Professional Documents
Culture Documents
on Practical Nanochemistry
Scientific Program
Chairman: Prof. Z. C. Li
11:30-12:20
Poster Presentation
1
Joint Symposium of Peking University & Waseda University on Practical Nanochemistry
March 19-22, 2006, Peking University, Beijing, China
Hiroyuki NISHIDE
Acknowledgments This work was partially supported by Grants-in-Aid for the 21COE
Program “Practical Nano-Chemistry” from MEXT, Japan.
2
Joint Symposium of Peking University & Waseda University on Practical Nanochemistry
March 19-22, 2006, Peking University, Beijing, China
Yuguo MA
3
Joint Symposium of Peking University & Waseda University on Practical Nanochemistry
March 19-22, 2006, Peking University, Beijing, China
Chemistry of chiral enolates has been developed during a few decades. Numerous enolates
have been investigated and some of them have been studied in detail and applied to the
natural product synthesis. However, there are few precedents to construct a tetra-substituted
carbon and are also few to study ketene N,O-acetals. During research of such problems, we
have developed some new chiral enolate chemistry. The enolates and ketene N,O-acetals in
Figure 1 showed specific features. The enolates 1, 2, and the ketene N,O-acetal 3 afforded the
products having a tetra-substituted carbon with high stereoselectivity, and ketene N,O-acetals
3 and 4 exhibited the
R R R
remote stereoinduction at γ γ
the γ-position.1-5
BnO
N O N O N O N O
α Me α Me α Me
These chemistry have Me O O O O BnO O O O O
Ti Na Si
been applied to the 1 2 3 4
syntheses of compounds Figure 1
shown in Figure 2. 6-8 The origin of the high stereoselectivity will also be discussed.
HO
OH
O HO O
N Me HO
O Me H Br
N HO
Me OH OH Me Me Me O
HO Cl
MeMe Br
NH
O Me CHO
Me O N O O O
Me H
madindoline A citreoviral convolutamydine B trichostatin D
Figure 2
4
Joint Symposium of Peking University & Waseda University on Practical Nanochemistry
March 19-22, 2006, Peking University, Beijing, China
Izumi HIRASAWA
5
Joint Symposium of Peking University & Waseda University on Practical Nanochemistry
March 19-22, 2006, Peking University, Beijing, China
Dip-Pen Nanolithography (DPN) utilizes the tiny water meniscus forming spontaneously in
the tip-substrate system as the transport media to deposit materials from the tip to the
substrate. This technique has been widely used in patterning organic and bio- molecules.
However, it is not so suitable for patterning inorganic materials with the normal DPN. Here, a
few novel DPN processes for preparing inorganic nanopatterns were developed.
A fast DPN process for directly patterning inorganic nano-clusters was proposed. With this
method, one can deposit nanoclusters onto the specific area at the speed of tens of microns per
second, which is as high as 10K times of the normal DPN process.
The DPN technique was also used to deposit nanomaterials onto the specified location at
nano-meter-scaled precision.
6
Joint Symposium of Peking University & Waseda University on Practical Nanochemistry
March 19-22, 2006, Peking University, Beijing, China
Poster Session:
P-2. "Radical Polymer and Its Application to a Non-Volatile Memory" Yasunori Yonekuta
(Waseda Univ.)