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)-JEE(Main)/19
FIITJEE JEE(Main)-2019
1. C 31. B 61. B
2. C 32. C 62. C
3. B 33. A 63. D
4. C 34. B 64. D
5. D 35. B 65. A
6. C 36. D 66. D
7. D 37. B 67. C
8. B 38. D 68. D
9. D 39. A 69. C
10. D 40. D 70. D
11. D 41. A 71. A
12. B 42. C 72. C
13. D 43. C 73. B
14. A 44. B 74. B
15. A 45. D 75. C
16. C 46. B 76. D
17. D 47. B 77. A
18. B 48. A 78. B
19. B 49. B 79. C
20. A 50. C 80. A
21. D 51. C 81. B
22. D 52. A 82. A
23. B 53. B 83. B
24. D 54. D 84. B
25. B 55. B 85. A
26. A 56. A 86. D
27. B 57. B 87. A
28. C 58. B 88. B
29. A 59. A 89. C
30. B 60. B 90. B
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AIITS-OT-PCM (Sol.)-JEE(Main)/19 2
Physics PART – I
SECTION – A
1. C
Sol. Vertical component of initial velocities are same. Hence, identical vertical motions.
2. C
RT
Sol. v
M
3. B
Sol. k2 k3
3
k= k
2
4. C
Sol. When u0 has such a value that bob will just stop when string is horizontal. Then the
situation given in option (C) will arise.
5. D
Mg Mg
Sol. Kx = ; x=
3 3k
6. C
Sol. T 2
geff
7. D
Sol. T Pa db Ec
T (ML1 T 2 )a (ML3 )b (ML2 T 2 )c
Comparing power on LHS and RHS.
a + b + c = 0, –a – 3b + 2c = 0, –2a – 2c = 1
8. B
ft
Sol. v vo
m
I
1 2f 2ft
fR = MR 2 ; R = ; ; v = R
2 m mR
ft 2ft
vo R
m mR
3ft mv o 2v
vo ; t ; v o
m 3f 3
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3 AIITS-OT-PCM (Sol.)-JEE(Main)/19
9. D
m T 2m 1 T
Sol. f ; n
2 4
10. D
1 5 1 3
Sol. v cm
2
2
1m / s
2
11. D
Sol. In SHM a = –2x and T = 2/
12. B
Rh
Sol. sin 90
R
R
R-h
90-
13. D
x x
Sol. t1 and t 2
v u
14. A
Sol. Translational velocity of A = Vo (towards right)
V
Rotational velocity of A = R = o (towards left)
2
15. A
GMm GMm GMm
Sol. W =
2 4R 2 2R 8R
16. C
Sol. PV = nRT
17. D
2 x H h
Sol. V 2gx,r 2gx
g
r 4x x H h
Hh
rmax at x
2
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AIITS-OT-PCM (Sol.)-JEE(Main)/19 4
18. B
Sol. When stones are there inside the boat. the volume of water displaced is equal to the
weight of the boat + stones. When stones are unloaded into the water the volume of
water displaced is equal to the volume of stones unloaded plus (weight of boat) /
(density of water). This time the displaced volume of water is smaller than in the first
case. Therefore the water level falls.
19. B
Sol. Pressure node is formed at the both the ends and in
the middle.
20. A
2
1 3 mgh
Sol. W = –mgh + m gh =
2 2 4
21. D
Sol. V (10 3 )2 (10)2 20
22. D
g
Sol. T – mg = m
2
mg
N = 2 mg – T =
2
23. B
I
Sol. 100°C – Ir – r Ir = 0°C
2
Ir = 40°C ; tF = 0° + Ir = 40°C
24. D
Sol. U = T(A)
2
R
U = T 1000 4 4 R2 = T × 4(9R2)
10
U = 36R2T
25. B
90
Sol. Total momentum = (dm)v cos
90
M
dm = Rd
R
M 2Mv
Total momentum = R vRd cos
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5 AIITS-OT-PCM (Sol.)-JEE(Main)/19
26. A
gh
Sol. Pressure due to liquid =
2
Force = (Total Pressure) (Area of wall)
27. B
MR2 Y
L
Sol. For disc z-axis I = X
2
By parallel axis theorem
C
mR2
IX X
4
mR2
IL = m(C cos 45o )2
4
28. C
dx
Sol. v v 0 gt ft 2
dt
1
dx vdt
0
29. A
V
1 v v
Sol. t t v s v1
2
t
Area under v – t curve = S
30. B
Sol. Component of force or force must be act in direction of displacement to do positive work.
