POTENCIALES ESTANDAR
DE REDUCCION*
Reaccién F (oltios) dE/aT (mv/k)
Aluminio
ABH Se" <= Alls) -1677 0.533
AICE+ 4 3e~ <= Al(s) + C1- =1,802
AIE3- + 3c = Al(s) + 6F~ 2,069
MOH); + 36 = Alls) +408" 2328 13
‘Antimonio
SbO* 42H + 3e- <= Shs) +0 0.208
Sb,0,(3) + 6H! +6e" = 28b(s) +3H,0 o4a7 0,369
Sb(s) +3H* +3e- = SbH,(g) =0,510 0,030
Arsénico
HAsO, +2H* +2e-<= H,As0, + H,0 0575
HAsO, + 3Ht 4 3e” = As(s) +311,0 02475
AS(s) +311" +3e> == ASHL(2) =0.238
Aautee
8,0} +2" = 280 201
$,07 + 4H" + 2c = 2H,50, ost
480, + 4H* + 6e~ <2 S,02-+2H,0 0539 =u
(Continia)
* Tada las especies son acuosas, so india To contario, El estado de referencia de las amalgams es una disolucin ifinitarente dui de elemento en He,
Fl coeficiente de temperatura, EU, nos permite calcular el potencialestndar, £7), a a temperatura T: ET) = E+ (AE%APYAT, donde AT es T~298,15 K.
Advetc que las unidades de JEMAT son mV/K. Si se eonoce E° dela reacién dela pila a la temperatura 7, se puede halla la constante de equilbvio, K de la
‘eacein uilizando Ia formula K'= 10°" 0, donde mes el nimero de electrones en cia una de is semireaciones, Fes la constant de Faraday y la cons-
tante de los gases
FLUENT: Lafuente mis sutorizada es G. ratsch, J. Phys. Chem. Ref Data 1989, 18, 1. Otos datos estén tomados de LG, Silen y A. E, Martell, Stability
Constants of Metal-lon Complexes (London: The Chemical Society, Special Publications Nos, 17y25, 1964 y 1971): G, Milazzoy S. Caroli ables of Standard
Electrode Poentals (New York: Wiley, 1978}; Mussni P. Long, y'. Rondinini, Pure Appl. com. 1988, 57,169. Ora buena fuente es A. J. Bard, R. Parsons
1yJ. Jordan, Standard Potentials in Aqueous Solution (New York: Marcel Dekker, 1985), Los potencies de reduccn de 1200 eacciones con radicales libres se
encuentran en P Wardman, J. Pi. Chem, Ref Data 1989, [8.1637
897 98
Reaccién
$0, 44H? + de" = S(s) +2H,0
2H,S0, + 2H* + 4e~ = S,07 +3110
S(s) +2H* + 20° = H,S(4)
S(s) + 2H? + 2e- = H,S(ae)
SO} + 2H + 2e- = 2HS,0;
58(s) +26" = 8?
2S(s)-+2e" <2 S}-
280} +3H,0+4e~ = $,03 + 60H-
SO} +3H,0 + 4e~ = S(s) + 60H-
SO} +411,0 + 6¢~ == S(s) + 80H
SO} +H,0+2e == SO} +20H
280} +2H,0+2e- == S,02 +40H-
280} +2104 2e-< S02 +40H-
Baro
Ba2* + 2e“+Hg = Ba(enHg)
Ba? + 2e~ = Ba(s)
Berio
Be + 2c = Bo(s)
Bismato
Bi3+ + 3e~ = Bis)
BICI; +3" = Bi(s) +4Ct
BiOCK(s) + 2H" + 3e~ <= Bi(s) +H,0 + CI
Boro
2B(s) + 6H* + 66 <2 Bylig(x)
BO} + 14H* + 12e- = 4B(s) +7H,0
B(OH), + 3H* +e” = Bls) +310
Bromo
BrOj +2H* + 2e~ <= BrOs +H,0
HoBr+H* +e = !br,(i)+4,0
Br05 + 6H + Seer 1Br,(1)+ 31,0
Br,(ac) + 2e- <= 2Br-
Br(l) +2e- == 3Br-
Bry +20 <2 3B
BrO- + H,0 + 2¢~ => Br-+ 20>
BrO; +3H,0 + 6e° = Br +60H
Cadmio
Cd? 4 2e- + He == Cen He)
Cd?* + 20> = Cds)
CA(C,O,)(5) + 2e- = Cals) + C05
CA(C,0,)3 + 2e° = Cals) +2€,0,
CA(NH,)}* 4 2e° = Cas) +4NH.
