy V-notch testing shall be in accordance with ASTM A 370;

1. Required test temperature shall be -46 deg C (-50.8 deg F) or lower.

2. Absorbed energy is minimum 48 J (36 ft-lbf) average and 36 J (27 ft-lbf) for single
value or corresponding energy level.
3. Materials originally tested by manufacturer at lower temperature or equivalent than
item (1) and (2) above are acceptable. No re-testing is required.

Document No. MYTZ-WE-LSZZZ-170001 Revision: CC Page 21 of 49

Document Title: Duplex Stainless Steel Requirements as per Industry Practice Project No. 124033

Technical Sheet 4.5: Duplex 22Cr Stainless Steel Plate

Ferrite Content ASTM E 562 or ASTM E 1245 shall be used for manual point count or AIA respectively
as follows:

1. Ferrite count shall be between 35% and 55%.

Metallographic 1. Samples shall be etched using ASTM E 470 etchant number 98-K3Fe(CN)6 or with
Examination KOH or NaOH.

Extend of Testing All testing shall be conducted on each heat, on each size and heat treatment lot.

Non Destructive 1. All plates shall have ferrite content determined in a minimum of three locations,
Ferrite Measurement including both the thickest section and the thinnest section using a Fischer
Feritscope ferrite scope.
2. Ferrite content shall be between 35% and 55%.

Repair of Defects Weld repairs shall not be allowed.

Document No. MYTZ-WE-LSZZZ-170001 Revision: CC Page 22 of 49

Document Title: Duplex Stainless Steel Requirements as per Industry Practice Project No. 124033

4.7 Technical Sheet: Duplex 22Cr Stainless Steel Seamless Pipe

Technical Sheet 4.7: Duplex 22Cr Stainless Steel Seamless Pipe

Product Form Process pipe.

Material 22Cr ferritic/austenitic stainless steel - often referred to as duplex stainless steel.

Manufacturer’s Materials supplied in accordance with this standard shall only be supplied by Company
Approval qualified manufacturers.

Specification ASTM A 790 / A 790M.

Grade(s) UNS S31803 and UNS S32205.

Heat Treatment All materials shall be delivered in the solution annealed (followed by water quenching)
condition.

Chemical Analysis A product chemical analysis shall be carried out for all heats.
and (PRE)
PRE = Cr + 3.3Mo + 16N. The PRE shall be greater than or equal to 34.0.

Hardness Per ASTM standard specified in this Technical Sheet. If no hardness is specified by the
ASTM standard, then the maximum hardness shall be HRC 28, HB 271 or HV10 310.

Impact Testing Charpy V-notch testing shall be in accordance with ASTM A 370;

1. Required test temperature shall be -46 deg C (-50.8 deg F) or lower.

2. Absorbed energy is minimum 48 J (36 ft-lbf) average and 36 J (27 ft-lbf) for single
value or corresponding energy level.
3. Materials originally tested by manufacturer at lower temperature or equivalent than
item (1) and (2) above are acceptable. No re-testing is required.

Ferrite Content ASTM E 562 or ASTM E 1245 shall be used for manual point count or AIA respectively
as follows:

1. Ferrite count shall be between 35% and 55%.

Document No. MYTZ-WE-LSZZZ-170001 Revision: CC Page 25 of 49

Document Title: Duplex Stainless Steel Requirements as per Industry Practice Project No. 124033

Technical Sheet 4.7: Duplex 22Cr Stainless Steel Seamless Pipe

Metallographic 1. Samples shall be etched using ASTM E 470 etchant number 98-K3Fe(CN)6 or with
Examination KOH or NaOH.

Extend of Testing All testing shall be conducted on a lot basis. A lot is defined as a maximum of 60 m (197
ft) of pipe of the same diameter, thickness, heat and heat treatment charge.

Non Destructive 1. 10% of all products shall have ferrite content determined using a Fischer Feritscope
Ferrite Measurement ferrite scope.
2. Ferrite content shall be between 35% and 55%.

Hydrostatic Test Pipe shall be hydro-tested in accordance with ASTM A 790 / A 790M.

Repair of Defects Weld repairs shall not be allowed.

Document No. MYTZ-WE-LSZZZ-170001 Revision: CC Page 26 of 49