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87
ASME PTC 4-2013
5-15.4 QpBSlf, Sulfation Credit, Percent 5-15.6 QrBSb, Sensible Heat in Sorbent Credit,
Sulfation is the reaction of sulfur dioxide (SO2) with Btu/hr (W)
calcium oxide (CaO) and oxygen to form calcium sulfate QrBSb 5 MrSb HSbEn, Btu/hr (W)(5-15-7)
(CaSO4). The reaction is exothermic.
where
MpSF
QpBSlf 5 MFrSc HrSlf , %(5-15-4) HSbEn 5 enthalpy of the sorbent entering the steam
HHVF generator envelope, Btu/lbm (J/kg)
MrSb 5 mass flow rate of sorbent, lbm/hr (kg/s)
where
HrSlf 5 heat generated in the reaction of sulfur
dioxide, oxygen, and calcium oxide to 5-15.7 QrBWAd, Energy Supplied by Additional
form calcium sulfate per pound of sulfur Moisture Credit, Btu/hr (W)
capture, 6,733 Btu/lbm (15 660 kJ/kg) Typical examples of additional moisture are sootblow-
MFrSc 5 mass fraction of sulfur capture, lbm/lbm ing and atomizing steam.
(kg/kg) 5 ¤ MrStEnz
QrLClh5
QrBWAd MrSbk MFrClhk
(HStEnzHrk , Btu/hrBtu/hr
– HWRe), (W) (W)
(5-15-8)
5-15.5 QrBX, Auxiliary Equipment Power Credits, where
Btu/hr (W) HStEnz 5 enthalpy of additional moisture entering
Typical auxiliary equipment includes pulverizers, gas the envelope, Btu/lbm (J/kg)
recirculating fans, hot primary air fans, and boiler circu- HWRe 5 enthalpy of water at the reference tem-
lating pumps. Note that credits shall not be calculated perature, Btu/lbm (J/kg)
for forced draft fans, cold primary air fans, and other MrStEnz 5 mass flow rate of additional moisture,
equipment when credits are calculated based on the lbm/hr (kg/s) at location z
measured fluid temperature exiting the equipment. For
example, when a credit is calculated for entering air in 5-15.8 Conversion of Credits on Rate Basis to Percent
accordance with para. 5-15.1, the energy added by the Input Fuel Basis
forced draft and primary air fans is included; thus, add- The credit calculated on a rate or unit of time basis
ing the credit for fan power would be accounting for the may be used to calculate efficiency directly. If the credit
energy added twice. on a percent input from fuel basis is desired, it may be
calculated after completion of the efficiency calculations
5-15.5.1 For Steam Driven Equipment using the calculated fuel input.
97
ASME PTC 4-2013
107
ASME PTC 4-2013
MrStDs 5 mass flow rates of the steam/water at the (c) the test main steam and reheat mass flow rates
design condition (for feedwater flow and utilized to calculate actual absorptions are corrected for
intermediate superheater flows, calcu- offdesign load by multiplying by the ratio of the design
lated based on the corrected spray water main steam flow divided by the test main steam flow,
flow), lbm/hr (kg/s) MFrStCr.
PDiSt 5 the measured pressure drop, psi (Pa) (d) main steam temperature and desuperheater spray
PDiStCr 5 the corrected pressure drop, psi (Pa) for once-through steam generators are not functions of
VhCr 5 velocity head correction (if applicable) surface arrangement, and corrections are not necessary.
calculated as follows: Main steam temperature is a matter of steam genera-
2 2 tor controls and should be acknowledged as achievable
1 ¨¥ MrStDs ´ ¥ MrStDs ´
VhCr 5 C2 © -
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ASME PTC 4-2013
QrF 5 MrF HHVF , Btu/hr ( W ) (D-3-2) for hFG at 778F (258C) and 1 psia (0.01 MPa) (the partial
pressure of water vapor in the combustion gas at one
where
atmosphere) for solid and liquid fuels is 1,050 Btu/lbm
HHVF 5 higher heating value of fuel, Btu/lbm
(2 422 kJ/kg). Calculation of LHV from HHV is then
(J/kg). Refer to subsection 5-8.