CAS(s) + 2e~ == Cd(s) + S*
F (voltios)
0450
00
0,174
oa
= 1,968
0,308
016
0,160
=0,150
~0.792
0.889
1.745;
584
1,513
1,098
L078
1,062
0.766
0.613
0,380
0402
0522
0572
0613
4175
Apendice Hm Potenciales estandar de reduecion
dE°/AT (mV/K)
0,652
0224
021
-116
1,06
-123
=1,288
“141
085
1,00
0.401
0,60
018
-0,296
~0,492
ost
0.75
0.419
0.499
-o611
0512
0,029
(Comtinia) Apéindice Hm Potenciales estindar de reduccién
Reacé
Calcio
Ca(s)-+2H* 4 2e” = Cals)
Ca? + 20° +He = Caten He)
Ca®* + 2¢° = Cals)
‘Calacetato)* + 2e” <= Cas) + acetato
Ca$O4(s) + 26 = Cats) + S0}-
Ca{malonato)(s) + 26 == Ca(s) + malonato?-
Carbone
Cylly(g) + 2H? +20 == Cyt Cg)
CH,OH + 2H? +2e~== CHy(g)+H,0
ficido deshidroascérbico + 2H* + 2e-<= dcido ascorbico + H,0
(CN)g(g) + 2H" + 20° = 2HCN (ae)
H,C0 4211" +2e- = CH,OH
C(s) +4Ht+4e- = CHG)
HCO,H +2H*+2e- <= H,CO+H,0
C0,(9)+2Ht + 2" = CO(g) + HO
CO,(g) + 2H" + 2e-== HCO,H
2CO,(g) +2H* + 2e" = H,C,0,
Cerio
Cet +e Cel
Cel Fe = Cals)
Cesio
Cst her + Hg = Cslen He)
Cot +e = Ca(s)
ine
ZnOH" + H* + 2e~ = Zn(s) +2H,0
Zn2* +26 <= Zn(s)
Zn? +2e°+Hg = Zn(en He)
Z(NH)2* + 2e- = Zn(s)+4NH
ZCO4(s) + 2e- = Za(s) + COR
Zn(0H); + 26° = Zn(s) + 30H
Zn(OH)} + 26° = Za(s) + 40H
Za(Ol1)9(s) + 2e- = Za(s) + 20H
Z0(s) + H,0 + 2¢- = Zn(s) +20H-
ZnS(s) + 20- = Zn(s) +S
Cireonio
Ze! + dem = Zils)
ZxO,(s) + 4H" + 4e- => Zn(s) +2H,0
0,700
0,583
0,390
0373
0.1315
0,029
0,103 8
0.432
12
170 HCIO,1F
144 HS0,1F
161 HNO 1F
147 HOHE
2336
1,950
dE-/dT (mV /K)
0,186
0,280:
172
0,03
0,119
0,999)
=1,160
0.67
~0,344
(Continia) Reaccién
Clore
HCIO, +28" + 26> = HOCI + HO
HCIO+ HY +e" = 4C1,(g) +H,0
105 + 6H? + Se~ = IC1,(—) +311,0
Ci,(ac)+2e" = 2C1
Chy(g) +2e- <= 2Cr
GIO; + 2H + 2e-< C10; +1140
C105 + 34+ 2e~ <= HCIO, + 11,0
C103 + 2H" + = C10, +11,0
C10; + = C103
Cobalto
Co +e Co?
