Chemistry Intensive Revision Program - Set 2

SEKOLAH TINGGI MELAKA

(Super Thinkers’ Module)
CHEMISTRY

PROGRAM ULANGKAJI INTENSIF

(PUI)

(Intensive Revision Program-IRP)

Panitia Sains
(Kimia)

MELIORA HIC SEQUAMUR

KE ARAH KECEMERLANGAN PENDIDIKAN

Set 2 1
Chemistry Intensive Revision Program - Set 2

PAPER 2 : Structure SECTION A

1 Diagram 1 shows the set-up of apparatus for the electrolysis 2.0 moldm -3 copper(II) chloride solution
using carbon electrodes.

Gas X

Carbon electrode Y Copper(II)sulphate solution 1.0 mol dm-3

Carbon electrode Z

Diagram 1
(a) Write the formula of all the ions present in the aqueous copper (II)chloride solution.

…………………………………………………………………………………….
[1 mark ]
(b) (i) State the observation at carbon electrode Z

...……………………………………………………………………………..
[1 mark ]
(ii) Write the half equation for the reaction at carbon electrode Z.

………………………………………………………………………………
[1 mark ]
(c ) Gas X is formed at carbon electrode Y. When gas X is delivered into
aqueous potassium iodide solution , the solution turns to brown.
(i) Name gas X.

……………………………………………………………………………….
[1 mark ]
(ii) Write the ionic equation for the reaction between gas X and potassium iodide
solution.

……………………………………………………………………………….
[2 marks ]
(iii) State the substance that acts as reducing agent.

………………………………………………………………………………
[1 mark ]
(d) When electrolysis is carried out after 2 hours , gas W which is a colourless gas is produced
at electrode Y.
(i) Name gas W.

…………………………………………………………………………….
[1 mark ]
(ii) Describe a chemical test to identify the gas W.

…………………………………………………………………………….

……………………………………………………………………………
[2 marks ]
Set 2 2
Chemistry Intensive Revision Program - Set 2

2 Diagram 2.1 shows the set-up of the apparatus for an experiment to construct the Electrochemical
Series through the ability of metals to displace other metals from their salt solution.

Silver nitrate solution

Zinc plate

Diagram 2.1
The experiment was repeated using silver, copper and P metals to replace zinc and P nitrate
solution to replace silver nitrate solution.
Table 2.2 shows the result obtained.

Experiment Metal Silver nitrate solution P nitrate solution

I Zinc Silver metal is displaced. P metal is displaced.

II Copper Silver metal is displaced. No reaction.

III P Silver metal is displaced.

Table 2.2

(a) What is meant by Electrochemical Series?

........................................................................................................................................
[1 mark]

(b) Based on the results in Table 2.2, arrange the metals silver, copper, P and zinc in ascending
order of electropositivity.

More electropositive [1 mark]

(c) Name the suitable metal P.

…………………………………………………………………………………….. [1 mark]
(d) Based on Experiment I :
(i) Zinc can displace silver metal from silver nitrate solution. Explain why.

…………………………………………………………………………………… [1 mark]
(ii) Write the chemical equation for the reaction.

…………………………………………………………………………………… [2 mark]
(iii) What is the change in the oxidation number of zinc?

…………………………………………………………………………………… [1 mark]
(e) Diagram 2.3 shows the set up of apparatus for the reaction between metal P and copper(II)
nitrate solution.

Copper(II) nitrate
Metal P plate solution

Diagram 2.3
What is the colour change of the of copper (II) nitrate solution?. Explain why.

…………………………………………………………………………………………..

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Chemistry Intensive Revision Program - Set 2

…………………………………………………………………………………………..
[2 marks]
(f) State two uses of the Electrochemical Series besides the determining the ability of a metal
to displace another metal from its salt solution.

……………………………………………………………………………….............

………………………………………………………………………………….............
[2 marks]
3 Diagram 3 shows the set- up of apparatus of Voltaic cell.

Copper plate
Zinc plate

Porous pot
Solution of Y
Zinc sulphate
solution

Diagram 3
(a) State the function of porous pot.

……………………………………………………………………………………
[1 mark]
(b) (i) Suggest one suitable solution of Y.

…………………………………………………………………………………
[1 mark]
(ii) Name the ions exist in the solution you have stated in (b)(i).

