Professional Documents
Culture Documents
Table of Contents
1 Introduction of company ..………………………………………………………3
11 Quality authentication
11.1 NSF Certification ………………………………………………………………………111
11.2 ISO 14000 Environmental system certification …………………………….112
11.3 ISO9000 Quality system certification ………………………………………….113
12 Addenda
12.1 Unit conversion …………………………………………………………………………..114
12.2 Common formula ………………………………………………………………………..115
12.3 The conversion of conductivity and salinity …………………………………….116
1 Introduction of company
Chanitex (Shanghai) Pure Water Equipment CO., LTD lays in MinHang district of
shanghai, close to traffic center of HongQiao, with an area of 33000square meters.
Our products cover all kinds of pure water equipments, filters and relative
components, including RO membrane, pump, filter, switch and solenoid. At
present, Chanitex has more than 150 professional and technical stuffs, distributed
in R&D, manufacture, QC, after-sales service and so on.
Chanitex pays much attention to product development through the ages. Every
year the expense on product development covers about 3% of sale and the
number of patent applications is for many years in the forefront of the country. We
own 66 items patents now, among which 12 items are invention patents, 25 items
are applied new pattern patents and 29 are appearance patents.
Chanitex was rated as shanghai high-tech enterprise in 2007 and its products are
certified by NSF, ROHS, CE, the ministry of health, UL, 3C and so on.
Chanitex (shanghai) Pure Water Equipment Co., LTD was founded in 2002 and
becomes one of the enterprises engaged in the manufacture of the reverse
osmosis membrane and relative products.
We have totally produced all kinds of more than 2 million sets RO membrane since
the first piece of membrane was produced and the numbers are top among the
nation. We produced 600,000 pieces of RO membranes in 2007 and the number is
top in China. At present, about 100 workers engage in membrane manufacture.
The yield of 4 inches membrane is 10,000 each month, 8 inches membrane 1,000,
household membrane 100,000, and the total yield is top among China.
Our aims
Better RO membrane
BW- 4040
BW - 8 365
TFC - 1812- 50
data is just for reference and doesn’t mean that it is completely same as the actual
LP low pressure brackish membrane: The pressure and energy consumption low down
40% with the same desalination rate;
TW tap water membrane: The best balance between high desalination and
XLE extreme low energy membrane: The water output is 10% more while the pressure
low down 30%. The perfect connection of low
ECO low pressure membrane: The most economical 4 inch membrane with best
membrane brand;
Characteristic of product
1) RO membrane sheet of well-known manufacturer is adopted to
guarantee the quality of product;
2) With multi series and complete specification, the membrane can meet
all kinds of requirement;
3) With high quality and low price, it reduce the expense of investment
and maintenance;
4) With strong ability of development, we can provide tailor service of
membrane for customer;
5) We can provide OEM service of membrane for customer;
Chanitex
produced by Chanitex
Note: The above chart shows the different performance of membrane. And doesn’t mean that
the actual data is the same as the dates listed on the chart, the chart is just for reference
Product characteristics BW brackish water membrane elements adopt the most advanced polyamide
sheets , and are combined with the experience we got over the years, so we
can have a treatment of desalination brackish water whose TDS is less than
8000mg/L, surface water, ground water, and other source water.
The characteristics of the membrane are as follows:
● High and owns perfect performance in wiping off SiO2. It can also reduce
the energy consumption and maintenance expense of resin, EDI and other
devices.
● With high stability and optimization structure. The membrane adopts the
design of wide feed net and short membrane leaves. This series of film
owns the high stability and can be cleaned.
● We supply wide scope of choice and complete specification. The Diameter
is divided into 2.5 inches, 4.0 inches, 8.0 inches and the length is divided
into 14 inches, 21 inches and 40 inches, so as to meet the need of
different requirement on water output. We can also make special
dimension and specification of membrane as customer require.
Performance parameters
Limited conditions:
Max operation pressure ………………………………………….600psi(4.2MPa)
Dimension Criterion
Diameter 2.5 inches series unit mm (inch)
Model A B C D
2514 356.0(14.0) 26.7(1. 05) 19.1(0.75) 61.0(2.40)
2521 533.4(21.0) 26.7(1. 05) 19.1(0.75) 61.0(2.40)
2540 1016.0(40.0) 26.7(1. 05) 19.1(0.75) 61.0(2.40)
Product characteristics BW brackish water membrane elements adopt the most advanced polyamide
sheets , and are combined with the experience we got over the years, so we
can have a treatment of desalination brackish water whose TDS is less than
8000mg/L, surface water, ground water, and other source water.
The characteristics of the membrane are as follows:
● High and owns perfect performance in wiping off SiO2. It can also reduce
the energy consumption and maintenance expense of resin, EDI and other
devices.
● With high stability and optimization structure. The membrane adopts the
design of wide feed net and short membrane leaves. This series of film
owns the high stability and can be cleaned.
● We supply wide scope of choice and complete specification. The Diameter
is divided into 2.5 inches, 4.0 inches, 8.0 inches and the length is divided
into 14 inches, 21 inches and 40 inches, so as to meet the need of
different requirement on water output. We can also make special
dimension and specification of membrane as customer require.
Performance parameters
Active area Test pressure Permeate water Rejection Recovery
Model
Ft2(m2) Psi(MPa) flow GPD(m3/d) (%) (%)
BW-4014 22(2.0) 225(1.55) 550(2.1) 99.3 8
Limited conditions:
Max operation pressure ………………………………………….600psi(4.2MPa)
Dimension Criterion
Diameter 4.0 inches series unit mm (inch)
Model A B C D
4014 356.0(14.0) 26.7(1. 05) 19.1(0.75) 100.1(3.94)
4021 533.4(21.0) 26.7(1. 05) 19.1(0.75) 100.1(3.94)
4040 1016.0(40.0) 26.7(1. 05) 19.1(0.75) 100.1(3.94)
Product characteristics BW brackish water membrane elements adopt the most advanced polyamide
sheets , and are combined with the experience we got over the years, so we
can have a treatment of desalination brackish water whose TDS is less than
8000mg/L, surface water, ground water, and other source water.
The characteristics of the membrane are as follows:
● High and owns perfect performance in wiping off SiO2. It can also reduce
the energy consumption and maintenance expense of resin, EDI and other
devices.
● With high stability and optimization structure. The membrane adopts the
design of wide feed net and short membrane leaves. This series of film
owns the high stability and can be cleaned.
● We supply wide scope of choice and complete specification. The Diameter
is divided into 2.5 inches, 4.0 inches, 8.0 inches and the length is divided
into 14 inches, 21 inches and 40 inches, so as to meet the need of
different requirement on water output. We can also make special
dimension and specification of membrane as customer require.
Performance parameters
Limited conditions:
Max operation pressure ………………………………………….600psi(4.2MPa)
Dimension Criterion
Diameter 8.0 inches series unit mm (inch)
Model A B C
8365/8400 1016.0(40.0) 29.0(1.1) 201(7.9)
Product characteristics LP brackish water membrane elements adopt the most advanced polyamide
sheets , and are combined with the experience we got over the years, so we
can have a treatment of desalination brackish water whose TDS is less than
5000mg/L, surface water, ground water, and other source water.
The characteristics of the membrane are as follows:
● High desalination rate, and big flow ,the running pressure lows down
30% more than the common brackish membrane. It can reduce the
energy consumption, the quality requirement of pump, pressure vessel,
pipe line, and save the expense of investment and maintenance.
● With high stability and optimization structure. The membrane adopts the
design of wide feed net and short membrane leaves. This series of film
owns the high stability and can be cleaned.
● We supply wide scope of choice and complete specification. The
Diameter is divided into 2.5 inches, 4.0 inches, 8.0 inches and the length
is divided into 14 inches, 21 inches and 40 inches, so as to meet the need
of different requirement on water output. We can also make special
dimension and specification of membrane as customer require.
Performance parameters
Limited conditions:
Max operation pressure ………………………………………….600psi(4.2MPa)
Dimension Criterion
Diameter 2.5 inches series unit mm (inch)
Model A B C D
2514 356.0(14.0) 26.7(1. 05) 19.1(0.75) 61.0(2.40)
2521 533.4(21.0) 26.7(1. 05) 19.1(0.75) 61.0(2.40)
2540 1016.0(40.0) 26.7(1. 05) 19.1(0.75) 61.0(2.40)
Product characteristics LP brackish water membrane elements adopt the most advanced polyamide
sheets , and are combined with the experience we got over the years, so we
can have a treatment of desalination brackish water whose TDS is less than
5000mg/L, surface water, ground water, and other source water.
The characteristics of the membrane are as follows:
● High desalination rate, and big flow ,the running pressure lows down
30% more than the common brackish membrane. It can reduce the
energy consumption, the quality requirement of pump, pressure vessel,
pipeline, and save the expense of investment and maintenance.
● With high stability and optimization structure. The membrane adopts the
design of wide feed net and short membrane leaves. This series of film
owns the high stability and can be cleaned.
● We supply wide scope of choice and complete specification. The
Diameter is divided into 2.5 inches, 4.0 inches, 8.0 inches and the length
is divided into 14 inches, 21 inches and 40 inches, so as to meet the need
of different requirement on water output. We can also make special
dimension and specification of membranes as customer require.
Performance parameters
Limited conditions:
Max operation pressure ………………………………………….600psi(4.2MPa)
Dimension Criterion
Diameter 4.0 inches series unit mm (inch)
Model A B C D
4014 356.0(14.0) 26.7(1. 05) 19.1(0.75) 100.1(3.94)
4021 533.4(21.0) 26.7(1. 05) 19.1(0.75) 100.1(3.94)
4040 1016.0(40.0) 26.7(1. 05) 19.1(0.75) 100.1(3.94)
Product characteristics LP series brackish desalination membrane of Chanitex adopt the most
advanced technology of polyamide complex, and combine the experience
we got over the years, so we can have a treatment of desalination
brackish water whose salinity is less than 5000mg/L,surface water,
ground water ,and other source water.
The characteristics of the membrane are as follows:
● High desalination rate, and big flow ,the running pressure lows down
30% more than the common brackish membrane. It can reduce the
energy consumption, the quality requirement of pump, pressure
vessel, pipeline, and save the expense of investment and
maintenance.
● With high stability and optimization structure. The membrane adopts
the design of wide page and short film. This series of film owns the
high stability and can be cleaned.
● We supply wide scope of choice and complete specification to meet
the need of different requirement on water output. We can also make
special dimension and specification of membrane as customer
require.
Performance paremeter
Limited conditions:
Max operation pressure ……………………………………………600psi(4.2MPa)
Dimension Criterion
Diameter 8.0 inches series unit mm (inch)
Model A B C
8365/8400/8440 1016.0(40.0) 29.0(1.1) 201(7.9)
Product characteristics Chanitax corporation TW series super low pressure tap water 2.5 inches
salty rejection reverse osmosis elements are made of super low
composite polyamide membrane combining with long term experience
in manufacturing reverse osmosis .It deals with the tap water with salt
lower than 2000mg/L and especially fits for the production of all the
drinking water .
The membrane has its characteristics as follows:
● High rejection .They give high rejection in treating with pesticides, by
product of disinfection often seen from the tap water.
● With high stability and optimization structure. The membrane adopts
the design of wide feed net and short membrane leaves. This series of
film owns the high stability and can be cleaned.
● We supply wide scope of choice and complete specification. The
Diameter is divided into 2.5 inches, 4.0 inches, 8.0 inches and the
length is divided into 14 inches, 21 inches and 40 inches, so as to
meet the need of different requirement on water output. We can also
make special dimension and specification of membrane as customer
require.
