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Abstract
Most of gypsum-enriched soils in Isfahan and neighboring provinces occur on alluvial fans,
dissected flood plains Žold dissected alluvium.and piedmont plains. Herein we investigate the
processes of formation and alteration of gypsic horizons and their pedofeatures. We described and
sampled representative pedons on a transect from the mountain to the piedmont plain. In the study
area, different gypsic pedofeatures have various kinds of internal lenticular cryslalitic fabrics.
Micromorphologic observations confirmed that gypsic horizons have an evolutionary sequence
across the different geomorphic surfaces from the upper fan to the piedmont plain. In primary
stages Župper fan., gypsum crystals occur individually in the soil groundmass or as clusters in
voids with idiotopic or xenotopic fabrics. Eventually, they form internal coatings or infillings and
pendants Žin middle and lower fans.. In the more developed horizons Ždissected flood plains or
plateaus., the fibrous gypsum crystals are banded and perpendicularly distributed with reference to
the gravels and soil surface. These loosely compacted fibers constitute the bulk of the soil
materials, leaving non-gypsic particles as islands between crystals. In these pedofeatures, perpen-
dicularly oriented fibrous crystals, with their lateral inter-connections give rise to a continuous
three-dimensional firm structure.
)
Corresponding author. Tel.: q98-31-757205; fax: q98-31-750099.
E-mail addresses: agresor@cc.iut.ac.ir ŽN. Toomanian., ajalalian@cc.iut.ac.ir ŽA. Jalalian.,
mkeghbal@cc.iut.ac.ir ŽM.K. Eghbal..
1
Fax: q98-8912254.
2
Fax: q98-8912254.
0016-7061r01r$ - see front matter q 2001 Elsevier Science B.V. All rights reserved.
PII: S 0 0 1 6 - 7 0 6 1 Ž 0 0 . 0 0 0 5 8 - 6
200 N. Toomanian et al.r Geoderma 99 (2001) 199–224
The fabric of these lenticular gypsum crystals is xenotopic or hyp-idiotopic. In the piedmont
plain, the idiotopic crystals have no preferred orientation and have random distribution. Internal
fabric of these pedofeatures is porphyrotopic. This study indicates that, physical environment
plays a great role in formation of different gypsic pedofeatures. q 2001 Elsevier Science B.V. All
rights reserved.
1. Introduction
1. Sabkhas, Playas and related areas ŽWarren, 1989; Nettleton et al., 1982. .
2. Hilly areas on gyprock ŽVan Alphen and de los Rios Romero, 1971;
Herrero et al., 1992..
3. River alluvial plains and Terraces with gypsum originating from past or
present water tables or by flooding ŽBarzanji, 1973..
4. Surfaces with eolian gypsum Ž Nettleton et al., 1982; Taimeh, 1992. .
5. In Vertisoils Ž Podwojewski and Arnold, 1994. .
6. Weathered gypsiferous marls Ž Mahmoodi, 1986; Stoops and Ilaiwi, 1981. .
Genesis of gypsiferous soils on alluvial fans and fan remnants, where the
gypsum source was from upper watersheds, has not been completely considered.
Our study focuses on the genesis of gypsic and hypergypsic horizons. In the
study area, gypsum originates mainly from the weathering of Cretaceous
limestone and Jurassic shale of the surrounding sediments Ž Toomanian, 1995. .
Working on origin of gypsum in surveyed area Ž Mountains and doted area, Fig.
1., Toomanian Ž1999. believes that some gypsum is present in different Creta-
N. Toomanian et al.r Geoderma 99 (2001) 199–224 201
The study area is located on the south slope of Jaafarabad mountain, which is
representative of the north Zayandehrud sub-watershed, 20 km north of Isfahan
ŽFig. 1.. The block diagram and cross-section of study area are shown in Figs. 2
and 3. The approximate surface of the area is 2756 hectares and the elevation of
landforms range from 1550 to 1870 m between the piedmont plain and adjacent
202 N. Toomanian et al.r Geoderma 99 (2001) 199–224
peaks. Soil parent materials are derived from weathering of calcareous sedi-
¨
ments and shale. According to the Koppen method Ž 1987. , the study area has a
Fig. 3. Cross-section showing the sedimentary petrology and different landforms of the study area.
N. Toomanian et al.r Geoderma 99 (2001) 199–224 203
dry and very hot climate with dry summers. Annual means of evapotranspira-
tion, temperature and precipitation are 1571 mm, 14.18C and 122.4 mm,
respectively. The climatic data for the study area are presented in Table 1.