Co(NH,),(H,0)3* + e- = Co(NH,),(H,0)?*
Co(NH)}* + e- = Co(NHy)2*
CoOH* + HY 4+2e- <= Co(s) + H,0
Co? + 2e- = Cols)
Co(OH),(s) + 20° <= Co(s) + 20H
Cobre
Cut +e" = Cals)
Cu2*+ 20° = Culs)
Cutt +e" = Cut
Cucl(s) +e = Cals) + C-
Cu(1O4),(9) + 26° = Cu(s) + 2105
Cu(etilendiamina)3 + e~ = Cu(s) + 2etilendiamina
Cul(s) +e° = Cuts) +P
Cu(EDTA)?> + 2e- = Cu(s) + EDTA
Cu(OH),(s) + 2e° = Cus) + 20H
Cu(CN)5 +e = Cu(s) +2CN~
CuCN(s) +e = Cu(s) + CN~
Cromo
(r,0} + 14H* + Ge" = 2Cr* +7H,0
CxO} +4H,0+ 3e- = COH),(s, hidratado) + SOH
CH +e Crt
Cr+ + 3e> Crs),
Cr?+ 4 20> =e Crs)
Disprosio
Dy3* + 3e- = Dy(s)
Eibio
Eri+ + 3e” = Er(s)
Escandio
Sc* + 3e> = Sc(s)
Estato
‘Sn(OHY} + 3H* + 2e~ = Sn?* + 6H,0
‘Sott + 2e> == Sn?*
E (voltios)
1.674
1,630
1438
1,396
1,3604
1.226
1157
130
1,068;
1.92
1817
1.850
0.37
ou
0,003
0,282
0.746
018
0.339
0.161
0.137
0,079
0,119
0,185
0.216
0429
01639
1,36
0,12
0.42
0.78
089
2,295
2331
2:09
142
04139
Apendice Hm Potenciales estindar de reduccién
dE*/dT (mV /k)
055
027
0.347
180, 3F
HNO) 4F
NHNO.1F
0.04
0,065
-102
0,754
ott
0776
0373
0,388
oat
HCILF
(Continia) Apéndice Hm Potenciales estindar de reduecién
Reaccién
Sn03(s) +481 +2e- <= Sn®* +2110
Sn2*+ 2" <2 Sats)
SaF3-+de~ = Sn(s) + 6F
Sn(OH)?- + 2e~ => Sn(OH); + 30H-
Sn(s)-+4H,0 + 4e = Snll,(g) +401
$103(s) +1130 + 26° <= SnO(s) + 20H
Sr + 2e- = Sr(s)
Europio
Bust 4 e~ <= Bu?
Eu + 3e~ = Eu(s)
Bu?* + 2c" == Eu(s)
Flor
Fy(g) +26" = 2F-
F,0(g) 42H" +46 <= 2F- + H,0
Pésforo
4p,(s, blanco) +3Ht + 3e°-< PH,(2)
}P4(s, t0)0) + 3H! + 3e-=> PH,(g)
HPO, +2H?+2e~ == H,PO, + H,0
HPO, +5H*+5e-<= 1Py(s, blanco) + 4H,0
HPO, +2H*+2e- <= H,PO) +H,0
HPO) + H* +e" = 1P,(s)+2H,0
Gadotinio
Gu + 3e- = Gus)
Galio
Gal" +32" <= Gals)
GaQOH(s) + 3H,0 + 3e~< Gals) + OH
Germanio
Get + 26° = Ge(s)
H,GeO, + 4H" + 4e- = Ge(s) + 4H,0
Hatnio
Hf +4e" = HI(s)
Hf03(s) + 4H* +4e> = HE(s) +2H,0
Hidrégen0
2H +20 <= H,(e)
1,0 +e-= $H,(g) ++ OH>
Hierro
Fe(fenanttolina)?* + ¢~ <= Fe(fenantrolina)3*
Fe(bipiidilo)}* +¢- = Fe(biptiilo)3*
FoOH?*+ + H*4+6~ = Fe’ +H,0
F (voltios)
0,094
=0,141
0.25
093
-1316
0,961
2,889
025
=1,991
-2,812
2,890,
2,168
0,016
0,088
~0530
0.402
0.48
-051
2219
0,549
=1,320
OL
~0,039
~155
=1,591