…………………………………………………………………………………
[1 mark]
(c) State the electrode acts as positive terminal. Explain your answer

..........……………………………………………………………………………………... [2 marks]
(d) State the observation at zinc electrode .

………………………………………………………………………………..........…….......[1 mark]

(e) Electrode zinc is replaced by silver metal and zinc sulphate solution is replaced by silver
nitrate solution.
Complete Table 3.1 to show the differences that happen in voltaic cell before and after zinc
electrode and zinc sulphate solution are replaced by silver electrode and silver nitrate solution.

Silver electrode Zinc electrode

and silver nitrate solution. and zinc nitrate solution

Observation at solution Y you

have suggested in (b) (i)

Half equation for the reaction

occur at copper electrode.

Table 3.1
[4 marks]

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Chemistry Intensive Revision Program - Set 2

(f) Explain why there are differences in observation you have stated in (e) in terms of the
number of Cu2+ in the solution.

…………………………………………………………………………………………………………

………………………………………………………………………………………..

[1 mark]

4 iagram 4 shows the set-up of apparatus to investigate the reaction between potassium iodide
solution and chlorine water through the transfer of electrons at a distance.

Diagram 4

(a) What is the function of galvanometer ?

..................……………………………………………………………………………………………[1 mark
]
(b) On the Diagram 4, draw the direction of the flow of electrons.
[1 mark]
(c) (i) What is the colour change in the solution around electrode P?

..................................................................................................................................[1 mark ]
(ii) Describe a chemical test to identify the product formed in the solution at electrode P.

..........……………………………………………………………………………..............

........ ……………………………………………………………………………...............
[2 marks ]
(d) What is the substance that is being oxidised in the experiment? Explain why.

.....………………………………………………………………………………………….....

…....……………………………………………………………………………………….....
[2 marks]
(e) Write a half equation for the reaction that occurs at electrode Q.

.......………………………………………………………………………………………….... [1 mark]
(f) Suggest another reagent that can replace chlorine water.

..................……………………………………………………………………………….......... [1 mark]
(g) What is the change in oxidation number of chlorine in the reaction?

.......................…………………………………………………………………………………… [1 mark]

Set 2 5
Chemistry Intensive Revision Program - Set 2

5 Diagram 5 shows a laboratory experiment to change Fe 2+ ion to Fe3+ ion.

Chlorine water

Iron (II) sulphate solution

Diagram 5

(a) State one observation in this experiment.

............................................................................................................................. [1 mark]
(b) Write the ionic equation for the reaction occured.

.............................................................................................................................. [2 marks]
(c) (i) What is the role of chlorine water?

.......................................................................................................................... [1 mark]
(ii) Explain your answer.

......................................................................................................................
[1 mark]
(d) State the changes in oxidation number of iron in this experiment.
.................................................................................................................................... [1 mark]
(e) Reducing agent is then added to the solution in diagram 5.
(i) What is meant by reducing agent in terms of electron transfer?
...................................................................................................................................
[1 mark]
(ii) Suggest one reducing agent that can be used .

................................................................................................................................. [1 mark]
(iii) What would you expect to observe when the reducing agent is added to the solution.

................................................................................................................................. [1 mark]

Set 2 6
Chemistry Intensive Revision Program - Set 2

6 Diagram 6.1 shows the apparatus set-up for the experiment to study the effect of
metals P and Q on the rusting of iron nail. The results are recorded after one day.

Experiment After 1 day Observation

A Some dark blue
precipitate.

B Large amount of dark

blue precipitate

C No dark blue precipitate.

Solution turns pink.

Diagram 6.1

(a) What is the function of Experiment A?

.................................................................................................................................[1 mark]

(b) Name the ion which gives the dark blue precipitate in the experiment.

.................................................................................................................................[1 mark]
(c) In which experiment, the rusting of iron nail does not occur? Explain your answer.

.................................................................................................................................

................................................................................................................................ [2 marks]

(d) Arrange the metals Fe, P and Q in order of decreasing electropositivity.

..................................................................................................................................[1 mark]
(e) (i) What happens to metal Q in test tube C?

….................................................................................................................[1 mark]

(ii) Suggest a metal that can be used as metal Q.

