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!Whvz<
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e tet A e tet e tet B e tet
1 n! a(2) i .Ni.(4)
a
N (1) (3)
a ia.Ni.N Ni.NX!I
N!aia.%x<
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lal %x<XIe<e<!siqbie!uqtg<aglaliGl< a
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s
a !
s a s
a s a s
an
s ! + asas a s
a
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a a
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P P
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27!
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5 n! ogz<miz<!Ljx!
Ljx! 5 n! 0.5
6 N! NH3 6 N! O2- , F-
7 N! uqjeOugl<! 7 N! (I), (II)
8 N! O2- , F- 8 -! gVg<guI!gv{q! uI!gv{q!
e te t e tet e te t e tet
9 -! gVg<
a ia.Ni.Ng uI!gv{q!
uI!gv{q !
a ia.Ni.N 9 N !
a ia.Ni.N
NH 3
a ia.Ni.N
10 Na!lal2/27 aslal 10 N asla!l yzq0hqe!< aslal
a s
a s 27!
27!
a s
a a s
a a s
a a saa
11 d dn! NO2 dad 11d d n! (2) (4) (1) (3)
aPdad aPdad
+

P a
P a P a
P P aPa P P
ww.12. N! ohim<misqbl<!sz< w . O.hm<!
w ww. 12
. N! uqjeOugl<!ww. . w ..
w
wwww 13 =! Lgh<H!jlb!gesKvl< wwww ! wwww 13 N! ohim<misqbl< wwww!sz<Ohm<! wwww
14 N! (I), (II) 14 =! Lgh<H!jlb!gesKvl<!
15 =! )n*!lx<
)n*!lx<Xl<!)N*!
)N*! 15 n! ogz<miz<!Ljx!
Ljx!

SECTION – II
)uqei!w{<!29g<G!gm<miblig!uqjmbtqg<gUl<*! 32/!slfqjz!osxqUgt<!lixilz<!-Vh<hkx<gie!giv{l<
ie!giv{l<;!!!!!!! !
e tet
27/!HuqbQIh<H!Ljxbqz<!hqiqk<<kz<;!
e tet e tet
!yV!lQt<!uqjebieK!slfqjzjb!njmf<k!hqxG!
e tet
i .Ni.N
!!!Oaljmm<?!out<tQbg<giz<!Ohie<x!gelie!Ng<j^M!
i .Ni.N
kiKg<gjt!nmIhqg<g!Wx<x!LjxbiGl</!Kitig<gh<hm<m!
a a a a .Ni.N
uqjehM!lx<Xl<!uqjtohiVt<gtqe<!osxqUgt<!Ofvk<jkh<!
i
ohiVk<K!lixilz<!-Vg<Gl</!lixi!ouh<hfqjzbqz<?!&cb!
a a a ia.Ni.N
s aslal s aslal
kiKju!siquie!ktk<kqz<!juk<K!Ouglig!YMl<!fQiqz<!!
gPuh<hMgqxK/!l{<!lx<Xl<!Ozsie!liSg<gt<!fQiqeiz<! s aslal
gzk<kqz<!Oukqs<!slfqjz!dVuiGl<!OhiK!osxqUgt<!
lixilz<!-Vg<Gl</! s aslal saa
a a a a a a a a a
P aPdad
! aPdad
nck<Ks<!osz<zh<hm<M!gelie!kiK!ncbqz<!kr<GgqxK/!!!!!!
P 33/!
P aPdad
33/!=k<Oke<!!givl<
! !gzf<k!KMnO4 J!
P aPdad
!fqxlqpg<gs<!
P aPdad
w ..
w 28/!gefQiqe<!-V!hbe<gt<;!
w ..
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z/ wk<kqzQe<!!givl<
!
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!!!2/
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2/n[g<gV!djzgtqz<
V!djzgtqz!fqB,m<vie<!Ougk<jkg<!Gjxg<g!
wwww wwww wwww wwww wwww
fqxlqpg<gs<!osb<gqxK/
qxK/!
lm<Mh<hMk<kqbig!hbe<
qbig hMgqxK//! !
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!!!3/!cB,m<ciqbl<
ciqbl<!kbiiqg<g!hbe<hMgqxK<! 34/!ohe<sQe<!yOvobiV!yx<jx!HOviOli!ohXkqjbBl<!
! &e<X!-vm<jm!HOviOli!ohXkqgjtBl<!d{<mig<Gukiz<!
29/!SmI!Osikjebqz<!Ohiqbl<!hs<js!Nh<hqt<!fqxk<jk! ohe<sQe<!sllie!NX!giIhe<!n[g<gjtBl<?!NX!
kVgqxK/!
kVgqxK/!Woeeqz<!Ohiqbk<jk!Smiqz<!jug<gh<hMl<OhiK!!!!!!!!jam<v\e<!n[g<gjtBl<!ohx<xqVg<gqxK/!!!!!!
wzg<m<vie<gt<!Nx<xjzh<!ohx<X!dbI!Nx<xz<!lm<mk<kqx<G! !!!!!!!!!!!!!!!!!!ytq/∆
df<kl<!ohXgqe<xe/!kip<fqjzg<Gk<!kqVl<Hl<!OhiK! 35/!
35/!C
/! 6H5CH3 + Cl2 C6H5CH2Cl
dxqR<sqb!Nx<xjz!Gxqh<hqm<m!njzfQtl<!ogi{<m!gkqjv! omiZuQe<!!!!!!!!!!!!!!!!ohe<jsz<!GOtijvM!
outq!kt<Tukiz<!Smiqz<!!hs<js!fqxk<jkk<!kVgqe<xe/!
!
2:/!-eg<gzh<H;! ;!e tet e tet e tet
SECTION – III (Q.No: 27 Compulsory) e tet
a i
!!!yOv!n[uqZt<
!!!
a.Ni.N a ia.Ni.N
t!Wxg<Gjxb!YOv!Nx<xz<!ogi{<m!
25
keqll<! %
a ia.Ni.N a i
Oliz<gtqe<!w{<{qg<jg! wtqb!uqgqkl!
a
<
.Ni.N
LPw{<!