Performance parameters
Limited conditions:
Max operation pressure ………………………………………….600psi(4.2MPa)
Dimension Criterion
Diameter 2.5 inches series unit mm (inch)
Model A B C D
2514 356.0(14.0) 26.7(1.05) 19.1(0.75) 61.0(2.40)
2521 533.4(21.0) 26.7(1.05) 19.1(0.75) 61.0(2.40)
2540 1016.0(40.0) 26.7(1.05) 19.1(0.75) 61.0(2.40)
Product characteristics Chanitax corporation TW series super low pressure tap water 4.0 inches
salty rejection reverse osmosis elements are made of super low
composite polyamide membrane combining with long term experience
in manufacturing reverse osmosis .It deals with the tap water with salt
lower than 2000mg/L and especially fits for the production of all the
drinking water .
The membrane has its characteristics as follows:
● High rejection .They give high rejection in treating with pesticides, by
product of disinfection often seen from the tap water.
● With high stability and optimization structure. The membrane adopts
the design of wide feed net and short membrane leaves. This series of
film owns the high stability and can be cleaned.
● We supply wide scope of choice and complete specification. The
Diameter is divided into 2.5 inches, 4.0 inches, 8.0 inches and the
length is divided into 14 inches, 21 inches and 40 inches, so as to
meet the need of different requirement on water output. We can also
make special dimension and specification of membrane as customer
require.
Performance parameters
Limited conditions:
Dimension Criterion
Diameter 4.0 inches series unit mm (inch)
Model A B C D
4014 356.0(14.0) 26.7(1.05) 19.1(0.75) 100.1(3.94)
4021 533.4(21.0) 26.7(1.05) 19.1(0.75) 100.1(3.94)
4040 1016.0(40.0) 26.7(1.05) 19.1(0.75) 100.1(3.94)
Product characteristics Chanitax corporation TW series super low pressure tap water 2.5 inches
salty rejection reverse osmosis elements are made of super low
composite polyamide membrane combining with long term experience
in manufacturing reverse osmosis .It deals with the tap water with salt
lower than 2000mg/L and especially fits for the production of all the
drinking water .
The membrane has its characteristics as follows:
● High rejection .They give high rejection in treating with pesticides, by
product of disinfection often seen from the tap water .
● With high stability and optimization structure. The membrane adopts
the design of wide feed net and short membrane leaves. This series
of film owns the high stability and can be cleaned.
● We supply wide scope of choice and complete specification. The
Diameter is divided into 2.5 inches, 4.0 inches, 8.0 inches and the
length is divided into 14 inches, 21 inches and 40 inches, so as to
meet the need of different requirement on water output. We can also
make special dimension and specification of membrane as customer
require.
Performance parameters
Limited conditions:
Max operation pressure ……………………………………………600psi(4.2MPa)
Dimension Criterion
Diameter 8.0 inches series unit mm (inch)
Model A B C
8365/8400/8440 1016.0(40.0) 29.0(1.1) 201(7.9)
Product characteristics Chanitex XLE series extreme low energy reverse osmosis membrane elements are
made of the largest productive composite polyamide membrane It deals with the
tap water with salt lower than 2000mg/L .
The membrane has its characteristics as follows:
● Super large productive .It can provide higher productive when the operational
pressure is 100 psi, which the flow is more than 10% compared with other
same products under the same pressure. It can also reduce investment costs
of pressure pump, pipe and pressure vessel.
● Effectively reducing the operating cost and design difficulties. When the feed
SDI is lower than3,it helps to reduce the quantity of pressure vessel , the
system investment and later operation and maintenance costs.
● With high stability and optimization structure. The membrane adopts the
design of wide feed net and short membrane leaves. This series of film owns
the high stability and can be cleaned.
● We supply wide scope of choice and complete specification. The Diameter is
divided into 2.5 inches, 4.0 inches, 8.0 inches and the length is divided into 14
inches, 21 inches and 40 inches, so as to meet the need of different
requirement on water output. We can also make special dimension and
specification of membrane as customer require.
Performance parameters
Limited condition:
Dimension Criterion
Diameter 2.5 inches series unit mm (inch)
Model A B C D
2514 356.0(14.0) 26.7(1.05) 19.1(0.75) 61.0(2.40)
2521 533.4(21.0) 26.7(1.05) 19.1(0.75) 61.0(2.40)
2540 1016.0(40.0) 26.7(1.05) 19.1(0.75) 61.0(2.40)
Product characteristics Chanitex XLE series extreme low energy reverse osmosis membrane elements
are made of the largest productive composite polyamide membrane It deals with
the tap water with salt lower than 2000mg/L .
The membrane has its characteristics as follows:
● Super large productive .It can provide higher productive when the
operational pressure is 100 psi, which the flow is more than 10% compared
with other same products under the same pressure. It can also reduce
investment costs of pressure pump, pipe and pressure vessel.
● Effectively reducing the operating cost and design difficulties. When the
feed SDI is lower than3,it helps to reduce the quantity of pressure vessel ,
the system investment and later operation and maintenance costs.
● With high stability and optimization structure. The membrane adopts the
design of wide feed net and short membrane leaves. This series of film
owns the high stability and can be cleaned.
● We supply wide scope of choice and complete specification. The Diameter
is divided into 2.5 inches, 4.0 inches, 8.0 inches and the length is divided
into 14 inches, 21 inches and 40 inches, so as to meet the need of different
requirement on water output. We can also make special dimension and
specification of membrane as customer require.
Performance parameters
Limited conditions:
Dimension Criterion
Diameter 4.0 inches series unit mm (inch)
Model A B C D
4014 356.0(14.0) 26.7(1.05) 19.1(0.75) 100.1(3.94)
4021 533.4(21.0) 26.7(1.05) 19.1(0.75) 100.1(3.94)
4040 1016.0(40.0) 26.7(1.05) 19.1(0.75) 100.1(3.94)
Product characteristics Chanitex XLE series extreme low energy & large productive reverse osmosis
membrane elements are made of the largest productive composite polyamide
membrane It deals with the tap water with salt lower than 2000mg/L .
The membrane has its characteristics as follows:
● Super large productive .It can provide higher productive when the
operational pressure is 100 psi, which the flow is more than 10%
compared with other same products under the same pressure. It can also
reduce investment costs of pressure pump, pipe and pressure vessel.
● Effectively reducing the operating cost and design difficulties. When the
feed SDI is lower than3,it helps to reduce the quantity of pressure vessel ,
the system investment and later operation and maintenance costs.
● Excellent stability , optimized element structure ,wide flow path and short
membrane leaf design ,XLE series of elements is provided with the super
reliable operation and most effective cleaning .
● Wide range and complete sets of products .There is 2.5 inches and 4.0
inches and 8.0 inches in diameter ,14 inches ,21 inches and 40 inches in
length that can meet different system demands about productive .Also,
we can design various sizes and specifications membrane elements
according to the clients’ needs.
Performance parameters
Limited conditions:
Max operation pressure …………………………………………….600psi(4.2MPa)
Dimension Criterion
Diameter 8.0 inches series unit mm (inch)
Model A B C
8365/8400/8440 1016.0(40.0) 29.0(1.1) 201(7.9)
Limited conditions:
Max operation pressure ………………………………………….600psi(4.2MPa)
Max feed water temperature ……………………………………45℃
Max feed water SDI ……………………………………………….5
Max feed water flux …………………………………………………14GPM(3.2M3/h)
Max free chlorine in feed water …………………………………<0.1mg/L
Range of feed water PH value of constant run………………3~10
Range of feed water PH value of chemical cleaning……….2~11
Max pressure drop of single membrane……………………….15Psi(0.1Mpa)
Dimension Criterion
Diameter 4.0 inches series unit mm (inch)
Model A B C D
4040 1016.0(40.0) 26.7(1.05) 19.1(0.75) 100.1(3.94)
Production characteristics FS-TFC household RO membrane elements adopt the most advanced polyamide
RO membrane sheets and combine with many of the years of experience in the
process of rolling –made membrane, which can treat with various tap water
from the municipal.
The features are as follows:
● TFC-1812-50GPD membrane has got the certification of NSF (ANSI/NSF
Standard 58);
● Outstanding performance ,high stability and reasonable price
● FS-TFC is a residential membrane brand with the most complete mode and
specification in the world, with the four Diameters of 1.8inches ,2.0
inches, 2.5inches and 3.0 inches ,pure water flux from 50 GPD to 300GDP.
The 400 GPD&500GDP will be developed in 2007.
Performance parameters
Limited conditions:
Dimension criterion
Household reverse osmosis series unit mm (inch)
Model A B C D E F
1812 298(11.7) 20.0(0.8) 19.1(0.75) 45.0(1.8) 264.8(10.4) 53.5(2.1)
2012 298(11.7) 20.0(0.8) 19.1(0.75) 48.0(1.9) 264.8(10.4) 53.5(2.1)
2512 298(11.7) 20.0(0.8) 19.1(0.75) 62.0(2.5) 264.8(10.4) 71.5(2.8)
3012 298(11.7) 20.0(0.8) 19.1(0.75) 81.0(3.2) 264.8(10.4) 81.5(3.2)
4040 element connector code: 42317 8040 element connector code: 40708
Specification
Name Code
d1 22
Specification
Name Code
d1 d2 S1 S2 h
Package information
3.6.1 The package information of commercial and industrial elements
Note: The gross and the net weight are calculated by the wet membrane .The deviation between
actual weight and the average is +5%
Filter refers to removing many or a certain substance in the gas or liquid and makes the gas and
liquid pass the hole with multi-hole medium on the effect of out force, and then impurity is left
on the filter medium to achieve the operation of separation.
1 The multi-hole medium is called filter medium. The usual filter medium contains filter bag,
filter core, filter membrane and filter material .The treated gas or liquid is called original liquid.
In the original liquid, the impurity left by filter medium, this is called filter sediment. The liquid
passed the filter mediums called filter liquid.
2 The force that make the liquid pass the filter medium include gravity, pressure, centrifugal
force or other drive force;
3 The purpose of filter may be to get more purified gas or liquid product. or to gain the certain
substance contained in the gas or liquid .(that is condensation or purification)
The usual liquid filter separation include: machinery filter, traditional filter, micro-filtration
Ultra-filtration, Nano-filtration reverse osmosis, electric permeating separation. They are
different in accuracy. The above chart is several separated accuracy and the operating pressure
range. From the chart we can see the filtration accuracy of the reverse osmosis is the highest. It
can remove almost all the impurity in the water including ion, organism microbes. However, the
range of corresponding operational pressure is higher, usual 100-1000psi. Other filters have the
regularity of operational pressure is lower as the filter accuracy does.
The best advantage of the crossing flow filter is: the excellent function of anti-pollution. For
most impurity left by filter membrane is taken by condensed water except a little left on the
surface. Meanwhile, the feed water often washes out the surface of the membrane to ensure the
long time and stable operation.
The worst disadvantage is: the emission of waste water. Because it needs the condensed water
to take the impurity out, which will cause the condensed water and drain the waste water. The
crossing flow filter must cause the waste water for the structure character of the filter
membrane .Once we stop the emission of the waste water, much impurity will leave on the
surface of the membrane so that the filter membrane will be covered with the impurity and lose
the filtering function.
It is the most common filter with wide range of use, such as machinery filter, quartz sand filter,
active carbon filter, manganese sand filter. ion exchanging filter , micro-filter , ultra-filtration and
bag filter .
In the 17 centaury, people discovered the osmosis phenomenon .At that time if people put the
distilled water into the bladder of the pig and then dipped it into the salty water, the distilled
water would permeate the pig bladder and enter the salty water, and also the density would
decease. The phenomenon that solvent passes the semi-trans-membrane and permeates from
the low part to the high one is called osmosis. If we do the experiment with salty solvent and
water, the water molecule will pass the semi-trans-membrane to permeate from the low TDS to
the high TDS. The reverse osmosis phenomenon refers to the solvent pass the
semi-trans-membrane and permeates from the high density t to the low one that is water
molecule permeates from the high TDS to the low part, which is equal to extract the fresh water
from the salty water. Two conditions must be needed to produce the reverse osmosis
phenomenon that is the input of outer energy and proper semi-trans membrane.