........…..........................................................................................................[1 mark]
(f) State the ion that causes the solution in test tube C to turn pink.
Set 2 7
Chemistry Intensive Revision Program - Set 2

....................................................................................................................................[1 mark]

7 Three different powdered metals oxide P, Q and R are heated and hydrogen gas is allowed to pass over
them as shown in Diagram 7.1. Table 7.2 shows the results obtained.

Dry hydrogen
gas P Q
R

Heat

Diagram 7.1

Metal oxide
During heating
P Glows dimly
Q Does not glow
R Glows brightly
Observation
After heating
The brown powder turns shiny grey
It turn yellow when hot and white when cold
The black powder turns brown

Table 7.2
(a) Why metal Q does not glow during the heating?

…………………………………………………………………………………………. [1 mark]
(b) Arrange metals P, Q, R and Hydrogen in descending order of reactivity.

…………………………………………………………………………………………. [1 mark]
(c) Based on the reaction between P and hydrogen gas, which substance is reduced?
State your reasons.

.......…………………………………………………………………………………...........
[2 marks]
(d) Which substance acts as the oxidizing agent in the reaction between P oxide and
hydrogen?

……………………………………………………………………………………………
[1 mark]
(e) Given that the oxide of metal P has the empirical formula of PO, write chemical equation to
represent the reaction between oxide P and hydrogen gas.

………….…………………………………………………………………………………
[2 marks]
(f) Name the brown powder formed.

………………………………………………………………………………………….
[1 mark]
(g) The following shows the positions of carbon and metals X, Y and Z in the reactivity series of
metals
X, carbon, Y, Z
Increasing reactivity

Can carbon can be use to extract metal X from its oxide? Explain your answer.

.........……………………………………………………………………………………

Set 2 8
Chemistry Intensive Revision Program - Set 2

……….........……………………………………………………………………………
[2 marks]

SECTION B
8 (a) What is the meaning of ‘oxidation’ and ‘reduction’ in terms of electron tranfer.
[2 marks]

(b) Describe the oxidation and reduction process in terms of the electron transfer that occurs in
each of the following reaction :

(i) combustion of magnesium in excess oxygen

(ii) Voltaic cell using zinc and copper as pair of metals.

Include half-equations and ionic equations in your answer.

[9 marks]
(c) You are supplied with the following apparatus :
 U-tube
 Carbon electrodes
 Galvanometer
 Connecting wire

Using suitable chemicals and the apparatus above,

(i) Draw a labelled diagram of the apparatus that you can use to investigate electron
transfer at a distance for the following reaction.

2Fe2+(aq) + Br2(aq) → 2Fe3+ (q ) + 2Br-(aq)

In your diagram, show the positive and negative terminal.
[5 marks]
(ii) Name the oxidising and reducing agents in the reaction in c (i).
[2 marks]
(iii) State the changes that can be observed after 10 minutes.
[2 marks]

9 (a) Table 9 shows two reactions and their equation respectively.

Reaction The equation

I KOH + HCl→ KCl + H2O
II Mg + 2HCl→ ZnCl2 + H2
Table 9
Based on the table 8, determine which reaction is a redox reaction and
which reaction is non-redox reaction. Explain your answer [4 marks]

(b) By using a suitable example for each of the reaction below, explain how these reactions
can occur.

(i) Oxidation of Mg atoms to Mg2+ ions.

[5 marks]
(ii) Reduction of MnO42- ions to Mn2+ ions.
[5 marks]
Include half-equations for the oxidation and reduction reactions in your answers.

(c) Diagram 9.1 shows the set-up of the apparatus of the displacement reaction.

Copper sulphate solution

Zinc plate

Set 2 9
Chemistry Intensive Revision Program - Set 2

Diagram 9.1

State the observation for this reaction and write the half equation for the chemical changes
that take place. Identify the oxidising agent and reducing agent for this reaction.
[6 marks]

SECTION C

10 (a) Using a suitable example explain the meaning of electrolyte.

