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Chemistry Workbook For Dummies, 2nd Edition
To calculate molarity, you may have to use conversion factors to move between units.
For example, if you’re given the mass of a solute in grams, use the molar mass (usually
rounded to two decimal places) of that solute to convert the given mass into moles. If
you’re given the volume of solution in milliliters or some other unit, you need to convert
that volume into liters. Units are the very first thing to check if you get a problem wrong
when using molarity. Make sure your units are correct!
The units of molarity are always moles per liter (mol/L or mol·L –1). These units are often
abbreviated as M and referred to as “molar.” Thus, 0.25 M KOH(aq) is described as
“Point two-five molar potassium hydroxide,” and it contains 0.25 mol of KOH per liter of
solution. Note that this does not mean that there are 0.25 mol KOH per liter
of solvent (water, in this case) — only the final volume of the solution (solute plus
solvent) is important in molarity.
Like other units, the unit of molarity can be modified by standard prefixes, as in
millimolar (mM, which equals 10–3 mol/L) and micromolar
Sometimes, the term percent solution is used to describe concentration in terms of the
final volume of solution instead of the final mass. For example:
“2% H2O2” can mean 2 mL hydrogen peroxide in 100 mL final volume. This is
a volume-volume percent solution.
First, calculate the molarity. Before you can use the molarity formula, though, you must
convert grams of H3PO4 to moles:
Note that the convention in molarity is to divide moles by liters, but the convention in
mass percent is to divide grams by milliliters. If you prefer to think only in terms of liters
(not milliliters), then simply consider mass percent as kilograms divided by liters.