Several geomorphic processes affect the landforms in the area. The first is the
removal of materials across the radial slope of watershed and the second is the
translocation of materials by watershed’s drainage system and subsequent
erosion processes. The latter is responsible for forming the existing old dissected
surfaces Ž plateaus. and piedmont plains Ž Figs. 2 and 3.. Geomorphological and
paleoclimatological studies of Krinsley Ž1970. , Bobek Ž 1961. and Wright Ž 1961.
have shown that central Iran had a colder and wetter climate in late Pleistocene
and early Quaternary periods. This made the translocation of eroded coarse
materials to far distances possible.
Only part of the piedmont plain is cultivated Ž Wheat, Barley. ; the rest of the
area is of low productive range. Sparse green cover consists of; Euphorbia sp.,
Alhaji comelorum, Artemizia alba, and Peganum harmal.
A transect, with soil profiles from mountain to adjacent piedmont plain, was
studied ŽFigs. 2 and 3.. Using USDA-SCS Ž1979. and ISWRI Ž1988. manuals,
pedons were described and soil samples were taken from genetic horizons. For
distinction, definition and designation of genetic horizons, Soil Survey Staff
Ž1998., FAO, ISSS, ISRIC Ž 1998. and FAO-UNESCO Ž 1989. were considered.
In the case of hypergypsic horizons, the nomenclature of Eswaran and Zi-tong
Ž1991. and Herrero et al. Ž1992. was followed.
Table 1
Climatic data of study area
Jan. Feb. Mar. Apr. May June July Aug. Sep. Oct. Nov. Dec.
Mean max. temp. 8.7 11.9 16.7 22.2 28 34 36.3 35.2 31.2 24.3 17.7 10.9
Mean min. temp y1.9 y0.3 4.4 9.4 14.3 19.2 21.6 19.9 15.2 9.3 3.7 y0.8
Mean temp. 3.4 4.4 8.6 12.4 17.4 22.4 24.1 22.7 19.2 16.7 10.4 5.1
Rainfall Žmm. 23.1 15.1 20.5 15.4 9.8 0.7 0.9 0.1 0 4.3 10.1 22.4
Pot. Evapo- 46.8 58.9 110 139.5 186.7 313.3 228.5 208 155.1 115.9 65.1 4.4
transpiration Žmm.
Freezing period 24.6 15.9 6.6 0.1 0 0 0 0 0 0 5.2 20.8
Relative humidity Ž%. 60.9 53.8 46.9 40.1 33.6 23.6 25 25.8 28.3 38.6 49.7 58.7
204 N. Toomanian et al.r Geoderma 99 (2001) 199–224
Table 2
Component and modifications of resin for saturating and mounting of samples
Resin constituents Rec. sample Revised Mounting
saturation rate saturation rate rate
Resin: Cannus C-32 2000 ml 50 ml 5 ml
Catalyst: Lupresol D.D.M. 1 ml 0.2 ml 0.1 ml
Accelerator: Cobalt naphthanate 0.2 ml 3 drops 0.5 drop
Solvent: Acetone 2000 ml 50 ml 2 ml
tion Service, 1972, 6f 1a. and was corrected for hydration water Ž Nelson et al.,
1978; Lagerwerff et al., 1965..This procedure involved Ža. changing of
soilrwater ratio from 1r5 to 1r500; Žb. increasing the first shaking period from
0.5 to 48 h; and Žc. increasing the sedimentation period, after adding acetone,
from 0.5 to 2 h.
Using pre-treatment described by Hess Ž 1976. , textures of samples were
measured by the pippet method. Silica gel was used for oven drying. All the
data are reported in percentage of dry matter, and corrected for two water
molecules of dried gypsum Ž Nelson et al., 1978. .
Soil micromorphology was described using thin section techniques. To avoid
crystallographic changes, during all preparation stages, samples were not al-
lowed to overheat. We modified cannus ŽC-32. resin Ž Murphy, 1986. mixing
rates for the thin section preparation ŽTable 2.. We described the thin sections
using the Bullock et al. Ž1985. handbook.
3. Results
205
206
Table 4
Genetic characteristic and micromorphological properties of gypsic horizons
Horizon Depth Žcm. Gy, % CrF related Fabric of Soil pedological properties
distributiona groundmass Micromorphological Macromorphological
gypsic pedofeatures characteristics
Upper fan
Profile No. 3
207
208
Table 4 Ž continued .