[2 marks]
(b) You are supplied with the following substances:
 Zinc plate
 Copper plate
 Copper (II) sulphate solution
By using the above substances and suitable apparatus in the chemistry laboratory, describe an
experiment to transform the chemical energy to electrical energy.
In your description, draw a labelled diagram, explanation how the transformation can occur and write
the half equation for the reactions. [8 marks]
(c) (i) One of the factor that affects the discharge of ion at the electrode for electrolysis of aqueous
solution is the position of ion in Electrochemical Series.
State two other factors. [2 marks]
(ii) Explain the electrolysis of copper (II) sulphate solution using carbon electrodes. In your
description, state the observations and write the half equations for the reaction at cathode and
anode. [8 marks]
11 (a) What is the meaning of electrolysis and ions?
[2 marks]

(b) Using lead(II) bromide as an example, explain the ionic theory during the electrolysisis of molten
lead (II) bromide.
[8 marks]
(c) You are provided with copper(II) sulphate solution and all the apparatus needed, describe an
experiment to determine the product of electrolysis at the anode and cathode. You are required to
describe the test to confirm the product at the anode. You should also include the half equation at
the electrodes. [10 marks]

12 (a) Using a suitable example , explain what is meant by a redox reaction in terms of oxidation numbers.
[4 marks]

(b) The transfer of electrons take place in many redox reactions.With the help of a labeled diagram,
describe an experiment that you can carry out to study the redox reaction through the transfer of
electrons.
Predict the observation and explain the reaction that will take place in the experiment.
[12 marks]
(c) Using a suitable example, explain why double decomposition is not redox reaction. Give another
example of reaction which is not a redox reaction.
[4 marks]

13 (a) A tablespoon of common salt is dissolved in 250cm3 of water and electrolysed using carbon
electrodes.Name the product at the cathode and write the half equation for the reaction. [2 marks]
(b) Diagram 12 shows a voltaic cell.

Set 2 10
Chemistry Intensive Revision Program - Set 2

Metal X Metal Z
Solution Z

Solution P Solution Q
Diagram 12

By naming suitable substances for P,Q,X,Y and Z, describe the reactions that occur in the voltaic
cell. Your explanation should include the observation and half equation for the reactions that take
place at the electrodes. [8 marks]

(c) A student intends to investigate the redox reaction by the transfer of electrons
at a distance. The chemicals supplied are
 Dilute sulphuric acid
 Acidified potassium manganate(VII) solution
 Iron(II) sulphate solution.
Design a laboratory experiment for the above purpose. [10 marks]

Paper 3

14 An experiment is carried out to construct an electrochemical series of metals. Diagram 14 shows the
set-up of apparatus of voltaic cell .The potential difference between electrode metal L and metal M is
measured. An experiment is repeated by replacing metal M with metal J and Q.

Metal L Metal M

Salt solution L
1.0 mol dm-3

DIAGRAM 14

Diagram 14.1 shows the potential difference of three voltmeters A, B and C for the voltaic cells
with pair of metal L/M, L/J and L/Q respectively.

1.5 2.0 1.5

1.0 2.0
1.0
0.5 V 2.5 0.5 V 2.5

A
· 3.0
0
· B
3.0

Set 2 11
Chemistry Intensive Revision Program - Set 2

1.5 2.0
1.0
0.5 V 2.5

Diagram 14.1
· 3.0
C

Voltmeter Potential Positive

Pair of Metals
difference(V) terminal
L dan M A L

L dan J B L

L dan Q C Q

Table 14.1

(a) Record the voltmeter reading for the pairs of metals in the table 14.1. [3 marks]

(b) State the hypothesis of the experiment

............................................................................................................................

........................................................................................................................... [3 marks]
(c) Arrange J, L, M and Q metals in the descending order in the electrochemical series

............................................................................................................................... [3 marks]
(d) Iron metal is located between metal M and metal L in the electrochemical series.
State which metals are more electropositive and less electropositive than iron metal.
More electropositive than iron

................................................................................................................................
Less electropositive than iron

................................................................................................................................. [3 marks]
(e) By using the data from that experiment, suggest the possible voltage, if M and Q metals is used to
construct electrochemical series.

…………...................................................................................................................... [3 marks]

15 The diagram below shows a simple chemical cell that was set up to investigate the arrangement of
metals P, Q, R and S.

Electodes

Electrolyte

The table below shows the pair of metals used for each experiment.
Exsperiment Pairs of metals Negative electrodes Voltmeter readings (V)

Set 2 12
Chemistry Intensive Revision Program - Set 2

I R and Q Q
II S and R S
III P and S P
IV S and Q

The voltmeter readings for each experiment are shown in the diagram below.