It is impossible that reverse osmosis phenomenon will happen without outer force .we will take
salty water for example to compare the phenomenon between osmosis and reverse osmosis:
Now the permeated pressure is larger than the pressure drop of the two sides of the
semi-trans-membrane .With the force of the permeated pressure, the water molecule
continuously passes the semi-trans membrane to enter the higher salty density to make the
liquid of the side higher and higher, and the salt keeps moving from the side of high density to
that of low one.
As the water molecule will move to the high salty density with the force of permeated pressure
to make the liquid surface higher and higher, the pressure drop of the two sides is larger and
larger. It will balance when the pressure drop is equal to the permeated pressure.
Now the water molecule will permeate to the two sides together .Although the permeating speed
is the same, the salt keeps moving from the high density to the low one.
If the liquid in the high density is given the outer force, which is larger than permeated pressure,
the water molecule will permeate reversely with the outer force, that is, to permeate from the
high density to the low one, which is called reverse osmosis. As the water molecule continuously
permeates to the other side, the density of high salty side will become higher and higher till the
permeated pressure is equal to the outer force. Then the osmosis phenomenon becomes
balanced again.
The salt keeps moving from the side of high density to that of low one.
There mainly are several philosophies about the process of the reverse osmosis in the theory
and model
Phenomenon model
Solution-diffusion model
Priority absorption-thin hole model
The H key theory
None of the theory can explain the theory of the RO phenomenon perfectly .Although the quality
of the RO phenomenon isn’t discovered ,people can make good use of it to produce the RO
membrane to gain the benefit .
Since the 20th century, People began to study electro dialysis, porous membrane, the early ultra
filtration, reverse osmosis; research potential is electro dialysis membrane electrode and the
foundation, and the early artificial kidney research. Since the 1950s, the study of film, electro
dialysis, porous and blood dialysis process, such as separation technology has begun to enter
industrial applications.
The 1960s, the development of the high rate of desalination, water penetration capability of
high-asymmetric cellulose acetate of reverse osmosis membranes, reverse osmosis technology
into industrial applications, to the 1980s, aromatic polyamide reverse osmosis membrane there.
There are two major reverse osmosis membrane material, cellulose acetate and aromatic
polyamide, the early reverse osmosis membranes are cellulose acetate, until the 1970s, reverse
osmosis polyamide successfully developed and gradually replace the acetate Cellulose film to
become the market mainstream products. The following table is two different comparative
advantages of film material:
Endurance Temp.
Material Rejection Production Flow Power pH Range
of chlorine Range
CA Low Low High Good 5~35℃ 1~12
PA High High Low Poor 5~45℃ 3~12
The main structure of reverse osmosis membranes are hollow fiber and composite film two:
Common use of reverse osmosis membranes of the non-symmetrical structure, from three
different material from the polymer composite materials, the bottom thickness of 80 microns is
about the non-woven fabrics, the middle is about the thickness of 40 microns, from the
transformation polysulfone 10% of the porous support layer, the top are from chloride and
stupid amine polymer from the interface of the desalination of polyamide, such multi-storey
composite structure with good compression, water production, desalination rate characteristics.
Reverse osmosis membrane component of the removal of different substances are also different,
the whole of the following:
z The removal rate of polyvalent higher than monovalent ion;
z The removal rate of complex higher than simple ion;
z Organic matter molecular weight below 100 is lower removal;
z The nitrogen group and its compounds the removal rate lower;
NaF 42 99 NaCN 49 97
NaCl 58 99 SiO2 60 98
NaHCO3 84 99 NaNO3 85 97
Methanol 32 30 Alcohol 46 70
Isopropanol 60 90 Carbamide 60 70
Lactic acid
90 99 Dextrose 180 98
pH5
Sucrose 342 99 Insecticide / >99
Desalination rate is divided into the apparent desalination rate and the actual rate of
desalination.
Permeate TDS
Apparent Rejection =(1- )×100%
Feed TDS
2×Permeate TDS
Actual Rejection=(1- )×100%
(Feed TDS + Concentrated TDS)× A
the formula did not consider surface water enrichment and the concentration polarization
pHenomenon The apparent desalination rate was slightly lower than the actual rate of
desalination.
Throughput refers to the unit area of reverse osmosis membrane in the unit of time can produce
the volume of water that the number, the unit normally used GFD (gallons / square feet × days)
and m3/m2 × D (cu m / m 2 × days ).
Film production components of water flux × = effective membrane area
4.5.3 Recovery
Recovery is that reverse osmosis membrane components or reverse osmosis system energy
efficiency a key indicator used to enter the water in the membrane component of the number of
products into the water, their formula is as follows:
Recovery = × 100%
Product water flow
Recovery = × 100%
Inlet water flow
As shown below, with the water temperature rises, decreasing the viscosity of water molecules,
and the speed increase, reverse osmosis membranes will increase water production,
desalination rate declined slightly. Under normal circumstances, reverse osmosis membrane of
the water temperature range is 5 ~ 45 ℃, the low temperature system would increase the risk
of freezing ice and water production is too low, relatively poor economic performance, it is not
recommended in water temperature below 5 ℃ when activated reverse osmosis system, while
more than 45 ℃, reverse osmosis membrane of the heavy water production, but also the risk of
pollution.
Desalination rate affected by temperature changes, due to temperature rise, increasing at a rate
of molecular movement, there will be more soluble ions penetrate into the salt water,
desalination rate of decline. Under normal circumstances, changes in the rate of desalination is
generally not more than 2%.
The flow of reverse osmosis membranes strongly influenced by water temperature, according to
industry practice, the film component of the flow is in accordance with the water temperature at
25 ℃ test drawn, and each temperature dropped 1 ℃, membrane components of the water
production will drop 3 to 3.5 percent . Due to the increasing temperature, the viscosity of water
molecules and reduce the speed increase, making it easier for water molecules through the
membrane.
Take LP4040 film components as an example, the table below is different when the water
temperature of the water production changes:
Temp(℃) 5 10 15 20 25 30 35
Pressure(Psi) 150 150 150 150 150 150 150
Flow(L/min) 3.2 4.0 4.8 5.8 7.0 8.0 9.1
Flow(GPD) 1250 1520 1850 2240 2700 3070 3500
Film on different components of production water temperature at 25 ℃ and the standard flow
calculation, please refer to the "membrane component temperature ---- flow correction factor"
section.
Reverse osmosis system is the water pressure affected the performance of the main parameters
of reverse osmosis membranes and water desalination production rate will be increased with the
increasing pressure, especially the increase in water production is particularly obvious.
Under normal circumstances, after the completion of the production of reverse osmosis
membranes, effective membrane area and patch on the permeability coefficient have been
identified, therefore, in other water conditions remain unchanged, the middle membrane
components only by water pressure on the net impact of pressure on the net With pump
pressure, so membrane components of water production and increased water pressure is linear
relationship.
Desalination of water pressure also by the impact of the one hand, reverse osmosis membrane
permeability of salt is a constant rate, the formula is as follows:
Salt both sides of membrane permeability = poor concentration × temperature correction factor
B × × patch of salt infiltration coefficient of effective membrane area
On the other hand, the increase in pressure caused by increasing water production, thereby
diluting the salt through the so-reduced water salinity and improve the rate of desalination. Take
LP4040 film components as an example, the table below is different under the pressure of the
water production and water desalination:
Water salinity will affect the performance of membrane components. As water salinity different,
the osmotic pressure is also different, indirect impact on the net pressure on the system, a direct
result of decreased water production, but compared to the pressure on the impact of water
production, water salinity of the water-less . In addition to seawater desalination membrane,
under normal circumstances water salinity increases every 200 mg / L, water production
declined about 1 percent;
Water salinity increases will make the reverse osmosis salt on both sides of the poor increased,
and will further increase the concentration polarization pHenomenon, made up of salt through,
desalination rate has dropped. Under normal conditions, water salinity to double production to
increase to the water salinity of the original concentration of 2.5 to 3 times the rate of
desalination by about 0.2 to 0.5 percent.
Take LP4040 element as an example, the table below is different when the middle class into the
water salinity changes:
Influent pH on the impact of reverse osmosis membranes in the main performance and capacity
for desalination of water on the TDS. Nature of a carbon dioxide dissolved in water are, dissolved
in the water after the reaction will occur as follows:
Acidic conditions, H + increase, the reaction to the left, the water main to the gas form of carbon
dioxide dissolved in water, basic conditions, the right response, mainly carbon dioxide carbonate
ions in the form of the neutral conditions, Both gaseous carbon dioxide, there will be bicarbonate
ions and carbonate ions exist. pH value of 4.4 or lower, with a presence of carbon dioxide; pH
value of 8.2, there is no carbon dioxide, all of bicarbonate. The pH value of 8.2 to 9.6, carbonate
and bicarbonate solution mutual balance. pH value of 9.6, there is no carbon dioxide and
bicarbonate, all of the carbonate alkalinity.
The characteristics of reverse osmosis membranes, for ions, and organic particles in the high
removal rate, but the gas is almost no removal rate, and plasma, the ion complex, high-priced
than the removal of the ion to In addition to high rates. Therefore, pH value is low, the water
through reverse osmosis membrane of carbon dioxide into the water production, neutral or
alkaline conditions, the water of carbon dioxide into bicarbonate ions and carbonate ions, which
in this reverse osmosis membranes The removal of two-high, resulting in the removal of reverse
osmosis membranes with the increase of pH value increased, but the pH value of more than 9.5,
the hydrogen and oxygen ions in water will increase significantly, reverse osmosis membranes
Removal rate will drop slightly.
In order to increase the rate of reverse osmosis desalination membrane, can be an appropriate
increase the pH value of water, but attention should be paid to prevent the pH value increased
after scaling a tendency to rise. For example, in between the two reverse osmosis water
production increased level of pH, can effectively raise the reverse osmosis desalination
second-class rate
4.6.5 Recovery
Acidic conditions, H + increase, the reaction to the left, the water main to the gas form of carbon
dioxide dissolved in water, basic conditions, the right response, mainly carbon dioxide carbonate
ions in the form of the neutral conditions, Both gaseous carbon dioxide, there will be bicarbonate
ions and carbonate ions exist. pH value of 4.4 or lower, with a presence of carbon dioxide; pH
value of 8.2, there is no carbon dioxide, all of bicarbonate. The pH value of 8.2 to 9.6, carbonate
and bicarbonate solution mutual balance. pH value of 9.6, there is no carbon dioxide and
bicarbonate, all of the carbonate alkalinity.
The characteristics of reverse osmosis membranes, for ions, and organic particles in the high
removal rate, but the gas is almost no removal rate, and plasma, the ion complex, high-priced
than the removal of the ion to In addition to high rates. Therefore, pH value is low, the water
through reverse osmosis membrane of carbon dioxide into the water production, neutral or
alkaline conditions, the water of carbon dioxide into bicarbonate ions and carbonate ions, which
in this reverse osmosis membranes The removal of two-high, resulting in the recovery of reverse
osmosis membranes also by changing the water and dense water salinity indirectly affect the
middle membrane components of the water and desalination. As the concentration of reverse
osmosis membranes, the higher recovery rate, concentrated the higher water salinity, the
greater osmotic pressure, and water desalination production rate will decline.
The following table recovery rate for different conditions, water salinity and concentration of
water salinity values:
Membrane component recovery (or system recovery) will directly affect the average water
salinity, thus affecting the pressure and salt through the net amount, resulting in water
production and capacity for water TDS changes. The higher recovery rate, the smaller the
production of water, producing water TDS greater value.