s aslal s aslal
s,p,d Ohie<x!ouu<OuX!NIhqm<miz<gt<!ye<Xme<!ye<X!
gzf<K!sl!Nx<xZme<!sl!w{<{qg<jgbqz<!Hkqb! saslal
giIhe<! 91! 91/12 = 6.66 s aslal uqgqkl!

7/77/ 6.66=1 2!
<
saa
a a a a a a a a a
aPdad aPdad aPdad aPdad aPdad
h{<HgTme<!Hkqb!NIhqm<miz<gjtk<!kVgqe<xe/!
P
.. P
..
31/!ouh<h!-bg<guqbzqe<!Lkz<!uqkq;!uqkq;! P
jam<v\e<! 31! 31/1
.. = 20 P
.. 20/6.66 = 3 4! P
..
w w !!!Nx< ww
!!!Nx<xz<!yV!ujgbqzqVf<K!lx<oxiV!ujgg<G!lix<xg<! ww ww w w
wwww wwww wwww wwww wwww
!!!!!SVg<gqb!uibh<hiM!= CH3
%cbK/!Neiz<!Nx<xjz!Ng<gOui!npqg<gOui!LcbiK/!
Oui!LcbiK/!

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! SECTION – IV
37/!gix<xqz<zi!$pzqz<!uXk<kz<;! 45/!OhiI!n[g<!ogit<jgbqe<!Ogim<hiMgt<;!
e tet
!!!kiKju!nke<!dOzig!Ng<jsmig!lix<Xl<!Ljx!
e
gix<xqz<<zi!$pzqz<!uXk<kziGl</!gix<xqz<zi!$pzqz<!kiK!
tet e tet
!!!2/!dm<gVjus<!Sx<xq!njlBl<!Gxqh<hqm<m!ujtb!
hijkgt<!nkiuK!NIhqm< e tet
NIhqm<!gtqz<!lm<MOl!wzg<m<vie<gt<!

