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ENRICHMENT OF PILOTED DIESEL BY HYDROGEN

IN A CI ENGINE WITH EXHAUST GAS


RECIRCULATION FOR OVERCOME ENERGY CRISIS

ABSTRACT combustion duration and on the emission


The futuristic automotive world characteristics Oxide of nitrogen , Carbon
suffers from the extinction of the fossil fuels monoxide and Smoke on a CI engine.
and depletion of available conventional
resources. That forced researchers to find 1. Introduction:
regenerative as well as non-hazardous fuels, Nowadays in daily life, Diesel
especially for the automobile sector. The engines are indispensable. Due to rapid
main criterion for finding an alternative is growth in vehicle population deplete
owing to the emission characteristics from resources and engine performance was a
the conventional fuels and its inverse effect concern for the environment has put
on the ecological balance in the ecosystem additional requirement. Toxic emission from
of the earth's nature. For all the requirement industrial processes and engine Outlet gases
and criteria considerations the green energy like NOX, SOx and PM have under
with less or no effect on atmospheric restriction due to climate change in recent
condition is to be found out. From this, the conference. There on IC engine research
best suitable as well as available abundant in active interest in upgrade performance,
the planet is hydrogen, and also hydrogen renewable fuel and harmless pollutant
burns separately with oxygen to produce emission due to strict engine emission
CO2 and H2O only. But the main difficulty norms. To rectifies the problem by
to solve is hydrogen's preparation or enhancing hydrogen as alternative source
separation from a tedious process replaced for fossil fuel [1]. There may few
requirement. In this paper, the Hydrogen's modifications to use hydrogen fuel is could
property and suitability for this planet are be the main attraction point of view fuel
verified under various field and places of hydrogen on existing engine. The addition
usages as an automobile blood under some manifold injection technique is complex
changes or conditions to be followed as modification [2,3].
about normal DI CI engine was converted to H2O emission during the combustion
operate as a gas engine. Hydrogen-induced of hydrogen as a fuel as main plus point. But
at the intake manifold at a pressure of 2 bars still, expensive process for separation of
along with recirculates outlet gas and air. hydrogen because it is not freely available
The experimental investigation by [4]. Moreover, there should be staunch
enrichment of hydrogen without EGR, with safety mechanism implemented at the actual
10% EGR and with 20% EGR. The rate of usage point as hydrogen is highly
hydrogen was set constantly at 2 L/M. This inflammable. On a commercial scale of
paper provided a potential to investigate the automobile gasoline engine have don't
effect of the addition of H2 with EGR, implemented in automobiles, but researchers
without EGR ratio on the performance such make modification from the conventional
us Brake thermal efficiency and Specific gasoline engine with hydrogen as fuel [6].
fuel Consumption, on the combustion Thereby higher octane number for
ignition delay (Ignition postpone) and hydrogen researchers such fuel in a gasoline
engine. No researchers taken modify a China, in this work with under four different
portion of existing diesel engine as hydrogen excess air ratio(1, 1.2,1.5 and 1.8) on the
fuel due to higher self-ignition temperature different hydrogen fractions (3.9%, 5.3%,
[7]. When lean mixture operating condition, 7.2%, 8.9% and 10.5% ) at an engine speed
using hydrogen fuelled in engine faces to the of 1500 rpm. The result shows that 42%
problem is higher NOx emission. Thereby peak in-cylinder pressure at λ = 1.2 than
the higher flame temperature of hydrogen on neat gasoline condition with 7.2% of
modified engine lead to higher NOx hydrogen addition fraction, At hydrogen
emission. Heffel et al, experimental additional fraction from 3.9% to 10.5% with
modified ford ZETEC engine with hydrogen λ = 1.8, raised 18% to 31% the effective
and cooled EGR. Reported that level of NOx thermal efficiency. Then emission such us