Note: This sections of the film icon that only components of changing trends and does not
represent the actual use of specific data
1.Surface water
Surface water is rain and snow, rivers, lakes, reservoirs and marine water, these are the
characteristics of the water with them is closely related to the formation process
3. River water
River water through surface runoff from the pool, it contacts the weathering of rocks and soil,
into some salts, the salt content higher than rain and snow. China's river water, the average salt
concentration is 166 mg/L. Because of its river water also washed away, with a large number of
volumes of silt, clay and other suspended material, the water contains high suspended solids
and colloid, high water turbidity. River water by the geographical environment and the impact of
climate conditions vary with the seasons and fluctuations, but also the hydrological and
meteorological conditions of the impact of changes in water easily, unstable and more
vulnerable to agricultural and industrial wastewater, sewage and other pollution.
5. Ocean water
Ocean water evaporation of the annual 40 × 10000 km 3, from the dissolved salts into the river
each year are 3.85 × 10 (9) 1986, and accumulated over many years of evaporation, the salt
content in sea water concentrations as high as about 35,000 mg per liter . Sea salts in the weight
ratio of basic stability, a high chloride content, chloride ion of about 55 percent of the total,
followed by sodium ions, about 30 percent, and other salts is mainly potassium ions, calcium,
Sulfate ions, re-carbonate ions, ion bromine, there are trace elements, such as dissolved gases
and organic matter. Ocean water only in exceptional circumstances were not used as domestic
water sources of water
6.Groundwater
Groundwater is rainwater through the soil strata and the penetration of mobile formed by water,
in its lengthy process and extensive contacts, into more soluble minerals, thus the hardness of
underground water, salt content, usually higher than that of iron High groundwater. On the
other hand, groundwater and soil formation due to the layers of filtering, colloidal suspension of
the content and very little water clear and transparent, low turbidity. As groundwater dissolved
oxygen is very low, not even bacteria can not survive. The price of ferrous ions and stability can
exist in water, groundwater and air contacts when the price of iron oxide into a quick three
highest bidders iron, and forming a flock of precipitation.
Overall, the quality of groundwater is superior to surface water quality, as long as the
appropriate treatment can be as drinking water, but with the ground pollutants and increase air
pollution, will be on the shallow groundwater pollution, should be in use Attention.
7.Tap water
Tap water is purified through the water treatment plants, produced after disinfection of drinking
water in line with national standards for people's lives, production use of water. It is mainly
through the Waterworks water pumping stations and underground water from rivers and lakes
(that is, these two types of water), and the precipitation, disinfection and filtration process, with
final adoption of pump stations transported to various users. Pump through the water by
pipeline transmission and distribution of water supply users. Must meet the national drinking
water health standards.
Conductivity of the water soluble ions that are conductive capability of indicators, in units of
micro-Siemens / cm (us / cm), it is relatively intuitive reaction of the ion content in the water;
TDS (total dissolved solids) is filtered and colloidal suspension of evaporation and water out
all the remaining minerals, in units of mg / L; it is relatively intuitive reaction of the salinity of the
water; water through the TDS Conductivity converted out, a rough method is: the reference to
sodium chloride solution, every 1 mg / L TDS value of the corresponding 2 us / cm conductivity;
BOD (biological oxygen demand) that the water degradable organic matter content of
oxygen to the MG / L value of units;
TOC (TOC) is the carbon MG / L value of unit testing and integration of organic carbon in the
total; organic matter does not include carbon dioxide, bicarbonate and carbonate, carbon
compounds. The typical natural organic matter, including negatively charged colloidal, SS,
tannic acid, lignin, the decay of plant-generated water-soluble humus acid mixture, decomposed
plant generated organic acid, and so on. RO systems can effectively remove the organic matter,
the molecular weight of more than 200 organic compounds can be removed more than 99
percent, less than 200 according to the molecular weight, shape, charged different, their
removal is also different;
Alkalinity mainly refers to carbon dioxide, bicarbonate, carbonate and hydroxides. Alkalinity
(especially for the boiler water chemistry) can be expressed as P M alkalinity and alkalinity. M
alkalinity refers to the calcium carbonate of Mg / L values that the total alkalinity of the water; P
alkalinity measurements bicarbonate, carbonate hydroxide and the volume;
Turbidity of the water difficult to precipitate the tiny colloidal suspension of testing indicators to
NTU as a unit; RO membrane components in the regular operating limits: the largest water
turbidity to 1.0 NTU.
SDI (pollution index) is a membrane system for testing the water to the suspension of
colloidal particles with the blockage of the 0.45-micron filter paper aperture speed of test data.
RO typical components of the use of the water requirements of the 15-minute maximum value of
4.0 SDI if the blockage 而使 SDI test because only five or 10 minutes, that water pollution of the
RO system will be very serious. Slightly treatment or no pretreatment circumstances, deep well
water the SDI value is equal to or less than 3, turbidity is less than 1. For surface water, to meet
the requirements of SDI and turbidity, to be used to remove pre-treatment And the suspension
of colloidal particles.
Brackish water, RO areas in the bitter and salty water can be defined as: TDS value in the salt
content in the low-level (up to 10000-15000 Mg / L), and can use the largest water pressure of
600 psi RO membrane to bitter and salty water The reverse osmosis water treatment
3. Excluded pool filter the air pressure. According to the type of filter, the water supply valve to
open in the circumstances, or open at the top of the filter exhaust valve, or screw-thread filter
jacket, full vent or exhaust valve closed after fastening the filter jacket thread ;
4. Using a scale of 500 ml graduated cylinder access filtering water through membranes to
measure the volume of water;
5. Full ball valve, measured from the valve full access to over 100 ml and 500 ml of water
samples and record the time required;
6. 5 minutes after the re-measurement collected 100 ml and 500 ml of water kind of time, 10
minutes and 15 minutes respectively after the same measurement;
7. If access 100 ml water sample the time required for more than 60 seconds, it means that
about 90% of the membrane filter area was blocked, this time has no longer need to carry out
experiments;
8. The end of the experiment and open the filter, will be the best preserved of the membrane,
and to prepare for future reference
5.1.3.3 Formula
SDI=P30/Tt=100×(1-Ti/Tf)/ Tt
SDI - pollution density index
P30 - In the water under the pressure of 30 psi plug the percentage of the membrane
Tt - The test of time, in units of minutes. Tt is usually for 15 minutes, but if within 15 minutes
that 75% of the membrane area was blocked on the need to shorten the test time
Tf - 15 minutes (or less) after the sampling time
Ti - The first time sampling
Description:
Access 500 ml water samples around the time required to access the necessary time to 100 ml of
water five times. If access for 500 ml
Time far greater than five times, in the calculation of SDI, access should be adopted by 100 ml of
time.
In order to accurately measure SDI value, P30 should not exceed 75 percent, if the P30 more
than 75 percent should be re-test in a relatively short period of time and access to Tf value.
5.1.4 RO pollutants
Film is being dealt with pollution from particulates in solution, colloidal particles or solute
interaction with the membrane, or because of the concentration polarization on the surface of
certain substances in concentrations exceeding its solubility caused by these substances in the
water channel, or membrane surface Hole absorption, sediment, causing water channels or
channel smaller or blockage of the phenomenon.
Types of pollutants
Different sources, different types of pollutants; different types of pollutants, nor the method of
cleaning up the same.
1. Suspended solids
Suspended solids commonly found in surface water, particle diameter> 1 µ m, such as sand,
mud Nien, SiO2 particles, water in the state can stop sediment down. It is very easy to set up a
system of reverse osmosis filter or fine sand filter medium filtered, after pretreatment, must
meet the following indicators: turbidity <1 NTU, 15 分钟 SDI value of <5.
2. Colloidal pollutants
Colloid of commonly found in surface water, mainly aluminum type of clay, such as silicate
compounds, Fe-Al oxides, sulfides, tannic acid, humus, such colloidal particle size in the range
0.3-1.0 µ m, with negative charge , Single-use filters can not be removed, the use of pool, filter
or a DC coagulation ways in which colloidal particles increased to 10-20 µ m filter removed.
When the SS, colloidal too much content, the need to unite, to clarify, filters.
3. Organic pollution
Organic pollution of the film is a complex, the main type of humic acid substances, clarification
and cohesion are only activated carbon filters to remove part of organic matter; ultrafiltration
can also be used to remove organic matter.
4. Biological pollution
Such pollutants usually bacteria, biofilm, algae and fungi. Bacteria will be cellulose acetate for
food and thus vulnerable to bacterial acetate film erosion of the membrane, is not susceptible to
bacteria against, but the bacteria will cause mucosal membranes of the sewage blocked. A
reverse osmosis system design technology, to control biological activity, the bacterial content of
water in the 10000 cfu / cm above, we must consider measures to remove.
General pollution from the thick film components of the net at the water surface sampling and
analysis of pollutants ingredients. Dense network of water at low velocity areas most vulnerable
to larger deposition of pollutants, including CaCO3 grain, bio-film, mesh organic film,
particulates, colloids and coagulant. These pollutants will lead to increased pressure on the
system and reduce water production. Film on the surface of the pollutants are usually close
attachment to the silicate compounds, sulphate, polymers, organic compounds, metal oxides
and hydroxides, and other pollutants. These lead to blocked sewage water production and
reduce the rate of decline in the rate of desalination
All the water they contained a certain concentration of suspended solids and dissolved
substances. Suspensions are the main mineral, colloidal and micro-organisms, algae and other
biological particles. Soluble material is soluble salt (such as chloride) and the insoluble salts
(such as carbonate, sulfate and silicate) metal oxide, acid and alkali, and so on. In the reverse
osmosis process, the reduction in the volume of water, suspended particles and the
concentration of dissolved substances on the increase. Suspended particles will be deposited in
the film, plugged into the flow, and increase frictional resistance (pressure drop).
Insoluble salt in more than a total saturation limit, from the thick sediment from the water,
formed on the surface scaling, reducing the RO membrane flux, increasing pressure on the
operation of the pressure drop, and lead to deterioration of water quality, in this surface On the
formation of sediment into the phenomenon known as fouling, fouling system performance is
the result of the deterioration. The need of raw water into the system prior to the reverse
osmosis membrane pretreatment, reverse osmosis membranes to remove possible pollution of
suspended solids, dissolved organic matter and excessive salt insoluble components, reducing
fouling tendencies. Pretreatment of the water objective is to improve water quality so that the
RO membrane access to reliable guarantee for the operation.
Pretreatment of the raw water to reflect the effect of TSS, TOC, COD, BOD, LSI and iron,
manganese, aluminum, silicon, barium, strontium and other pollutants reduce the absolute
value of the water quality objectives. Characterization fouling tendency another important
indicator is the quality of SDI. In addition to the above through the pretreatment indicators of
reverse osmosis membranes to reduce the water requirements of the context, there are
important point is to minimize the SDI, the ideal SDI (15 minutes) is less than 3.
Suitable for the programmed depends on the pretreatment water, raw water composition and
application conditions, and mainly depends on the raw water sources, such as the well water,
surface water and municipal wastewater to be treated differently. Under normal conditions,
water quality and stability, the possibility of low-pollution, just a simple pretreatment, such as
acid or set up and increase inhibitors and 5 µ m filter to security. On the contrary, surface water
is a directly affected by the seasonal effects of water; microorganisms and colloid have occurred
both the possibility of a high degree of pollution. The pretreatment than well water complex and
require other steps, including the pretreatment chlorine disinfection, Flocculation / condensate
help to clarify, multi-media filter, dechlorination, and acid or increase scale agent. Industrial and
municipal wastewater containing more complex organic and inorganic elements, some
organisms may seriously affect RO membrane; caused a serious decline in water production or
degradation of the membrane, thus there must be more comprehensive design of the
pretreatment.
Once identified by the optional water sources, must conduct a comprehensive and accurate
analysis of all the raw water. It is establish appropriate programmers and RO pretreatment
system are the basis for the design of the most critical.
