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J.M. Vaught
Vaught Engineering Incorporated
Indianapolis, Indiana
Presented at the International Gas Turbine and Aeroengine Congress and Exposition
The Hague, Netherlands — June 13-16, 1994
This paper has been accepted for publication in the Transactions of the ASME
Discussion of it will be accepted at ASME Headquarters until September 30, 1994
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Program Objectives Other measurement specifications such as those used for
The Standard is written to provide guidelines for the emissions aircraft gas turbines(5) and for reciprocating engines(6) were
measurement of stationary gas turbine engines It is designed to reviewed for methods and content. These specifications were
simplify, standardize, and reduce the cost of the measurement found to be only indirectly applicable to the testing of stationary
process wherever possible. The expected users are engineers gas turbines in the United Slates.
and measurement technicians who require information on the
immurement of emissions from gas turbines. The Standard also
is written to inform project managers, contract and procurement CONTENT
stag and engineers not directly involved with emissions of the The Standard contains information that will guide the user in
measurement control and compliance of gas turbines. the technologies of emissions compliance and control as well as
Specific criteria for the Standard were established by the measurement During their review of requirements, the Steering
Steering Committee early in the program. These criteria were: Committee found that many agency staffs had little experience
with most of the gas turbines used in the United States that are
1. To standardize measurement techniques, analysis operated on clean fuels, natural gas, and distillate oil. Also,
procedures, and reporting criteria. they found that agency personnel were unfamiliar with the
2. To follow ANSI format and the ASME Guide to Writing practical aspects of engine operation, the formation, identity,
Codes and Standards. and concentration of the various components in the exhaust of
3. To be applicable to all industrial gas turbine engines turbines, the measurement of these components, and methods of
operating on natural gas and distillate fuel oil emission control As a result, the Standard was designed to
4. To be applicable to engines with emission controls such as provide information and references on these subjects as well as
water injection and selected catalytic reduction (SCR). to establish the best measurement practices. The subjects
5. To provide reference to other turbine regulations and covered in the Standard are as follows:
measurement procedures.
6. To have general approval of industry and the USEPA Definitions. Terms most likely to be encountered in emissions
7. To not set regulatory limits or control regulations. measurement, compliance, and control.
S. To incorporate the International Standards Organization
(ISO) gas turbine emissions measurement specification to Exhaust Components. Description of each of the chemical
the extent feasible. components in the gas turbine exhaust
Since there are many different sizes and applications of Responsibilities. Gas turbine manufacturer and user
stationary gas turbines throughout the world, it was an objective environmental responsibilities.
of the program that these differences be considered in the
development of the new Standard. Emissions measurement of Operating and Test Conditions. Specification of system
turbines using heat recovery after firing and steam and water operating and test conditions.
injection for NOx controls was included. The very low
concentration of pollutants typical of turbines using dry low Measurements. Recommended methods of measurement of
NOx combustion and SCR after treatment also was considered. gaseous components, smoke, particulates, and fuel. Definition
Current measurement methods were researched to find the of the measurement system, sampling, instrumentation, and
best methods, reduced to commercial practice, to include in the quality provisions.
Standard. Where applicable, the measurement methods are
referenced to EPA protocols. Since the development of Calculations and Conversions. Specification of methods of
measurement instrumentation is ongoing, future improvements calculating emissions.
will require periodic updating of the Standard.
It also was necessary to incorporate methods to measure each General References. Information on reference conditions,
of the exhaust components controlled by the various regulatory physical properties, air laws, regulations, air toxins, and
agencies and emission regulations. Laws and rules were emission control methods.
researched, and the results became one of the bases for the
Standard.
Concurrently, the specification "Gas Turbines — Exhaust Gas MEASUREMENT OF GASEOUS COMPONENTS
Measurement" was being developed by IS0(3X4). While this The Standard specifies the gaseous components in the exhaust
specification did not provide for use of USEPA protocols and and the methods to be used to measure them. These
was not acceptable for use in the United States, considerable components are listed in Table 1. This listing was determined
effort by an international working group bad been expended in by the Steering Committee based on the regulatory requirements
its development It was an objective of the program that the new of the EPA, the state agencies, and the collective experience of
Standard incorporate as much of the ISO document as was the members. It is recognized that measurement technology is
practical. advancing rapidly, and this listing deserves regular updating.
2
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Measurement System TABLE 1 GASEOUS EXHAUST COMPONENTS
The three basic elements of the measurement system are (1)
the sampling probe, (2) transfer and conditioning, and (3) Component Recommended Method
analytical instruments and data acquisition. These elements are
described in detail in the Standard and refer to EPA protocols. Oxides of nitrogen (N0,) Chemiluminescence
Carbon monoxide (CO) Nondispersive infrared
A schematic of the measurement system is shown in Figure 1.