0,000
08280
1,147
1,120
0,900
901
dé*/aT (on /X)
031
0.2
=1,057
=1,129
0,237
13
0.338
026
=1,870
=1,208
oats
061
=1,08
0,429
0.68
-0,355
0
-0.8360
0,096
(Continia} Reaccién
FeO} +3H,0 + 3" <= FeOOH(s) + 50H
Fe 4 es Bett
FeQOH(s) + 3H? +e>< Fe2* +2H,0
ferricinio* +e = ferroceno
Fe(Cn)g +e = Fe(CN)
Fe( lutamato)3* +e = Fe( ghitamato)?*
FeOH" +H" +26 = Fe(s) +H,0
Felt 4 20 <2 Fe(s)
FeCO4(s) +2e° = Fe(s) + COP
Holmio
Ho +3e" = Hols)
Indio
In +3e-+He
In¥¥+3e~ = In(s)
In 42" = Int
In(OH),(5) + 3e- = In(s) + 30H-
In(en He)
Iii
hee +e = Clg
UBre +e SUB
WCIz-+4e = Irs) + 6C-
IrO,(s) +41" + 4e~ = In(s) +2130
Wig te =n
Lantano
La + 3e- = Las)
1La(suecinato)* + 3e~ = La(s) + succinato?
Litio
Lit +e" + Hg = Li(en Hg)
Lit +e-= Lils)
Lutecio
Lu + 3e° = Luts)
Magnesio
Mg?* +2e~+Hg <= Ma(en Hg)
Mg(OH)* +11" + 2e- = Mg(s) +110
Mg2* + 2e~ == Mg(s)
Mg(C,0,)(s) + 26° Mats) +€,07-
Mg(OH),(s) + 2e” = Mg(s)+20H.
Manganeso
MnO; +4H* + 3e~= MnO,(s) + 2H,0
Mn3¥4+ > == Mn2*
‘MnO; + 8H" +5e~ = Mn?*+4H,0
Apéndice Hm Potencialesestindar de reduccién
E (voltios) dE*/dT (an /K)
080 -159
-0.16 1175
0.44
0.756
077
0.732 HOME =1,05
0.767 HCIO, 1F
0.746 HNO, 1F
074
0.400 oor
0.356 07
0.240
2.33 0371
0313
0,338 042
0.444
099 095
1.026 HCLLF
0947 NaBr2F
0835
073 -036
0485 KU
0.242.
0514
228 ola
=1980
2,022 025
0,199
2493,
2,690) 0.946
1.692 -o671
1536 18
1,507 0.646
(Continia) Apendice Hm Potencialesestindar de reduccién
Reaccién
Mn, 0,(s) + 6H* + 2e~ == 2Mn?* + 31,0
MaQ,(s) + 4H? 4 2e- == Mn?*42H,0
‘Ma(EDTA) +e = Mn(EDTA)*
Mn0j-+e" = MnO}
3Mn;0,(3) + HO + 2c <= 2Mn,0,(s) + 20H
MnO, (s) + 4H,0 + 2- = 3Mn(OH),(s) +201
Mn? 2e~ == Mn(s)
Mn(OH)3(3) + 26-=* Mn(s) + 20H-
Mercurio
2g? 420° = He}
Hy?" 4 2e- = He(l)
He}? + 26° = 2Ha(d)
Hg,80,(s) ¢2e" = 2He(t) +807
Hg,Cl,(s) +2" = 2Hg(1) + 2C1
Hg(OH); + 2e- == Hg(!) +30H-
Hy(OH), + 2e~= H(i) + 20H-
Hg,Br,(s) +2c° = 2Hg(1) + 2B
Hg0(s, amarillo) + H,0+2e~ == He(0) + 20H
Hg0(., rojo) + H,0 + 2e-=* H(i) + 20H
Molibdeno
MoO}- + 2H,0 + 2e~ = MoO,(s) +40H-
MoO}- + 41,0 + 6e~ <= Mo(s) + 80H
MoO)(s) + 2H,0 + 4e~ == Mo(s) + 40H
Neodinio
Nd*++ 30 = Na(s)
Neptunio
NpOf +2H* +e <= NpO# +H,0
NpO3* +e" == NpO}
NpO} 44H? + e--<= Np!*42H,0
Npt +e <= Np!