a ia.Ni.N
nke<!dVGfqjzjb!uqm!Gjxf<k!ouh<hfqjzbqz<!fe<G!
a ia.Ni.N i .Ni.N i
dm<gVjus<!Sx<xq!uVgqe<xe/!-u<ujtb!hijkgt<!
a a a a.Ni.N
s aslal
dbIouh<hfqjzg<G!dm<hMk<kh<hMgqxK/!!
w/gi!!!!!!!!!!!!!!!!!∆! s aslal s aslal s aslal
Gxqh<hqm<m!Nx<xz<gjt!ohx<Xt<tkiz<!-jugt<!Nx<xz<!
%Mgt<!)n*!Nx<xz<!lm<mr<gt<!)n*!Gui{<ml<!lm<mr<gt<! saa
a a a a a a a a a
aPdad aPdad aPdad aPdad aPdad
CaCO3 (S{<{il<Hg<!gz<*!!!!!!!CaO + CO2↑ we<X!njpg<gh<hMgqe<xe/!-jugt<!2?3?4?5……/!)n*!
P
.. ∆!
P
..
MgCO3(lig<<ejsm<*!!!!!!!!!!!MgO + CO2↑
P
.. P
K,L,M,N…… we!Gxqh<hqmh<hMgqe<xe/!
..
!!!3/!wzg<m<vie<gt<!Gxqh<hqm<m!NIhqm<!cz<!-Vg<Gl<OhiK! P
..
w w w w w w w w
Nx<xjzh<!ohxOui!)n*!-pg<gOui!osb<biK/!nkiuK! ww
wwww wwww wwww wwww wwww
∆!
MgCO3.CaCO3(Omizjlm<*!!!!!!MgO + CaO + 2CO2↑ Nx<xz<!lixiK/!weOu!-u<ujg!NIhqm<gt<!fqjzgt< fqjzgt!we!
! njpg<gh<hMgqe<xe/!
38/n[hVle<gtqe<!WXuiqjs;!
WXuiqjs;! !!!4/!Ogi{!df<kl<!h/2π we<x!lmr<gqz<!njlbh<!ohx<x!
!!i) Li < Na < K ii) N < O < C iii) Ca < Sr < Ba wzg<m<vie<gjt!Wx<Gl<!NIhqm<gt<!lm<Ml<!Wx<gh<hMl<!
NIhqm<gt<!NGl</!NIhqm<cz<!Sx<xquVl<!wzg<m<vieqe<!Ogi{!
28. lqz<zI!ktl<;! df<kl<!mvr NGl</!weOu!
!! !!!!!!!mvr = nh/2 π (n = 1, 2, 3, 4……….)
! 5/!Yi<!wzg<m<vie<!yV!fqjzbie!fqjzbqz<!-Vf<K!
! lx<oxiV!fqjzg<G!lixqeiz<!Gxqh<hqm<m!nkqIou{<!djmb!
! e tet e tet e tet
gkqIuQs<js!dxqR<Sl<!)n*!outqk<kt<Tl</!-u<uiX!
e tet
!
! a ia.Ni.N a ia.Ni.N i .Ni.N
ohxh<hMl<!fqxfqvz<!OgiMgt<!Nvl<h?!!
-Xkq!lm<mr<gjt!ohiVk<kjlBl</!!
a a a ia.Ni.N
s aslal s aslal
3:/!ui{<mIuiz<^<!lixqzqgtqe<!Lg<gqbk<Kul<;! !
saslal
!!!!!!!!!!!!!!!!!)nz< )nz<zK*!
K*s aslal saa
a a a a a a a a a
P aPdad P aPdad P aPdad
NIk<Oki!!jam<v\e<;!
!!!!jam<
!!!!
P aPdad
v\e<!&zg<%xqz<!dt<t!-V!jam<v\e<!
P aPdad
w ..
w w ..
w ww.. w ..
n[g<gtqe<!HOvim<mie<gTl<!yOv!kqjsbqz<!Spe<xiz<!
w w ..
w
NIk<Oki!jam<v\e<!weh<hMl</!
wwww wwww wwww hivi!jam<v\e<;!
!!!!jam<
!!!! wwww
v\e<!&zg<%xqz<!dt<t!-V!jam<v\e<! wwww
n[g<gtqe<!HOvim<mie<gTl<!wkqovkqI!kqjsbqz<!Spe<xiz<!
hivi!jam<v\e<!weh<hMl</!! !
! !
! !
41/!SO
41/! 2 e<!ucujlh<H;! ;! !
!!!SO2 &zg<%xqz<<!sz<hI!n[uqz<!&e<X!wzg<m<vie<! !!
O\icgt<!-Vh<hkiz<!njlh<H!Lg<Ogi{!! Nb<ug!ouh<hfqjzbqz<!sikiv{!jam<v\eqz<!86%!
e tet
ktliGl</!Neiz<!YI!keqk<k!wzg<m<vie<!!
e tet e tet
NIk<OkiUl<!36% hivi!jam<<v\El<!dt<te/!
e tet
i .Ni.N
O\ic!-Vh<hkiz<!ujtf<k!njlh<jhh<!!
ohx<Xt<tK/!lp – lp uqzg<G!uqjsbiz<!hqj{h<Hg<!
a a a ia.Ni.N .Ni.N
!!jam<<v\El<!dt<te/!
a a a a.Ni.N
36K!ouh<hfqjzbqz<<!::% hiviUl<!2%!NIk<Oki!
i i
! s aslal s aslal
Ogi{lieK!2311!bqzqVf<K!22:/61!Ngg<!Gjxf<Kt<tK/!
s aslal aslal
GuiIm<^<!gzeqz<!dt<t!Dg<g&m<<mh<hm<m!giq!31Kz<!
s saa
a a a a a a a a
hivi!jam<v\je!Lx<xqZl<!dxR<SgqxK/!
a
P aPdad
42/!hqe<e!gib<s<sq!uck<kz<;!
P aPdad
!!!-l<Ljxbqz<!lqgs<!sqxqb!ogikqfqjz!OuXhiMjmb!
P aPdad
!
46/!i) P aPdad
46/! Ohivie<!uzqjlbie!yMg<gq;! q;! P aPdad
w ..
w ..
ye<Oxiomie<X!fe<G!gzr<gg<!%cb!OsIlr<gjt!hqiqk<K!
w w ww.. !!!giIhe<
!!!
w ..
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!jm!Ng<jsjm!giIheig!yMg<GgqxK/!
w ..
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Kib<jlh<hMk<kh<hMgqxK/!wtqb!gib<s<sq!uck<kz<!Ljxjb!
wwww wwww wwww wwww wwww
3CO2 + 4B 2B2O3 + 3C
Ohie<xkiGl</!Neiz<!uijzg<Gl<!GtqIuqh<hiEg<Gl<! !!!!!!!!!!!)nz<zK*!
-jmOb!yV!hqiqjg!nMg<G!dt<<tK/! !!!sqzqgiju!sqzqgeig!yMg<gqxK/!
!!!fQi<lg<!gjvszqz<!gzf<Kt<t!fQIls<!! !!!3SiO
!!! 2 + 4B 2B2O3 + 3Si
OsIlr<gjt!nux<xqe<!ogikqfqjzbqz<!! ii) Ohivig<^qzqVf<K!Ohivie<!hqiqk<okMk<kz<;
Nuqbigh<!hqiqk<K!hqe<!Gtqvs<!osb<K!!
Na2B4O7 + 2HCl!! !!!!!!!!!!
!!!!!!!!!!3
!!!!!!!!3NaCl + H2B4O7!!!!!!!!!!
hqiqk<okMh<hK!hqe<e!gib<s<sq!uck<kz<!weh<hMl</!!!
! !!!!!H !!!!!!!!! 4H3BO3!
!!!!! 2B4O7 + 5H2O!!!!!!!!!
43/!nsqm<czqEme<!YOsie<!uqje;!
uqje;! ∆
!!! O 2H3BO3 B2O3 + 3H2O!