A water sample performance of a specific water quality in a given time. Therefore, through a
water sample and can not fully understand the entire operation of the time, can affect the
operation of the system trends or changes. In addition to a number of water samples collected
to get a better understanding of water resources, but also the reasons for the changes in water
quality analysis. Understanding of an existing or potential sources of water of the correct
distribution profile is a reverse osmosis system design and operation of the essential elements.
A suitable container to collect samples of water to ensure accurate analysis of the key. Must be
considered because of pollution caused by containers. Regular use of plastic or glass containers
with samples. Sample container must be cleaned before use, so as to avoid contamination
samples. Sulfuric acid or bottles dichromate cleaning solution, to avoid this solution on the bottle
of organic pollution particularly effective. Plastic containers can be used laboratory or scrub with
detergent concentrated hydrochloric acid rinse, and then spent deionizer water to wash. The
containers used for sampling the need for disinfection.
Brackish water treatment system is the main constraints of nature, namely, calcium carbonate or
calcium sulfate compounds because of water constantly being concentrated, when more than its
solubility plot, the film will surface in precipitation, or scaling; industrial or municipal Wastewater
treatment system there are a lot organics, inorganic, viruses and microorganisms such as
bacteria and algae, such constraints is not just its physical and chemical factors, microbial index,
a film with a pro-reaction and the organic carbon or biological degradable Dissolved organic
carbon. Brackish water in a very wide scope, in order to put a better process design, the need for
full analysis of water quality.
Cation Anion
Item Unit Testing value Item Unit Testing value
Na+(Sodium) ppm CO3 2-(Carbonate ion) ppm
K+(Potassium) ppm HCO3 -(Bicarbonate ion) ppm
Ca2+(Calcium) ppm SO4 2-(Sulfate) ppm
Mg2+(Magnesium) ppm Cl-(Chloride) ppm
Total Fe(Iron) ppm NO3 -(Nitrate) ppm
Mn2+(Manganese) ppm F -(Flouride) ppm
Ba2+(Barium) ppm PO4 3-(Phosphate) ppm
Sr2+(Strontium) ppm
Cu2+(Copper) ppm
Al3+(Aluminun) ppm
Zn2+(Zinc) ppm
Others
Item Unit Testing value Item Unit Testing value
PH Hardness
DDS Alkalinity
TDS H2S(Sulfide)
Turbidity Colloid
SiO2(Silica)
Chroma Active
Total plate count CO2(Carbondioxide)
COD Free chlorine(FCR)
TOC BOD
The integrated evaluation of water quality:
Common seal
Date
The traditional reverse osmosis system design, common aperture 5 µ m micro-filter (commonly
known as 5 µ filter), as a pretreatment system in the final steps in the reverse osmosis unit from
the security role, it also called the security filter. With the rise of ultra filtration technology, the
pretreatment system in the last processes tends to UF. Ultra filtration water SDI <2, the water
quality is better than micro-filter.
Microorganisms entering a RO system find a large membrane surface where dissolved nutrients
from the water are enriched due to concentration polarization, thus creating an ideal
environment for the formation of a biological fouling of the membranes may seriously pressure
from feed to concentrate, finally leading to telescoping and mechanical damage of in membrane
element, and a decline in membrane flux. Sometimes, biogouling develops even on the
permeate side, thus contaminating the product water.
2, Activated carbon adsorption. Organic matter in water with activated carbon adsorption,
reducing microbial source of nutrition. However, the activated carbon adsorption organic
nutritional adequacy has become an ideal breeding places of microorganisms.
3. Sterilization. Microbial control with fungicides very effective, it is the most commonly used
method, but also control of anti-microbial systems the last barriers. Fungicides commonly used
as a capacity of the compounds, such as Cl2, NaClO, H2O2, O3, and so on and KmnO4.
Fungicide-point increase as much as possible in the higher processes, so that the contact time is
sufficient so that the water entering the film installations completed before the disinfection
process.
4. Ultra filtration (UF)。UF can remove microorganisms and especially algae that are sometimes
very difficult to remove by standard techniques. The UF membranes should be made from a
chlorine-resistant material to withstand periodic treatment with biocides. UF membranes ,
however, do not remove the low molecular weight fractions of organic matter and other
compounds that are nutrients for microorganisms. Pretreatment with UF membranes helps to
retard and to control the onset of bio-fouling, but it is no safeguard by itself.
7, Regular sterilization. Even with these means of sterilization, a small amount of bacteria will
survive. Microbial breeding fast, so these bacteria survive in those who do not have the ability to
sterilization large number of breeding places again, there is a need for these places disinfected
regularly. For example, the box regularly to the Anti-Water chlorination.
Can be activated carbon adsorption many impurities in the water, with the exception of residual
chlorine, there are suspended solids, organic matter, such as oil.
For surface water, the chlorination, clarification, filtration, the water of iron and manganese
content in general is qualified; for groundwater, particularly of iron and manganese-rich
groundwater, should take measures to remove the iron-manganese. For example: aerated water,
iron generated Fe (OH) 3 precipitation, and then using contacts to get rid of filtration; increase
Na2SO3 remove dissolved oxygen, to prevent the oxidation of iron and manganese to maintain
the dissolved state
Due to water scarcity and environmental concern, adding a brine (RO concentrate) recovery
system to increase recovery has become more popular. To minimize precipitation and scaling, it
is important to establish well-designed scale control measures and avoid exceeding the solubility
limits of sparingly solute salts. In an RO/NF system, the most common sparingly soluble salts
encountered are CaSO4, CaCO3, and silica. Other salts creasing a potential scaling problem are
CaF2, BaSO4, SrSO4, and Ca3
(PO4)2. Solubility products of sparingly soluble inorganic compounds are listed in Table 5-1.
In order to prevent the membrane surface in inorganic salt scaling, should adopt the following
measures:
By adding H+ as acid, the equilibrium can be shifted to the left side to keep calcium carbonate
dissolved. Use food –grade quality acid.
Sulfuric acid is easier to handle and in many countries more readily available than hydrochloric
acid, however, additional sulfate is added to the feed stream, potentially causing sulfate scaling.
CaCO3 tends to dissolve in the concentrate stream rather than precipitate. This tendency can be
expressed by the Langelier Saturation Index (LSI) for brackish waters ad the Siff & Davis
Stability Index(S&DSI) for sea waters. At the PH of saturation (PH5), the water is in equilibrium
with CaCO3.
To control calcium carbonate scaling by acid addition lone, the LSI or S&DSI in the concentrate
stream must be negative. Acid addition is useful to control carbonate scale only.
SHMP is inexpensive but unstable compared to polymeric organic scale inhibitors. Minor amount
adsorb to the surface of microcrystal, preventing further growth and precipitation of the crystals.
Food-grade quality SHMP should be used. Care must be taken to avoid hydrolysis of SHMP in the
dosing feed tank. Hydrolysis will not only decrease the case inhibition efficiency, but also create
a calcium phosphate scaling risk. Therefore, SHMP is generally not recommended.
Organophosphonates are more effective and stable than SHMP. They act as antifoulants for
insoluble aluminum and iron, keeping them is solution
can still soften the water by adding a certain amount NaOH (until pH8.2) to Will be residual CO2
into the water re-carbonate, to be re-carbonate film by the removal, reverse osmosis water
conductivity lower middle class.
If timely regeneration, the use of strong acid cation exchange for softening the tree that is very
effective and insurance scale, but mainly for small and medium-sized bitter and salty water
system. The main shortcoming of this process is very high NaCl consumption, the existence of
environmental problems, not economic.
In most cases, there does not want to yield water CO2, then can the original water or
water-degassing to achieve, but when the existence of biological contamination when the
suspect (surface water, high or high TOC colony total), water from the middle Gas more
appropriate. Membrane system in the higher CO2 concentration can inhibit the growth of
bacteria, when the hope that the system is running at a high rate of desalination, water use
degassing more appropriate, the removal of CO2 will cause the pH increased influent pH> 6, the
membrane system Removal of water than the rate of pH <5 should be high.
If you need completely softened, and can be created strong acid-sodium exchange resin process,
or even weak acid resin can be placed on the same exchange column, so the consumption of
renewable still than the separate use of strong acid resin at the low, but a higher initial
investment, a Only when the combination of large capacity when meaningful.
Another way to overcome this shortcoming in the alkalinity of the water from Canada inhibitors,
although so far, people used on their own weak acid-base from that tree, also unprecedented in
scale, but we still strongly recommend You calculate the solubility of salt residue insoluble, and
take corresponding measures.
Due to the saturation level of resin in the run-time changes, the weak acid from alkali treatment
of effluents from its pH value will be 3.5 to 6.5 within the framework of changes, such cyclical
changes in pH, the rate of the desalination plant becomes very difficult to control. When the pH
<4.2, inorganic acid will be covered by the film, may increase the production of water TDS,
therefore, we recommend that users of a parallel increase in weak acid to soften, control at
different times for regeneration, in order to deal with the water evenly weak acid pH, to prevent
other very The low pH of the water is removal of CO2 by adding NaOH or weak acid to soften
after adjusting the pH of the water.
Solubility also depend on temperature and pH, the water containing silicon, raising the
temperature and pH can increase its solubility, silica is often the only consideration for the need
to adjust these operating parameters to prevent scaling reasons, because the regulation of
these parameters, there are some Shortcomings, such as energy consumption or other
high-scaling of risk (such as high pH of precipitation-prone CaCO3).
For small systems, the low recovery rate and choice of preventive cleaning mode of operation is
to control the scaling one of the most convenient means
LSIC Regulation
Most natural water without treatment, LSIC will be positive, in order to prevent CaCO3 scale,
unless the water system in the film adding inhibitors on the front or take preventive measures to
clean, or else the need to ensure LSIC was negative.
Most of the high salinity of natural water without treatment, S & DSIC is generally positive, in
order to prevent CaCO3 scale, it is necessary to increase the S & DSIC acid into a negative, if by
adding inhibitors to prevent precipitation of CaCO3, S & DSIC value for Positive, the maximum
allowed S & DSIC value and scale of the required dosage, please refer inhibitors manufacturer's
technological information.
Most natural water, the barium content will lead to concentration of barium sulfate in water
sedimentation, the limit concentration of barium in brackish water is less than 5µg/L, when
adding the current face of sulphuric acid, it should be less than 2µg/L.
Preventive measures and preventive measures calcium sulfate the same
The process of silicon scale formation in the Concentrated water is different from the feed water,
because the pH Value of the concentrated water are changing as the increased concentration of
SiO2, so the calculation of SiO2 scale should be according to the feed water quality analysis and
reverse osmosis operating parameters.
If a certain amount of metal appears, such as Al3+, it might change the SiO2 solubility through the
formation of metal silicate. The existence of aluminum or iron in the water is the main reason of
silicon Scale formation. Therefore, if the existence of silicon, it should ensure that there is no
aluminum or iron, and it’s better to use the 1 µ m security filter, meanwhile take the preventive
measures such as acid washing.
In order to increase the recovery rate, when taking the lime - Soda softening pretreatment, some
amount of aluminum or magnesium should be added into the water to reduce the solubility of SiO2,
meanwhile, the effective operation of the softening process is very important to prevent the
appearance of insoluble metal silicate in the reverse osmosis system;
Because the pH value lower than 7the or higher than 7.8 can increase the solubility of silicon,
regarding to the prevention of silicon scale formation, add the acid or alkaline in the water can
increase the recycling rate, but in the high pH conditions, it should avoid the formation of CaCO3
sediment; regarding to the silica scale, when use a heat exchanger to increase water temperature, it
can significantly increase the water recycling rate, but the maximum temperature of the membrane
system allowable is 45 ℃; polymer resin of polypropylene acid inhibitors can be used to increase the
solubility of silica.