emission compared with the non-EGR mode UHC and CO emissions decreased but Nox
at a rate of hydrogen on 20 LPM [3].. emission simultaneously increases with
To operate as HCCI engine mode by hydrogen addition fraction it could be
using hydrogen, the cylinder gas balanced by lean burn condition at large
temperature should be increased adequately range[5].
high so on the appropriate time is taken for
hydrogen to reach an auto ignition on the 2. Hydrogen in CI engine
cylinder[9].to attain the auto ignite hydrogen The idea in IC engines using of
by a pilot diesel injection around 10° to 60° hydrogen is not new. In the absence of air
CA before TDC. [10–13]. Hydrogen high preheating is not possible in CI engine
diffusivity is the main criteria as fuel. because of its auto-ignition temperature is
Hence, the supply of less quantity of 858 K for hydrogen[4]. The alternative
hydrogen either by a manifold or direct method for implement hydrogen with diesel
injection in-cylinder could reduce fuel, induction of hydrogen on intake along
heterogeneity of spray diesel and sequent with air and by pilot injection of diesel on
combustion [14].For all load range exhibit the compression stroke. Hydrogen
the similar brake thermal efficiency on combustion is major different from
hydrogen engine [15]. hydrocarbon fuel combustion. Thereby
Methods for hydrogen implement having more extensive flammability for
like continuous manifold injection, hydrogen than diesel fuel. Some major
continuous carburetion, pulsed manifold properties of diesel and hydrogen are
injection and low-pressure direct injection indicated in Table 1 [MAdhujit Deb et al
have been proposed by previous researchers 2015]. As the flame velocity of hydrogen is
[16,17]. Previous studies show with the high, extremely quick combustion usually
supply of 0.15 kg/h of hydrogen leads to takes place [4].Hydrogen requires minimum
upgrading in brake thermal efficiency of ignition energy of 0.02 MJ, which enables
1.29%.there with approximately similar the engine that uses hydrogen to run on even
brake power develop with enriched extremely lean mixtures.
hydrogen, a higher thermal efficiency and a Md. Atiqur Rahman et al (2016)
lower emission compared to diesel engine of Malaysia, have done experimentally by
the similar load ranges [18,19]. Combustion biodiesel (BD40) with hydrogen gas at a
knock, a higher level of pressure rise, and constant flow rate (4 l/m) as BI fuel diesel
temperature are few problems should engine compared with neat diesel. The result
carefully deal with the proper study to shows that by 10% of EGR is added to
control it [20,21].Renxu Niu et al (2016) reduce 12.8% of EGT and 20% of Nox
emission at final load condition. Thereby by 3.Exhaust gas recirculation
BD40 with hydrogen at maximum load To control NOx emission effective
condition without EGR enhanced to raise and economic method could exhaust gas
21.9% of BTE while comparing with neat recirculation (EGR) in IC engine. The main
diesel. 63.3% of UHC emission decreases by exhaust component gases such as NOx, HC,
induced hydrogen compared with diesel Smoke, CO and particulate matter in CI
[22]. The experimental investigation by engine. To reach volumetric efficiency,
enrichment of hydrogen without EGR, with thereby attain the exhaust gas temperature is
10% EGR and with 20% EGR. The rate of to be higher than normal intake air. A little
hydrogen was set constantly at 2 L/M. This quantity of fresh air entered the combustion
paper provided a potential to investigate the chamber during the recirculation of exhaust
effect of the addition of H2 with EGR, gas feeding.
without EGR ratio on the performance such
us Brake thermal efficiency and Specific Their effect on exhaust emission by the
fuel Consumption, on the combustion oxygen level reduction in the combustion
ignition delay (Ignition postpone) and chamber. The specific heat of charge
combustion duration and on the emission increased by induced of exhaust gas into an
characteristics Oxide of nitrogen , Carbon engine cylinder. This results in suppressed
monoxide and Smoke on a CI engine. combustion rate of the air-fuel mixture. By
decrease oxygen content of air influence to
Table 1.Properties of Hydrogen with decrease combustion rate so the peak
Diesel temperature will reduce.