Carbon dioxide (CO2) Nondispersivicinfrared
With the exception of sulfur dioxide, sulfuric acid mist, and Sulfur dioxide (S02) Fuel analysis
water vapor, the gaseous measurements are to be made by Sulfuric acid mist (112504) Impinger train • -
continuous flow sampling instruments. These instruments are Total hydrocarbons Flame ionization detector
combined into a measurement system. NMHC and VOC Gas chromatograph
Ammonia IN113) Chemiluminescence difference
Oxygen (02) Electrochemical or paramagnetic
Sampling Water vapor (H2E) Impinger train
The approach taken to sampling gaseous components is
designed to save test time and effort. It differs from the
multipoint traverse usually required by the USEPA in Method
2(7), which requires at least eight and normally many more measurement methods that are recommended. These are
sampling locations in two planes. listed in Table 1. For additional detailed information, specific
The Standard recommends that the sample be proven to be USEPA methods and ISO standards are given as references.
representative using a carbon balance. Once that is done, Each of these measurement methods listed in Table I will not
sampling may be achieved using a three-holed sampling probe be covered in this summary paper. Some of the findings and
tube or a single probe located at 16.7, 50, and 83.3% of a recommendations on measurement methods that were
measurement line taken through the centroid of the duct area. formulated during the development of the Standard are
Ducts larger than 2.4 meters can be sampled at 0.4, 1.2, and 10 discussed below.
meters from the wall to reduce probe ovediang. The use of three
sampling points is based on the EPA Continuous Emission Hydrocarbons and VOC. In most instances in the United
Monitoring Specification 2(8) and is illustrated in Figure 2. States, a measurement of the volatile organic e. ompormds (VOC)
The number of sampling points is reduced because, in the emitted by the engine is required. VOC are usually defined as
majority of industrial turbine installations, the exhaust gas the total of all hydrocarbons (HC) emitted minus the methane
stream is well mixed and the concentration of the individual and ethane components. In many instances the term non
components is, from a practical standpoint, uniform across the methane hydrocarbons (NMHC) is used synonymously with
entire exhaust duct This uniformity is due to the length VOC. In modem engines, emissions of VOC are often at a very
of exhaust ducting, the changes in direction and cross section low concentration, less than I to 10 ppmC (methane equivalent).
required for the installation of boilers and silencers, and the Their measurement requites the accurate determination of
requirement for stack heights. As a result, the number of sample concentrations of both the total and methane exhaust
points required for sampling gas turbine gaseous components is components. This determination is accomplished by measuring
far less than that required for most industrial plants. The EPA total HC and subtracting measured methane
CEM Specification provides substantiation that a representative It is recommended that the measurement of total
gas sample can be obtained with three sampling points. hydrocarbons be made using a flame ionization analyzer and
volatile organic compounds by gas chromatograph (GC). Direct
analyzers combine the features of both these instruments to
Sample Transfer and Conditioning obtain VOC concentrations.
Long lines are often unavoidable in the measurement of large Separate analyzers can also be used to obtain VOC emissions.
turbine systems; however, the sample transfer time should be To improve accuracy, it is recommended that the ratio of VOC
kept as short as possible. It is important to avoid condensation to total HC be obtained using the GC, and this ratio be applied
of the various constituents, particularly water vapor, to the total HC obtained by FM to obtain the concentration of
hydrocarbons, and sulfates. It is recommended that the entire VOC in the exhaust
sample line be heated above the condensation temperature of
each constituent, considering its concentration. The sample is Ammonia. Ammonia in the exhaust of a turbine resulting from
to be conditioned in a manner compatible with the various NOx emission control equipment, such as SCR, must be
analyzers. controlled to low concentration level, typically 10 ppm. The
chemilanxinescence difference method was listed as the best
method then available However, none of the methods
Instrumentation commercially available was considered accurate enough. It was
Descriptions, general requirements, and performance recognized that considerable research on ammonia measurement
specifications are given for each of the instruments and is in progress, and the Standard will require subsequent
updating
VOC
(CH4 a OsM4)
Gas Grecinstogra;41
HC
11 Raertaantalisn
detezzor
10
NOx
2 Chernilersnescenca
02
Zirconium a**
at paramagnetic
Legend
CO
1 Probe Nanespe"she
2 Gas inlet for system check
3 Sample line
4 Dump pump to vent, if required
CO2
5 Filter
6 Sample pump
Fdrand
7 Back pressure reducer
8 Chillier/separator operating s3°C
9 Gas inlet for instrument calibration SO2
10 NO2 —■ NO converter
NcedSpersin
11 Heated section Onveel
12 Analyzer
N H3
Gneenturninescence
&Enna
Water Vapor. The exhaust from a gas turbine can contain and summation of all sources. In the case where direct
varying quantities of water vapor, approximately 2 to 15% by measurement is required, the reference method cited in EPA
volume. The absolute amenmt depends on the products of Method 4(9) is recommended.