CaCO3
CaSO4
BaSO4
SrSO4
SiO2
CaF2
SDI
Fe
Al
Bacteriu
Oxidant
Organics
Add acid 1 1 1 1 1
Anti-scalelant 2 2 2 2 2 2
softening 2 2 2 2 2
Ion exchange 2 2 2 2 2
From base
Lime softening 1
Preventive 1 1 1 1 1 1 1 1 1 1 1
cleaning
Adjustment of 1 1 1 1 1 1 1 1 1 1 1 1
recovery
Multi-media filter 3 1 1 1
Oxidation - filter 1 2
Online flocculation 1 1 1
MF/ UF 2 2 2 2 2
Cartridge filtration 3 1 1
chlorination 1 2
Remove-Chlorine 2
Sterilization 2
GAC Filtration 2 2
Notes: 1. Likely to be effective, 2. Very effective, 3. Combination of several methods can be used
together, blank is void.
Reverse osmosis system design is based on the raw data such as the feed water quality, the
requirement of output water quality and amount, the requirement of water discharge amount
and the venue situation, choose a reasonable water treatment process, choose the appropriate
membrane components, determine the number of membrane elements and the arrangement of
their components, use high-pressure pump, and so on; reduce the operating pressure and the
costs of membrane components, and increase the recovery rate as much as possible, reduce
contamination speed of the system so as to extend its cleaning cycle, reduce the frequency of
cleaning system, increase its the long-term stability, reduce the maintenance costs of cleaning ,
so the design work is an important part of the water treatment system construction, it often
plays a decisive role in controlling of the quality, investment and water producing cost.
The feed water quality is an important basis for the reverse osmosis system design, it determine
the type of membrane and pre-treatment system required by the reverse osmosis system; in
reverse osmosis system design process, we not only need the right analysis data of feed water
quality, but also need to select the proper model of reverse osmosis desalination membrane,
design the arrangement of components and after-treatment system according to the changing
trend data of the source water quality.
The basic processes of reverse osmosis system include three stages: pretreatment, reverse
osmosis and post-treatment.
The after-treatment processes need to be set based on their own need for use, such as remove
CO2, ion-exchange desalination, electrode ionization desalting (EDI), and so on.
In each pressure container, which can install a membrane component, and also can install
several membrane components, usually, each pressure container can be installed in one to
seven membrane components.
In choosing the pressure specifications of pressure container, it should meet the water supply
pressure requirements which come from systematic calculation, and take the pressure that need
to be increased due to the contamination from the operating process into account.
The pressure vessel’s material has two kinds: one is made of stainless steel and another one is
made of glass steel (FRP), you should try to choose the FRP membrane housing, especially the
8-inch element. Because there are many differences in precision of the Stainless steel pressure
container processing, so it often leak slightly, and lead to hydropower higher. In addition, the
stainless steel housing has many defects as well, first, the concentricity can’t up to the
requirement; Second, if the water content of chlorine root is too high, it is likely to cause the
pitting perforated, and lead to the leakage of membrane housing.
When use of the longer stainless steel membrane tube, you must ensure the fulcrum distribute
evenly, and ensure the fulcrum‘s same level and coaxial, avoid the bending of the membrane
tube; if there are some incorrect in welding the interface of the inner membrane tube, it always
has a flow accompanied, even the V-shaped ring emerge phenomenon will appear, in this time,
place the seam side down will be better. Regarding to the lubricant choosing, not only need to
ensure no contamination to the membrane components, but also should differentiate it
according to the V-ring edge, the thinner edge the better sealed, but if the membrane tube’s
round is not perfect(vertical diameter larger than the level) ,the welding interface isn’t handled
properly (weld seam upward),it maybe cause the V-ring prone to come out; if the edge thicker,
using of the glycerin and other water-soluble lubricant to seal is not very well, in some
circumstances (such as treatment of wastewater),it will speed up the seal ring’s aging rate, if the
water temperature is lower, you can smear a small amount of Vaseline Medical as well; generally,
the above-mentioned problems arise less in use of glass steel membrane tube.
The number of components in each pressure container is directly proportional to the system
recovery. Typically, single-membrane component’s recovery rate is in the range of 8% to 15%,
6 series-one sector’ system-recovery rate will be up to 50 percent, two sector’s system recovery
rate maybe up to about 75%, the three sector’s system recovery will up to 85%, as the following
table:
The number of series The sector number of 6
System recovery (%)
components including pressure Vessel
40~60 6 1
70~80 12 2
85~90 18 3
In general, choosing the membrane elements which the diameter is less than 2.5 inch if the
water output is lower than 0.2 m3 / h; choosing the 4 inch membrane elements if the water
output is lower than 3.0 m3 / h; choosing the 8 inch membrane elements if the water output is
higher than 3m3 / h (if the recovery rate is too low, you can choose the 4 in membrane
elements).
Determine the booster pump models by the final inlet water flow which is calculated according to
different characteristics of inlet water that choose a suitable water output and the recovery that
the system required.
The following table is the range of water output when the membrane elements under different
feed water conditions:
SDI<1 SDI<3 SDI<3 SDI<5 SDI<3 SDI<3
Type of feed water RO water Deep well Feed The surface Ocean Waste
output water water water water water
The flow rate of
30 25 20 18 15 15
water output (GFD)
The max recovery of
30 20 20 15 10 10
the elements
2540 elements 840 700 560 504 420 420
G
4040 elements 2400 2000 1600 1440 1200 1200
P
8365 elements 10950 9125 7200 6570 5500 5500
D
8400 elements 12000 10000 8000 7200 6000 6000
At the same time, in order to prevent excessive water inlet which may cause the Pressure
difference’s highly increase and lead to the "telescope phenomenon", so we have developed the
max inlet water flow according to different sizes of the membrane elements; in order to ensure
the low recovery rate of the membrane, we must limit the minimum flow of the concentration
water, the scale appears easily if the system‘s flow lower than the minimum concentration water
flow. The following table is the recommended maximum and minimum concentration water flow
of 2.5-inch, 4-inch and 8-inch membrane elements:
6.2.4.5 The element which have the same arrangement form a section.
The choosing and arranging of the membrane should not only comply with the design guidelines
of the suppliers, but also take the quality of source water, the water output requirements of the
users and the recovery rate and other factors into account
This form is a multi-stage concentrated system, the first section’s concentrated water as the
second section’s inlet water, and the second section’s concentrated water will be as the next
section’s inlet water, at this time, the water through every section will directly outflow, so as the
section increase, the recovery rate will increase as well. The flow of the Concentrated water will
decrease as the section increase, in order to keep the same flow speed of the every section of
membrane surface, we can gradually reduce the number of parallel membrane elements, and
ensure the same inlet water flow into the every elements, this is the common arrangement in
water treatment, this process applies to the large needed and higher recovery occasion, and
widely used in the industrial desalination application.
Concentrated
Feed
Permeate
The typical ratio is 2:1 (ratio of the number of above to bellow containers).
2 Multi-pass arrangement
Multi-pass reverse osmosis system is that the RO water output from the first pass as the water supply
of the second pass, the water output from the second stage as the water supply of the next stage, It
will produce high-purity fresh water by the several after-diluted.
Feed
Concentrated
Permeate
We called the water treatment process of one stage a reverse osmosis system as the
post-treatment, so the two stage reverse osmosis can belong to the range of reverse osmosis
post-treatment according to this concept.
The arrangement of reverse osmosis post-treatment technology is related not only to the user’s
requirement, but also to the fresh water salinity and the source water.
The RO system engineering is a combination of reverse osmosis equipment, tube, valves and
other devices, and form a complete sets of equipment. This equipment include not only the
reverse osmosis membrane elements, but also the pressure container, high-pressure pump,
security filters, metering pump inhibitors, valves, Instruments and other related equipment.
1. The RO framework
This is the reverse osmosis framework that assembling the reverse osmosis membrane elements,
pressure container, bulk piping, valves, locally-operated equipment and instrumentation, and
other equipment in a Sliding shelf. Generally, the framework is made up of A3 steel materials, its
surface has antirust Paint, and small devices also can use stainless steel materials.
Pressure container generally has 2-3 force strong points, so you should design the proper
reverse osmosis framework according to different sizes of the pressure tank. The framework
should also consider the earthquake intensity of the local scene.
1. Security filter
Security filter is placed on the inlet of the reverse osmosis system in order to prevent the
impurities from the pretreatment water and avoid the mechanical damage to high-pressure
pump and the membrane elements. Usually, security filters adopt the 5 µ m filter which material
is polyethylene or polypropylene. To avoid corrosion, filter body should be used stainless steel or
plastic materials.
Security filters not only can hold back the impurities particles, but also can remove the turbidity
and colloidal iron in a certain degree, reduce the SDI. In system design, security filters only can
prevent the impurities from pretreatment enter into the high-pressure pumps and reverse
osmosis membrane elements, and can’t be using in reducing the SDI or removing the
impurities , so the inlet water which will enter into security Filter must comply with the inlet
water standards of the membrane elements.
2. High-pressure pump
High-pressure pump is one of the core equipment of the reverse osmosis system. It supply the
inlet water with sufficient pressure in order to reduce the osmotic pressure and running
resistance to meet the flow volume of the device; and the flow volume should be established by
the calculation software.
High-pressure pump’s performance will have a direct impact on the desalination effect and the
economy, so you should choose the stable performance, highly efficient, noise small and
anti-wear high-pressure pump.
In order to ensure the safe operation of high-pressure pump, the water outlet should be
installed check valves, high and low voltage protection switch to prevent the high-pressure
continually running under the condition of water shortage.
3. Dosing pump
Pretreatment system needs the dosing pump to increase acid, inhibitors, fungicides, reducing
agent, pharmaceutical flocculent and so on. Generally, we use the piston pump and diaphragm
pump to meet the requirements of small flow, accurate measurement and adjustable flow.
Regardless of what form will be adopted, the flowing materials of the dosing pump must meet
the requirements to the corrosion of Tran-sportive media.
The water tubes and valves of the tank and low pressure switch parts should adopt the
corrosion-resistant PVC, U-PVC, ABS engineering plastics, glass or stainless steel materials.
The water tubes and valves of security filters, high pressure pumps and high pressure switch
parts should adopt different kinds of stainless steel according to the different salinity of source
water.
In addition, in the course of designing and producing, should prevent the formation of stagnant
water in the pipeline, stainless steel tubes should adopt the inert gas to protect the welding; you
should take the protective measures such as pickling or aestivation after the completion of pipe
manufacturing.
Even if the design and operation of reverse osmosis pretreatment system comply with the
standard, the membrane still can be contaminated, generally, you should clean reverse osmosis
equipment every six months or a year. Therefore, it should be considered to design a special
cleaning system.
2. Cleansing pump
the glass steel or stainless steel pumps should be available, the resistance range of the security
filters and reverse osmosis device and pipelines that the 扬程 can overcome is from 0.3 to 0.5
MPa.
3. Cleansing tube
the cleaning tube should adopt the Lining Plastic , ABS or UPVC pipe
4. Micro-pore filtration
Its function is to remove the machinery impurities from the cleaning process and the insoluble
falling off from the reverse osmosis device.
In order to ensure the reverse osmosis device’s operation and supervision normally, help us to
discover the problems and failures timely, so it should be installed the necessary instrument and
control equipment.
1. Pretreatment system
The most important monitoring project of pretreatment system (RO water supply) water output
is SDI. It is important parameters to judge whether the water quality is up to the standard.
Other monitoring projects include the amount of coagulant added, multi-media filters, activated
carbon filters different operating pressure, COD, the concentration of free chlorine, the amount
of anti-scale preparation added, the PH value of acid system, the pressure of security filter.
The flow volume includes reverse osmosis water inlet, condensed water, and the water output
flow, because the ratio of these flows determine the recovery rate of reverse osmosis equipment,
and the too high or too low recovery rate will have an adverse consequences on its
performance, so ensure the accuracy of the monitoring instrument is particularly important.
