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Introduction
Physical chemistry is the study of macroscopic, atomic, subatomic, and particulate phenomena in chemical
systems in terms of laws and concepts of physics. It applies the principles, practices and concepts of
physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics
and dynamics, equilibrium.
Physical chemistry, in contrast to chemical physics, is predominantly (but not always) a macroscopic or
supra-molecular science, as the majority of the principles on which physical chemistry was founded, are
concepts related to the bulk rather than on molecular/atomic structure alone.
Physical Chemistry is a basic chemistry course the aim of which is to give a foundation of physical
chemistry to chemical Engineering students to enable them to tackle follow-up modules such as
Thermodynamic I and II
Atoms, Molecules, Bulk Matter, Energy, The Relation between molecular and bulk
properties, Electromagnetic fields, Units. The properties of gases; The perfect gas laws: the
states of gases, Impact on environmental science-the gas laws and the weather; The real gases:
molecular interactions; the Van der Waals equation Week 1
The basic concepts: work, heat and energy; the internal energy; expansion work; heat
transformation; enthalpy; Impact on biochemistry and materials science: differential
scanning calorimetry; adiabatic changes Week 2 & 3
The first quantum theory: Max Planck and black body radiation
Photons: the quantization of light. photoelectric effect, The quantization of matter: the Bohr
model of the atom, Wave-particle duality, the double-slit experiment, Application to the
Bohr model ,Uncertainty principle, Wave function collapse, The Pauli exclusion principle,
Quantum field theory, Quantum electrodynamics, Interpretations, Applications
Compton effect, Particle in one dimensional box, The simple harmonic motion oscillator Week 2 & 3
Postulates of quantum mechanics
Chapter 5 Electrochemistry
Electrode processes: reversible cells;. Types of half cells; Electrochemical cells;. The Week 5 &
standard emf of cells; Standard electrode potentials, 478. 31. Standard free energies and Week 6
entropies of aqueous ions;. Measurement of solubility products;Electrolyte-concentration
cells, Electrode concentration cells; Balance redox reactions using the half-reaction
method; Describe galvanic cells; Calculate standard cell potentials; Relate cell potential to
the reaction conditions.
Lectures 24 hrs
Tutorials 6 hrs
Practicals+ Industrial visit 12 hrs
Assessment will be done as follows:
Assignments 2 5%
Tests / Mock Exam 2 10%
Practicals 3 25%
Final Exam 1 60%
1. Any student without theory coursework or practical coursework or both is not allowed to sit for the
final exam.
2. Any student who attends less than 80% of lectures, tutorials and practical classes is not qualified to
enter into the final examination.
3. Students should be punctual for classes, late comers will not be allowed.
4. All assignments and practical reports must be submitted on the due date.