209
210
N. Toomanian et al.r Geoderma 99 (2001) 199–224
Table 5
Some of the physico-chemical and morphological characteristics of pedons
Horizon Depth Žcm. Texture Sat. Per. Ž%. Gravel Ž%. V.F.S. Ž%. Structure pH ECe. ŽdSrm. O.M. Ž%.
Clay Silt Sand
Profile No. 3
A 0–15 53 30 17 23 60 11.5 Sg 8 1.1 0.622
C1 15–70 68 21 11 28 60 13.7 Sg 8 1.06 0.54
2C2 70–100 81.4 12.6 6 30 30 11.1 Sg 8.15 0.84 0.307
2Byb 100–140 31.5 44.5 26 44 20 10 Sg 7.8 2.9 0.4
Profile No. 5
A 0–15 69.5 17.5 13 18.4 20 5.2 Gr,2,f 7.85 3.09 0.6
Bk1 15–38 59.5 16.5 24 32.2 15 7 Sbk,1,f 8.15 0.792 0.369
Bk2 38–65 65.5 14.5 22 25.7 40 7 Massive 8 1.07 0.662
By 65–130 57 13 30 42.6 15 5 Massive 7.7 4.7 0.636
Profile No. 9
Ay 0–17 60 30.5 9.5 18.7 10 12.6 Gr,2,vf 7.7 2.7 0.488
Y1 17–54 64 33.5 2.5 21.4 5 11.8 Massive 7.5 2.6 0.135
By1 54–98 53 41 6 22 15 7 Massive 7.75 2.75 0.133
By2 98–150 52 45.5 2.5 25 20 5.2 Massive 7.75 2.7 0.287
Profile No. 11
A 0–15 55.3 33 11.7 18.7 30 11.2 Massive 7.7 3.25 0.253
Y1 15–73 72 22 6 16 45 11.5 Massive 7.9 4.3 0.137
Y2 73–115 65 27 8 20.7 40 8.1 Massive 7.8 4.43 0.163
2Y3 115–150 63 20 17 25.4 5 14.2 Massive 7.7 3.7 0.22
Profile No. 14
Ap 0–25 55 20 25 27.5 15 10.2 Gr,1,f 7.9 3.5 0.34
211
212
N. Toomanian et al.r Geoderma 99 (2001) 199–224
Fig. 4. Horizon sequences and scheme of features in representative pedon.
N. Toomanian et al.r Geoderma 99 (2001) 199–224 213
Fig. 7. Xenotopic and hyp-idiotopic fabrics of anhedral and subhedral crystals ŽXPL, X: 100..
Fig. 12. Connections of lenticular gypsum crystals to form vertical fibers and threads ŽXPL, X:
40..
N. Toomanian et al.r Geoderma 99 (2001) 199–224 217
Fig. 13. Xenotopic fabric of crystals in interconnections part Žknots. of vertical threads ŽXPL, X:
100..
in the Y1 and By1 horizons. As the soil depth increases, the length of banded
vertical fibers Ž threads. decrease and their lateral inter-connection parts grow
ŽFig. 11.. Fine gypsum crystals and aggregates constitute the groundmass of
Fig. 16. Vertical growth of euhedral crystals under sandstone to form pendants ŽXPL, X: 100..
N. Toomanian et al.r Geoderma 99 (2001) 199–224 219
Fig. 17. Vertical threads made by lenticular gypsum crystals ŽXPL, X: 100..
these soils and nongypsic materials remain as isles. Internal fabric of crystals in
the threads and the knots are hyp-ididiotopic and xenotopepic Ž Figs. 12 and 13. .
Profile No. 11 on dissected old alluvium Ž gravelly old geomorphic surface.
has a thin surface layer of fine, loose soil material below a desert pavement.
Beneath this layer, silt size soil materials with vesicular pores provide a unique
kind of soil crust Ž Fig. 14. . Underneath this crust, gypsum occur as pendants.
Long vertical gypsum crystals mostly under round gravels Ž Boyadgiev and
Sayegh, 1992. connect laterally to make a strong network throughout the whole
profile. Below a depth of 115 cm, gravels are lacking and arrangement of
gypsum crystals change to a somewhat boxwork-likes arrangement Ž Fig. 15. .
Fig. 18. Euhedral crystals with porphyrotopic fabric in soil groundmass ŽXPL, X: 40..
220 N. Toomanian et al.r Geoderma 99 (2001) 199–224
The least non-gypsic, fine soil materials appear as isles inside a continuous
crystalline gypsic pedofeatures. Gypsic pedofeatures constitute the bulk of these
horizons. The internal fabric of these crystalline features are hyp-idiotopic and
xenotopic ŽFigs. 16 and 17..