The pressure includes reverse osmosis inlet water, the inlet water of every section, condensed
water, and water output pressure and so on. Under constant pressure and temperature
condition, the decline of water output represent the membrane is being contaminated.
Conductivity includes reverse osmosis inlet and outlet water conductivity, the level of electrical
conductivity reflect the salinity level in the water, and reflect the change of output water quality.
Temperature, pressure, flow is three interrelated parameters, which are combined with the PH
value and the conductivity ,then you can detect whether the reverse osmosis system operate
normally through standardization, whether there is contamination or scale, whether need to
clean, so it is an important parameters to judge the operation of the reverse osmosis.
The reverse osmosis system usually adopts the way of auto-control, the content of which should
include the following aspects:
The control of booster pump. When the feed water pressure is lower or higher than the designed
value, the pump will stop automatically; concerning the Large-scale advanced reverse osmosis
system, the booster pump needs to adopt the frequency conversion control to control the
pump’s outlet water pressure by adjusting its operating frequency.
The procedures start and stop of the reverse osmosis equipment. The reverse osmosis
equipment should complete automatically the start and stop including the pump with medicine,
booster pump, and electrical slowly opening door and so on. The reverse osmosis equipment
and the water level of the tank are connected; the procedure will stop when the water level is
high but start when the water level is low.
The surface low pressure flushing on the condition of the reverse osmosis’s started and stops.
When the reverse osmosis equipment starts or stops, it will automatically open the electrically
flushing water drainage valve, operating the low-pressure flushing for the membrane’s surface
and drawing off the concentrated water inside the membrane elements.
The supervision and warning on the unusual working status. In the equipment’ s working
process, the control system will supervise automatically the working status of various
equipments such as booster pump, the pump with medicine, electrical valve and so on and show
an alarm warning. Meanwhile it also can supervise the executed parameters like temperature,
water flow, pressure, water level, conductivity, red ox potential, PH value and so on, and will
show the corresponding alarm signal , and then decide whether to stop the working or not
according to different conditions.
The automatically control and adjustment of adding medicine. The electric current signal or the
impulse signal offered to the water flow of tube way, redox potential, PH value tester by the
reverse osmosis adjust automatically the amount of medicine addition,finishing proportionally
automatic adjustment of the amount of adding medicine.
With unceasing enhancement of the automatic control level, the enterprises also have enhanced
their requirements for the control level of the water purifier equipments, there are even many
companies who request that the water purifier equipments could work without person’s
supervision.
2. Before connecting the reverse osmosis equipment with the tube ways, you should blow and
clean the tube ways ( including the reverse osmosis inlet water tube)
3. Check all the tube ways which should be connected according to technological requirement,
every valve’s on-off performance should be good.
4. Check all the measuring appliances to confirm that they have been equipped and tested
correctly.
5. Confirm that the booster pump and slowly electrical opening should be in the condition of
immediate operation and the water inlet of the pump should be in the condition of being
opened.
6. Confirm that interconnection, warning, control parameters and connectors have been
equipped correctly.
7. Confirm that every medicine case should have more than 2/3 liquid level which has been
stirred evenly, the measurement amount and system of adding medicine all should be in the
normal status for use.
8. Prepare all the needed reagents and measuring appliances for operation supervision.
9. Conform that the unqualified water outlet (water outlet valve) should be opened.
10. The concentrated water control valve should be placed at suitable start position.
The reverse osmosis operation methods: the selection switch “Manual-Stop-Auto” should be
placed at the manual location.
2. Put every unit measurement pump of adding medicine into operation (initially to adjust it in
manual way).
3. Open the flushing valve, open the manual adjusting valve of the booster pump (1/3), start
the slowly electrical opening, letting the water flow into the reverse osmosis equipment on
the condition of low pressure and small amount of water flow offered by the pretreatment
system in order to release the air inside the system (about 5min for air releasing while 3min
above for flushing), meanwhile the protection liquid in the new membrane also could be
flushed out.
4. Check the system to confirm there is no leakage. After which air releasing and low pressure
flushing come to an end.
5. Close the slowly electrical opening and the flushing water outlet, open the concentrated
water outlet valve (the concentrated water outlet valve could be opened fully while the
flushing outlet valve could only be opened slightly, about 1/3) .
6. Start the booster pump and the slowly electrical opening, if there is no the latter one, you
should adjust manually the manual adjusting valve of the booster pump, the increase rate of
the feed water pressure of the membrane must be lower than 10psi every second, which
makes the inlet water will keep flushing the equipment when the water pressure is lower
than 50% until the protection liquid in the water drainage has been discharged completely
(the flushing time is 30min at least).
7. Confirm that the unit measurement pump of adding medicine should work smoothly.
8. Slowly increase the strength of opening the water outlet manual adjusting valve of the
booster pump, meanwhile keep adjusting the strength of the concentrated water outlet
adjusting valve without stop until it could meet the flow and return rate of the feed water,
then adjust various medicament amount of adding medicine for its stability.
9. When the system has reached the designed condition, check the pressure of sections, total
water flow, fresh water flow, concentrated water flow and its LSI.
10. After the system’s stable operation (about one hour), record all the executed parameters.
Close the unqualified water drainage valve for normal tendency, ensuring the equipment’s
normal water making.
11. Check the product conductivity of every pressure vessel and analyze the happened or the
possible malfunction.
12. After operating for 24 -48 hours, record all the operation data( inlet water pressure,
pressure difference, water flow, return rate, electrical conductivity and so on), do remember
to retain the data record of the initial operation and extract the relative sample of the inlet
water and concentrated water to test their contents, to compare and confirm the
characteristics of the system.
13. When the reverse osmosis equipment’s operation is stopped by manual way, first of all, the
slowly electric opening is closed after which the booster pump’s operation stops.
7.2 The automatic start and stop of the reverse osmosis system
The automatic start of the system is completed by the operation on the central control board.
Since finishing all the preparation before start and completing the initial start successfully, the
pretreatment system has been supplying water; the reverse osmosis equipment could do
automatic operation.
2. Put various measuring appliances into operation and open the water inlet and outlet of the
measurement pump of adding medicine.
3. Check the interconnection, warning and measuring appliance to ensure their normal
working.
4. Press down the button of “The reverse osmosis start”, at the time, the automatic procedure
will start automatically the measurement pump, booster pump, the slowly electrical opening,
after which the system will enter into the operation period of salt rejection and water
making.
5. If you need to stop the equipment’s operation, press down the button of “the reverse
osmosis stop”, the automatic procedure will automatically close the slowly electric opening,
stopping the operation of the booster pump and the measurement pump.
6. After every stop of the reverse osmosis equipment, there must be a low pressure flushing.
1. The total amount of the inlet water (namely the sum of the pure water and the concentrated
water) should be controlled by the RO feed water adjusting valve, if there is no change
concerning the amount of feed water, do not adjust the valve arbitrarily, complete opening
and closing are forbidden; RO adjusting valve for the concentrated water drainage is used to
adjust the return rate, if there is no change concerning the return rate, do not adjust the
valve arbitrarily, complete opening and closing are forbidden absolutely.
2. When the reverse osmosis equipment shows the warnings of HP and LP, first of all, you
should check that whether the manual valve strength between the security filters and the
booster pump is too small, then check that whether the RO feed water adjusting valve and
the drainage valve of the concentrated water are working normally, after which you should
press down the reset button of the warnings of HP or LP pressure to restart the equipment.
3. Control strictly the feed water quality, confirm that the equipment should be operated
complying with the standard requirements of the feed water.
4. The pressure control operation should take the lowest pressure value under the premise of
meeting the water amount and water quality, which is good for the decrease of the
depression of the water flux and the membrane’s replacing rate.
5. The control of the feed water temperature, take the lowest temperature of the critical
pressure that can not meet the requirement for the water yield and water quality as the feed
water temperature in this period according to the actual water consumption, which can
reduce the possibility of membrane’s depression.
6. The control of the drainage, due to the variation of water temperature and operation
pressure, the amount of water making also has the corresponding variation, in this situation,
you should adjust the drain amount, and otherwise it will have an effect on the equipment’s
salt rejection.
7.4 The stop and the maintenance for use of the RO system
7.4.1 The membrane elements maintenance before equipping the reverse
osmosis system
The membrane elements are all packed in the vacuum plastic bag with protection liquid after
being produced. In the proceed of storage and transport before being equipped and used, the
membrane elements should be preserved in a dry environment, the preserved temperature
should be between 20 and 30℃; Do not put the membrane elements at the place under the
direct sunlight or nearby oxidized gas.
1) Flush the reverse osmosis system with feed water; meanwhile do eliminate the gas from
the system completely;
2) The system should be operated for 1 hour or 2 hours every day, close the relative valves in
order to avoid the gas’s penetration;
■ Isothiazolinones,
Dosage: 15-25mg/L
The “kathon”of the Rohm&Hass or the “ Simicide C-68” of the Betz company
Could be used as the disinfectant of long-term preservation
■ Sodium bisulfate
Dosage: 500mg/L, could be used for 30min-60min
1.0% liquid could be applied to long-term preservation
Due to the fact that the pretreatment couldn’t completely remove the pollutant such as inorganic
salt filthy ,microorganism, colloid pellet, insoluble organic matter, after the period of normal
operation, the diaphragms of the membrane elements may be polluted under the function of the
reverse osmosis concentration, which will lead to the depression of the membrane elements’
function. The membrane elements should be cleaned on the following conditions:
z The standard amount of making water has decreased 10% above since the last cleaning
z The standard salt rejection has increased 5% above
z The standard pressure difference between feed water and concentrated water has
increased 15% above since the last cleaning
z Before long-term operation stop
z As daily maintenance
First of all, disassemble the two membrane elements of feed water inlet and water outlet from
the membrane housing and watch their appearances to judge that whether the follow situations
have happened:
Check the housing of the membrane elements to ensure its perfect, in some systems, if there is
the phenomenon of water hammer or membrane elements’ blockage which may increase the
pressure difference between water inlet and water outlet of the membrane elements, leading to
the breakage of the glass fiber reinforced plastic coverings of the membrane elements.
Concerning the explanation for water hammer, please refer to page 105 of the manual “10.6
what is the water hammer? What is the damage to membrane elements caused by the water
hammer?”
1. Confirm that the membrane elements housing and bottle cap of the water inlet should not
be attached with any substance like sand, in some reverse osmosis systems that couldn't be
designed well, the float of the feed water couldn’t be eliminated, so it will enter into the
membrane elements along with water current, as the figure below, if this situation happened, in
the surface pretreatment, the particles rejection rate couldn’t reach the feed water requirements;
2. Check the feed water end surface of the feed water membrane elements to make sure that
there are no sundry substances such as large particles, activated carbon and so on, as the follow
figure:
The existence of particulate substances on the water inlet end surface indicates that the
pretreatment’s function of eliminating particles couldn’t reach the feed water requirement of the
reverse osmosis system, please test SDI value, meanwhile check the security filters and replace
filters
As to the weight of the elements that have not been used, please refer to the sixth section of the
third chapter of the manual: the net weight of membrane elements in “packing information”.
The symptom: The decrease of the salt rejection rate and water making
The increase of system pressure drop,
There is settling on the concentrated water end surface of the elements,
The weight of membrane elements has increased by 50% above
Cleaning medicament : ① 2% lemon acid liquid, the PH value of ammonia water is 4.0, the
temperature is 40℃;
② you can also use 2.0% Hydrochloric acid peroxide solution with PH
value of 2~3 to clean
Cleaning procedures:
The first step: you should better use the reverse osmosis water to clean; good infiltration
water is also feasible (do not use the feed water including special chemical material which may
response with the cleaning liquid).
The second step: you should use the cleaning liquid specially configured by the reverse
osmosis water, to measure it correctly and mix it evenly to make sure that the PH value and the
medicament content of the cleaning liquid should comply with the relative standards.