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AIITS-OT-PCM (Sol.)-JEE(Main)/19 6
Chemistry PART – II
SECTION – A
31. B
Sol. XeF4 is planar because Xe is sp3d2 hybridised. Due to the presence of two lone pairs of
electrons, the shape is reduced to a square planar. CCl4 is tetrahedral because C is sp3
hybridised. The correct answer is (B)
32. C
Sol. SO32 get oxidized and its `n’ factor is 2.
The metal must have been reduced.
Applying the law of equivalence
50 0.1 (3 – n) = 25 0.1 2
n=2
33. A
Sol. It is a test for unsaturation. As benzene and naphthalene is also unsaturated, but they
are stabilized due to resonance, and thus does not give Bayer’s test.
34. B
Sol. Peroxide effect is observed when unsymmetrical alkene is treated with HBr only (and not
with HCl and Hl).
35. B
Sol. Absorption line in the spectra arise when energy is absorbed i.e., electron shifts from
lower to higher orbit, out of a and b, b will have the lowest frequency as this falls in the
Paschen series.
36. D
Sol. In (A) P O43 and S O42 both are isoelectronic and tetrahedral in shape. Same is in (B)
also. In (C) each C atom in C2H2 is sp hybridized same as C in CO2 hence, both are
linear. Only in (D) N2O is linear whereas NO2 is bent and therefore, the answer is (D)
37. B
2
Sol. Qp =
P NH3
(3)2 9
atm2 = 1.125 atm–2.
3 3
P P (1)(2) 8
N2 H2
Since value of Qp is larger than Kp (4.28 10–5 atm–2), it indicates net reaction will
proceed in backward direction.
38. D
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7 AIITS-OT-PCM (Sol.)-JEE(Main)/19
40. D
PM MB MA
Sol. i) Density of a gas . Since . at the same pressure A = B.
RT TB TA
But if pressure is different then A ≠ B.
ii) Pressure of the gases would be equal if their densities are equal other wise not.
3
iii) KE per mole = RT
2
It will be different for the two gases
3RT T T
iv) Urms , Since A B ; Urms of A = Urms of B
M MA NB
41. A
Sol. PV = nRT
w RT RT
P
M V M
PM eff
RT
M eff (0.79 28) (0.20 32) (0.01 39.9) 28.9
28.9 1
1.18 g / lit
0.0821 298
42. C
Sol. SiO 2 SiF4 H2 SiF6
43. C
Sol. Si OH4 2H4SiO4
H O
H6Si2O7 2
44. B
Sol. Anti elimination.
45. D
Sol. Ring expansion.
46. B
2
PNOPBr2
Sol. KP 2
PNOBr
47. B
Sol. G = -ive for spontaneous
48. A
Sol. Mg has full filled s-orbital.