e tet
HC CH H2O CHO
e tet e tet
Ohivie<! cjv! Ng<j^Mme<! Na (or) K (or) Mg
K{<Mgt<!gzf<k!gzjujb!yV!Hiqjsbqz<!wMk<K!osf<fqx!e tet
CH = CH + O3
a ia.Ni.N O O CHO
a a.Ni.N
+ H 2O 2
i i .Ni.N i .Ni.N
$m<cz<! ouh<hh<hMk<kh<hMgqxK/!hqe<! nmI!HCl z<! ogikqg<g!
a a a a
!
s aslal s aslal saslal s aslal
juk<K! olg<eQsqb! Ng<j^M! lx<Xl<! Ohiiqg<! nlqzl<!
Ngqbux<jx! outqObxqb! hqe<! gVl<hPh<H! fqx! hcglx<x! saa
a a
!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
a a a a a a a
aPdad aPdad aPdad
Ohivie<!Kit<!gqjmg<gqxK/!
!!!!!!!!!!!!!!!!!!!!!!!!!!!
!!!!!!!!!!!!!!!!!!!!!!!!!!!3HCOOH
!!!!!!B2O3 + 3Mg a dad2B + 3MgO a dad
P
.. P
..
uqbihiv!iQkqbqz<!ohe<sQe<!kbiiqk<kz<;!
33.uqbihiv!iQ P
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W/ 1470K P
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w w !!ohm<
!!
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Ovizqbk<jk!hqe<eg<gib<s<sq!ucg<Gl<!OhiK!
ww BBr !Nuq!+ H w
3 w
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2 ! ww

wwww wwww wwww !!!!!!!!!!!!!!!!! ww wwww!

