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Chapter 1
Atoms, molecules & chemical
bonding
David P. White
c
Prentice Hall © 2003 Chapter 6
The Wave Nature of Light
The Wave Nature of Light
E 2.18 10 18
1
J 2
n
where n is the principal quantum number (i.e., n = 1, 2, 3, … and nothing else).
the –ve sign indicates that the energy of the electron in the atom is lower than the
energy of a free electron
Many-Electron Atoms
Electron Configurations
Hund’s Rule
• Electron configurations tell us in which orbitals the
electrons for an element are located.
• Hund’s rule: When more than one orbital has the same
energy, electrons occupy separate orbitals and do so
with parallel spins.
• Electrons fill orbitals starting with lowest n and moving upwards;
• No two electrons can fill one orbital with the same spin
(Pauli).
• Molecular orbitals:
• each contain a maximum of two electrons;
• have definite energies;
• can be visualized with contour diagrams;
• are associated with an entire molecule.
Electronegativity
Bond Polarity and
Electronegativity
Electronegativity and Bond Polarity
• Difference in electronegativity is a gauge of bond
polarity:
• electronegativity differences around 0 result in non-polar
covalent bonds (equal or almost equal sharing of electrons);
• electronegativity differences around 2 result in polar covalent
bonds (unequal sharing of electrons);
• electronegativity differences around 3 result in ionic bonds
(transfer of electrons).
Dipole-Dipole Forces
Intermolecular Forces
Dipole-Dipole Forces