Np + 3e~ <= No(s)
Niobio
ANb,04(s) + H® +e = NbO,(s) + H,0
INpjO4(s) + 5H +e" =Nb(s) + 3H,0
No0,() + 2H*-+ 26° = NbO(s) + H,0
NOO3(s) + 4H 4 4e~ = No(s) +2H,0
Nitrégeno
HIN, + 3Ht 4-20" = No(g)+NHZ
N,O(g) +2H* + 20° = No(e)+H,0
2NO(4) + 2H* + 22° == N,O(g)+H,0
NO* +e" == NO(s)
INH, OH* 4 Ht 4 26” = N,HE + 2,0
903
F (oltios) dE JAT (nV /K)
1485 0926
1,230 =0,609
0.825 =1.10
0.56 -2,05
0,002 “1,256
0,352 61
1182 1,129
=1,565 =1,10
0.908 0,095
0,852 0.116
0.796
ota
0.268
0.241 (electrode de calomelanos saturado)
0231
0.206 -124
0.140
0.0983 =1,125
0.0977 =1,1206
0818 -169
-0.926 =1,36
~0,980 = 1196
=2,323 0282
2,04
1.236 0,058
0.567 3.30
0.157 153
~1,768 O18
=0.248 ~0.460
0,601 -0,381
=0,646 -0347
=0.650 ~0,361
2,079 047
1.769 -0,461
1587 =1,359
146
1.40 00
(Comtinia) Reaccidn
NH,OH? + 211" + 2e- = NH; +H,0
Nyllg + 3H 4 2e~<= 2NHf
HNO, +H? +e-= NO(s)+H,0
NO5 + 4H* +30 <= NO(g) +2H,0
NO3 + 3H* +2 = HNO, +H,0
NOj+2H*+e-= 1N,0,(¢)+H,0
g(a) + 8H¥ + 66~ <= INH}
Nj(g) 45H*44e- == NGHE
N,(4) +2H,0 +411" +26 * 2NH,OH*
IN, (g) +H re HIN,
Niguel
NiOOH(s) +3H* +e- = Ni2++2H,0
Nit* +e = Nils)
Ni(CN)} + 6° =* N(CN)}-+CN-
Ni(OH),(s) + 2e-= Ni(s) + 20H-
O10.
Aut :e-= Au(s)
Audt 4 2e~ = Aut
AuCls +e" = Au(s) +2Cl-
AuCl; +22" = AuCl; + 2C1
Osmio
Os0,(s) + 8H*4 Be~ = Os(s) +4H,0
OsCIf + €° = OSC
Oxigeno
OH+Ht +e = H,0
O(g)+2H* +2 <= HO
4(g)-+2H* + 2e° = On(¢) +210
10,421" + 26-2 21,0
HO, +Ht +e" = HO.