The third step: input the cleaning liquid to the reverse osmosis system by using usual
cleaning flow and the pressure of 20Psi, the backwater in the early beginning should be drained,
avoiding the liquid’s being dilution. Then let the cleaning liquid recycled in the tube way for
15min, watch the opacity and PH value of the backwater, if the water has been obviously
polluted or its PH value has exceeded 0.5, you should add cleaning medicament again to make
the cleaning liquid meet the cleaning requirements.
The fourth step: stop cleaning the circulating pump, watch the pollution situation of the main
elements, the membrane elements should be soaked in the cleaning liquid for about one
hour(two hours at best). During the period you could start the circulating pump with
intermittence to keep constant cleaning temperature (25~30℃).
The fifth step: enlarge the water flow to the 1.5 times of its normal flow to clean, during the
period, the pressure shouldn’t be too high, taking the pressure of the system without water or
little water as limitation. The circulating time should be 15 minutes.
The sixth step: use the qualified pretreatment yielding water to flush the system for 20-30
minutes, the pressure should be lower than 20Psi, the lowest temperature is 10℃ in order to
avoid settling, flowing the cleaning liquid out without retention. Start the system operation to
check the flushing result; do not use the yielding water.
The second step: you should use the cleaning liquid specially configured by the reverse
osmosis, to measure it correctly and mix it evenly to make sure that the PH value and the
medicament content of the cleaning liquid should comply with the relative standards.
The third step: input the cleaning liquid to the reverse osmosis system by using usual
cleaning flow and the pressure of 20Psi, the backwater in the early beginning should be drained,
avoiding the liquid’s being dilution. Then let the cleaning liquid recycled in the tube way for 3 to
5 minutes, watch the opacity and PH value of the backwater, if the water has been obviously
polluted or its PH value has exceeded 0.5, you should add cleaning medicament again to make
the cleaning liquid meet the cleaning requirements.
The fourth step: after using the cleaning liquid to clean the circulating pump for one hour, stop
cleaning the circulating pump, if the pollution of the sulfate happened, the main membrane
elements should be soaked in the cleaning liquid for 24 hours. During the period you could start
the circulating pump with intermittence to keep constant cleaning temperature (25~30℃).
The fifth step: after being soaked for 24 hours, enlarge the water flow to the 1.5 times of its
normal flow to clean, during the period, the pressure shouldn’t be too high, taking the pressure
of the system without water or little water as limitation. The circulating time should be between
30 and 60 minutes.
The sixth step: use the qualified pretreatment yielding water to flush the system for 20-30
minutes, the pressure should be lower than 20Psi, the lowest temperature is 10℃ in order to
avoid settling, flowing the cleaning liquid out without retention. Start the system operation to
check the flushing result; do not use the yielding water.
As to the appearance of the inorganic salt pollution, you could make cleaning in terms of
carbonate pollution, if the performance change of the membrane elements is not obvious after
or before flushing, you can judge it as sulfate pollution or other inorganic salt pollution. The
former is the kind of pollution that can hardly be cleaned; the membrane elements performance
often has little change after being cleaned.
The cleaning result of some inorganic salt pollution is not obvious, such as silicate, Fluoride and
Silicon-fluoride and so on, concerning the feed water with high content of those substances, the
corresponding equipment must be designed in the system of the pretreatment, such as softener,
adding anti-scalelent and so on, avoiding membrane elements pollution.
You can also use 2.0% Hydrochloric acid peroxide solution of PH2-3 to clean
Cleaning procedure: refer to the cleaning methods and procedures of the Carbonate pollution
Oxide oxidants membrane element is the most serious phenomena of membrane pollution.
Because oxide damages the rejection layer of membrane surface directly, it breaks -CO-NH- and
disables semi permeable membrane. Besides, membrane element oxidation is irreversible, once it
happens, membrane can not be cleaned nor resume to its function, the unique way is change to new
membrane element. So, during pretreatment, it’s necessary to adopt activated carbon reducer to
remove various oxides in water.
Notice:
1. Membrane element must be cleaned by specialist. Please be
advised to consult supplier or manufacture before cleaning.
When the membrane element is right used and of maintenance according to Chanitex
membrane element technology swatch and technology document, if there’s problem caused by
manufacture technology and material Chanitex will give guarantee for the product in 36 months
since the purchasing day. If the products really has quality problem tested according to this
article, Chanitex will guarantee to keep it in good repair or replace it.
9.1.2.2 Within initial three years movement period,based on the specified test condition of
Chanitex product manual,salt rejection does not surpass the product sample rating
3 times,the lowest permeated water flow is not lower than the product sample rating
70%.
9.1.2.3 From the date of membrane element first time use or six months from the factory
delivers goods(take arrives the time first as),Chanitex guarantee three years
The membrane element must operates on the condition of which in Chanitex company's manual,
technological manual, and design guide stipulated。If any condition below is not to be able to
a. Feed water of membrane element does not include oil, fat or other harmful module organic
c. The membrane element should carry on the maintenance under the suggested cleaning
condition and without pollution of granule, sediment, suspended solid or microorganism.
d. The membrane system design parameter, the membrane element arrangement, the
recovery as well as the measuring appliance and other spare parts must conform to the
reliable project experience。
e. The buyer has the responsibility to provide handbook of reasonable system operation and
insure the users have ability to clean and system diagnoses and restore on some
sharp-edged situations;
f. The user must retain the membrane system all operating records since start, including
breakdown handling, the routine maintenance management and so on, and reorganize
these data by standard form, the data is convenient for analysis and search breakdown
reason, it must provide the operating record data to Chanitex company when call for
compensation.
9.1.3.1 During the first three years of operation of the element(s), Chanitex warrants that
minimum permeate flow, when operated under standard conditions published by
chanitex, shall be at least 70 percent of the specified initial average flow. Chanitex
further warrants that maximum salt passage, when an element is operated under
standard test conditions published by Chanitex and pressure required to give the
initial rated flow, will not exceed 1.35x the specified maximum value. Chanitex will,
on confirmation of loss of performance during the warranty period, credit 1/36 of the
original purchase price of the element for each unused month of the warranty period
toward the purchase of a replacement element at the current prevailing price.
9.1.3.2 If element is not used in permission storage time, the membrane element is
considered outside the use permission storage period.
9.1.3.3 The membrane element which is returned with non-guarantees reason must not be
used, and maintains the original factory packing。It will not be accepted or gather
the extra cost when the returned membrane element is not conform to the above
standards.
Chanitex has no warrant responsibility for the accident, the economic loss and other aftereffect
which is caused by causal, accidental, especially or the malicious damage, or the damage of
membrane created by the third party not necessary and other reasons.
9.2.1 Approval of Chanitex company post-sale service department must be obtained before
9.2.2 When returns the membrane element, the user needs to assist following provision:
z Insures the membrane element be sealed in the bag, and puts in the carton to avoid
mechanical damage, simultaneously guards against damp and exposes to the sun.
z In order to avoid the change of membrane element performance caused by excessively long
time of storage, the user should send off membrane element as soon as obtain return
notice.
9.2.3 If Chanitex quality testing department discovered returned goods already being
damaged (the reason including inappropriate use, storing, transportation and arbitrarily
transform membrane element), Chanitex has no responsibility for exchange and ship
9.2.4 All returned goods which is not used must of the original factory packing.
9.2.5 Regarding membrane element in warranty period, if the examination result prove the
problem of membrane element is caused by membrane material or membrane
production process, Chanitex will undertake the complete expense; and compensate
user membrane element which conform to the technological standard. Otherwise,user
undertake the complete expense。
9.2.6 If membrane element surpasses the warranty period, the user undertake the complete
expense (including the examination expense, the fitting replacement expense as well as
the transport expense.)
9.2.7 If it is the user’s mistake, the user undertake returned goods expense; If it is Chanitex's
mistake, Chanitex undertake transport expense。
10.1 How many years can the membrane element use generally?
The membrane service life is decided by the membrane chemical stability, the element pHysical
stability, cleanability, feed water, the pretreatment, the clean frequency, the operation
management level and so on. Under the reasonable operation can uses for 3 years。
It is generally 1%(W)food grade NaHSO3 solution. Might add 10% propanediol as antifreeze
in winter。
The pressure, the temperature are higher, the permeated water flow is higher, vice versa, works
under the high temperature condition, should lower the working pressure, makes the water flux
maintenance invariable, vice versa. Membrane element withstanding high pressure high
temperature ability. The water flux change refers to temperature and membrane flux formula
computation in the appendix.
The temperature and feed water TDS are higher, salt rejection is lower, the permeated water
flow is smaller。
The salt rejection rate increases along with the pressure, but the salt rejection rate no longer
increase when surpasses certain pressure, , certain saline matter and water molecule will
penetrate the reverse osmosis membrane element。
Water hammer can make stress damage to membrane element, for example the end cover
bursts, the connector damage, the FRP enclosures bursts, even the internal membrane sheet
and obstruct net bursts. Water hammer results in the membrane element abandonment directly.
Therefore it must design corresponding protective device in the Reverse Osmosis system to
prevent water hammer.
The above drawing shows, when RO system start, water pressure distributed tendency in
membrane housing. If water hammer is too big, it can directly cause fast raise of the pressure
difference of membrane element FRP cover two sides, finally causes the FRP enclosures to burst.
Picrue below shows membrane element damaged by water hammer.
10.8 Why does the initial period produces the water TDS be very high during the
Because the salinity osmosis does not need ambient pressure, even if system stop, the salinity
osmosis also work, feed water TDS is higher than the pure water, the salinity can osmosis to
pure water; But there’s no ambient pressure, pure water pipeline is installed the check valve, the
water osmosis stopped, in this case, the pure water salinity could be higher and higher, until
both salinity are equal. This is the reason.
The colloid dirt Feed water Silt Density Clean membrane element
Permeated Salt
biological dirt Whether there is biology
increase
10.11 What does the feed water hardness affect reverse osmosis membrane
system?
Feed water hardness rise to increase the membrane element scaling tendency when feed
water TDS invariable, the reverse osmosis membrane easily appear the inorganic salt scaling,
block the membrane element,the direct consequence of is: permeated water flux decrease,
permeated water TDS rise, the two sides pressure difference increases. Feed water hardness
raise will not pollute the membrane element immediately, but with the membrane surface is
polluted along with the inorganic salt scaling, the membrane element performance will of
obvious change。
For the reason of the reverse osmosis membrane inspissations, when feed water hardness
increases, possibly causes salty(difficult to dissolve in concentrated water) density to surpass
its saturated solubility, this salt can crystallize from concentrated water,deposits on membrane
element surface and forms the inorganic salt scale.
The principle of reverse osmosis membrane system feed water is not to occur scaling even after
inspissations, so suggest to soften or to add the anti-scalelent during pretreatment for feed
water, please get the concrete information in other chapters of this handbook。
11 Quality Certification
11.1 NSF certification
12 Appendix
Lengh :
Pressure:
Volume:
1 US gallon(U.S.gal)= 3.785 L
Flux:
1GPM(Gallon/ Minute)=3.785LPM(Liter/Minute)
Concentration:
1mg/L=1mg/L=103ppb=103µg/L
Permeated Water Flow (gpd)= Membrane Flux (gfd) ×(Membrane active surface).
×100%
Real Salt Rejection =1-【Permeated Water Salinity /(【Feed Water Salinity +Concentrated
Water Salinity】/2×A)】×100%
Tcoff=EXP{2640×1/(273.15+25)-1/(273.15+T)} T≤25℃
Tcoff=EXP{3020×1/(273.15+25)-1/(273.15+T)} T≥25℃
TDS = K × EC25
The unit of TDS is mg/L, which is ppm.
EC25 is the conductivity when temperature is 25℃,the unit isµs/cm
EC25 treat all salt as NaCl and don’t considerate the permeability of CO2.
300~4000 0.55
Brackish Water
4000~20000 0.67