Professional Documents
Culture Documents
Solve
nN2 0.8
Chemical process Calculation
Ans: nH2 3.4
nNH3 0.4
Solve Solve
An ammonia converter is fed with a mixture of nitrogen and hydrogen.
Calculate the excess air used in a furnace when the dry Conversion of ammonia is 25% based on nitrogen fed in the convertor.
All of the ammonia formed from the reactor is separated by liquefaction
flue gas Orsat analysis is CO2-8.2, O2 – 9.9, CO-0.1, H2- and the unconverted reactants are recycled back and mixed with the
feed stream to be fed in the convertor. Evaluate the following, if the
0.4, N2-81.4 (everything is in %). fresh feed and recycle are at 873K and 2.5 atm gauge pressure, the
Assume the nitrogen source is only air. ammonia production rate is 8500 Kg/hr.
• A labeled flowsheet of the process, indicating all the units and sub-
Ans: Oxygen excess : 9.65 units (DO it yourself)
• Degree of freedom analysis of the units and sub-units (DO it
% Excess: 80.48% yourself)
• Recycle ratio (Ans=3000/1000 =3)
• The volume of the fresh feed (Ans: 1000 kmol feed– convert it into
volume using PV=nRT gives- V= 19293.47 m3)
• Volume of the recycle required (Ans: 3000kmol recycled-
conversion into volume gives: 57880.41 m3)
Oxidation
Absorber
10% NH3, unit
90 % Air (Mole %) HNO3
Air
Air
1
14-Mar-18
A local utility burns coal having the The average Orsat analysis of the • Moisture in the coal was 3.90% and the air on the
following composition on a dry flue gas during a 24-hr test average contained 0.0048 lbm H2O/lbm dry air.
basis: was:
• The refuse showed 14.0% combined elements as in the
Component Percent coal (i.e. C, H, O, N, S) and the remainder being ash. It
C 83.05 Component Percent may be assumed that these combined elements occur in
CO2+SO2 15.4 the same proportions as they do in the coal.
H 4.45
CO 0.0 • Estimate the amount of amount of flue-gas (dry basis),
O 3.36
O2 4.0 • amount of water coming out of the process, and the
N 1.08
%excess air.
S 0.70 N2 80.6
Solved problem from HIMMELBLAU, check the combustion
Ash 7.36 Total 100.00 section for answers.
Total 100.00
Flowsheet