40,(@) +2H* +2e° = H,0
0,(g) +2H*+2e° = H,0)
0;(g) +H +e" <= HO,
Paladio
Put + 2e- <= PAs)
PdO(s) +2Ht +26 <* Puls) +H,0
PACs + 26° = Pals) + 6CI-
PO, (s)-+H0+ 26° = PuO(s) + 20K
Plata
Aah se-= Agt
Aght4 20° = Agt
AgO(s)+H* +e == $Ag,0(s) + HH
Apéndice H a Potenciales estindar de reduccién
E (voltios) ‘dE*/dT (mV/K)
133 “od
1250 028
0984 0519
0955 002s
0282
107
-0816
“078
-09%
-241
2,015 =117
0236 ots
-oa0t
“0.4 =102
169 “I
a1
Lisa
006
os -0458
085 HCL
256 -10
2.4301 =11484
2015 -0,489
1,763 -0,698
en “07
1.2291 -08456
069s -0993
0s au
os oz
019 -033
ois
064 12
HCIO.4F
0.99
HNO,4F
(Continia) Apéndice Hm Potencialesestindar de reduccién 905
Reaccion eS F (oltios) dE [dT (on)
Agt te = Agls) 0.7993 ate
Ag,C,04(s) + 2e" = 2Ag(s) +C,03 0.465
ABN (8) +e-= Avis) + Ny 0,293,
a = 0222
OR ES 0,197 KCI saturada
AgBr(s) +e> <= Ag(s) + Br 0.071
Ag(S;03)} + = Ag(s) +28,07 0017
Aal(s) +e = Ag(s) +E
‘AgyS(s) +H? + 2e- <= 2Ag(s) + SH 0.27
Plating =0,05
Pitt + 2e-< Pi(s) 118 0.36
PXO,(s) +4H* + de = PU(s) +H,0. 92
PCIE + 2e~ = PU) +4C- 0755
Piz +2e° = PCH} + 2c 0.68
Plomo
Pht +2e- <= Pb? HNO,1F
PbO3(s) + 4H" + S03 + 2c" = POSO4(s) +2H,0
PhO,(s) +41" +2e- <= PD?" + 21,0
3POO,(s) + 21,0 + 4e~ == Pb,O,(s) + 40H"
Pb,0,(s) + HO + 2e- = 3Pb0(s, rojo) + 20H
Ph,O,(s) + H,0 + 2c = 3PbO{s, amarillo) + 20H-
Phe + 2e- = Pb(s)
PbF3(s) + 2e- = Ph(s) + 2F-
PHSO, (x) + 2e- = Ph(s) + $0}
Plutonio
PuO} +e" = PUuO,(3) 039
PuO}* + 4H + 20-=> Putt + 24,0 16151
Putt ee~ = Put La
PuO}t + e~ = PuOS 0.03
PuO,(s) +4H* +4e-<* Pu(s) +20 0,38
Put + 3e- <= Pu(s) 0.23
Potasio
K+ ses He<* K(en He)
Kt ee-+He = Kis) =1074
Prascadimio
Prttee- Pit 32 1
Prt + 3e- = Pris) 2,353 0,291
Promec
Pmi++3e" = Pm(s) 0.29
Radio
Ra? +2e- = Ra(s) 2,80 044
(Continia) 906
Reaccién E (voltios)
Renio
ReOj + 2H? +e" <= ReOs(s)+ 1,0 on
ReOj + 4H* + 3e° = ReO,{s}+2H,0 0510
Rodio
Rh& + 3e> <= Rh?+
Rh** +e == Rh?*
RHI +e" = RHI 12
Rh* + 3e> = Rh(s), 0,76,
2Rh+ + 2e~ => Rhj* 07
RhCI}> + 3e~ = RACs) +6CI- oa
Rubio
Rbv+e"+He= Rb(en Hg) -1970
Rb* +e" <= Rb(S) 2943
Rutenio
uO; +6H* 4 3e-= Ru(OH)3* + 2H,0 153
Rucdipridilo)3+ + e- = Ruipiidlo)?* 129
RuO,(s)+8HT* + 8e~ = Ru(s) +4H,0 1032
Ru? +2e~ <= Ru(s) 08
Rutt + 3e~ = Ru(s) 0,60
Rud ber == Rut 024
Ru(NH,)$* + e- == Ru(NH,)3* o2i4
Samario