Profile No. 14 on the piedmont plain overlies a remnant of old coarse
alluvium. Calcic horizons occur in the upper part and gypsic ones below.
Isolated lenticular euhedral gypsum crystals occur in the groundmass or in voids
ŽFig. 18.. The groundmass of the lower horizons consist mainly of gypsum
crystals with nongypsic materials between them.
4. Discussion
this stage gypsic spots and little pendants may be observed in the field. Very
large individual crystals are also formed. The fabric of groundmass is lenticular
gypsic, but the soil micromass has speckled to striated b-fabric with chitonic to
enoulic distribution patterns ŽTable 4. . Internal fabrics of fine and coarse
crystals in gypsic pedofeatures are xonotopic or hyp-idiotopic and seldom
idiotopic ŽFig. 8.. The soil in this stage meets gypsic horizon criteria and the
amounts of gypsum range from 15% to 60%.
Dissected surfaces and piedmont plains in our study area are in lower parts of
the watershed and received gypsum from two sources. First, they received
gypsum by late Pleistocene or early Quaternary flooding. Second, continued run
off from radial slopes added additional gypsum.
As a result of their super enrichment with gypsum, soils on these surfaces
have complicated pedofeatures. To explain these, we divide the 4th stage into
the following three parts, based on the effect of the soil physical environment on
crystal formation, crystal arrangement and distribution.
Ž1. In soils on old non-gravelly surfaces, centimetric lenticular gypsum
crystals connect diagonally to form long vertical fibers Ž Fig. 12. . These crystals
have banded interlaced basic distribution. In this crystallitic gypsic groundmass,
three-dimensional connection of fibers form a continuous porous media. Water
moves along the connected voids and over crystal faces of soil. This phe-
nomenon thickens the fibers, establishes lateral connections and destroys lenticu-
larity of crystals. The equigranular xenotopic crystals have basic random
orientation pattern in the inter connection parts Ž knots.. Some of the crystals
within the fibers have hyp-idiotopic to idiotopic fabric Ž Fig. 13. . To form the
threads, centimetric fibers have banded and interlaced basic distribution, and
related to soil surface, they also have perpendicular distribution. The soil
groundmass consists mostly of lenticular gypsic crystallitic and isles fabrics.
These soils meet all hypergypsic requirements.
Ž2. On old gravelly alluviums, gypsum enters through runoff water. Evapora-
tion causes this water from underneath the gravels to recrystalize as vertically
arranged lenticular crystals Ž Fig. 16. . As the process continues, new crystals are
formed beside or along the previous ones. This process forms gypsic fibers and
eventually centimetric threads underneath gravels Ž Fig. 17. . These bearded
gravels are called gypsic pendants.
The formation, growth and connection of pendants in these gravelly soils
establish a firm continuous crystalline network Ž porous media. that constructs
the whole profile. Formation of lenticular gypsic crystallitic and isles fabrics are
the results of these processes. Considering soil data and new taxonomic propos-
als Ž Eswaran and Zi-Tong, 1991; Herrero et al., 1992. the soil would be
classified as a hypergypsic.
222 N. Toomanian et al.r Geoderma 99 (2001) 199–224
5. Conclusion
1. Mountain runoff water is the first source for the soil gypsum.
2. Amounts of gypsum and thickness of gypsic horizons increase stepwise
from mountain front to the old dissected alluviums. Depths to these gypsic
horizons decrease across the same transect.
3. The physical environment largely determines the distribution, arrangement
and orientation patterns of the secondary gypsum crystals. Amounts of
gypsum, texture, structure, CrF relationship and void patterns also play a
considerable role in formation of different gypsic pedofeatures.
4. Although all crystals in gypsic pedofeatures are not completely distinctive,
they are secondary and lenticular.
5. Depths of existing gypsic horizons can be correlated with depth of
percolated water and depending on the amount of gypsum, different kinds
of gypsic horizons are formed.
6. Although it is not used, but field and micromorphologic observations
support designation of By1, By2 horizons in profile No. 9 and 2By2
horizon in profile No. 14 as hypergypsic horizons.
7. All oriented or arranged gypsum crystals without considering their size,
form and habitat have to be determined as secondary.
Acknowledgements
The first author wishes to thank the Iranian Research, Education and Exten-
sion Organization for providing him a postgraduate scholarship for his MSc
program, part of which is presented in this work. Grateful acknowledgments are
extended to reviewers for their constructive comments and suggestions.
N. Toomanian et al.r Geoderma 99 (2001) 199–224 223
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