1 2 1 2
0 0

Experiment I Experiment II

1 1 2
2
0 0

(a) Read and record the voltmeter readings in the table above. [3 marks]
Experiment III Experiment IV
(b) State the variables for this experiment.

(i) The manipulated variable.

………………………………………………………………………................……………………

(ii) The responding variable

………………………………………………………………………………………………………

(ii) The fixed variable

…………………………………………………………………………………………………… [3marks]
(c) State the hypothesis for this experiment.

………………………………………………………………………………………………………

……………………………………………………………………………………………………… [3 marks]

(d) Predict the negative terminal in experiment IV.

……………………………………………………………………………………………………… [3 marks]
(e) Based on the voltmeter reading, arrange the metals of P,Q, R, dan S according to ascending order
of electropositivity.

……………………………………………………………………………………………………… [3 marks]
(f) What is the inference that can be made for the mass of the negative electrode and the positive
electrode in each experiment after a certain time interval?
Set 2 13
Chemistry Intensive Revision Program - Set 2

……………………………………………………………………………………………………….

……………………………………………………………………………………………………… .. .. [3 marks]
(g) Why is the voltmeter reading for experiment II bigger than experiment IV?
………………………………………………………………………………………………………

………………………………………………………………………………………………………

[3 marks]
(h) In experiment I, if Q is copper metal, R is silver metal, and sulphuric acid is used as the electrolyte,
(i) state two observations that can be made in the experiment.
………………………………………………………………………………………………

………………………………………………………………………………………………
[3 marks]
(ii) write the half equation for the reaction that occurs at the copper metal.

………………………………………………………………………………………………
[3 marks]

(i) Classify the metals that can displace and cannot displace metal Q from the salt solution of Q.

Metals that can displace metal Q Metals that cannot displace metal Q
from salt solution of Q. from salt solution of Q.

[3 marks]
17 The diagram below shows two sets of electrolysis that can be carried out on copper(II) sulphate solution
using different types of electrodes. The two experiments will give two different results.

Carbon Copper
Carbon electrode electrode Copper
electrode electrode
Copper(II)
sulphate
solution

Intensity of the blue colour decreases Intensity of the blue colour remains the same .

Based on the observations above, plan an experiment to investigate the effect of type of electrodes in the
electrolysis of copper(II) sulphate solution.
Your planning must consists of the following:
(a) Statement of the problem
(b) Hypothesis

Set 2 14
Chemistry Intensive Revision Program - Set 2

(c) Variables
(d) List of substances and apparatus
(e) Procedures
(f) Tabulation of data
[17 marks]

ANSWER:
1 (a) Cu2+ , H+ , Cl- , OH- 1
(b) (i) Brown solid deposited 1
(ii) Cu2+ + 2e → Cu 1

(c ) (i) Chlorine 1
(ii) Cl2 + 2I- → I2 + 2Cl-
The formula of reactants and product correct 1
Balanced 1
(iii) Potassium iodide / iodide ion 1

(d) (i) Oxygen 1

(ii) Put a glowing wooden splinter near the mouth of the test tube 1
Glowing wooden splinter is lighted up 1

2 (a) An arrangement of metals based on the tendency of each metal atom to

donate electrons. 1
(b)
silver Copper P zinc

More electropositive 1
(c) Iron //Tin // Lead 1
(d) (i) Zinc is higher than silver in the Electrochemical series//
Zinc is more electropositive than silver 1
(ii) Zn + 2AgNO3→ Zn(NO)3 + 2Ag
The formula of reactants and products correct 1
Balanced 1
(iii) 0 to +2 1
(e) Blue to colourless / become fade / paler 1
The number / the concentration of Cu2+ becomes lower 1
Set 2 15
Chemistry Intensive Revision Program - Set 2

(f) Determine the terminal of a voltaic cell 1

Compare the standard cell voltages of voltaic cells 1

3 (a) to allow the flow of ion 1

(b) (i) Copper(II) sulphate// Copper(II) chloride// Copper(II) nitrate 1
(ii) Copper (II) ion, sulphate ion//chloride ion//nitrate ion 1
(c) Copper 1
Copper less electropositive than zinc 1
(d) zinc becomes thinner 1

(e)
Silver electrode and Zinc electrode and
silver nitrate solution. zinc nitrate solution