Properties Diesel Hydrogen


Cn Thus, lead to NOx creation in the
Chemical H1.8n engine is decreased. The percentage of EGR
H2
composition (C8- (Ƞ (EGR)) in the engine is defined as
C20)
Auto-ignition Volume of EGR
530 858 Ƞ(EGR)= Total charge into the cylinder x100 (1)
temperature (K)
Minimum ignition
- 0.02 AFT is decreased because of
energy (mJ)
increase inert gases concentration in
Flammability limits
0.7-5 4-75 combustion chamber [8].Higher soot and
(volume %in air)
PM causes at full loads while usage of EGR,
Cetane number 40–55 -
this problem due to reducing diffusion
Octane number 30 130
combustion. On the part and lower load
Diffusivity in
– 0.63 certain unburned HC shorten in HC
air/(cm2/s) emission on next cycle. In this paper, the
Density 160 °C and 833– engine was an experimental investigation at
0.0838
1.01 bar/(kg/m–3) 881 different EGR rates with Hydrogen flow at 2
Flame L/M. With 10% EGR and 20% EGR is that
30 265–325
velocity/(cm/s) exhaust gas granted on inlet air and
Net heating hydrogen mixture. In this paper, the
42.5 119.93
valve/(MJ/kg) combustion parameters, Performance and
emission characteristics were analyzed.
4. Experimental Setup Mechanical pump-
Type of injection
The schematic diagram of the nozzle injection
experimental setup is shown in Fig. 1. In this
Injection timing 23°before TDC
paper, for experimental investigation on a
four-stroke, direct injection diesel engine Injection pressure 220 bar
used. The specifications of the test engine
are listed in Table 2. At 150 bar pressure, Lubrication oil SAE 40
Hydrogen was stored in the cylinder and by
a pressure regulator to an outlet pressure
regulated to 2 bars. With the help of control Flame arrestor placed to next to NRV as the
valve fine adjust of hydrogen flow. The rate additional safety aspects. In the hydrogen
of flow hydrogen was measured with a system to suppressed the backfire by water
thermal mass flow meter. The non-return to extinguish the flame on the flame trap
valve (NRV) act as a flow reverse barrier in with sliding sleeve. Next, to flame trap with
the system. the carburetor, it functions to control the
hydrogen flow into the manifold. This
method of mixture preparation with air and
fuel (hydrogen) is called mixture
enrichment. The hydrogen flow rate was 2
L/min. With 10% EGR and 20% EGR is
that exhaust gas granted on inlet air and
hydrogen mixture. In this paper, the
combustion parameters, Performance and
emission characteristics were analyzed.

5. Results and discussion

In this experiment Combustion


parameter of Ignition Delay and Combustion
Fig 1. Schematic diagram of experimental duration, performance parameters such as
setup brake thermal efficiency, BSEC, volumetric
efficiency were determined and emissions
Table 2. specifications of the test engine such as NOx, HC, smoke and carbon
monoxide are measured. The experiment
Details Specification was carried out keeping hydrogen flow
Rated power& remain same as 2 LPM in absence of EGR,
5.2kW & 1500 rpm the addition of exhaust gas recirculation
speed
with 10% EGR and 20% cooled EGR.
Number of
Single cylinder
cylinders
5.1 Performance Analysis:
Compression ratio 17.5:1
Bore & stroke 87.5mm & 110mm 5.1.1. Brake thermal efficiency :( Ƞbth)

Injection timing, The graph shows the comparison of


23
ºCA bTDC Ƞbth with the load for normal diesel, diesel
Eddy current with 2 LPM of hydrogen upgrade without
Method of loading
dynamometer EGR, with 10% EGR and 20% EGR is
shown in fig 2. The brake thermal cylinder. When exhaust gas is applied, there
efficiency for hydrogen with diesel as is further decrease in Ƞvol. With 10% EGR
ignition source is 33.6% at 80% load with a it is 77.2% and with 20% EGR it is 75.03%
flow rate of hydrogen 2 LPM, whereas that at 80% load. The figure shows that Ƞvol
of baseline diesel fuel is 30.8%.experiment decreases with the increase in EGR
conclude that flow rate of diesel is inverse of percentage at each load up to 80% loading.
the flow rate of hydrogen. Thereby the high When exhaust gas is recirculated to the
flame velocity properties in hydrogen intake manifold, it occupies a portion of the
enhanced the combustion process effectively incoming air. This results in a reduction in
and lead to rising the thermal efficiency. Use Ƞvol. modification of intake manifold
of EGR has a negative effect on engine during an experiment to induction of exhaust
efficiency that rises with its percentage of gas and hydrogen. So there is obstacle
EGR with the same 2LPM of hydrogen. At offered to fresh charge, which further
80% load with 10% EGR brake thermal decreases Ƞvol.
efficiency is 31.4% and with 20% EGR, it is
32.23%. Result shows decrease of Ƞbth in
case of EGR because negative effect on
combustion due to less availability of the
oxygen concentration on intake air