‘Sm3* + 3e~ = Sm(s) 2,304
Sm? + 2e~ = Sm(s) 2,68
Selenio
ScO}- + 411 + 2e- = H,Se0, + H,0
H,Se0, + 4H? + 4e~ = Se(s) + 3H,0
Se(s) + 2H* + 2e~ == H,Se(e)
Se(s) + 2e" == Se
Silicio
Si(s) + 4H? +4e" = SiHl,(2)
$i0,(s, cuarz0) +411" + 4e~ =Si(s) + HO
SiE}- + 4e~ =Si(s) + 6F-
Sodio
Nat +e-+Hg = Na(en He)
Nat +SHig(@) +¢°= Nai(s)
Nat te-= Na(s)
Talio
1,280
077
Ti + 2e-== THY 122
123
126
148 HCIO,1F
144 H,S0,3F
Apsinice H Wm Potenciales estindar de veduccion
dE*/dT (mV /K)
117
=0,70
oa
1140
~0,467
279
028
0483
0,562
0.238
=ia
0,196
0,374
=1550
0,757
097
(Continia) Apéndice H m Potenciales estindar de reduccién
Tit +e+He = Tien He)
Tite = TK)
TICI(s) +e = THs) + CI
Téaalo
Ta,0s(s) + 10H* + 100 == 2Ta(s) + 5H,0
Teenecio
Te; +2H,0+3e" = TeO,(s) + 40H
TeO; +4H,0+7e~ = To(s) + 80H”
Teluro
TeO}- +3H,0+4e~ = Te(s) + 60H
2Me(s) +20 = Te}
To(s) +22 <= Te?
Terbio
TH be = TH
Tot 4 Je = TH(s)
Titanio
TiO* +211" +e-= Ti+ +H,0
Totter ee TH
T1O,(s) +4H* + de Ti(s) +21,
TIFF + 4e- = Tis) + 6F-
Ti? + 2e-= Tis)
Torio
Tht + de~ = This)
Taio
Tm't+3e" = Tim(s)
Uranio
UO}-+4H" +e UY +2H,0
03" + 4H + 26-<= U4 +2H,0
VO} +e = UOt
Ut eee Ue
US+430-= Us)
Vanadio
VOs+2H? +e = VO2+H,0
VO! +2H* +e == VIt+H,0
V8t pee V2"
Vit4 20" = V3)
Woltramio
WCN)P +e" = WN)
Wor pers Wit
WO,(s) + 6H + 6e- = W(s)+3H,0.
WSt ee Wit
F (voltios)
0,294
0,336
0557
2319
039
0273
0416
~0577
1,642
1,001
0,337
255
=1,125
0457
026
=0,091
-03
HCLIQF
HLF
dE /dT (env /k)
1312
0377
182
146
139
15
0350
06
15
0,365
0,16
0557
0,394
3
=1582
02
Lol
02
~0,901
-16
1s
=O,L1
=0389
(Continia) Reaccién
WO,(s)+2H,0+ 4e- = W(s) + 40H-
WO? (s) + 41,0 + 6e- = Wis) + 80H
Xenén
H,Xe0, + 2H? + 2c” <= XeO, +3H,0
XeP, +2H* + 2e" = Xe(g) + 2HF
XeO, +6H* + 6e~ = Xe(g) +3H,0
Yodo
10j + 2H* +2e" = 105 +H,0
H1O, +2H* +2e- = HIO, +3H,0
HOL+H* +e = 41,(3) + H,0
ICly(s) + 3e- = f(s) + 3C-
ICls) +e = Hy{s) + Cr
105+ 6H? + Se == $Iy(s) +310
10+ SH? + de~ == HOL+2H,0
Iy(ac) + 22" = 2I-
165) +26 = 2
Iy+2e 30
10, + 3H,0 + 6e- = I-+ 60H"
Yeerbio
Yb! +3e" <= Yb(s)
Yb +2e" = YO(s)
Yerio
Yr 43e° = Y(s)
F (voltios)
0982
1,060
238
22
21
1.589
1,567
1,430
1.28
122
1.210
List
0,620
0535
0535
0.269
219
2.76
-2:38
Apéndice Hm Potenciales estindar de reduccién
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