combustion that are fuel related, the absolute humidity of the air
ingested into the engine, and the amount of water injected into
the engine for emission control or power augmentation. Water Instrument Calibration Gases
entering the engine from evaporative inlet coolers and water fuel The calibration of instruments through the use of calibrating
emulsions also must be considered. gases is described in the Standard. These gases, introduced at
The water vapor content of the exhaust is used in making the sampling probe, are to have certificates of compliance per
emission calculations, and determining this value accurately is ISO standards or USEPA protocols. Accuracy requirements for
important The quantity of water in the exhaust can be a number of calibration gases, including zero gas, are
determined either by direct measurement or by measurement recommended in the Standard.
4
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CIRCULAR EXHAUST DUCT
with visual opacity tests made during source testing. In order to
be effective, this procedure must be agreed to by the cognizant
regulatory agency so that when questioned by an inspector,
compliance during routine operation of the engine can be
demonstrated using the referee method.
Smoke Density
Iteestnement In the United States regulations do not require smokemeter
plane
readings. Since these readings are required in Europe and other
regions, smoke density measurement was included in the
Standard.
Two different methodologies are available: smoke spot and
optical. In the smoke spot procedure, a metered quantity of
exhaust is passed through a filter paper and the density of the
smoke stain on the paper is graded optically. In the optical
procedure, a continuous flow of exhaust is extracted, metered,
and passed through a cell that measures its light obscuration.
Three of the most common methods of measuring smoke from
gas turbines were evaluated for inclusion in the Standard. These
Measurornent line established Drat to flow enough the eardrold of exhaust are described below.
duet meastwentent plane and In direction of expected stratification.
FIGURE 2 SAMPLING POINTS ICAO/SAE Aircraft Method. The SAE Aircraft Method is a
spot filtration procedure that is designed and used to measure
the smoke density of aircraft gas turbine exhaust In this
SMOKE MEASUREMENT method, the mass of exhaust collected and the optical grading of
Smoke emitted from gas turbines is measured in two general the stain are closely controlled. This method is specified by the
ways: (1) visible plume opacity, and (2) smoke density that International Civil Aviation Organization (ICAO) and aviation
measures soot in the exhaust. Smoke measurements are made agencies throughout the world(14).
of engines operating on liquid fuels. Engines operating on
natural gas will normally have no visible exhaust plume Bacharach/ASTM. Bacharach is the spot filtration method
specified by ISO(3) and used throughout Europe to measure
both turbine and diesel engines. It is not as precise as the
Visual Opacity aircraft method and employs a different scale for smoke density.
Currently, visual determination using I.JSEPA Method 9(10) is The method, also identified as ASTM D2156, was designed for
the only accepted and practical method of determining the visual use with oil heating equipment(15).
opacity of the exhaust plume of a gas turbine. However, this
method does not produce results of acceptable accuracy. Rolls-Royce Optical Smokemeter. The Rolls-Royce optical
Other methods were examined and found deficient. LIDAR smokemeta was designed to measure smoke from gas turbines
measurements(11) were found to be too expensive for routine and component rigs on a continuous basis. It provides a
source testing. Transmissometers(12) measure the light measurement of the carbon density based on a standard cell that
obscuration caused by smoke in the exhaust duct but do not take can be calibrated in units of carbon mass (milligrams per cubic
into accmmt plume behavior or plume illumination. meter) or in terms of Bacharach or SAE Smoke Numbers(16).
Method 9 requires that a trained observer, holding a valid
USEPA certificate, make and record one or more sets of
observations. The positive error of Method 9 for black plumes Comparison of Methods
is cited as less than 5%. Evaluations of Method 9 during These methods were compared for accuracy in the range of
certification training(13) show that at the opacity values of 10% low smoke density typical of modem gas turbine engines. This
and 20%, which are the usual compliance levels for gas evaluation based on the accuracy stated in the description of
turbines, the standard deviation of measurement was 3.16% and each method, was to determine if a difference in accuracy that
5.25% opacity, respectively. could be easily discernible and lead to a recommended method
When the standard deviation is as high as 25 to 33% of the acisted.
measured value, compliance difficulties can be expected, Figure 3 shows the results of the accuracy evaluation. In
particularly in cases where compliance is marginal. When this order to obtain a direct comparison between the methods, the
deviation occurs, referee measurements of smoke density are smoke number values from the SAE and Bacharach methods
recommended. These measurements would be made using a were converted to carbon mass per unit of exhaust gas using
smokemeter or in-stack tzansmissometer that was correlated published conversion data.