49. B
Sol. O H
O=N=O , N , N
O O H H
H
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AIITS-OT-PCM (Sol.)-JEE(Main)/19 8
50. C
2p 2 2p2y
Sol. 1s2 , 1s2 , 2s2 , 2s2 , 2p2 , 2py2 2p2z
z
51. C
Sol. Pequm = 1 atm
K1 pCO2 1atm
K 2 pNH3 pH2S = 0.5 0.5 = 2.5 10–2 atm2 = 0.25 atm2
2
2 2 1
K 3 pNH3 pCO2
3 3
4 1 4
0.148 atm3
9 3 27
The order is K1 > K2 > K3
52. A
0.693 0.693 A 1.386
Sol. K1 = K0 0
t1/2 40 2t1/2 2 20
K 1 0.693 40
K0 40 1.386
0.693
= 0.5mol– litre
1.386
53. B
Sol. AgCl Ag+ + Cl–
In CaCl2
CaCl2 Ca+2 + 2Cl–
0.01 0.01 20.01
In NaCl
NaCl Na+ + Cl–
0.01 0.01 0.01
In AgNO3
AgNO3 Ag+ + Cl–
0.05 0.05 0.05
common ion effect is maximum in AgNO3
So, S1 > S3 > S2 > S4
54. D
Heat Na2 CO3
Sol. SiCl4 H2O Si(OH)4 SiO2 Heat
Na2SiO3
A B C
55. B
Sol. The dimeric formula, Al2Cl6, is retained in non-polar solvent but is broken into
Al H2O 6 Cl3 on dissolution in water on account of high heat of hydration.
56. A
Sol. Borax dissolves in water and gives an alkaline solution.
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9 AIITS-OT-PCM (Sol.)-JEE(Main)/19
Na2B4 O7 7H2O
2NaOH 4H3BO3 Strong Weak
base acid
57. B
COOH Conc. H SO
2 4 KOH Cl2
CO + CO2 CO
Sol. –H2O CO2 is Poisonous gas
absorbed
COOH COCl2
58. B
Sol. SiO2 is a compound of oxygen and silicon, the two most abundant elements of earth’s
crust and is used in building construction.
Si + 2CO (poisonous gas and a stable diatomic SiO2 + 2C molecule)
59. A
Sol. 2A 3B
t=0 a 0
t = t a – 2x 3x
3x a 2.3 a
given 1 i.e. x t –2
log = 11.0 min
a – 2x 5 4.6 10 a – 2x
60. B
nH2 1
Sol. Initially
nH2S 2
8H2S 8H2 + S8
Initial moles : 2 1 –
moles at equil : 2–x 1+x –
nH2 1 x
At equilibrium : 2
nH2S 2 x
Hence x = 1
KP = 28/18 = 256
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AIITS-OT-PCM (Sol.)-JEE(Main)/19 10
SECTION – A
61. B
Sol. Here x , 5 0,
(1, 5)
We have x 2 5x x a 3
x 2 4x a 3
From the graph 0 a 3 5
3 a 2
–5 –4 O
Number of integral values of a
2, 1,0,1,2
5
62. C
Sol. We can consider a like x and b like y
P x, y is a point which lies on 3x 4y 25
x 2 y 2 is distance of any point from (0, 0)
minimum value of x 2 y 2 is distance of 3x 4y 25 from (0, 0)
25
x2 y2 5
9 16
minimum x 2 y2 25
63. D
C1C2
Sol. cos ec15o
1
1
sin15o
o
1 15
1
sin 45o 30o C1 C2
M
1
sin 45 cos 30 cos 45o sin30o
o o
1 2 2
1 3 1 1 3 1
.
2 2 2 2
2 2 3 1
3 1
2 3 1 6 2
C1M C1C2 C2M 6 2 1
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11 AIITS-OT-PCM (Sol.)-JEE(Main)/19
64. D
Sol. For shortest normal chord t 2, 2 B
A
A 2,2 2
D 2, 2 2
C 8, 4 2
B 8,4 2
D
area of ABCD C
1
8 2 4 2 8 2 3 12 2 36 2
2
65. A
Sol. Here SB OB ' 7 9 4 B’
B ' 0, 4 (0, 3)
x2 y2
equation is 1 B E1
7 16
O S 7, 0 (4, 0)
66. D
Sol. PA .PB PT2
T
2 8 2 PT 2
PT 4
B (10, 11)
P (2, 3) A (3, 4)
67. C
Sol. S 1,2
S ' 5,5
2 2
SS ' 2ae 5 1 5 2 5
5
ae
2
2a 4 a 2
5 5
2e e
2 4
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AIITS-OT-PCM (Sol.)-JEE(Main)/19 12
1 1
Now 2
2
1
e e '
1 1
2 1
25 / 16 e '
1 16 9
2
1
e' 25 25
25 5
e' 2 e'
9 3
68. D
Sol. We know that t n 5t n 1 8t n 2 0
t 6 5t 5 8t 4 0
t 6 8t 4
1
5t5
69. C
x2 y2 x2 y2
Sol. Here 1and 1 are orthogonal then they will be confocal also.