Observation on Y The intensity of blue The intensity of blue

solution you have colour increases. colour decreases.
suggested in (b) (i)

Half equation for the

reaction at cooper Cu Cu2+ + 2e Cu2+ +2e Cu
electrode

1+1+1+1
(f) If silver metal is used, the number of Cu2+ ion increases but if Zn metal is used, the number
of Cu2+ ion decreases. 1

4 (a) To detect the flow of electric current 1

(b)

e e
G
e e
Electrode P ectrode Q

Potassium iodide solution

Chlorine water

Dilute sulphuric acid

(c) (i) Colourless to brown 1

(ii) Put a few drops of starch solution 1
A blue precipitate is formed 1
(d) Potassium iodide // Iodide ion 1
Loss electron // increase in oxidation number 1
(e) Cl2 + 2e→ 2Cl- 1
(f) Bromine water // acidified KMnO4 solution // acidified K2Cr2O7 solution 1
(g) 0 to -1 1

5 (a) The colour of the solution changes from green to brown/yellow 1

(b) Cl2 + 2 Fe2+ → 2Fe3+ + 2Cl-
The formula of reactants and products correct 1
Balanced 1
(c) (i) Oxidising agent 1
(ii) Change Fe2+ to Fe3+ 1
Set 2 16
Chemistry Intensive Revision Program - Set 2

(d) +2 to + 3 1
(e) (i) The substance that loss of electrons 1
(ii) zinc 1
(i) The colour of the solution changes from brown to green 1

6 (a) Control experiment 1

(b) Iron(II) ion 1
(c) Experiment C. Iron(II) ion does not exist/present 1+1
(d) Q, Fe, P 1
(e) (i) Metal Q corrodes 1
(ii) Zinc/Aluminium/Magnesium 1
(f) OH-//hydroxide ion 1

7 (a) because hydrogen is less reactive than metal Q/

Hydrogen is unable to reduce the oxide of metal Q 1
(b) Q, Hydrogen, P, R 1
(c) (i) P oxide, 1
loss oxygen/gain of electrons/decrease in oxidation number 1
(ii) P oxide 1
(iii) PO + H2 P + H2O 2
(d) Copper 1
(e) No, 1
because carbon is less reactive than metal X/
Carbon is unable to reduce the oxide of metal X. 1
10

8 (a) Oxidation is loss of electron 1

Reduction is a gain of electron. 1

(b) (i) Magnesium atom loses two electrons to form magnesium ion / Mg 2+ 1
Mg → Mg + 2e 1

Oxygen molecule gains the electrons to form oxide ions / O2- 1

O2 + 4e → 2O2- 1

Ionic equation :
2Mg + O2 → 2Mg + 2O2- 1

(c) (ii) At anode :

Copper(II) ion / Cu2+ gain two electrons to form copper atom 1
Cu2+ + 2e → Cu 1

At cathode :
Zinc atom gains two electrons to form zinc ion / Zn 2+ 1
Zn → Zn2+ + 2e 1

Ionic equation :
Zn + Cu2+ → Zn2+ + Cu 1……10
(Max : 9)

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Chemistry Intensive Revision Program - Set 2

(c) (i)
[ Suggested answer ]

V Carbon
Positive terminal Negative terminal

Bromine water
Iron (II)
sulphate
solution

Sulphuric acid

Funtional diagram 1
[Lables for :
bromine water 1
iron(II) sulphate solution 1
sulphuric acid 1
Positive and negative terminal 1… 5

(c) (i) Oxidizing agent : bromine water / Br2 1

Reducing agent : iron(II) sulphate solution / iron(II) ion / Fe 2+ 1

(ii) The green colour of iron(II) sulphate changes to yellow/brown colour.

The brown colour of bromine water becomes colourless. 1
1

20

9 (a) Reaction I is a non-redox reaction 1

Because all the elements in reaction I do not undergo any change
in oxidation numbers I

Reaction II is a redox reaction 1

Because zinc and hydrogen undergo changes in oxidation numbers 1

(b) (i) Magnesium react with copper(II)sulphate solution 1

Magnesium atoms are oxidized to magnesium ions 1
Copper(II)ions are reduced to copper atoms 1
Mg→Mg2+ + 2e 1
Cu2+ + 2e→ Cu 1..

