Unit Operations (III) Spring 2016

Instructors:
Part 1: Office number: 93716 Ext: 62647
Part 2: Office number: 93612 Ext: 62693
Part 3: Office number: 93610 Ext: 62633

Teaching assistants:
Part 1: Office number: 93726 Ext: 275
Part 2: Office number: 93650 Ext: 277
Part 3: Office number: 93652 Ext: 278

Textbooks:
(A). J.R. Welty, G.L. Rorrer, D.G. Foster, Fundamentals of momentum, heat, and mass
transfer, 6th edition, John Wiley & Sons, NY (2015).
(B). W.L. McCabe, J.C. Smith, P. Harriott, Unit operations of chemical engineering, 7th
edition, McGraw -Hill, NY (2005).

Outlines:
Chapters Contents
Part 1: (about 5.5 weeks, from Feb. 22 to March 29)
A22-A26 Mass transfer in a homogeneous phase
A27 Convective mass transfer between phases
Part 2: (about 5.5 weeks, from March 30 to May 10)
B20 Equilibrium-stage operations
B21 Distillation
B22 Introduction to multi-component distillation
B23 Leaching and extraction
B26 Membrane separation processes
Part 3: (about 5.5 weeks, from May 11 to June 17)
B18 Absorption
B19 Humidification operations
B24 Drying of solids
B25 Fixed-bed separations
B27 Crystallization
B28-B29 Operations involving particulate solids
Syllabus, Supplementary Information, and Homework download:
http://www.che.ncku.edu.tw/FacultyWeb/YangYM
18-1
18-2
19-1
19-2
19-3-1
19-4-1
19-5-1
19-5-2
 Eq.(19.37) : tie line
hxa
slope
kyaM B
equilibrium line
Hy*

Hi Hy*-Hy
Hy Hi-Hy
operating line

Ti Tx
Water temperature , Tx

From Eq.(19.35) ,
dH y k y aM B ZT k y aM B ZT ------Eq.(19.38)
dZ
Hi H y Gy ' 0 Gy '

From Eq.(19.39) ,
dH y Ky a ZT ZT ZT ------Eq.(19.40)
* dZ Gy '
Hy Hy Gy ' 0 H oy
( )
K ya
NTU=Noy
HTU=Hoy

19-6-1
19-7
24-1
24-2
24-3
24-4
Constant-rate period : Tw=const. , heat transfer controlled drying

hot gas

dTh
Tw Thb
T

Packed
bed

Tha

distance

mg cs d (Th ) h(Th Tw )d ( A)
Tha
dTh h A
Thb T T 0 dA
h w mg cs
T h
ln( ha Tw A
Thb Tw ) mg c s

Thb Tw h
or ln A
Tha Tw
m g cs

24-5
25-1
 ceq. in Fig. 25.6(a) ; c* in Eq. (25.7)

favorable
adsorption

ceq. c
c , ppm

(c-ceq.) = driving force for mass transfer in fluid phase.

strongly favorable irreversible

c
ceq. c ceq. 0 c

Eq.(25.7)
Eq.(25.12)

25-2
25-4-1
25-4-2
25-4-3