a2 b2 A 2 B2
ae Ae '
a2e2 A 2e '2
a 2 b2 A 2 B 2
45 45 5 25
5
4 4 4
4 25 1
4 4 45
4 5
9
9 36 5
4 36
9
70. D
1
Sol.
4
4 sin3 10 4 sin3 50 4 sin3 70
1
3 sin10 sin30 3 sin 50 sin150 3 sin70 sin 210
4
1 3
3 sin10 sin 50 sin70
4 2
1 3 1 3 3
3 2 sin30 cos 20 sin70 3 cos 20 sin 70
4 2 4 2 8
71. A
Sol. sin x cos x 0 or
16 sin4 x sin3 x cos x sin2 x cos2 x sin x cos3 x cos 4 x 11
16 1 2 sin2 x cos2 x sin x cos x sin2 x cos2 x sin x cos x 11
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13 AIITS-OT-PCM (Sol.)-JEE(Main)/19
16 1 2 sin2 x cos2 x sin x cos x sin2 x cos 2 x 11
16 1 sin 2
x cos2 x sin x cos x 11
16 sin2 x cos2 x 16 sin x cos x 5 0
4 sin x cos x 5 4 sin x cos x 1 0
4 sin x cos x 5 0
sin x cos x 0 and 4 sin x cos x 1
1
sin 2x
2
5 9 13 17 21
x , , , , ,
12 12 12 12 12 12
There are 6 solutions in 0, 2
72. C
Sol. 2,H1,H2 ,.....H20 ,3 are in H.P.
1 1 1 1 1
, , ,........, , are in A.P.
2 H1 H2 H20 3
Suppose common difference is d
1 1 1 1
2 H1 3 H20
Now
1 1 1 1
2 H1 3 H20
1 1 1 1 1 1 1 1
2 H1 3 H20 3 2 H20 H1 21d 19d
= 40
d d d d
73. B
n n
Sol. Given expression is equidistant be x 3 x 2
Coefficient of x r nCr xr .3nr nCr x r .2nr nCr 3nr 2nr xr
74. B
Sol. For z 2i 2 2, centre (0, 2)
Y
radius is 2 2 P (z)
z 2
APB arg
z 2
1
ACB C
2 C
1
B A
2 2 4 (2, 0)
X
(–2, 0)
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AIITS-OT-PCM (Sol.)-JEE(Main)/19 14
75. C
Sol. Say argz
z x iy and z r
1
z 2 i
2
z cos z sin
2 2 xy
x 2 y 1
2
Distance of (x, y) from (2, 1) = Distance of (x, y) from line x – y = 0
locus of z is a parabola
76. D
Sol. Select any 4 points we will get a quadrilateral and for each quadrilateral we will get one
point of intersection of diagonals.
77. A
Sol. Number of solutions of the given equation is same as the number of solutions of the
equation x1x 2 x3 x 4 30 2 3 5 (there x 4 is dummy variable) hence number of
solutions is 43 64
78. B
Sol. Number of ways getting one correct
1 1 1 1 1 1
7C1. 6 1 7C1 265
1 2 3 4 5 6
Number of ways of getting two correct
1 1 1 1 1
7C2 5 1 7C2 44
1 2 3 4 5
Number of ways of getting three correct
1 1 1 1
7C3 4 1 7C3 9
1 2 3 4
Required number of ways 7 C1 265 7 C2 44 7C3 9
79. C
25 r r
25 r 2 3
Sol. Tr 1 25 Cr ab x
.c r . x
25 r r
n 25, 0 r 15
2 3
T16 25 C15 a10b10c15
Given 10a 10b 15c 1
Apply A.M. G.M.