(ii) Acidified potassium manganate (VII) solution react with

iron(II)chloride solution 1
iron(II) ions are oxidized to iron(III)ions 1
Manganate (VII) ions are reduced to Mn2+ ions 1
Fe2+→Fe3+ + e 1
MnO2-4 + 8H+ + 5e→ Mn2+ + 4H2O 1

(c ) Zinc dissolve //Brown precipitate /deposited//blue solution becomes

colourless 1
Zn→Zn2+ +2e 1
Set 2 18
Chemistry Intensive Revision Program - Set 2

Cu2+ + 2e→ Cu 1
Zinc acts as a reducing agent 1
Copper (II)ions acts as an oxidizing agent 1

10 (a) Compound that can conduct electricity in molten state

or aqueous solution. 1
[ example: suitable electrolyte] 1

(b) Functional diagram 1

Labelled 1

Copper plate and zinc are dipped into the beaker contains
copper(II) sulphate solution 1
Copper plate and zinc are connected to voltmeter. 1
Voltmeter shows readings// the voltmeter needle deflected 1
The flow of electrons form zinc to copper produces electrical energy. 1

Zn→ Zn2+ + 2e 1

Cu2+ + 2e→ Cu 1

(c) (i) concentration of ion 1

Type of electrode 1

(ii) OH- ion and SO42- ion move to anode 1

OH- is selected to be discharged to produce oxygen. 1
Bubble of gas is formed at anode 1

4OH-  O2 + 2H2O + 4e 1

Cu2+ ion and H+ ion move to cathode 1

Cu2+ ion is discharged to form copper 1
Brown solid deposited at cathode 1

Cu2+ + 2e  Cu 1

11 (a) Electrolysis is a process whereby a compound is decomposed into its

constituent elements when an electric current passes through
an electrolyte 1
Ion : The charged particle // negative (or positive) charged particle 1

(b) the ions presents are lead ions / Pb2+ and bromide ions / Br- 1
lead ions / Pb2+ are attracted to the cathode 1
bromide ions / Br- are attracted to the anode 1
at the cathode the lead ions / Pb2+ receive 2 electrons to become lead metal 1
Pb2+ + 2e → Pb 1
at the anode the bromide ions / Br- to become bromine atom 1
2 bromine atom combine to form bromine gas / molecule 1
2Br- → Br2 + 2e 1

(c)
Diagram
Functional 1
Labelled 1

Procedure :
1. Pour the copper(II) sulphate solution into the electrolytic cell 1
2. Fill the test tube with copper(II) sulphate solution and inverted the test
tube on the carbon electrodes . 1
3. Switch on the current. 1
4. Collect the gas produce at the anode. Test the gas. 1
Observation
Set 2 19
Chemistry Intensive Revision Program - Set 2

Cathode : Brown solid deposited 1

Anode : Colourless gas released 1
Place a glowing wooden splinter near the mouth of the test tube 1
glowing wooden splinter is lighted up 1
Equation :
Cathode : Cu2+ + 2e → Cu 1
Anode : 4OH- → 2H2O + O2 + 4e 1
Max 10
12 (a) changes in the oxidation number 1
[ state a suitable example//write chemical equation of redox reaction] 1
Example:The reaction between chlorine and potassium iodide solution
[The element that undergoes oxidation has increase of oxidation number] 1
Example: Iodide ion is oxidized to iodine because the oxidation number
of iodine increase from -1 to 0.
[The element that undergoes reduction has decrease of oxidation number]
Example: Chlorine is reduced to chloride ion because the oxidation
number of chlorine decrease from 0 to -1 1

(b) [Material : Any suitable oxidizing agent , any suitable reducing agent
and any suitable electrolyte] 1

[ Apparatus : U-tube , carbon electrodes , connecting wires and galvanometer] 1

Diagram
Functional 1
Labelled 1
Prosedure
1 Sulphuric acid is put in a U-tube until 1/3 full 1
2 Bromine water is put in one end of the U-tube while potassium
iodide solution is put in the other end of the U-tube 1
3 carefully 1
4 Two carbon electrodes connected by connecting wires to a galvanometer
are dipped into the two solution at the two ends of the U-tube. 1
Observation
1 The colour of bromine water change from brown to colourless 1
2 The colour pf potassium iodide solution change from
colourless to yellow/brown 1
3 The needle of the galvanometer is deflected 1