PARTICULATE MEASUREMENT
The measurement of particulate material (PM) is frequently FIGURE 3 VARIABILITY OF SMOKE MEASUREMENT
required in the United States by state and local agencies if the
gas turbine is run on liquid fuel. In some instances PM
measurement has been directed by local agencies even when the made when Method 5 is used to measure gas turbine PlvL These
engine is rim on natural gas. changes, described below, were incorporated in the Standard.
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measurement using Method 5. In some instances, agencies have Determination of Air Toxic Compounds
required sampling times as long as 24 hours in order to obtain a Air toxic compounds emitted by the engine must come from
viable sample. the fluids introduced into the engine during its operation. These
fluids are fuel, air, lubricating oil, water, steam, and engine
washing compounds. Each installation should be considered as
AIR TOXICS specific. If determinations of the presence and quantity of
As a result of the 1990 Clean Air Act Amendments, numerous emissions of air toxic compounds must be obtained, it is
compounds have been listed as air toxics(20). The emission of recommended that an analysis of each of the fluids used by the'
these compounds is regulated at the levels of 10 tons per year, engine be made to determine the presence and expected
or 25 tons in combination. concentrations of compounds that can form air toxic
compounds.
Because of very low concentrations, direct measurement of
Occurrence in Gas Turbine Exhaust these compounds in the exhaust is not recommended. If exhaust
At these regulated levels, the emission of these quantities of measurement is mandated, the prior identification of each air
air toxic compounds from gas turbine engines operating on toxic compound, its source, and probability of occurrence is
natural gas and high quality distillate fuels is unlikely due to the recommended.
cleanliness of the fuels and the design and installation
characteristics of industrial turbine engines. Some air toxic
compounds cannot be generated by gas turbines. More specific SUMMARY AND CONCLUSIONS
reasons are as follows: B133.9 New Standard
The revised ANSI Standard B133.9 has been completed and is
1. High fuel quality is required to extend engine endurance life available from the American National Standards Institute. Its
and maintain performance. The level of contaminants in the use will provide the following
fuel must be closely controlled in order to prevent erosion
and corrosion of the engine gas path. ASTM specifications 1. The guidance and criteria for the measurement of exhaust
require that trace metal concentrations of vanadium, sodium emissions from stationary gas turbines.
and potassium (in combination), calcium, and lead be held 2. Standardized measurement techniques, analysis, and
to 0.5 ppm by weight(21). reporting in the United States and internationally.
2. High combustion efficiency and large dilution ratios are 3. Reduced labor and cost of source testing by simplified
design characteristics of stationary gas turbine engines. sampling, exhaust flow measurement, and measurement of
Typical combustion efficiencies are 99.99°% and air-to-fuel particulates.
ratios are approximately 50. In combination, these 4. Improved understanding of the character and measurement
characteristics along with careful design control of of gas turbine emissions by industry and government staff
combustors have resulted in total HC emission levels in the involved in the permitting process.
exhaust gas of I to 10 ppm, measured as methane. As a
result, only minute fractions (ppb or less) of unburned fuel
components will be present in the exhaust. Contract Vs Committee Methods
3. Good fuel filtration is required in order to prevent finely In the past most standards, including ANSI BI33 Gas Turbine
divided solids containing earth compounds and metals from Procurement Standards, have been written by volunteer
entering the fuel system and fouling and eroding control committee members whose membership and time were
orifices and fuel injectors. sponsored by their various employers. Because this committee
4. High quality inlet air filtration is used to prevent airborne activity was secondary to their main work, standards
particles from entering the engine and causing deterioration development was a slow and limited process. Recent reductions
of engine performance and life. These particles also are in technical staffs have made voluntary committee work even
prevented from subsequently being oxidized and reinjected less productive.
into the atmosphere. Changing this procedure to one in which research,
5. Close specification control of other fluids such as water, development, and drafting of the standard are performed by a
steam, and lubricating oil used in gas turbines is maintained. contractor under the technical direction of a steering committee
These fluids have specifications that stipulate allowable has proven to be advantageous to the sponsoring groups. Our
levels of contaminants to prevent deposition, corrosion, and experience in writing the new B133 Exhaust Fmiccions Standard
erosion in the engine. Particularly rigid control is required has shown the following advantages of using the committee
to minimi7A the induction of halogen compounds to prevent method:
them from entering the gas path. This class of compounds is
particularly corrosive and greatly reduces engine life. • Defined scope. The specific work requirements are defined
by contact that can be monitored and administered.
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