MrF 5 measured mass flow rate of fuel, lbm/hr
H 2F 8.937 H 2OF
(kg/s) LHV 5 HHV C1 , Btu/lbm (kJ/kg)
100
QrF 5 heat input from fuel, Btu/hr (W)
QrB 5 summation of credits, Btu/hr (W) basis. (D-4-1)
Refer to Section 5 for the general method where
of calculation. For the credits calculated on C1 5 1,050 Btu/lbm (2 442 kJ/kg)
a percent input from fuel basis, multiply H2F 5 the quantity of H2 in the fuel, % mass
by (QrF/100) to convert to Btu/hr (W). H2OF 5 the quantity of H2O in the fuel, % mass
Below are supplementary comments on the
calculation of credits that are not measured For gaseous fuels, the LHV should be calculated based
directly. on the LHVs specified for the individual gas fuel con-
stituents in ASTM D3588.
The credits due to heat in entering dry air (QrBDA) It is recognized that calculation of LHV (and fuel effi-
and moisture in entering dry air (QrBWA) require the ciency) is dependent upon the temperature at which the
mass flow rate of dry air. The mass flow rate of dry test is conducted. However, the difference in the cal-
air is calculated stoichiometrically from the ultimate culated LHV due to the difference between 77°F (25°C)
fuel analysis and unburned carbon in the refuse (refer and the temperatures of the laboratory test is minor and
to Section 5 and the Combustion Calculation Form, within the uncertainty of the measured HHV.
Nonmandatory Appendix B). For units that do not LHV will be on the same basis, constant pressure or
utilize sorbent for reduction of sulfur emissions, it may constant volume, as HHV.
be necessary to calculate unburned carbon in the refuse The systematic uncertainty of the LHV must consider
(refer to the Unburned Carbon in Refuse Calculation the uncertainty of determining the quantity of hydrogen
Form, Nonmandatory Appendix A). For units that do and moisture in the fuel as well as systematic uncertainty;
use sorbent, it will be necessary to calculate the mass however, the additional uncertainty is usually minimal.
fraction of sulfur capture as well as the unburned carbon Efficiency on a lower heating value basis is calculated
in the refuse (refer to the Sorbent Calculation Form, by substituting the lower heating value for the higher
Nonmandatory Appendix A). The credit due to sulfation heating value in all computations. Since the LHV is
(QrBSlf) is calculated from the mass fraction of sulfur calculated by reducing the fuel HHV by the latent heat
capture that is calculated above. The use of sorbent also of vaporization of the water formed from the combus-
impacts the mass flow rate of dry air. tion of the H2 in fuel and the water content of solid or
liquid fuels, the method of calculating the LHV losses
D-4 EFFICIENCY ON A LOWER HEATING VALUE, due to water from fuel are different depending upon
LHV, BASIS whether calculated on a HHV or LHV basis. The energy
loss on an HHV basis is based on the difference in the
This Code uses the higher heating value of the fuel enthalpy of steam at the exit gas temperature, HStLvCr,
as the preferred method to determine fuel energy input. and the enthalpy of water, HWRe, at the reference
This Section explains how to compute efficiency on a temperature. The energy loss on an LHV basis is based
lower heating value (LHV), or net calorific value, basis. on the difference in the enthalpy of water vapor, at the
Refer to para. 3-1.2 regarding the disadvantages of exit gas temperature, HWvLvCr, and the enthalpy of
expressing efficiency on a lower heating value basis. water vapor, at the reference temperature, HWvRe. Thus,
It is necessary to calculate LHV from the measured HHV. the loss due to water formed from the combustion of H2
There is no universally accepted standard for calculation on an LHV basis, QpLH2FLHV, is calculated per the fol-
of LHV; the constant used for heat of combustion and the lowing equation:
temperature used to determine the latent heat of vaporiza-
tion (hFG) vary between references. Some published meth- QpLH 2FLHV 5 100 MqWH 2F ( HWvLvCr HWv Re) HHV LHV, %
ods are incorrect for SOLID OR LIQUID fuels that contain (D-4-6)
water. It is important that the temperature used for the cal-
culation of hFG be consistent with the basis for the boiler where
efficiency calculations, otherwise the calculated fuel mass MqWH2F 5 water produced from the combustion of
flow rate for a given boiler output will be incorrect. H2 in the fuel on a mass per energy input
This Code specifies a reference temperature of 778F on an HHV basis
(258C). Based on the ASME International Steam Tables It is recommended that parameters associated with
for Industrial Use, IAWPS-IF97, the recommended value the fuel or input from fuel continue to calculated on an
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