Reaction that take place

Oxidation reaction : Br2 + 2e→ 2Br- 1
Reduction reaction: 2I- → I2 + 2e 1
Max : 12

(c) [Any suitable example of double decomposition] 1

[ A balanced equation] 1
The reaction is not redox reaction because the oxidation number of
all elements do not undergo any change 1
Neutralization 1

13 (a) Hydrogen 1
2H+ + 2e→ H2 1
(b) X=Zinc ,Y=Copper ,Z=Potassium chloride ,
P=Zinc sulphate , Q= copper(II)sulphate 1

Zinc negative terminal 1

Zn→Zn2+ + 2e 1
Zinc becomes thinner 1

Copper is the positive terminal 1

Cu2+ + 2e→ Cu 1
Brown solid deposited//Intensity of the blue colour of copper(II)
sulphate solution decreases 1

Set 2 20
Chemistry Intensive Revision Program - Set 2

electron flow from zinc to copper 1

(c ) Apparatus: U-tube , galvanometer, connecting wires, carbon electrodes 1

Dilute sulphuric acid is poured into U-tube 1

Iron(II)sulphate solution is added into one of the arms of the U-tube 1
Carefully 1
Acidified potassium manganate(VII) solution is added to the other
arm of the U–tube 1
A carbon electrode is then immersed into each arm of the U-tube 1
The electrodes are then connected to the galvanometer by connecting
Wires 1
The green colour of iron(II)sulphate turns to yellow 1
The purple colour of potassium manganate(VII) decolourises 1
The deflection of the galvanometer needle shows that electrons
Flow from iron (II) sulphate to acidified potassium manganate(VII) 1

Paper 3 :
Question
Rubric Score
Number
[Able to write potential difference with two decimal correctly]
Pair of metals Potential Positive
difference(V) terminal
14(a) 3
L and M 1.10 L
L and J 1.80 L
L and Q 0.40 Q
[Able to give the hypothesis accurately]
14(b) The further the distance between two metals in the electrochemical 3
series, the higher the potential difference / voltage
[Able to arrange the metals in the electrochemical series in
14(c) descending order correctly] 3
J, M, L, Q
[Able to classify the metals correctly]:
14(d) More electropositive : J, M 3
Less electropositive : L, Q
[Able to predict correctly]
14(e) Answer: 1.50V 3

15 (a) Experiment Voltmeter reading(V) 3

I 0.60
II 1.00
III 1.60
IV 0.40
(b) Manipulated : Pairs of metals//Different pairs of electrodes 3
Responding: Voltmeter reading
Fixed: Volume and concentration of the electrolyte.
(c) The further the distance between two metals in the electrochemical 3
series,the higher the value of the voltage/ voltmeter reading.
(d) S 3
(e) R, Q, S, P 3
(f) Mass of negative electrode decreases but the mass of positve electrode 3
increases.
(g) Distance between S and R is further than S and Q in the 3
Electrochemical Series.
(h)(i) Copper strip becomes thinner. 3
Intensity of blue colour remains the same.

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Chemistry Intensive Revision Program - Set 2

(h)(ii) Cu  Cu2+ + 2e 3
(i) Can displace:P,S 3
Cannot displace: R
Jumlah 30
16 Problem Statement
How does the type of electrodes affects the products of electrolysis of 3
copper(II) sulphate solution?
Variables
a) manipulated: type of electrodes / carbon and copper electrodes
b) responding : product of electrolysis
c) fixed: volume and concentration of copper(II) sulphate solution
Substances 3
Copper(II) sulphate solution 1.0 mol dm-3
Apparatus
Batteries, connecting wires with crocodile clips,ammeter, rheostat,
carbon electrodes, copper strips and beaker. 3
Procedures
 Two copper strips are cleaned with sand paper and the mass is
recorded.
 A beaker is filled with copper(II) sulphate solution. 3
 Two copper strips are immersed in the copper(II) sulphate.
 Both copper strips are connected to the connecting wires, switch,
ammeter and rheostat.
 On the switch/ complete the circuit and let the experiment continue
for 20 minutes.
 Record the observation of the solution, anode and cathode.
 Repeat the experiment by using carbon rods
Table
Type of Observations
electrodes Anode Cathode
Copper electrode. 3
Carbon electrode
Jumlah 15 + 2

Set 2 22