10a 10b 15c 35 10 10 15
a b c
35
35
1
a10b10 c15
35
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15 AIITS-OT-PCM (Sol.)-JEE(Main)/19
80. A
2
Sol. 2a b 3c 2a b 2c 2 0
2a b c 2a b 2c 0
2a b c 0 2, 1
1
2a b 2c 0 1,
2
81. B
1 1 1 1 1
Sol. S 1 1 1 2 2 .....
2 3 2 2 3
S 1 1 1
1 2 ....
3 3 2 3
2S 1 1
1 2 2 .....
3 2 3 2 .3
2S 1 6 9
S
3 1 5 5
1
6
82. A
Sol. Inverse of p q r q p is ~ p q r ~ q p
~ p ~ q r ~ q ~ p
~ p q ~ r ~ q ~ p
83. B
Sol. Let AP be the lamp post of height h at a point A on a P
circular path of radius r and centre C. h
Let B be the point on this path such that
PBA AB h cot A
o
Since AB subtends an angle 45 at another point of the
path it subtends an angle of 90 o at the centre C so that
BCA 90o
Also CA CB r B
C
AB 2r
Also h cot 2r
h 2 r tan
84. B
Sol. Let us denote by P (n) the statement:
11n2 122n1 is divisible by 133.
For n 1, we find P (1) is true i.e. 113 123
11 12 112 11 12 122 23 133 is divisible by 133.
P (n) is true for n = 1.
Assume that the result is true for n k .
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AIITS-OT-PCM (Sol.)-JEE(Main)/19 16
86. D
Sol. Given, a,a1,a 2 ,.....a 2n ,b are in A.P.
a b a1 a 2n a 2 a 2n 1 ....... an an 1
Also given a,g1,g2 ,.......g2n ,b are in G.P.
ab g1g2n g2 g2n 1 gn gn 1
2ab
Further h
ab
The given expression
n a b a b 2n
2n
ab 2ab h
87. A
Sol. Let P be (h, k). If m be the slope of a normal, then m3 m 2 h k 0 .
k
Now m1m2m3 k m3
k3 k
So, 2 h k 0
3
k2 1
This 3 2 h 1 0
2 h k2 0
3 2
locus is 3 2 2 2 x y 2 0
2 as the locus is y 2 4x
88. B
Sol. Both are rectangular hyperbolas.
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17 AIITS-OT-PCM (Sol.)-JEE(Main)/19
89. C
n
Sol.
Given 5 2 6 I f …..(1)
0 f 1
n
Let 5 2 6 F
0 F1
I f F in an integer, f F is integer
0 f F 2 f F 1
1 f F
n
From (1), we get I 5 2 6 f
1 1
f f
F 1 f
90. B
Sol. Consider the series
x2 x3
log 1 x x .....
2 3
i
Put x e 3
i i i2 i3
e 3 e 3
log 1 e 3 e 3 .....
2 3
i i2 i3
sin 3
e 3 e 3
log 1 cos i e .....
3 3 2 3
i i2 i3
e 3 e 3
log 2 sin2 2i sin cos e 3 .....
6 6 6 2 3
i i2 i3
e 3 e 3
log 2i sin cos i sin e 3 .....
6 6 6 2 3
i i2 i3
i
2
i
6
e 3 e 3
3
loge loge e .....
2 3
i i2 i3
e 3 e 3
i i e 3 .....
2 6 2 3
i i2 i3
e 3 e 3
i e 3 .....
3 2 3
i i2 i3
e 3 e 3
i e3 .....
3 2 3
Compose imaginary part both sides.
2 3
sin sin
3 3 ....
sin
3 3 2 3
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