gqjmg<Gl<!fih<kiju!nZlqeiUme<!%cb!hqtimcel<! <!
dbI!nPk<k!lqe<uqz
BCl !Nuq!+wHw !!!!!!gVjl!hcglx<x!Ohivie<
Dg<gqbqe<!lQK!osZk<kq!ohe<sQe<!ohxh<hMgqxK/!uqbihiv!
3 2
iQkqbqz<!:1% ohe<sQe<!ohm<Ovizqbk<kqzqVf<K!ohxh<hMgqxK/!
2
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)nz<zK*!
K*! 37 i)!! ytq! Oukquqje! H,\<b! uqje! ujgjbs<! siIf<kK!
K
ohIg<gqzq!.
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q!Ljx;! Woeeqz<! uqjebqe<! Ougl<! uqjehMl<! ohiVt<gtqe<!
e tet
ye<xqz<!lx<oxie<X!ohiVk<kh<hm<m!-V!Gpib<gt<!
dt<te/!dm<Gpibqe<!SuI!yV!%X!HguqMl<! e tet tet
osxqUgjt!siIf<kqVg<guqz<jz/!
e e tet
a ia.Ni.N
su<uqeiz<!NeK/! !
a ia.Ni.N a ia.Ni.NH2 (g) + Cl2(g)
hν
a i .Ni.N
2HCl(g)
a
s aslal s aslal
dm<Gpibqz<!gjvh<hiEl<?!dm<Gpib<g<Gl<!
outqg<Gpib<g<Gl<!-jmbqz<!gjvsZl<!dt<te/! ! s aslal s aslal
!!!!!!!!!!!!uqjeOugl<!= k[A]0
saa
a a a a a a ii) !uqjeujg!lx<
a a
uqjeujg!lx<Xl<!&zg<%X!w{<!WOkEl<!4OuXhiM;
4OuXhiM;!
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a
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outqg<Gpib<!Kh<hig<gq!dOzigk<kiz<!NeK/! !
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P
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w w w w
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Ofvcbig!ntuqmh<hMgqxK/!uqjvuieK/! !
e tet e tet e tet
.Ni.N
gjvszqe<!osxqU!liXukqz<jz/!
i
!
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outq! nPk<kk<kiz<! yV! %X! HguqMl<! su<U! Gjxf<k!
a a a a ai .Ni.N
a a ia.Ni.N
! s aslal
ntU!lQm<sqg<G!dm<hMk<kh<hMgqxK/!
s aslal
!
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a a a a a a a a a
P aPdad
47/!∆U
47/!
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lx<Xl<!∆Hg<
!!! = U + PV
P aPdad
g<G!dt<t!okimIH;!
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d )nz<zK*!
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dad
aqbz<
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w ..
w w ..
∆H = (H2 – H1) = (U2 – U1) + P(V2 – V1)
w ww.. w ..
gtqe<!sqxh<
w
Hgt<;
w ..
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!!!∆H = ∆U + P∆V 2
∆U = q – w (or) q - P∆V
0!∆U + P∆V = qp 3
sle<hiM!3!lx<Xl<!4!e<hc!
!!!∆H = qp!!!!!!!!!!!!!!!!!!!!!!5!
!!!lixi!ouh<hfqjzbqz<!fz<zqbz<H!uiBs<!sle<him<ce<hc!
!!!PVr = nr RT
lixi!nPk<kfqjzbqz<!fz<zqbz<H!uiBs<sle<him<ce<hc!
!!!PVp = np RT
!!!uqjehM!ohiVt<!okimg<g!fqjzbigUl<?!uqjtohiVt<!!
e tet
!!!-Xkq!fqjzbigUl<!wMk<Kg<!ogi{<miz<! e tet e tet e tet
a a.Ni.N
!!!P(Vp – Vr) = RT (np - nr)
i 5
a ia.Ni.N .Ni.N
ii) C H ai!!!hcuiqjs!OsIlr<
a gt<<;!Nz<a
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P∆V = !∆ngRT !!!
n 2n
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∆H = ∆U + P∆V
a
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a
6
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a s
gt<<;!Nz<
a s a saa
P aPdad
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