Fig 3. Comparison of Ƞvol with engine


load

5.1.3. Brake specific energy consumption:


(BSEC)
Fig 2. Comparison of Ƞbth with engine
load

5.1.2. Volumetric efficiency: (Ƞvol)

Fig. 3 shows the variation of Ƞvol


with a load of normal diesel, diesel with 2
LPM of hydrogen upgrade without EGR,
with 10% EGR and 20% EGR is shown in
the figure. the Ƞvol obtained for 2 LPM
hydrogen enrichment without EGR is
85.02% compared to normal diesel fuel of
85.6% at 80% load. This reduction in Ƞvol
is due to the fact that hydrogen being much Fig 4. Comparison of BSEC with engine
less dense than air displaces an appreciable load
amount of it while being inducted inside the
Fig. 4 shows the variation of BSEC with a which injected pilot and lubrication oil. On
load of normal diesel, diesel with 2 LPM of again to less availability of oxygen in case
hydrogen enrichment without EGR, with of EGR leads to increase in CO emission.
10% EGR, and 20% EGR. It can be Cylinder temperature and reaction speed is
observed that BSEC without EGR is 10045 inverse of EGR rate at the same time, more
whereas the BSEC of normal diesel is recirculate exhaust gas minimizes the O2
13500.09, with 10% EGR it is 11050.02 and concentration. These reasons weaken the
with 20% EGR, it is 12540. All these oxidation reaction and lead to cause more
readings are at 100% load of rated load. CO emission.
BSEC decreases with the increase in brake
power. This trend is maintained in all four 5.2.2. Oxide of Nitrogen (Nox)
cases viz normal diesel operation, 2 LPM
hydrogen enrichment without EGR, with
10% EGR and with 20% EGR. But BSEC in
case of hydrogen enrichment without EGR
is low.

5.2. Emission Characteristics:

5.2.1. Carbon monoxide (CO)

Fig 6. Comparison of NOx emission with


engine load

Fig. 6 shows the variation of NOx with a


load of normal diesel, diesel with 2 LPM
hydrogen enrichment without EGR and the
same with 10% EGR and 20% EGR. NOx
emission for hydrogen enrichment without
EGR is 1604 ppm compared to normal
Fig 5. Comparison of CO emission with diesel fuel of 1300 ppm at 80% load. The
engine load peak In-cylinder temperature and high-
temperature gases residence in the cylinder
Fig. 5 depicts the variation of CO with the for a long span of time was the reason for
load. At 100% load CO emission for normal rising in NOx concentration in the case of
diesel, the operation is 0.88% by volume, enriched hydrogen without EGR. The figure
while it is .55% by volume with 10% EGR depicts that with 10% EGR NOx formation
and .58% by volume with 20% EGR. In case is 1200 ppm at 80% load and that of 20%
of 2 LPM hydrogen enrichment without EGR is 1150 ppm. So thereby increase in
EGR CO emission is .45% by volume. Due Percentage of EGR into the cylinder is a
to the absence of any carbon on hydrogen problem-solving method to reduce NOx
enrichment leads to low CO emission, the formation. Therewith inert nitrogen, CO2,
yield CO emission is also by the diesel and higher specific heat are the main sources
of exhaust gases. When EGR to engine inlet combust properly and results in higher HC
it can reduce oxygen level and act as a heat emission.
sink. All the combustion process is delayed
with diluted air, premixed combustion, 5.2.4. Smoke
diffusion combustion and late diffusion
combustion. On the result whole combustion The variation of the smoke level with load is
process is moves further into the expansion shown in Fig. 8. As load increases, diesel
stroke, leading to low combustion engines tend to generate more smoke. It is
temperature. Low combustion temperature is observed that at 100% load smoke no in case
the reason for the decrease of NOx. of diesel is 58 whereas corresponding values
for diesel with 2 LPM hydrogen enrichment
5.2.3. Hydrocarbon (HC) without EGR and the same with 10% EGR
and with 20% EGR are 35, 48 and 52,
respectively. Due to the absence of any
carbon on hydrogen enrichment leads to low
smoke emission. Higher smoke level of the
exhaust is observed when the engine is
operated with EGR compared to without
EGR. Smoke level is directly proportional
to EGR and engine load. Thereby less
availability of oxygen for combustion of fuel
causes to improper combustion and lead to
formation of smoke level is higher in using
of EGR

Fig 7. Comparison of HC emission with


engine load

Fig. 7 shows the variation of HC with the


load for neat diesel, diesel with 2 LPM
hydrogen enrichment without EGR and the
same with 10% EGR and 20% EGR. It can
be observed that HC emission for hydrogen
enrichment without EGR is 44 ppm whereas
that of neat diesel is 125 ppm, with 10%
EGR it is 83 ppm and with 20% EGR, it is
94 ppm. All these readings are at 100% load.
Due to the absence of any carbon on
hydrogen enrichment without EGR leads to Fig 8. Comparison of smoke emission
reduce HC emission. In case of EGR, there with engine load
is lower excess oxygen available for
combustion. Lower excess oxygen 5.3. Combustion Analysis
concentration results in rich A/F mixtures at
different locations inside the combustion 5.3.1. Ignition delay (ID)
chamber. This diverse mixture does not
Fig 9 demonstrates the variation of Fig 10. Comparison of combustion
ignition delay with load at 10% and 20% of duration with engine load
EGR with hydrogen fuel. It is observed from Fig 10 illustrates the variation of combustion
Figure that the ignition delay (ID) of all the duration with the load of the engine at 10%
fuels decreases with an increase in engine and 20% EGRs. This time duration starts
load. The ignition delay formation is high in from the starting of the heat release to the
neat diesel, which is 18.32 °CA, compared end of heat release. The combustion
to that without EGR of 18.04 °CA. The duration in normal diesel fuel at full load is
ignition delay of 10% and 20% EGR is 50.34 °CA, while with 20% EGR, it is 54.18
18.03 °CA and 17.56 °CA respectively. The °CA and 53. °CA, and with 10% EGR and
ignition delay (ID) is longer for diesel, without EGR it is 52.28 °CA. increase in
compared to that with 10% EGR, with 20% combustion duration because of fuel
EGR and without EGR. The longer ignition injection on high mass while the load
delay (ID) is caused by the chemical increases, At any particular load, the
reaction during the injection time, which combustion duration increases as the EGR
slows down the physical delay period. rate also increases.

6. Conclusion:

The experiment was carried out


keeping hydrogen flow remain same as 2
LPM in absence of EGR, the addition of
exhaust gas recirculation with 10% EGR and
20% cooled EGR. The following
conclusions are made on the basis of
experimental results.

Fig 9. Comparison of ignition delay with  On comparing of neat diesel with


engine load hydrogen supply without EGR has
9.09% Ƞbth higher in percentage.
5.3.2. Combustion Duration But the effect of using EGR has a
negatory effect on engine efficiency
the rise in its percentage, this is due
to dilution of EGR.
 Higher Ƞvol for normal diesel
operation then hydrogen supply
without EGR. There will still more
reduction in Ƞvol while using of
EGR. Causes for this reduction to the
replacement of a portion of fresh air
by hydrogen and recirculate gas.
 Higher BSEC for normal diesel
operation then hydrogen supply
without EGR. This is due to
hydrogen higher calorific valve so
the there hydrogen operated engine
is to be in lean burn conditions. The shows that NOx formation problem faced in
rise in BSEC in case of EGR is due hydrogen combustion with diesel fuel. EGR
to the negatory effect of on technique is used for the decrease of NOx
combustion by EGR. level. In doing so there is reduce
 On comparing of neat diesel with performance level and increase in emission
hydrogen supply without EGR has level. So lower EGR % is preferred.
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